Eclogite Formation Research Articles

Remobilization of metasomatized mantle lithosphere: a new model for the Jiaodong gold province, eastern China

The ~ 120 Ma Jiaodong province in the North China Craton, composed of abundant Mesozoic granites that intrude Precambrian metamorphic basement, is bordered by the Sulu orogenic belt, which formed through the collision between the North China and Yangtze cratons in the Triassic. Insights on the geodynamic setting and source of gold and fluids in the Jiaodong gold province are based on a detailed study of the Sanshandao deposit. The δ13CPDB and δ18O values of hydrothermal calcite from this deposit range from − 4.3 to − 6.5‰ and 11.4 to 15.1‰, respectively, which are compatible with a mantle source. Pre-ore mafic dykes in the deposit show typical arc-like geochemical features, suggesting that the mantle source was metasomatized prior to the basic magmatism. The δ34S values of gold-related pyrite from Sanshandao and other large deposits in the province range from 10.9 to 11.5‰ and are higher than those of the country rocks, but consistent with the signature of orogenic gold deposits sourced from a Neoproterozoic sedimentary reservoir. These high positive δ34S values are interpreted to be inherited from auriferous Neoproterozoic sedimentary rocks of the northern Yangtze Craton, which were subducted into the mantle lithosphere beneath the North China Craton during the formation of eclogite in the adjacent Sulu orogenic belt in the Triassic. The syn-ore Lower Cretaceous mafic dykes display oceanic island basalt-like geochemical features, suggesting that asthenosphere upwelling triggered the release of gold and sulfur from an enriched and fertilized mantle lithosphere, contributing to the auriferous fluid which formed the widespread gold mineralization in the Jiaodong province at ca. 120 Ma.

Confirmation of the Major Grenville Event in the Qinling Complex of the Qinling Orogenic Belt, Central China

The Qinling Complex from the Qinling orogenic belt was generally considered to be part of the Caledonian orogeny, however information of the Grenville event of the Qinling Complex has been poorly recognized. Two granite samples of greenschist-facies and two paragneiss samples of amphibolite- faices are identified from the Qinling Complex. The granites occur along the regional gneissosity of the Qinling Complex, thus it is suggested that their magmatic zircon ages (~970 Ma) mark the lower boundary of the main metamorphic age (amphibolite-granulite facies). In addition, some early-formed metamorphic zircons (~1 000 Ma) are distinguished in the granites, which may reflect the information about the source area of the granites. Therefore the major metamorphism of amphibolite-granulite facies in the Qinling Complex is constrained at Early Neoproterozoic (~1 000 Ma), not Early Paleozoic as conventionally considered. In the Early Paleozoic, the Qinling Complex was characterized by multiple extension- shear activities, overprint of greenschist-facies metamorphism and emplacement of extensive granites. These granites and related thermal events could reset the U-Pb isotopic system of the early-formed zircons, leading to the apparent zircon ages younger than their protolith age. As a result, the Qinling Complex is a modified Early Neoproterozoic orognenic belt or an independent block, which became a continental margin arc during the Early Paleozoic, being accompanied by metamorphism, deformation, and emplacement of continental arc granites. The Erlangping, Kuanping, and Taowan groups to the north of the Qinling Complex show more intensive deformation of the Caledonian, and their oblique subduction towards the Qinling Complex caused the formation of eclogites. Afterwards, the Qinling Complex was amalgamated with the Erlangping, Kuanping, and Taowan groups, which all experienced the same Caledonian orogeny, and possible later orogenies.

Evidence of cumulate crystallization and local development of the eclogite-facies metamorphism in the olivine gabbro of the Marun-Keu complex, Polar Urals, Russia

The paper presents the results of a detailed petrological study of olivine gabbro transformed to different extent by eclogite-facies metamorphism. Textural features of cumulate crystallization in the rock are presented. Plagioclases underwent the greatest alteration and replaced by finegrained aggregate during eclogite-facies metamorphism. Corona textures are developed along the boundaries of the plagioclase (felscic) domains at the contacts with (Fe,Mg)-minerals during eclogite facies event. The mineral thermobarometry and phase equilibrium modeling provide P-T metamorphic conditions in relatively narrow range of temperature 680±60 ᵒC and pressure Р=2,2±0.4 GPa. This is in a good agreement with the previously established conditions for the formation of eclogites and garnet-amphibole peridotite from the same complex.

High Pressure Metamorphism Caused by Fluid Induced Weakening of Deep Continental Crust

Studies of mineral equilibria in metamorphic rocks have given valuable insights into the tectonic processes operating at convergent plate margins during an orogeny. Geodynamic models simulating orogenesis and crustal thickening have been constrained by temperature and pressure estimates inferred from the mineral assemblages of the various lithologies involved along with age constrains from increasingly precise geochronological techniques. During such studies it is assumed that the pressure experienced by a given rock is uniquely related to its depth of burial. This assumption has been challenged by recent studies of high pressure (HP) and ultrahigh pressure (UHP) rocks. Here, we describe an example of Caledonian HP metamorphism from the Bergen Arcs in western Norway, and show that the associated formation of Caledonian eclogites at the expense of Proterozoic granulites was related to local pressure perturbations rather than burial, and that the HP metamorphism resulted from fluid-induced weakening of an initially dry and highly stressed lower crust when thrust upon the hyperextended margin of the Baltic shield.

