The rapid development of basin resource-based cities (BRCs) in developing countries have led to severe resource and environmental problems centered on the “water-energy-carbon” (WEC) nexus. Based on their spatiotemporal evolution, WEC constraints are evaluated via a multidimensional coupling coordination degree (CCD) mode. Resource-environmental efficiency (REE) under these constraints is measured via the superefficiency SBM model. The path of resource and environmental improvement via new urbanization (NU) is discussed based on the spatial econometric model. Water resource consumption in the BRCs decreased by 12.22 %, but energy consumption and carbon emissions increased by 20.1 % and 70.05 %, respectively, and the CCD of the WEC nexus showed a “highly coordinated - seriously imbalanced” change. Therefore, the REE increase of 44.03 % was unsustainable. NU improved REE and reduced water resource consumption but did not reduce energy consumption or carbon emission, and there is significant regional variability. Scientific and technological innovation, economic agglomeration and land structure diversity contributed to the resource-environmental improvement effects of NU, but optimized industrial structures and environmental governance had masking effects. The policy implication is that during NU, efficiency gains must be combined with policies to promote industrial structure optimization and environmental governance and thus achieve sustainable urban development.