Early Cementation Research Articles

Hydration Hardening of Early Strength Low-Heat Cement under a Low-Pressure Environment

Hydration Hardening of Early Strength Low-Heat Cement under a Low-Pressure Environment

One-part alkali-activated GGBFS as a cement for enhancing compacted filtered iron ore tailings disposal by stacking

Brazil is one of the top world iron ore producers. However, it implies the generation of millions of tons of iron ore tailings (IOTs). Dewatering technologies now permit the obtainment of a compactable geomaterial rather than the slurry consistency tailings that were commonly stored in impoundments. Thus, this filtered compacted geomaterial can be stacked in piles. In this regard, the incorporation of small amounts of cement into the filtered tailings has the potential to strengthen the geomaterial. By using alkali-activated binders, strengthening the IOTs’ mechanical properties can be achieved with minimum environmental drawbacks. Accordingly, the present study evaluates the strength, mineralogy, and microstructure of compacted iron ore tailings-binder blends. A one-part alkali-activated cement (AAC) composed of ground granulated blast furnace slag (a residue of steel industry), sodium silicate, and sodium hydroxide was used, highlighting the circular economy appeal of this cement. A response surface approach was used in the definition of this cement’s composition. As well, tests using a commercially available high early-strength Portland cement were conducted. The optimized AAC outperformed the early strength Portland cement regardless of the test conditions, associated with the formation of a more developed cementitious matrix (C-S-H and C-A-S-H gel of amorphous structure).

Evolution of early hydration in mortar by using waste dolomite powder as a micro-aggregate

The evolution of early hydration in cement – based material is always one of important issues for investigating their engineering application. This study investigated the early hydration reaction of mortars containing different waste dolomite powder (WDP) contents. Compared to the reference sample (WDP0), the hydration process, hydration products, pore structure and mechanical properties of samples prepared by WDP were studied at the early stage. For the hydration process, the 1H low – field nuclear magnetic resonance (NMR) and chemical shrinkage testing results indicated that the process of early hydration of cement could be significantly accelerated by incorporating WDP. Meanwhile, the quantities of hydration products (Portlandite and calcite) in samples with WDP have a significant variation by X-ray diffraction results and thermogravimetric analysis. In addition, the WDP40 has denser pore structure and higher mechanical properties than WDP0. After curing 3 d, the pore volume of WDP40 has a reduction of 17.84 %, the flexural and compressive strength of WDP40 were increased by 6.6 % and 18.06 %, respectively. Based on the mechanism analysis, the filling effect and nucleation effect of WDP in mortars contributed to the improvement of early cement hydration. This study is meaningful to evaluate the impact of WDP on the evolution of early cement hydration, which is expected to offer a reliable reference for the application of inert materials in cement – based materials.

Effect of Wet Grinding Concrete Slurry Waste on Hydration and Hardening Properties of Cement: Micro-Nano-Scale Modification.

The concrete slurry waste (CSW) produced by concrete mixing plants is a type of hazardous waste that is difficult to handle. To better recycle the CSW separated from the aggregates, this study uses a variety of wet-grinding processes to refine the solid in it, replaces some of the cement with the solid particles in wet grinding concrete slurry waste (WCSW), and investigates the properties of WCSW and its effect on the hydration and hardening properties of cement. The results show that a suitable wet-grinding process can ensure that the particle size in WCSW is less than 10 μm, the particle morphology is more flat, and the degree of hydration is higher. The WCSW particles can promote early cement hydration; after adding WCSW, the heat release peak of cement hydration appears earlier and more early hydration products are produced, and with the increase in the substitution amount, the promoting effect on early cement hydration will be more significant. The WCSW particles have a great effect on improving the strength of mortar, especially in the early stage. At 1 d, when the substitution amount is 7.5 wt.%, the compressive and flexural strength is increased by 43.67% and 45.04%; this is related to the filling of matrix pores and the improvement of the interface transition zone by micro- and nanoparticles. After the wet grinding of CSW, fine WCSW particles are obtained, which can improve the performance of cement-based materials by replacing cement.