Age and setting of Permian Slide Mountain terrane ophiolitic ultramafic-mafic complexes in the Yukon: Implications for late Paleozoic-early Mesozoic tectonic models in the northern Canadian Cordillera

The Yukon Tanana (YTT) and Slide Mountain terranes (SMT) of the Cordillera in Canada and Alaska were interpreted in terms of opening and closing of a Late Devonian-Permian Japan Sea-style backarc basin behind a continental arc built upon YTT, which rifted from Laurentia during the Famennian-early Mississippian. Formation of Famennian transitional oceanic lithosphere supports rifting, but a combination of existing and new data on the setting and age of SMT ophiolites do not support the Japan Sea model.The studied Clinton Creek and Midnight Dome complexes represent suprasubduction zone ophiolites formed at ca. 265 Ma, consistent with analyses of other SMT ophiolites. Ultramafic rocks dominate most ophiolites. They lack sheeted dikes and contain relatively minor volumes of mafic plutonic and volcanic rocks, suggesting they formed in oceanic core complexes characterised by slow spreading and low magma productivity. The Permian ophiolites formed during or immediately after eclogite formation in YTT, coeval with or immediately preceding emplacement of orogenic peridotites into YTT due to hyperextension. Several tectonic scenarios are discussed. We propose that YTT is a composite terrane comprising a continental block and an oceanic arc-backarc complex with the latter obducted onto the former during the middle Permian-early Triassic Klondike orogeny. Obduction may have come from the west or east, but east-directed obduction is most consistent with geological constraints. Obduction was followed by initiation of west-dipping subduction east of the composite YTT; slab roll back causing extension in the composite upper plate, leading to exhumation of orogenic peridotites. Tectonic relationships show many analogies to the collision between Australia and the New Britain arc, in which collision in the Huon Peninsula of New Guinea is contemporaneous with extension in Australian crust in the adjacent Woodlark basin. Syn-orogenic Permian Klondike calc-alkaline magmatism is attributed to extension in a Woodlark basin-like setting rather than a representing a continental arc.

Origin of zircon-bearing mantle eclogites entrained in the V. Grib kimberlite (Arkhangelsk region, NW Russia): Evidence from mineral geochemistry and the U-Pb and Lu-Hf isotope compositions of zircon

The concentrations of major and trace elements in minerals, reconstructed whole-rock compositions of zircon-bearing equigranular eclogites from the V. Grib kimberlite pipe located within the Arkhangelsk Diamondiferous Province (North-Western Russia), and results of the U-Pb and Lu-Hf isotope analyses of zircon grains from eclogites and granulite xenoliths are reported. These data suggest that the equigranular eclogites could represent the fragments of mid-ocean-ridge basalt that were metamorphosed during Paleoproterozoic subduction at 1.7–1.9 Ga. The Hf isotope compositions of the eclogitic zircon display uniformity and indicate corresponding Hf-depleted mantle model ages of 2.2–2.3 Ga. The formation of zircon in eclogites could have resulted from interactions with metasomatic/subduction-related fluids just prior to, but associated with, Paleoproterozoic eclogite formation. A link between eclogitic zircon formation and continental lower-crustal rocks can be excluded based on differences in the Hf isotope compositions of eclogitic and granulitic zircon grains. The U-Pb upper intercept age of granulitic zircon of 2716 ± 61 Ma provides a new minimum age constraint for zircon crystallisation and granulite formation. The U-Pb ages obtained from granulitic zircon show two stages of Pb loss at 2.2–2.6 Ga and 1.7–2.0 Ga. The late Paleoproterozoic stage of Pb loss recorded in granulitic zircon is due to the intensive reworking of basement crustal rocks, which was caused by a tectonic process/subduction event associated with equigranular eclogite formation. Our data, along with evidence previously obtained from the V. Grib pipe coarse-granular eclogites, show at least two main subduction events in the lithospheric mantle of the Arkhangelsk region: the Archean (2.8 Ga) and Paleoproterozoic (1.7–1.9 Ga) subductions, which correspond to major magmatic and metamorphic events in the Baltic Shield.

