Melting Of Eclogite Research Articles

東南極，日の出岬の藍晶石を含むトーナライト：特に，石灰珪質岩塊近傍に産出するものについて

The Cape Hinode area in East Antarctica exposes Mid-Proterozoic tonalites, which are similar in chemical composition to high-SiO2 adakites and Archean tonalite-trondhjemite-granodiorite. They contain enclaves of ultrabasic-intermediate and calc-silicate metamorphic rocks of various dimensions, as well as xenocrystic garnet and kyanite. Pinite and carbonate minerals surrounding kyanite inclusions in plagioclase are alteration products after coronas of anorthite and spinel with or without corundum, alkali feldspar, rutile and magnetite. Further observations reveal that thin tonalitic veins cutting calc-silicate enclaves carry kyanite fringed by similar anorthite coronas. Such kyanite sometimes encloses quartz inclusions. The thin tonalitic veins are characterized by the occurrence of dark green clinopyroxene as the main mafic mineral, low aluminum saturation index (0.75) in spite of the occurrence of kyanite, and a non-adakitic geochemistry. The calc-silicate enclaves in tonalites are composed mainly of calcic plagioclase, Ca-garnet and/or clinopyroxene. The symplectitic intergrowth of anorthite and Ca-garnet is chemically close to epidote, and may be produced by successive melt-involving and epidote-consuming reactions. These chemical and textural features of kyanite and other minerals occurring in and around kyanite, thin tonalitic veins, calc-silicate enclaves, and tonalites indicate the significance of metamorphic and magmatic epidotes during partial melting of eclogites of young and hot slab origin.

Partitioning of trace elements between Na-bearing majoritic garnet and melt at 8.5 GPa and 1500–1900 °C

New experimental data on trace element partitioning between Na-bearing majoritic garnet and melt at P=8.5GPa and T=1500–1900°C applicable to partial melting of Na-rich eclogite are presented. We have found that Na-bearing garnet is a liquidus phase of the system at 1850–1650°C being accompanied by enstatitic pyroxene at lower temperatures. With decreasing temperature, Na concentration in garnet increases up to >1wt.% Na2O due to progressive incorporation of a Na majorite component (Na2MgSi5O12). Most of the studied trace elements are incompatible, except for Er, Tm, Yb (in some runs), Lu, and Sc (in all runs), which are distributed into garnet. The main characteristic of the trace-element partitioning in our experiments is a different behaviour of the LREE (La, Ce, Pr) in comparison with MREE and HREE (Nd, Sm, Eu, Gd, Tb, Dy, Y, Ho, Er, Tm, Yb, and Lu). In particular, a significant increase of D values for LREE with the increase of Na2O concentration in garnet is observed. As predicted from lattice strain, partitioning coefficients for REEs entering the X site of garnet exhibit a near-parabolic dependence on ionic radius. The results of the study are applied to the formation of inclusions of Na-bearing majoritic garnets in diamonds, and equilibrium melts significantly enriched in LREEs.

Melt–peridotite reactions in upwelling eclogite bodies: Constraints from EM1-type alkaline basalts in Payenia, Argentina

The processes of magma generation in upwelling eclogite bodies of recycled lithospheric material are not fully understood but are important for our understanding and modelling of major and trace element variations in many ocean island basalts (OIB). The primitive alkaline intraplate basalts from the Payenia volcanic province (34–38 °S) in Argentina, for which Sr, Nd and double-spike Pb isotope ratios are presented, and from other north Patagonian volcanic fields may provide details of the eclogite melt–peridotite reactions taking place in the melting column of an upwelling OIB-type mantle. The isotopic composition of the uncontaminated lavas is highly restricted but the Payenia basalts fall in two distinct trace element groups termed the high and low Nb/U groups, which both have EM1-type trace element patterns but with subtle differences that cannot be explained by contamination, fractionation or simple variations in degrees of mantle melting. The difference is also clear in major elements where the low Nb/U basalts have markedly higher alkali contents but lower FeO and Ni than the high Nb/U basalts. Four melt components have been identified based on olivine fractionation corrected compositions: a low Nb/U pyroxenite melt component which is interpreted as an eclogite melt that experienced low degrees of melt–peridotite interaction, a high Nb/U pyroxenite melt component which is interpreted as an eclogite melt that experienced high degrees of melt–peridotite interaction, a low pressure peridotite melt component which contributes to most high Nb/U, Payún Matrú, Matancilla and Auca Mahuida basalts and finally, a melt component with similarities to peridotite melts contributing to many low Nb/U lavas. The high Nb/U type basalts are interpreted to have been formed from mantle with higher temperature than ambient mantle while the low Nb/U basalts may have been formed from normal temperature mantle.