Microstructure, mechanical properties and interaction mechanism of seawater sea-sand engineered cementitious composite (SS-ECC) with Glass Fiber Reinforced Polymer (GFRP) bar

With increasing demand for sustainable and long-lasting materials, seawater sea-sand engineered cementitious composite (SS-ECC) has emerged as a promising alternative to conventional concrete in near-ocean construction projects. Glass fiber reinforced polymer (GFRP) bar with excellent corrosion resistance is an ideal choice for these applications. This study evaluated the bond performance of GFRP bars embedded in normal-strength ECC with polyvinyl alcohol (PVA) fibers and high-strength ECC with polyethylene (PE) fibers through pull-out tests. Additionally, tests were conducted on GFRP bars in pristine ECC made with freshwater and river sand for comparison. Further investigation explored the structural properties and uncovered load transfer mechanisms. Results indicated that saline content facilitated early cement hydration of normal-strength ECC, resulting in finer pore structure (10.5% lower porosity and 12.5% lower sorptivity), slightly enhanced compressive performance (1.2% higher compressive strength and 8.3% higher elastic modulus), denser microstructure at GFRP-ECC interface (13.7% lower porous transition zone thickness, 19.2% narrower transition zone and 19.7% higher Ca/Si ratio), and superior bond performance (28.3% higher bond strength and 22.6% higher fracture energy). Conversely, saline content imposed a limited impact on the mechanical properties of high-strength ECC, primarily attributed to the ultra-fine microstructure and early strength characteristics exhibited by the silica fume (SF)-based cementitious binder.

Dolomitization history and fluid evolution of end-ediacaran multi-phase dolomites from the near-surface to deep burial depths in the tarim craton, northwestern China

The deeply buried (>8 km) end-Ediacaran Qigebrak Formation dolostones in the Tarim Basin, China, have significant petroleum potential, but have experienced multi-stage dolomitization that has resulted in the occurrence of diverse dolomite phases. The features and origins of the different dolomite types were merely investigated, which hinders an in-depth understanding of the complex dolomitization processes. This paper presents an integrated petrological, geochemical (C–O–Sr isotope and in situ trace element), fluid inclusion microthermometric, and dolomite U–Pb dating study of outcrop and core samples, to investigate the dolomitization mechanisms, and the nature and evolution of the dolomitizing fluids. The results indicate the occurrence of early dolomitization triggered by seepage–reflux of mesosaline seawater, which retained the primary marine geochemical properties of most of the matrix dolomite. Subsequently, during early diagenesis, fibrous dolomite cement was precipitated from marine porewaters, which have similar geochemical characteristics to the matrix dolomites. Following this, during intermediate-depth burial diagenesis in the Ordovician, fine-to medium-crystalline dolomite cements formed at temperatures of 80–117 °C in association with dissolution–reprecipitation of the matrix and early fibrous cements or diagenetic interactions with clay minerals of the lower Cambrian Yurtus Formation shales. During deep burial diagenesis and dolomitization in the Carboniferous, coarse-crystalline dolomite cements formed at temperatures of 104–138 °C from saline brines enriched in middle rare earth elements. Saddle dolomites, formed by hydrothermal dolomitization (162–184 °C) that was closely related to Permian–Triassic volcanic activity, have positive Eu anomalies and depleted δ18O values, that resulted from the mixing of basinal brines with 87Sr-enriched hydrothermal fluids. This study provides a detailed description of multiple dolomitization events in deep time that affected deeply buried dolostones.

Calcareous bioconstructions formation during the last interglacial (MIS 5) in the central Mediterranean: A consortium of algal, metazoan, and microbial framebuilders (Capo Colonna - Crotone basin - South Italy)

The last interglacial (MIS 5) transgressive-regressive deposits of the Capo Colonna marine terrace provide a good fossil example of a Central Mediterranean infra/circa-littoral setting, characterized by both calcareous coralline algae-dominated low-relief bioherms and biostromes, equivalent respectively to the modern coralligenous and mäerl habitats. The skeletal primary framework of the bioherms, consists of laminar to massive encrusting coralline red algae acting as main bioconstructors, with minor bryozoans, encrusting foraminifera, and serpulids as secondary frame-builders. Whereas, the autochthonous mäerl tabular beds are mainly composed of free-branched coralline red algae rudstone. A variable amount of sandy bioclastic sediment is laterally interbedded with the bioconstructions and tends to be entrapped in their cavities and pockets. All sedimentary sub-facies of the bioconstructions and associated sediment are rich in autochthonous syn-sedimentary microbial-mediated micrite, forming aphanitic, peloidal, clotted peloidal, and filamentous fabrics. Microbial micrite can also trap and bind a variable amount of grains, or be a secondary component of the sandy sediment as micritic rims surrounding the clasts. All these early-lithified micrites show the typical nanostructure of the primary microbial-mediated carbonates, rather than a detrital mud particles accumulation, as they consist of nanospheres coalescing into subhedral microcrystals that replace both microbial cells (present with several morphological types) and extracellular substances. This in turn implies the original widespread presence of benthic lithifying microbial biofilms which colonized both the cavities of the skeletal framework of the bioconstructions, and the intergranular space of the associated sediment. These microbial communities, thanks to the metabolic processes of the microorganisms that induced the carbonate precipitation, significantly contributed to the early cementation of all the studied deposits.