Rapid formation of eclogites during a nearly closed ocean: Revisiting the Pianshishan eclogite in Qiangtang, central Tibetan Plateau

The Pianshishan eclogites discovered in central Qiangtang are a key piece of evidence constraining the main suture of the Paleo-Tethys Ocean in Tibet. Based on the eclogite-facies metamorphic inclusions found in them, a previous study interpreted the zircon grains as metamorphic in origin, although their catholuminescence images were similar to zircons of igneous origin. Distinguishing metamorphic from igneous zircons can be difficult, however, especially in high-pressure metamorphic rocks. In this study, we report new SIMS zircon U-Pb dates along with zircon O isotope and trace element analyses, to constrain the origin of these zircons and the interpretation of zircon dates. Twenty-five of 26 zircons analyzed from three samples yielded zircon U-Pb dates ranging from 239 to 236Ma with an average of 238±1Ma. The zircon rare earth element (REE) patterns are characterized by positive Ce and negative Eu anomalies, strongly indicating an igneous origin. This interpretation is also supported by the high Ti-in-zircon temperatures (>700°C) and depleted mantle-like zircon O isotope ratios (5.15±0.57‰, 2SD). Thus, we conclude that the protoliths of the Pianshishan eclogites were generated at ~238Ma. Their geochemistry is similar to the oceanic island basalts (OIB), and they were probably generated by small extents partial melting of enriched oceanic asthenospheric mantle within the garnet stability field and emplaced or erupted as a seamount in the Paleo-Tethys Ocean. We infer the age of eclogite-facies metamorphism to be ~233Ma based on previously reported Lu-Hf isochron ages, and that this metamorphism marks the collision between the Southern and Northern Qiangtang terranes. Thus, metamorphism of the eclogites occurred within 5My of protolith generation and exhumation occurred only 13 to 19 My later, based on the 40Ar/39Ar dates of 220–214Ma. The time between protolith generation and exhumation was thus <24My. This rare rapid evolution may be due to the protoliths having formed as a “petit-spot” seamount in response to outer rise flexure as the Paleo-Tethys Ocean entered the Longmu Co-Shuanghu subduction zone.

Nd-Sr-Os systems of eclogites in the lithospheric mantle of the Kasai Craton (Angola)

We studied the Sm-Nd, Rb-Sr, and Re-Os isotope compositions of mantle xenoliths (eclogites and peridotites) from diamondiferous kimberlites of the Catoca cluster of the Kasai Craton. In the eclogites, the primary strontium isotope composition 87Sr/86Sr varies from 0.7056 to 0.7071, and the neodymium isotope composition eNd, from 1.8 to 2.6. The 187Re/188Os and 187Os/188Os ratios range from 135 to 80 and from 1.3110 to 1.9709, respectively, which indicates a significant portion of radiogenic Os: yOs = 129-147. These isotope values exceed the values assumed for model reservoirs (primitive upper mantle (PUM) and bulk silicate Earth (BSE)) and those of chondrites. The isotope composition of the studied systems indicates the formation of eclogites from a rhenium-enriched source, namely, the subducted oceanic crust transformed as a result of metasomatism and/or melting under upper-mantle conditions.

Varieties of the Himalayan eclogites: A pictorial review of textural and petrological features

AbstractA pictorial review and brief description of metabasites (mainly eclogites) exposed in the western part of Himalaya, north Pakistan are presented. The metabasites occur in the Kaghan and Neelum valleys in the form of thick sheets, dikes, lenses, and zoned bodies. On the basis of petrography and mineral paragenesis, they can be distinguished into greenschist, amphibolites, garnet‐amphibolites, eclogites, amphibolitized eclogites, and garnetites. In this review, first a brief history of the term eclogite and its origin for understanding the process of eclogite formation is presented. Then, a description on the occurrence of various metabasites/eclogites outcrops in the western Himalaya is given. Later, detailed petrological and textural features observed in hand specimen and under the microscope are discussed for individual rock types. Finally, an overview of the Himalayan metabasites tracing back from their magmatic basaltic source to their transformation into amphibolites and eclogites via multi‐stage metamorphism is provided. The field features, with the aid of petrological and geochemical evidence of these metabasites, help to constrain the tectono‐metamorphic evolution of the continent–continent collision type orogenic belts such as the India–Asia collision‐related Himalayan metamorphic belt.

Lithospheric diamond formation as a consequence of methane-rich volatile flooding: An example from diamondiferous eclogite xenoliths of the Karelian craton (Finland)