Origin of eclogite and pyroxenite xenoliths from the Victor kimberlite, Canada, and implications for Superior craton formation

A suite of 30 eclogite and pyroxenite xenoliths recovered from the Jurassic Victor kimberlite in the western Superior Province are investigated to determine their formation and emplacement in the sub-continental lithospheric mantle (SCLM). The samples have a wide compositional range, including low-Mg and high-Mg varieties. The low-Mg eclogites have a shallow origin as plagioclase-bearing protoliths that were subsequently subducted and emplaced into the SCLM. This is supported by their generally flat MREE to HREE compositions, the presence of kyanite and a positive Eu anomaly in the kyanite-bearing sample, as well as δ18O in three low-Mg eclogites that are higher than the pristine mantle value. LREE depletion in the low-Mg eclogites, along with unradiogenic 87Sr/86Sr indicate that they were not affected by widespread metasomatism after emplacement in the SCLM. The high-Mg eclogites and pyroxenites have compositional characteristics that require a distinct origin to the low-Mg eclogites. Their bulk compositions, LREEN-enriched trace element patterns and in particular, occurrence of unradiogenic 187Os/188Os in pyroxenite, is consistent with formation by reaction of broadly siliceous melts (generated from the melting of low-Mg eclogites) with depleted peridotite. A subduction origin of the eclogites studied here is consistent with seismic and field-based studies that have reported terrane accretion by successive subduction of the west–east orientated terranes in the western Superior Province. Although the timing of eclogite and pyroxenite formation could not be constrained, radiogenic 187Os/188Os require long-term isolation from the convecting mantle and supports a Neorchaean age for their formation.

Reactive Infiltration of MORB-Eclogite-Derived Carbonated Silicate Melt into Fertile Peridotite at 3 GPa and Genesis of Alkalic Magmas

We performed experiments between two different carbonated eclogite-derived melts and lherzolite at 1375°C and 3 GPa by varying the reacting melt fraction from 8 to 50 wt %. The two starting melt compositions were (1) alkalic basalt with 11·7 wt % dissolved CO2 (ABC), (2) basaltic andesite with 2·6 wt % dissolved CO2 (BAC). The starting melts were mixed homogeneously with peridotite to simulate porous reactive infiltration of melt in the Earth’s mantle. All the experiments produced an assemblage of melt + orthopyroxene + clinopyroxene + garnet ± olivine; olivine was absent for a reacting melt fraction of 50 wt % for ABC and 40 wt % for BAC. Basanitic ABC evolved to melilitites (on a CO2-free basis, SiO2 ∼27–39 wt %, TiO2 ∼2·8–6·3 wt %, Al2O3 ∼4·1–9·1 wt %, FeO* ∼11–16 wt %, MgO ∼17–21 wt %, CaO ∼13–21 wt %, Na2O ∼4–7 wt %, CO2 ∼10–25 wt %) upon melt–rock reaction and the degree of alkalinity of the reacted melts is positively correlated with melt–rock ratio. On the other hand, reacted melts derived from BAC (on a CO2-free basis SiO2 ∼42–53 wt %, TiO2 ∼6·4–8·7 wt %, Al2O3 ∼10·5–12·3 wt %, FeO* ∼6·5–10·5 wt %, MgO ∼7·9–15·4 wt %, CaO ∼7·3–10·3 wt %, Na2O ∼3·4–4 wt %, CO2 ∼6·2–11·7 wt %) increase in alkalinity with decreasing melt–rock ratio. We demonstrate that owing to the presence of only 0·65 wt % of CO2 in the bulk melt–rock mixture (corresponding to 25 wt % BAC + lherzolite mixture), nephelinitic-basanite melts can be generated by partial reactive crystallization of basaltic andesite as opposed to basanites produced in volatile-free conditions. Post 20% olivine fractionation, the reacted melts derived from ABC at low to intermediate melt–rock ratios match with 20–40% of the population of natural nephelinites and melilitites in terms of SiO2 and CaO/Al2O3, 60–80% in terms of TiO2, Al2O3 and FeO, and <20% in terms of CaO and Na2O. The reacted melts from BAC, at intermediate melt–rock ratios, are excellent matches for some of the Mg-rich (MgO >15 wt %) natural nephelinites in terms of SiO2, Al2O3, FeO*, CaO, Na2O and CaO/Al2O3. Not only can these reacted melts erupt by themselves, they can also act as metasomatizing agents in the Earth’s mantle. Our study suggests that a combination of subducted, silica-saturated crust–peridotite interaction and the presence of CO2 in the mantle source region are sufficient to produce a large range of primitive alkalic basalts. Also, mantle potential temperatures of 1330–1350°C appear sufficient to produce high-MgO, primitive basanite–nephelinite if carbonated eclogite melt and peridotite interaction is taken into account.

Dehydration melting of UHP eclogite and paragneiss in the Dabie orogen: Evidence from laboratory experiment to natural observation

