The objective of this paper is to validate and evaluate the orbit accuracy of the BeiDou Navigation System (BDS) using satellite laser ranging (SLR) data over a 5-year time series. The microwave-based precise orbits of BDS derived from four Analysis Centers (ACs) are validated from 2013 to 2018, including three Multi-GNSS EXperiment (MGEX) ACs from WHU, CODE and GFZ, as well as a fourth AC, known as ISC in China, with the corresponding products designated as WUM, COM, GBM and ISC. The validated orbits of BDS include the Geostationary Earth Orbit (GEO) satellite of C01, the Inclined Geo-Synchronous Orbit (ISGO) satellites of C08, C10, and C13, as well as the Medium Earth Orbit (MEO) satellite of C11. In addition, the performances of the BDS orbits during noneclipse, eclipse and Yaw Maneuver (YM) period are evaluated. Finally, the dependencies of SLR residuals on the satellite nadir angle and on the Sun elevation angle β are analyzed in detail. The results demonstrated that (1) the optimal orbit accuracies of C01, C08, C10, C11 and C13 are 522.8 mm from WUM, 53.3 mm from ISC, 54.3 mm from ISC, 38.2 mm from ISC and 51.5 mm from COM, respectively. And the orbits derived from ISC have more stable and excellent accuracy than the other ACs due to the advantages of its orbit combination algorithm. (2) Due to the deficiencies of the Solar Radiation Pressure and the YM modeling for BDS satellites from four ACs, the microwave-based orbit accuracy of BDS IGSO and MEO satellites is significantly deteriorated during the eclipse period, especially in the YM period, while the accuracy of GEO C01 during the eclipse period is better than that during the noneclipse period. (3) The dependency of SLR residuals on the satellite nadir angle has been analyzed, but limited by the number and type of all the validated BDS satellites, the nadir-dependency offset of the SLR residuals cannot be well assigned from the characteristics of the SLR detector system, or the Laser Retro-reflector Arrays. (4) By analyzing the dependency of SLR residuals on the Sun elevation angle β, some commonalities of the patterns derived from four ACs have been found for BDS IGSO and MEO satellites, and the patterns are similar to that of the GLONASS, rather than those of GPS and Galileo.