A collection of 61 xenocrystic and 12 eclogite xenolith-derived diamonds from the 600Ma Lahtojoki kimberlite in central Finland has been investigated. Calculated pressure and temperature conditions for the diamondiferous eclogites are in excess of 5.5GPa and 1300°C, suggesting residence depths greater than 180km, near the base of the Karelian cratonic mantle lithosphere. Geochemically, the eclogite xenoliths have gabbroic compositions showing positive Eu and Sr anomalies, relatively low ΣREE and elevated Al2O3 contents, yet garnets have ambiguous δ18O values of 5.7‰ and 5.9‰. Gabbroic eclogite formation could therefore be linked to either subduction processes during the 1.9Ga Svecofennian orogeny or to cumulate processes during 2.1Ga rift-induced magmatism. Determination of the oxygen fugacity of Lahtojoki eclogite xenoliths from both this work and previous studies suggests that diamond-bearing eclogites may be more reduced (ΔFMQ-3.5) compared to barren eclogites (ΔFMQ-1.7).While recycled oceanic crust protoliths for the eclogites remain a possibility, the carbon isotopic compositions and nitrogen abundances of the Lahtojoki diamonds indicate mantle-derived volatile sources. All diamonds (i.e., loose and eclogite xenolith-derived) display a restricted range of δ13C values from −7.8‰ to −3.7‰ that overlaps with the carbon isotopic composition of Earth’s mantle. The Lahtojoki diamond δ13C values form a negatively skewed distribution, indicating diamond growth from reduced mantle-derived carbon sources such as methane- (CH4) bearing fluids. Nitrogen contents of the Lahtojoki diamonds range from 40 to 1830atomic ppm with a mean of ∼670atomic ppm; these elevated nitrogen contents combined with the close association to eclogites suggest an eclogitic or crustal volatile source. However, the Karelian craton was periodically intruded by ultramafic alkaline magmas since at least 1.8Ga, noting in particular the occurrence of phlogopite-rich kimberlites and olivine lamproites between 1200 and 700Ma. We argue that this punctuated volatile-rich magmatism simultaneously metasomatised the cratonic mantle lithosphere, forming nitrogen enriched phlogopite-bearing metasomes. We propose that reduced, carbon-bearing and nitrogen-rich fluids were remobilized to form the Lahtojoki diamonds. The diamond-forming event(s) most probably occurred during or shortly prior to the entraining kimberlite magmatism as indicated by the diamond nitrogen aggregation systematics. Involvement of reduced diamond-forming fluids is supported by both the negative skewness of Lahtojoki diamond δ13C values and the more reduced nature of the diamondiferous Lahtojoki eclogites compared with their more oxidized barren counterparts. Our results from the diamondiferous eclogites derived from the deepest parts of the Karelian cratonic mantle root are in support of methane being the stable carbon volatile species at the base of thick continental lithosphere.

Early Mesozoic retrograded eclogite and mafic granulite from the Badu Complex of the Cathaysia Block, South China: Petrology and tectonic implications

The high-grade metamorphic terrane in the Badu region along the northeastern Cathaysia Block in South China preserves retrograded eclogites and mafic granulites. Here we present the petrology, mineral phase equilibria and P-T conditions based on pseudosection computations, as well as zircon U-Pb ages of these rocks. Mineral textures and reaction relationships suggest four metamorphic stages for the retrograded eclogite as follows: (1) eclogite facies stage (M1), (2) clinopyroxene retrograde stage (M2), (3) amphibole retrograde stage (M3), and (4) chlorite retrograde stage (M4). For the mafic granulite, three stages are identified as: (1) plagioclase-absent stage (M1), (2) granulite facies stage (M2) and (3) amphibolite facies stage (M3). Metamorphic evolution of both of the rock types follows clockwise P-T path. Conventional geothermometers and geobarometers in combination with phase equilibria modelling yield metamorphic P-T conditions for each metamorphic stage for the eclogite as 500–560°C, 23–24kbar (M1), 640–660°C, 14–16kbar (M2), 730–750°C, and 11–13kbar (M3). The chlorite retrograde stage (M4) is inferred to have occurred at lower amphibolite to greenschist facies conditions. Phase equilibria modelling of the mafic granulite shows P-T conditions for each metamorphic stage as 600–720°C, >13kbar (M1) and 860–890°C, 5–6kbar (M2) and M3 at amphibolite facies conditions. LA-ICPMS zircon U-Pb dating and trace element analysis show that the high pressure metamorphism occurred at 245–251Ma. Protolith age of the mafic granulite is 997Ma, similar to that of the mafic to ultramafic rocks widely distributed in the Cathaysia Block and also along the Jiangnan belt. Subduction of ancient oceanic lithospheric materials (or crustal thickening) during Mesozoic and formation of eclogites suggest that the Cathaysia Block was perhaps in the Tethyan oceanic domain at this time. The granulite formation might have been aided by Mesozoic mafic magma underplating associated with lithospheric delamination, heating and retrogression of the eclogite accompanied by rapid uplift.

Details of the gabbro‐to‐eclogite transition determined from microtextures and calculated chemical potential relationships