Dehydration melting of subducted continental crust is significant during exhumation, and its study from both experimental and petrological observations is of great importance to our understanding of continental geodynamics. Dehydration melting experiments were carried out on ultrahigh-pressure (UHP) eclogite from Bixiling in the Dabie orogen using a piston cylinder at 1.5–3.0 GPa and 800–950°C to investigate partial melting of eclogite induced by phengite breakdown. The phengite-bearing eclogite started to melt at T⩽800–850°C and P=1.5–2.0 GPa and produced about 3% granitic melt. The products of dehydration melting vary with temperature and pressure. Such results provide valuable constraints on the micro-texture related to partial melting of UHP rocks in the Dabie-Sulu orogenic belt. Three types of polyphase inclusions were identified in garnet from the Shuanghe UHP eclogite. K-feldspar and quartz inclusions are interpreted to represent the products of segregation and crystallization of minor amounts of melt that formed during dehydration melting of phengite by the inferred reaction Phengite+Omphacite±Quartz→Amphibole±Garnet+Melt (K-feldspar+Quartz±Plagioclase). Polyphase inclusions of phengite and K-feldspar+Quartz inclusions were also found in zoisite/clinozoisite and garnet from the Shuanghe garnet-bearing paragneiss. These polyphase inclusions provide evidence for a continuous process from sub-solidus dehydration to partial melting within the UHP gneissic rocks. The compositional variation of garnets demonstrates that breakdown of epidote-group minerals may have played a crucial role during dehydration melting reaction of phengite. The Ti-in-zircon thermometry and Si content of phengite in zircon suggest that partial melting would occur at 783–839°C and 2.0–2.5 GPa. Therefore, both experimental results and petrological observations indicate that dehydration melting and fluid activity within the Dabie UHP rocks at micro-scale are controlled by the breakdown of phengite.

The Neoproterozoic granitoids from the Qilian block, NW China: Evidence for a link between the Qilian and South China blocks

The field occurrence, petrography, geochemistry, Sm–Nd isotopes, and geochronology of the Neoproterozoic granitoids exposed at Tuole, Huangyuan, Gahai, Haiyan, Riyueshan, Baokuhe, and Maxianshan in the Qilian block were studied. The Neoproterozoic granitoids in the Qilian block form two age groups: ca. 800Ma and ca. 900Ma. The ca. 800Ma group granitoids consist of granodiorite and granite, whereas the ca. 900Ma group granitoids quartz diorite, granodiorite, and potassic granite. They have intruded the Huangyuan Group in the basement sequence of the Qilian block. The foliations are moderately to well-developed and are concordant with those of the country rocks. The granitoids of both age groups all show enrichment in LREEs, but this enrichment is more pronounced in the ca. 800Ma group than in the ca. 900Ma group. All granitoids show negative europium anomalies, but the ca. 800Ma group granitoids are more varied in Eu/Eu* values (0.23–0.83) than most of the ca. 900Ma group granitoids (0.54–0.98). Spider diagrams of both groups also exhibit enrichment in large ion lithophile elements, i.e., Rb, Th, U, and K, and negative anomalies in Nb–Ta, Sr, P, Ti, and, with exception of the Maxianshan quartz diorite, Ba. The ɛNd(1Ga) and TDM are −6.7 to −12.7 and 2.2–3.0Ga for the ca. 800Ma granitoids and are −4.3 to −5.2 and 2.0–2.3Ga for the ca. 900Ma granitoids. The granitoids of the ca. 900Ma group are interpreted to have formed in an arc tectonomagmatic environment on an active continental margin, whereas those of the ca. 800Ma group are thought to form in a continental rift environment. The ca. 900Ma granitoids are I-type and could be formed from partial melting of K-rich metabasalt or eclogite with significant amount of mantle components at a pressure of 1–4GPa in the lower crust. The strongly peraluminous or peraluminous Gahai granites and Haiyan granodiorite are S-type and could be derived from melting of clay-poor, mature psammitic sources.Similarities in age and tectonic environment of magma genesis suggest a correlation of Neoproterozoic granitoid magmatism between the Qilian and South China block. This correlation gives a strong support to the consideration that the two blocks might be unified in the Neoproterozoic. In other words, the Qilian block might be a part of the South China block or, more precisely, the Sibao orogen, in the Neoproterozoic time.

Trace element composition of continentally subducted slab‐derived melt: insight from multiphase solid inclusions in ultrahigh‐pressure eclogite in the Dabie orogen

AbstractThe ultrahigh‐pressure (UHP) eclogite in the Dabie orogen preserves petrological evidence for the existence of hydrous silicate melts that formed during continental subduction‐zone metamorphism. This is indicated by occurrence of multiphase solid (MS) inclusions in garnet that primarily consist of K‐feldspar + quartz ± epidote/allanite. All the MS inclusions are euhedral to subhedral in morphology and surrounded with radial cracks in the host garnet. Their trace element compositions were analysed by two different approaches of laser sampling. The mass budget method was used to estimate the trace element abundances of MS inclusions from their mixtures with the host garnet. The results are compared with the direct sampling of MS inclusions, providing a first‐order approximation to the trace element composition of MS inclusions. The MS inclusions exhibit consistent enrichment of LILE, Sr and Pb, but depletion of HFSE in the primitive mantle‐normalized spidergram. Such arc‐like patterns of trace element distribution are common for continental crustal rocks. The melts have variably high K, Rb and Sr abundances, suggesting that breakdown of phengite is a basic cause for partial melting of the UHP eclogite. These MS inclusions also exhibit consistently low HFSE and Y contents, suggesting partial melting of the eclogite in the stability fields of rutile and garnet. Consequently, the trace element composition of MS inclusions provides a proxy for that of hydrous silicate melts derived from dehydration melting of the UHP eclogite during continental collision.

