Renewable energy based multigeneration systems help satisfy the diverse demand for marine resources exploration in off-grid island area, where the storage of fluctuating renewable energy for continuous power supply becomes necessary. Therefore, this paper proposes a solar-driven multigeneration system for island environment integrated with energy storage and production of electricity, cooling, heating, and freshwater. The system comprises an ejector power subsystem, a multiple-effect distillation subsystem, and a CO2 binary mixture-based compressed gas energy storage subsystem. The system performance from the perspectives of energy, exergy, economics, and environment, as well as the impact on performance of the working fluid and several key system parameters, are investigated in this paper. According to the results, an increase in the mass fraction of organic in the CO2 mixture leads to an improvement in system energy efficiency and exergy density at the cost of lower system power efficiency. Increasing the high-pressure tank pressure enhances system performance except for system power efficiency. Increased low-pressure tank pressure leads to improved system energy efficiency and exergy density, accompanied by lower system power efficiency and exergy efficiency. When the ambient temperature increases from 298 K to 303 K, the system energy efficiency noticeably decreases, whereas an increase in direct normal irradiance improves various system performance indicators. Among several mixtures, CO2/R32 mixture was chosen for further analysis and optimization for its wider operating range with R32 mass fraction and better system performance. The optimal operating point had system energy efficiency, exergy density, and modified levelized cost of energy of 1.281, 22.216 kWh/m3, and 0.131 $/kWh, respectively. The proposed system in this research is proven to be a novel technical solution to meet the diverse energy demands on unique island environments.
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