AbstractPermian‐aged metagabbros from the eclogite type‐locality in the eastern European Alps were partially to completely transformed to eclogite during Eoalpine intracontinental subduction. Microtextures developed along a preserved fluid infiltration and reaction front in the gabbros record the incipient gabbro‐to‐eclogite transition, allowing the details of the eclogitization process to be investigated. Original, anorthite‐rich igneous plagioclase is pervasively replaced by fine‐grained intergrowths of clinozoisite, kyanite and Na‐rich plagioclase. Where plagioclase was in contact with igneous orthopyroxene, 100–200 μm thick bimineralic coronae of symplectic kyanite and diopsidic clinopyroxene form along the edges of the grains. The rims of igneous orthopyroxene develop a complementary bimineralic corona of diopsidic clinopyroxene and garnet. Igneous clinopyroxene does not show any breakdown textures; however, jadeite content gradually increases towards the rims. In addition, exsolution lamellae inherited from the igneous clinopyroxene become progressively more jadeitic as eclogitization proceeds. Given that the igneous plagioclase is pervasively replaced by clinozoisite, kyanite and Na‐rich plagioclase, whereas kyanite–diopside symplectites are confined to narrow rim zones, we suggest that the development of these textures was controlled by the (im)mobility of different elements on different length scales. The presence of hydrous minerals in the core of anhydrous plagioclase indicates that H2O diffusivity occurred on a mm‐scale. By contrast, the size of the anhydrous diopside–kyanite and diopside–garnet symplectites indicate that Fe–Mg–Ca–Na diffusivity was limited to a 10s of μm scale. Chemical potential relations calculated in the idealized NCASH chemical system show that the clinozoisite–kyanite–albite intergrowths formed due to an increase of μH2O to plagioclase, whereas all other elements remained effectively immobile on the scale of this texture. Fluid conditions indicated by this texture span from virtually dry conditions (0.15) to H2O‐saturation, and therefore does not imply that the rocks were ever fluid‐saturated. Calculations in the CMAS and NCFMAS systems show that the gabbro‐to‐eclogite transition is characterized by the growth of garnet, diopsidic clinopyroxene and kyanite due to diffusion of Ca (+ Na) and Mg (+ Fe) along a μCaO (+ Na2O)–μMgO (+ FeO) chemical potential gradient developed between orthopyroxene and plagioclase compositional domains. The anhydrous nature of the textures indicate that the gabbro‐to‐eclogite transition is not driven by hydration; however, increased μH2O acts as a catalyst that increases diffusivity of all elements and rates of dissolution–precipitation, allowing the overstepped metamorphic reactions to occur. Our results show that crustal eclogite formation requires low H2O content, confirming that true eclogites are dry rocks.

Tectonic significance and redox state of Paleoproterozoic eclogite and pyroxenite components in the Slave cratonic mantle lithosphere, Voyageur kimberlite, Arctic Canada

Mantle-derived eclogite and pyroxenite xenoliths from the Jurassic Voyageur kimberlite on the northern Slave craton in Arctic Canada were studied for garnet and clinopyroxene major and trace element compositions, clinopyroxene Pb and garnet O isotopic compositions, and garnet Fe3+/ΣFe contents. The Voyageur xenoliths record a wide range of pressures, but are cooler compared to mantle xenoliths derived from the nearby, coeval Jericho kimberlite. The CaO, TiO2 and Zr contents of Voyageur eclogites increase with depth, which is also observed in northern Slave peridotite xenoliths, demonstrating ‘bottom-up’ metasomatic processes within cratonic mantle lithosphere.The Voyageur eclogites have positive Eu anomalies, flat HREEN patterns, and major element compositions that are consistent with ultimate origins from basaltic and gabbroic protoliths within oceanic lithosphere. Clinopyroxene Pb isotope ratios intercept the Stacey-Kramers two-stage terrestrial Pb evolution curve at ca. 2.1Ga, and form an array towards the host kimberlite, indicating isotopic mixing. The 2.1Ga eclogite formation age broadly overlaps with known Paleoproterozoic subduction and collision events that occurred along the western margin of the Slave craton. Unlike the eclogites, the Voyageur pyroxenites contain garnet with distinctive fractionated HREEN, sinusoidal REE patterns of calculated bulk rocks, and clinopyroxene with 206Pb/204Pb ratios that intercept the Stacey-Kramers curve at 1.8Ga. This suggests a distinct origin as Paleoproterozoic high-pressure mantle cumulates. However, the pyroxenite Pb isotope ratios fall within the eclogite array and could also be explained by protoliths formation at ca. 2.1Ga followed by minor isotopic mixing during mantle metasomatism. Thus, an alternative scenario involves pyroxenite formation within the mantle section of Paleoproterozoic oceanic lithosphere followed by variable metasomatism after incorporation into cratonic mantle lithosphere. This model allows for a linked petrogenesis of the Voyageur eclogites (crust) and pyroxenites (mantle) as part of the same subducting oceanic slab.Oxygen fugacity determinations for one pyroxenite and ten eclogite xenoliths show a range of 3 log units, from −4.6 to −1.6 ΔFMQ, similar to the range observed for nearby Jericho and Muskox eclogites (ΔFMQ −4.2 to −1.5). Importantly, the northern Slave eclogite and pyroxenite mantle components are highly heterogeneous in terms of redox state provided that they range from reduced to oxidized relative to Slave peridotite xenoliths.Moreover, the Voyageur eclogites do not exhibit any trend between oxidation state and equilibration depth, which contrasts with the downward decrease in fO2 shown by Slave and worldwide cratonic peridotite xenoliths. Our investigation of mantle eclogite and pyroxenite fO2 reinforces the important influence of recycled mafic components in upper mantle processes, because their high and variable redox buffering capacity strongly controls volatile speciation and melting relations under upper mantle conditions.