Garnet clinopyroxenite layers from the mantle sequences of the Northern Apennine ophiolites (Italy): Evidence for recycling of crustal material

This study aims to define the origin of garnet clinopyroxenite layers from the mantle sequences of the External Ligurian ophiolites. These mantle sequences retain a subcontinental origin and were exposed at a Jurassic ocean–continent transition. The garnet clinopyroxenites are mafic rocks with Mg# values of 66–71. Their chondrite-normalised REE patterns are characterised by severe LREE depletion (CeN/SmN=0.1–0.2) and nearly flat (Type-A pyroxenites) to moderately enriched HREE (Type-B pyroxenites). In addition, Type-A pyroxenites display a small positive Eu anomaly. The whole-rock REE variations are paralleled by the garnet REE compositions. We attribute the major and trace element characteristics of the garnet clinopyroxenites to recycling of gabbroic protoliths that underwent partial melting under eclogite facies conditions. The garnet clinopyroxenites may represent variably evolved garnet+clinopyroxene cumulates formed by eclogite-derived melts. In an alternative hypothesis, Type-A and -B pyroxenites are residual rocks after eclogite melting and cumulates derived from the eclogite melts, respectively. The high pressure fractionation event that gave rise to the garnet clinopyroxenites is considered of Triassic age on the basis of Sm–Nd and Lu–Hf isotope correlations. The Nd–Hf isotopic compositions of the garnet clinopyroxenites in the Triassic (εNd=+4.7 to +7.6, εHf=+4.4 to +12.8) lie below the mantle array, in agreement with recycled ancient MOR-type material. The oxygen isotopic composition of garnet and clinopyroxene from the garnet clinopyroxenites (δ18O=+4.9‰ to +5.2‰) may be reconciled with subduction-related recycling of the lowermost oceanic crust, or delamination and foundering of underplated gabbros from the continental lithosphere. The potential involvement of the garnet clinopyroxenites in the melting processes that gave rise to the MOR-type oceanic crust in the Jurassic would account for the moderate Nd isotope variability and the garnet geochemical signature of the ophiolitic basalts.

Water-present eclogite melting to produce Earth's early felsic crust

The geochemistry of well preserved Archaean Tonalite–Trondhjemite–Granodiorite (TTG) rocks, such as the trondhjemites of the Meso-Archaean Barberton granitoid–greenstone terrain in South Africa, provides insight into the origins of Earth's early felsic continental crust. This is particularly well demonstrated by the high pressure (HP)-type of Archaean TTG magmas, where the geochemistry requires that they are formed by high-pressure melting of a garnet-rich eclogitic source. This has consequently been interpreted as evidence for the formation of these magmas by anatexis of the upper portions of slabs within Archaean subduction zones. Most of the experimental data relevant to TTG genesis has been generated by studies of fluid-absent melting of metabasaltic sources. However, water drives arc magmatism within Phanerozoic subduction zones and thus, understanding the behaviour of water in Archaean subduction zones, may have considerable value for understanding the genesis of HP-type Paleo- to Meso-Archaean trondhjemites. Consequently, this study investigates the role of high-pressure water-present melting of an eclogite-facies starting material, in the production of Paleo- to Meso-Archaean HP-type TTG melts. Water-saturated partial melting experiments were conducted between 1.9 and 3.0GPa; and, 870°C and 900°C. The melting reaction is characterised by the breakdown of the jadeite molecule in the clinopyroxene, together with quartz and water, to form melt in conjunction with a less sodic clinopyroxene: Qtz+Cpx1+Grt1+H2O=Melt+Cpx2+Grt2 and produced melt compositions that, if allowance is made for the low Mg# and almost K2O-free character of the starting material, are an excellent major element match with HP-type TTG compositions. In two of the experimental run products, melt segregated efficiently from residual crystals, allowing for the measurement of a full range of trace elements, via Laser Ablation Inductively Coupled Plasma Mass Spectroscopy (LA-ICP-MS). The experimental glasses produced are Light Rare Earth Element (LREE) (24–44ppm La; 50–86ppm Ce) and Zr (101–228ppm) enriched; and Heavy Rare Earth Element (HREE) (0.4ppm Yb; 50.9 La/Ybn), Y (2.2–3.2ppm; 82–142 Sr/Y), Sm (2.1–4.3ppm; 40.9–50.8 Zr/Sm) and Nb (1.7–2.8ppm) depleted compared to the DSE4 starting material. Thus, the REE element compositions of the experimental glasses are also similar to HP-type TTG compositions, and in more particular they are strikingly similar to Meso-Archaean Barberton trondhjemites. Additionally, we propose that due to Cpx being a major reactant, Ni and Cr contents (4–29ppm Ni and 43ppm Cr) of the glasses which where analysed for these elements, are within the compositional range displayed by HP-type Archaean TTG. This study suggests that the geochemistry of HP-type Archaean trondhjemites may reflect high pressure water-present partial melting of an eclogite facies metabasaltic source. Consequently, we propose that water-present melting of an eclogitic source is a viable mechanism for the genesis of this component of Paleo- to Meso-Archaean TTG crust.

