With regard to the sealing structure characteristics of the underwater clamp connector, based on the Hertz contact theory, this article studies the method of solving the extreme value of the radius of curvature on the two curved surfaces at the sealing contact point; first, the method of calculating the extreme value of the radius of curvature at any surface point of the rotary part is obtained, and then the equivalent radius of curvature is solved. Using finite element simulation to study the contact sealing characteristics without considering the edge thickness and width of the sealing gasket, it is verified that the Hertz contact theory is applicable to the metal contact theory of underwater clamp connectors. Then, the sealing simulation with the influence of the detailed dimensions of the sealing gasket is compared with the theoretical result of the direct application of the Hertz contact theory in the underwater clamp connector contact, and the theoretical correction coefficient of metal contact seal for underwater clamp connectors is introduced to solve the errors. The pressure sealing experiment is carried out on six-inch flange and metal sealing gasket, which proves that the coefficient can greatly enhance the theoretical calculation accuracy of the contact sealing of the underwater clamp connector.