Argon, oxygen, and boron isotopic evidence documenting 40ArE accumulation in phengite during water-rich high-pressure subduction metasomatism of continental crust

The Luliang Shan area of the North Qaidam high pressure (HP) to ultrahigh pressure (UHP) metamorphic terrane in northwestern China features thick, garnet- and phengite-rich metasomatic selvages that formed around gneiss-hosted mafic eclogite blocks during HP conditions. Here we present new 40Ar/39Ar, δ18O, and δ11B results from a previously studied 30 m, 18 sample traverse that extends from the host gneiss into a representative eclogite block. Previous thermobarometry and new mica-quartz oxygen isotope thermometry from the traverse reveal that the phengite-rich selvage formed at temperatures similar to those recorded by the eclogites at peak pressure. Quartz and white mica δ18O data from the selvage cannot be explained by simple mixing of gneiss and eclogite, and indicate a fluid/rock ratio >1 during regional-scale infiltration of high δ18O (ca. 14‰) fluids. Heavy δ18O overgrowths of metamorphic zircon over lighter δ18O detrital grains indicate that the gneiss was similarly affected. Starkly contrasting boron content and δ11B compositions for the host gneiss and the selvage also cannot be explained by local-scale devolatilization of the gneiss to form the selvage. Instead, the boron systematics are best attributed to two distinct phases of fluid infiltration: (1) low-boron selvage phengite with δ11B from −10 to −30‰ grew under HP conditions; and (2) tourmaline and boron-rich muscovite with generally positive δ11B crystallized in the host gneiss under subsequent lower pressure epidote–amphibolite facies conditions as the Luliang Shan gneiss terrane was exhumed past shallower portions of the subduction channel. Consistent with observations made worldwide, we were able to identify uptake of excess argon (40ArE) in phengite as a high pressure phenomenon. Phengite 40Ar/39Ar ages from massive eclogite exceed the ca. 490 Ma zircon U–Pb age of eclogite metamorphism by a factor of 1.5. However, phengite ages from the more permeable schistose selvage were even older, exceeding the time of eclogite formation by a factor of 1.7. In contrast, lower pressure retrograde muscovite present within the host gneiss and in discrete shear zones cutting the selvage yield 40Ar/39Ar ages that were younger than the time of HP metamorphism and consistent with regional cooling age patterns. Our observation of high 40ArE concentrations in phengite from schistose rocks infiltrated by regionally extensive fluids at HP conditions runs contrary to widely held expectations. Conventional wisdom dictates that low phengite/fluid partition coefficients for argon (Dphg/fluidAr=10−3to10−5) coupled with the dry, closed systems conditions that are widely reported to characterize HP metamorphism of continental crust explains why high concentrations of 40ArE partitions are able to accumulate within phengite. We alternatively propose that phengite/fluid partition coefficients for argon increase linearly with pressure to values as high as 10−2 to allow phengites to accumulate large amounts of 40ArE from aqueous fluids under HP to UHP conditions.

Syn-collapse eclogite metamorphism and exhumation of deep crust in a migmatite dome: The P–T–t record of the youngest Variscan eclogite (Montagne Noire, French Massif Central)

In many orogens, high-pressure (HP) metamorphic rocks such as eclogite occur as lenses in quartzofeldspathic gneiss that equilibrated at much lower pressures. The pressure–temperature–time (P–T–t) history of eclogite relative to host gneiss provides information about mechanisms and timescales of exhumation of orogenic crust. The Montagne Noire of the southern Massif Central, France, is an eclogite–bearing gneiss (migmatite) dome located at the orogen-foreland transition of the Variscan belt. Results of our study show that it contains the youngest eclogite in the orogen, similar in age to migmatite and granite that crystallized under low-pressure conditions. P–T conditions for an exceptionally unaltered eclogite from the central Montagne Noire were estimated using a pseudosection supplemented by garnet–clinopyroxene and Zr-in-rutile thermometry. Results indicate peak P∼1.4 GPa and T∼725°C for Mg-rich garnet rim (50 mol% pyrope) + omphacite (36 mol% jadeite) + rutile + quartz. U–Pb geochronology (LA-ICP-MS) of 16 zoned zircon grains yielded ∼360 Ma (4 cores) and ∼315 Ma (12 rims and cores). Rare earth element abundances determined by LA-ICP-MS for dated zircon are consistent with crystallization of ∼315 Ma zircon under garnet-stable, plagioclase-unstable conditions that we interpret to indicate high pressure; in contrast, the ∼360 Ma zircon core corresponds to crystallization under lower pressure plagioclase-stable conditions. Based on garnet zoning and inclusion suites, rutile textures and Zr zoning, P–T results, and zircon petrochronology, we interpret the ∼315 Ma date as the age of eclogite-facies metamorphism that only slightly preceded dome formation and crystallization at 315–300 Ma. This age relation indicates that eclogite formation at high pressure and migmatite dome emplacement at low pressure were closely spaced in time. We propose that collapse-driven material transfer from the hot orogen to the cool foreland resulted in thickening of the orogen edge, leading to eclogite facies metamorphism of the deep crust. Soon after, the low-viscosity partially molten crust flowed from the plateau toward the foreland, incorporating and exhuming eclogite. The P–T–t history of the Montagne Noire eclogite shows that some dome material ascended from >40 km depth to shallow crustal levels, likely in a single decompression event, and that migmatite domes are therefore very efficient at exhuming the deep crust.