Review of melting experiments on carbonated eclogite and peridotite: insights into mantle metasomatism

Experimental studies on the partial melting of eclogite and peridotite provide important clues on mantle metasomatism. Here, we review results from some of the recent experiments and show that melting of carbonated eclogite and peridotite can produce carbonatitic to carbonated silicate melt, in which carbonates melt preferentially before Ti oxides and silicates. Low-degree melting results in carbonatitic melt coexisting with Ti oxides and silicates. This process also leads to the fractionation between some high-field strength elements (Nb, Ta, Zr, Hf, and HREE) and highly incompatible elements (U and Th) in the melt. When Ti oxides are nearly exhausted in eclogite, extremely high TiO2 contents (e.g. 19 wt.%) are present in the melt with marked concentration of Nb and Ta. These results help to explain the features of carbonatitic metasomatism and the Nb–Ta spike in oceanic island basalts as identified in experimental studies. These studies also explain the reducing conditions that stabilize diamond in the deep mantle (>150 km) as well as the occurrence of diamond at different depths reported in various studies. Melting in such a reduced mantle can happen through redox reaction between diamond, pyroxene, and olivine, in which the initial liquid is a carbonated silicate melt. However, the theoretical oxygen fugacity (fO2) in the asthenosphere is much lower than that predicted by the reaction and requires elevated fO2, which can be caused by the addition of relatively oxidized materials from the lower mantle, deep asthenospheric material, and various recycled components. A combination of these processes generates locally oxidized domains in the deep mantle.

The geochemistry and isotopic age of eclogites from the Belomorian Belt (Kola Peninsula): evidence for subducted Archean oceanic crust

We present results of geochemical studies and isotope dating of eclogites and associated rocks from the Kuru-Vaara quarry, Belomorian Belt, Northeastern Baltic Shield. The southern and northern eclogites are similar in geochemical features. Their protoliths were primitive, mainly high-Mg basalts of oceanic affinity derived from a primitive mantle source rather than from a depleted mantle source characteristic of modern MORB. The post-eclogitic intrusive rocks show obvious evidence for crustal contamination. The eclogite-hosting tonalitetrondhjemite-granodiorite (TTG) gneisses form a coherent series including high-Al and low-Al varieties. The trace element data show that the TTG series formed through the hydrous partial melting of the southern eclogites in the presence of garnet and amphibole in the field of the rutile stability (>15 kbar). Zircons from the southern eclogites exhibit features of their strong re-equilibration by coupled dissolution–repre-cipitation processes but have locally preserved patches with a primary magmatic zoning. The geochemistry of the patches points to the oceanic provenance of protolithic zircons; their isotope dating (SHRIMP-II) yielded a concordant age of 2821 ± 21 Ma. Zircons from the trondhjemite gneiss with geochemical features of Archean adakite were dated at 2805 ± 11 Ma, which suggests the syneclogitic facies origin of the TTG melts. The concordant age of high-pressure zircons from the northern eclogites is 2722 ± 21 Ma, close to the age of the earlier described Gridino eclogites. The overview of the isotopically dated eclogite bodies show the presence of at least three temporally distinct groups of eclogites in the Belomorian Belt, ∼2.86–2.87, ∼2.82–2.80, and ∼2.72 Ga, which is in a good accordance with the known isotopic ages for major crust-forming events in the belt. This, in turn, implies a close genetic relationship between the eclogites and the TTG origin, which might be consistent with the model of the short intermitted events of subduction of the thickened Archean oceanic crust. The presence of HP/UHP eclogites of different ages and the structural style of the Belomorian Belt permit it to be assigned to megamélange belts.

Experimental investigation on low-degree dehydration partial melting of biotite gneiss and phengite-bearing eclogite at 2 GPa

The ultrahigh-pressure (UHP) eclogite and gneiss from the Dabie (大别)-Sulu (苏鲁) oro- gen experienced variable degrees of partial melting during exhumation. We report here dehydration partial melting experiments of biotite gneiss and phengite-bearing eclogite at 2 GPa and 800-950 ℃. Our results show that the partial melting of gneiss is associated with the breakdown of biotite into almandine-rich garnet starting at 900 ℃. About 10% granitic melt can be produced at 950 ℃. In con- trast, the partial melting of phengite-bearing eclogite exists at slightly lower temperatures (800-850 ℃). The melt fraction is in general more in biotite gneiss than in phengite-bearing eclogite under similar pressure and temperature conditions. Both melts are rich in silica and alkali, but poor in FeO, MgO and CaO. These results suggest that low-degree partial melting of gneiss and eclogite is often associated with dehydration of hydrous mineral, such as micas. The dehydration temperature and melt composi- tion can place important constraints on the partial melting phenomena (granitic leucosome and multi-phase mineral inclusions) recorded in UHP rocks.

Oxygen isotope constraints on the structure and evolution of the Hawaiian Plume

The oxygen isotope stratigraphy of Ko‘olau volcano, Hawaii, is constructed by analyzing olivine phenocrysts from the KSDP drill core and submarine land-slide deposits. Along with those of subaerial (Makapu‘u) Ko‘olau olivines (Eiler and others, 1996a), they span the full range of the δ^(18)OVSMOW variation previously observed in Loa-trend Hawaiian volcanoes (Lō‘ihi, Mauna Loa, Hualalai, and Ko‘olau), vary systematically with the stratigraphic position, and correlate with other geochemical properties of their host lavas (Tanaka and others, 2002; Haskins and Garcia, 2004; Huang and Frey, 2005; Salters and others, 2006; Fekiacova and others, 2007). These observations can be explained if the Loa-trend volcanoes (including Ko‘olau) are constructed of magmas made by mixing peridotite melt with variable proportions of eclogite melt derived from a mafic constituent of the Hawaiian plume having a composition resembling recent mid-ocean-ridge basalts. We present a model of this magma mixing process that simultaneously explains the correlations among oxygen isotopes, major elements, trace elements and radiogenic isotopes. Although a number of models of this kind, differing in several parameters, describe the data equally well, all statistically acceptable models require an component with a MORB-like HREE pattern and enriched oxygen isotope composition (δ^(18)OVSMOW = 7.8-9.7‰), consistent with this component being an upper crustal (layer 1 or 2) basalt or gabbro with a low-temperature alteration history, possibly containing a small amount of sediment. Abundances of some minor elements—Ni and Ti—are not well described by this model; we show that these shortcomings are derived from the compositional assumption and operational difficulties, that is, TiO_2 content is too high in our assumed eclogite end-member, and the inversion of NiO content in the melt by the olivine addition calculation is imprecise due to the sensitivity of D_(NiO)^(olivine/melt) to the melt composition and to crystallization process. Previous studies have advocated that Hawaiian lavas were derived from partial melts of an olivine-free pyroxenite formed by reaction of eclogite-derived melt with peridotite (for example, Sobolev and others, 2005). Our study shows that the peridotite-derived and eclogite-derived melt-mixing model can explain the geochemistry of Hawaiian lavas as well, including high-Ni Ko‘olau olivines. We find that an olivine-free mantle source for Hawaiian lavas is unnecessary, although melt-rock interaction could be important in modifying melt composition. Inverting for mixing proportions and degree of melting, we estimate that the amount of recycled crust in the Hawaiian plume is <24 weight percent. Comparison of the late shield-stage Loa-trend (particularly Ko‘olau lavas) and Kea-trend (particularly Mauna Kea lavas) suggests that the geochemical diversity of Hawaiian lavas is produced by a thermally and chemically-zoned plume.

Highly depleted Hadean mantle reservoirs in the sources of early Archean arc-like rocks, Isua supracrustal belt, southern West Greenland

Growing evidence from the accessible geological record reveals that crust–mantle differentiation on Earth started as early as 4.4 Ga. In order to assess the extent of early Archean mantle depletion, we obtained 176Lu– 176Hf, 147Sm– 143Nd, and high field strength element (HFSE) concentration data for the least altered, well characterized boninite-like metabasalts and associated metasedimentary rocks from the Isua supracrustal belt (southern West Greenland). The metasediments exhibit initial εHf (3720) values from −0.7 to +1.5 and initial εNd (3720) values from +1.6 to +2.1. Initial εHf (3720) values of the least altered boninite-like metabasalts span a range from +3.5 to +12.9 and initial εNd (3720) values from −0.3 to +3.2. These initial Hf-isotope ratios display coherent trends with SiO 2, Al 2O 3/TiO 2 and other relatively immobile elements, indicating contamination via assimilation of enriched components, most likely sediments derived from the earliest crust in the region. This model is also consistent with previously reported initial γOs (3720) values for some of the samples. In addition to the positive εHf (3720) values, the least disturbed samples exhibit positive εNd (3720) values and a co-variation of εHf (3720) and εΝd (3720) values. Based on these observations, it is argued, that the most depleted samples with initial εHf (3720) values of up to +12.9 and high 176Lu/ 177Hf of ∼0.05 to ∼0.09 tap a highly depleted mantle source with a long term depletion history in the garnet stability field. High precision high field strength element (HFSE) data obtained for the Isua samples confirm the contamination trend. Even the most primitive samples display negative Nb–Ta anomalies and elevated Nb/Ta, indicating a subduction zone setting and overprint of the depleted mantle sources by felsic melts generated by partial melting of eclogite. Collectively, the data for boninite-like metabasalts support the presence of strongly depleted mantle reservoirs as previously inferred from Hf isotope data for Hadean zircons and combined 142Nd– 143Nd isotope data for early Archean rocks.

High-Mg# andesitic lavas of the Shisheisky Complex, Northern Kamchatka: implications for primitive calc-alkaline magmatism