Chromium-rich kyanite, magnesiostaurolite and corundum in ultrahigh-pressure eclogites (examples from Pohorje Mountains, Slovenia and Tromsø Nappe, Norway)

Chromium-rich kyanite, magnesiostaurolite and corundum (ruby) were found in ultrahigh-pressure (UHP) eclogites associated with garnet peridotite and serpentinite from Pohorje Mountains (Eastern Alps) and the Tromso Nappe (Northern Scandinavian Caledonides). The concentrations of Cr 2 O 3 in kyanite and magnesiostaurolite from the Pohorje Mts. (17.0 and 15.0 wt%, respectively) are the highest Cr values ever reported for these minerals, and the Cr content of corundum from this area (≤12.2 wt% Cr 2 O 3 ) also belong to the highest reported from natural samples. The Cr-rich kyanite of turquoise-blue colour contains inclusions of chromite (Cr* = 0.74–0.78) and Cr-rich magnesiostaurolite (6 to 15 wt% Cr 2 O 3 ; X Mg = 0.7–0.8). Kyanite is commonly surrounded by a corona composed of the assemblage Cr-bearing sapphirine (up to 5.5 wt% Cr 2 O 3 ) + corundum + Al-rich spinel + plagioclase. Blue-green, Cr-rich magnesiostaurolite (5.4–8.5 wt% Cr 2 O 3 ; X Mg = 0.76–0.82) forming ≤500 μm large crystals is associated with Cr-rich kyanite, Cr-rich spinel and Cr-rich corundum which are surrounded by pargasitic amphibole and zoisite. Chromium enrichment in kyanite, magnesiostaurolite and corundum was controlled by substitution for Al in the octahedral sites (Cr 3+ Al −1 ). Magnesiostaurolite compositional variations indicate at least two additional substitutions: Fe 2+ Mg −1 and M 2+ Si(Al,Cr) −2 , where M 2+ are the divalent cations Mg, Fe, Mn, Ni and Zn. The highest Si content and near absence of tetrahedrally coordinated Al was observed in the most Cr-rich magnesiostaurolite. Chromian kyanite, magnesiostaurolite and ruby formed by reactions involving primary chromite derived from a magmatic protolith characterized by high Cr, Mg, Al and low Si, during prograde metamorphism and formation of eclogite at HP-UHP conditions.

Prograde transformations of amphibolites into eclogites and eclogite-like rocks in the low-pressure field of the eclogite facies (by the example of the Belomorian Mobile Belt)

Plagioclase-bearing garnet-omphacite (Grt-Omp) eclogites and garnet-augite eclogite-like (Grt-Aug) schists from the amphibolite and gneiss beds of the Belomorian Mobile Belt have been studied. They are spread over a large area. In most of the studied objects, these rocks have preserved primary concordant relations with the host amphibolite and gneiss strata; they are not disturbed by late tectonic processes and are not genetically related to tectonic-melange zones. Their protoliths were amphibolite lenses in gneisses or large mafic zones composed of amphibolites. The Grt-Omp eclogites formed in the low-pressure field of the eclogite facies (P = 12.5-13.0 kbar, T = 600-630 °C), and the eclogite-like Grt-Aug rocks, at the boundary between the amphibolite and eclogite facies (P = 9.6-11.1 kbar, T = 630-700 °C), under the intense impact of metamorphic fluid on the amphibolites. The compositional evolution of the rock-forming minerals during the formation of Grt-Omp eclogites and eclogite-like Grt-Aug rocks followed the same scheme. The petrographic diversity of apoamphibolite rocks (Grt-Omp eclogites and Grt-Aug schists) might be due to the difference both in the bulk composition of the metabasic protolith and in the ratios of CaO and Na2O activities in the metamorphic fluid. The relatively low content of CaO leads to the formation of Grt-Omp paragenesis in eclogites. Higher CaO contents give rise to eclogite-like Grt-Aug rocks containing jadeite-poor clinopyroxene.

The fall and rise of metamorphic zircon

Zircon geochronology and geochemistry are increasingly important for understanding metamorphic processes, particularly at extreme conditions, but drivers of zircon dissolution and regrowth are poorly understood. Here, we model Zr mass balance to identify P-T regions where zircon should dissolve or grow. Zirconium contents of major metamorphic minerals were assessed from published data and new measurements, and models were constructed of mineralogical development and zircon abundance for hydrous MORB and metapelitic compositions along representative P-T paths. Excluding zircon, the minerals rutile, garnet, and hornblende strongly influence Zr mass balance in metabasites, accounting for as much as 40% of the whole-rock Zr budget. Clinopyroxene and garnet contain more Zr than plagioclase, so breakdown of plagioclase at the amphibolite to eclogite facies transition, should cause zircon to dissolve slightly, rather than grow. Growth of UHP zircon is predicted over a restricted region, and most zircon grows subsequently at much lower pressure. In metapelites, zircon is predicted to undergo only minor changes to modal abundance in solid state assemblages. Partial melting, however, drives massive zircon dissolution, whereas melt crystallization regrows zircon. From a mass-balance perspective, zircon growth cannot be attributed a priori to the prograde amphibolite-eclogite transition, to UHP metamorphism, or to partial melting. Instead, zircon should grow mainly during late-stage exhumation and cooling, particularly during oxide transitions from rutile to ilmenite and melt crystallization. As predicted, most zircons from HP/UHP eclogites of the Western Gneiss Region and Papua New Guinea substantially postdate eclogite formation and maximum pressures.

Receiver function imaging of crustal suture, steep subduction, and mantle wedge in the eastern India–Tibet continental collision zone

To understand the along-strike variation of crustal deformation and tectonic processes in the India–Tibet continental collision zone, we deployed a linear array of broadband seismic stations along 92° E to image lithospheric structure. Our receiver-function cross-section reveals a prominent negative converter dipping ∼20° north from ∼10–55 km depth below sea-level, almost through the whole crust, beneath the southern Lhasa terrane. We interpret it to be a manifestation of the Yarlung–Zangbo suture zone (YZS) separating the continental crust of the Indian and Eurasian plates. This implies the hypothesized channel-flows of Indian middle crust extruding southwards from Tibet are limited at this longitude to the southernmost portion of the Lhasa terrane. A positive converter, consistent with previous suggestions of eclogite formation, is seen about 10–15 km above the Moho and continuing 50 km north of the 20°-dipping YZS converter. We image this positive converter continuously from ∼60 km south of the surface trace of the YZS to the vicinity of the Jiali fault, supporting the interpretation of sub-horizontal underplating of Tibetan crust by Indian crust to ∼31° N at 85° E on the Hi-CLIMB transect. However, we also show a negative mantle converter sub-parallel to the crustal YZS converter, from the northern limit of the underplating Indian lower crust to at least 140 km depth, that we interpret as the base of Tibetan lithosphere overlying an asthenospheric mantle wedge. Based on the lithospheric structure observed in this and other studies, we infer that Indian mantle lithosphere currently detaches from Indian lower crust at the “mantle suture” that is nearly 50 km south of the surface trace of the YZS at 92° E, south of the mantle suture suggested by INDEPTH transect beneath the surface trace of the YZS at ∼90° E, and far south of the mantle suture suggested to be at the 31° N northern limit of underthrusting Indian lower crust suggested by Hi-CLIMB transect at ∼85° E. A change from underplating in the west to steep subduction in the east can reconcile all these observations.

Combined geochemistry and geochronology constrains coupled subduction of oceanic and continental crust in the Huwan shear zone, central China

Subduction of rocks into the mantle results in high-pressure metamorphism and the formation of eclogites from basaltic precursor rocks. In general, many kilometers of oceanic lithosphere are ultimately consumed prior to the subsequent continental slab subduction and collision. The exposure of the eclogites derived from oceanic subduction and continental subduction at the surface of Earth today record provide different P-T-t records of the subduction process. The Huwan shear zone in the Hong’an orogenic belt, marking a former ocean-continent transition zone, has been the focus of many studies on subduction-related high-pressure metamorphism. In this study, Lu-Hf garnet, U-Pb zircon, and Ar- Ar mica ages are combined with geochemical data to understand the origin of two coexisting eclogite bodies exposed along the Xuehe River in the Huwan Shear zone. In total, the results indicate that the two eclogites have different protoliths but experienced a similar metamorphic history. This observation requires new tectonic model for the coupled subduction of oceanic and continental crust in subduction zones. Combined geochemistry and zircon U-Pb geochronology suggest distinct oceanic and continental affinities for the eclogite protoliths. The Lu-Hf dates of 261.5 ± 2.4 Ma of the continental-type eclogite and 262.7 ± 1.7 Ma of the oceanic-type eclogite reflect garnet growth and are interpreted to closely approximate the age of eclogite-facies metamorphism. Therefore, both the geochemically oceanic- and continental-type eclogites underwent the same episode of Permian eclogite-facies metamorphism. The Permian Lu-Hf ages of ca. 262 Ma and the obtained Triassic Ar-Ar ages (~240 Ma) of the oceanic-type and continental-type eclogites imply coupled subduction and exhumation of oceanic and continental crustal materials in the Hong’an orogenic belt during the Permian and the Triassic. Though limited, the geochemical and geochronological results of this study, together with the discrepant Carboniferous dates for the nearby eclogites of previous studies, apparently suggest that the Huwan shear zone was not always a single coherent unit but instead comprises different tectonic slices that were metamorphosed at different times before final assembly. Some slices of the oceanic and continental crust underwent two subduction cycles during the Carboniferous and the Permian, whereas some eclogites registered only a single subduction-exhumation loop during the convergence between the South China Block and the North China Block in the Huwan shear zone. The consistent ages of the oceanic- and continental-type eclogites disfavor the traditional mélange model that high-pressure rocks are dismembered fragments that have been assembled and intercalated with rocks devoid of any high-pressure history at shallow crustal levels, forming a tectonic mélange.