Primitive arc magmatism and mantle wedge processes are investigated through a petrologic and geochemical study of high-Mg# (Mg/Mg + Fe > 0.65) basalts, basaltic andesites and andesites from the Kurile-Kamchatka subduction system. Primitive andesitic samples are from the Shisheisky Complex, a field of Quaternary-age, monogenetic cones located in the Aleutian–Kamchatka junction, north of Shiveluch Volcano, the northernmost active composite volcano in Kamchatka. The Shisheisky lavas have Mg# of 0.66–0.73 at intermediate SiO2 (54–58 wt%) with low CaO ( 3.0 wt%) and K2O (>1.0 wt%). Olivine phenocryst core compositions of Fo90 appear to be in equilibrium with whole-rock ‘melts’, consistent with the sparsely phyric nature of the lavas. Compared to the Shisheisky andesites, primitive basalts from the region (Kuriles, Tolbachik, Kharchinsky) have higher CaO (>9.9 wt%) and CaO/Al2O3 (>0.60), and lower whole-rock Na2O (<2.7 wt%) and K2O (<1.1 wt%) at similar Mg# (0.66–0.70). Olivine phenocrysts in basalts have in general, higher CaO and Mn/Fe and lower Ni and Ni/Mg at Fo88 compared to the andesites. The absence of plagioclase phenocrysts from the primitive andesitic lavas contrasts the plagioclase-phyric basalts, indicating relatively high pre-eruptive water contents for the primitive andesitic magmas compared to basalts. Estimated temperature and water contents for primitive basaltic andesites and andesites are 984–1,143°C and 4–7 wt% H2O. For primitive basalts they are 1,149–1,227°C and 2 wt% H2O. Petrographic and mineral compositions suggest that the primitive andesitic lavas were liquids in equilibrium with mantle peridotite and were not produced by mixing between basalts and felsic crustal melts, contamination by xenocrystic olivine, or crystal fractionation of basalt. Key geochemical features of the Shisheisky primitive lavas (high Ni/MgO, Na2O, Ni/Yb and Mg# at intermediate SiO2) combined with the location of the volcanic field above the edge of the subducting Pacific Plate support a genetic model that involves melting of eclogite or pyroxenite at or near the surface of the subducting plate, followed by interaction of that melt with hotter peridotite in the over-lying mantle wedge. The strongly calc-alkaline igneous series at Shiveluch Volcano is interpreted to result from the emplacement and evolution of primitive andesitic magmas similar to those that are present in nearby monogenetic cones of the Shisheisky Complex.

Partial melting of the dry mafic continental crust: Implications for petrogenesis of C-type adakites

C-type adakites have been commonly considered as a result of partial melting of the mafic lower continental crust (LCC) at high pressure, as supported by high P-T experiments on hydrous basalts. However, because the mafic eclogitic LCC is generally dry, experiments on water-bearing materials cannot be used to constrain the melting processes of the dry mafic LCC. Due to the lack of systematic melting experimental studies on dry mafic rocks at crustal pressures, MELTs software was applied to simulating melting of the dry mafic LCC at 1–2 GPa. Comparison of model results with experimental data indicates that, when melting degree is greater than 20%, melts from the dry mafic LCC at 1–3 GPa cannot produce the C-type adakitic melt with high SiO2 content (∼70%). Although the limited experimental results about dry mafic rock melting at 1–2 GPa in the literature suggest that low degree melting ( 1.8 GPa, low-degree melting can produce dacitic melt with high K2O/Na2O (∼1) if SiO2 content of the melt is controlled by residual garnet. Furthermore, the simulation also suggests that, if pressure is <1.8 GPa, abundant plagioclase (plg) in the residual phase may decrease SiO2 content in the melt to below 62%, much lower than that of the C-type adakites observed in eastern China. Given the high P-T conditions required to produce melts with high SiO2 and extremely low HREE contents, such melts could easily be contaminated by other crustal-derived melts, implying that the C-type adakites from eclogite melting could be less commonly observed in the outcrops than previously believed. Besides the interpretation that garnet fractionates Sr, Y, and REE, high Sr/Y and La/Yb could be also produced by multiple ways such as inheriting the source features and fractional crystallizing clinopyroxene (cpx). Therefore, it may be problematic using high Sr/Y and La/Yb as criteria to identify adakites. Instead, REE patterns with strong depletion of HREE relative to MREE (e.g. high Gd/Yb) could be a better parameter to identify the role of garnet and thus adakites. Finally, geochemical models based on MELTs simulation indicate that Eu anomaly cannot be simply used to constrain the role of plg in magmatism because Eu anomaly in the melt is a function of source characteristics, oxygen fugacity (fO2) of magmatic systems, and plg/mafic minerals mode ratio.

Eclogite-melt/peridotite reaction: Experimental constrains on the destruction mechanism of the North China Craton

To study the mechanism of melt-peridotite reaction pertinent to the destruction of the North China Craton (NCC) lithosphere, a series of experiments were performed at a pressure of 2.0 GPa and temperatures from 1250 to 1400°C using Bixiling eclogite and Damaping peridotite as starting materials. The experimental results show that the reaction between eclogite melt and peridotite causes dissolution of olivine and orthopyroxene and precipitation of clinopyroxene in the melt. The experimental run products, characterized by a lherzolite/pyroxenite/garnet-pyroxenite sequence, are consistent with the mantle xenoliths in the Neogene Hannuoba basalt of the NCC found by Liu et al. (2005). It suggests that the mafic lower continental crust was probably recycled into the mantle during the Mesozoic Era. In the experiments conducted at 1300 and 1350°C, the resulting melts have a high Mg# andesite signature, indicating that the melt-peridotite reaction may have played a major role in the generation of high Mg# andesite. Our experimental results support the hypothesis that melts derived from foundered eclogite in the asthenosphere will consume the lithospheric peridotites. Therefore, melt-peridotite reaction is an important mechanism for the destruction/thinning of the lithosphere.

Siberian meimechites: origin and relation to flood basalts and kimberlites

Here we combine petrological-geochemical and thermomechanical modeling techniques to explain origin of primary magmas of both Maimecha–Kotui meimechites and the Gudchikhinskaya basalts of Norilsk region, which represent, respectively, the end and the beginning of flood magmatism in the Siberian Trap Province. We have analyzed the least altered samples of meimechites, their olivine phenocrysts, and melt inclusions in olivines, as well as samples of dunites and their olivines, from boreholes G-1 and G-3 within the Guli volcanoplutonic complex in the Maimecha–Kotui igneous province of the northern Siberian platform. The Mn/Fe and Ni/MgO ratios in olivines indicate a mantle peridotite source of meimechites. Meimechite parental magma that rose to shallow depths was rich in alkalis and highly magnesian (24 wt.% MgO), largely degassed, undersaturated by sulfide liquid and oxidized. At greater depths, it was, likely, high in CO 2 (6 wt.%) and H 2O (2 wt.%) and resulted from partial melting of initially highly depleted and later metasomatized harzburgite some 200 km below the surface. Trace-element abundances in primary meimechite magma suggest presence of garnet and K-clinopyroxene, in the mantle source and imply for genetic link to the sources of the early Siberian flood basalts (Gudchikhinskaya suite) and kimberlites. The analyzed dunite samples from the Guli complex have chemistry and mineralogy indicating their close relation to meimechites. We have also computed thermomechanical model of interaction of a hot mantle plume with the shield lithosphere of variable thickness, using realistic temperature- and stress-dependent visco-elasto-plastic rocks rheology and advanced finite element solution technique. Based on our experimental and modeling results we propose that a Permian–Triassic plume, with potential temperature of about 1650 °C transported a large amount of recycled ancient oceanic crust (up to 15%) as SiO 2-supersaturated carbonated eclogite. Low-degree partial melting of eclogite at depths of 250–300 km produced carbonate-silicate melt that metasomatized the lithospheric roots of the Siberian shield. Further rise of the plume under relatively attenuated lithosphere (Norilsk area) led to progressive melting of eclogite and formation of reaction pyroxenite, which then melted at depths of 130–180 km. Consequantly, a large volume of melt (Gudchikhinskaya suite) penetrated into the lithosphere and caused its destabilization and delamination. Delaminated lithosphere that included fragments of locally metasomatized depleted harzburgite subsided into the plume and was heated to the temperatures of the plume interior with subsequent generation of meimechite magma. Meimechites showed up at the surface only under thicker part of the lithosphere aside from major melting zone above because otherwise they were mixed up in more voluminous flood basalts. We further suggest that meimechites, uncontaminated Siberian flood basalts and kimberlites all shear the same source of strongly incompatible elements, the carbonated recycled oceanic crust carried up by hot mantle plume.

Source components of the Gran Canaria (Canary Islands) shield stage magmas: evidence from olivine composition and Sr–Nd–Pb isotopes

The Canary Island primitive basaltic magmas are thought to be derived from an HIMU-type upwelling mantle containing isotopically depleted (NMORB)-type component having interacted with an enriched (EM)-type component, the origin of which is still a subject of debate. We studied the relationships between Ni, Mn and Ca concentrations in olivine phenocrysts (85.6–90.0 mol.% Fo, 1,722–3,915 ppm Ni, 1,085–1,552 ppm Mn, 1,222–3,002 ppm Ca) from the most primitive subaerial and ODP Leg 157 high-silica (picritic to olivine basaltic) lavas with their bulk rock Sr–Nd–Pb isotope compositions (87Sr/86Sr = 0.70315–0.70331, 143Nd/144Nd = 0.51288–0.51292, 206Pb/204Pb = 19.55–19.93, 207Pb/204Pb = 15.60–15.63, 208Pb/204Pb = 39.31–39.69). Our data point toward the presence of both a peridotitic and a pyroxenitic component in the magma source. Using the model (Sobolev et al. in: Science 316:412–417, 2007) in which the reaction of Si-rich melts originated during partial melting of eclogite (a high pressure product of subducted oceanic crust) with ambient peridotitic mantle forms olivine-free reaction pyroxenite, we obtain an end member composition for peridotite with 87Sr/86Sr = 0.70337, 143Nd/144Nd = 0.51291, 206Pb/204Pb = 19.36, 207Pb/204Pb = 15.61 and 208Pb/204Pb = 39.07 (EM-type end member), and pyroxenite with 87Sr/86Sr = 0.70309, 143Nd/144Nd = 0.51289, 206Pb/204Pb = 20.03, 207Pb/204Pb = 15.62 and 208Pb/204Pb = 39.84 (HIMU-type end member). Mixing of melts from these end members in proportions ranging from 70% peridotite and 30% pyroxenite to 28% peridotite and 72% pyroxenite derived melt fractions can generate the compositions of the most primitive Gran Canaria shield stage lavas. Combining our results with those from the low-silica rocks from the western Canary Islands (Gurenko et al. EPSL 277:514–524, 2009), at least four distinct components are required. We propose that they are (1) HIMU-type pyroxenitic component (representing recycled ocean crust of intermediate age) from the plume center, (2) HIMU-type peridotitic component (ancient recycled ocean crust stirred into the ambient mantle) from the plume margin, (3) depleted, MORB-type pyroxenitic component (young recycled oceanic crust) in the upper mantle entrained by the plume, and (4) EM-type peridotitic component from the asthenosphere or lithosphere above the plume center.