Unraveling marine phosphogenesis along the Miocene coast of Peru: Origin and sedimentological significance of the Pisco Formation phosphorites

Phosphorite deposits form through phosphogenesis, a mechanism of diffusion and concentration of interstitial phosphate in sediments leading to Ca-phosphate mineral precipitation in a favorable sedimentary regime at the seafloor. Stretching along the Peruvian coast, the East Pisco Basin is known to host phosphorite beds of Miocene age. In this study, we investigate the petrographic, mineralogical and chemical composition of the Miocene phosphorite layers of the East Pisco Basin, and discuss the phosphogenetic mechanism(s) and sedimentary dynamics that led to the genesis and accumulation of P-rich deposits. Phosphorite samples were collected from layers overlaying stratigraphic unconformities within the Pisco Formation and subsequently analyzed through multiple methods: optical microscopy, XRD, XRF, SEM-EDS, EPMA, ICP-MS and LA-ICP-MS. Our results indicate that these layers consist of phosphatic clasts and nodules along with dolomite clasts, basement boulders, shark teeth, mollusk molds and vertebrate bone fragments. The P-rich clasts are mainly composed of phosphatic intraclasts and small phosphatic nodules. They occur associated with minor amounts of dolomite clasts coated by Fe-oxyhydroxides and laminites. Clasts and nodules are cemented by both early and late diagenetic cements, such as dolomite, calcite, silica, gypsum/anhydrite and baryte. Our observations suggest that the Pisco phosphorite deposits are transgressive lags laying on ravinement surfaces. They formed just below the sediment-water boundary during the early transgression phases, when the porewaters were enriched in phosphorus due to the abundance of organic-rich sediments and the microbial activity, as typical of upwelling settings. These deposits formed in shallow marine conditions, characterized by high biological productivity and low net sedimentation rates, with suboxic conditions at and beneath the sediment-water interface. The concentration of phosphate-coated clasts was then favored by a sedimentary condensation mechanism of dynamic bypassing. Overall, this study provides new insights into the genesis of phosphorite layers in the East Pisco Basin and highlights the importance of understanding the complex interplay between authigenic and sedimentological processes in the formation of these economically and geologically relevant sedimentary rocks.

Petrography and Diagenesis of Thin-Bed Reservoirs from the Eastern Folded Belt of Bangladesh

The main purpose of the study is to identify the thin-bed reservoirs of the Eastern Folded Belt (Sylhet and Bandarban) and characterize them with diligence. A detailed qualitative and quantitative analysis has been carried out. It is based on thin-section petrographic analyses of sandstone samples. These samples are from the reservoir horizons of the Sylhet region and Bandarban region fields. The purpose of this analysis is to characterize the textural and mineralogical properties. Additionally, it aims to evaluate the post-depositional diagenetic changes. The results obtained from the field and laboratory analysis are studied extensively to characterize the thin-bed reservoirs. Samples from the Sylhet area are medium-coarse-grained, fairly sorted, tight packing, submature-mature sublithic characteristics. Contrarily, samples from the Bandarban region are mature-submature sublithic arenites, which are fine-medium-grained, moderately well-sorted, and moderately loosely packed. Despite the similarity of the detrital elements (quartz, feldspar, lithic grains, mica, etc.) in the two areas, silica cementation is more frequent in Sylhet region samples than early carbonate cementation in Bandarban region samples. Comparatively speaking, the sediments in the Sylhet region are more compact than those in the Bandarban region. The most important outcome of this study is that the thin bed of the unconventional reservoir and the conventional reservoir are in close proximity. The Thin-bed reservoir units of the Eastern Folded Belt are found to be medium to fine-grained and well sorted, with frequent alteration of sand-shale with the prevalence of parallel bedded sandstone. Average porosity is 4% to 12%, and pore spaces are interconnected. So, the permeability rate is good enough to flow the hydrocarbon through these pore spaces. Most importantly, the thin bed and tight reservoir (average porosity 4% to 12%, but pore spaces are not interconnected) are not more prominent than 1 meter or 2 meters. Subsequently, though the vertical thickness is not so high, they keep up a momentous tirelessness of horizontal progression. On the contrary, at whatever point it comes to a conventional reservoir, the vertical thickness is higher than that of the unconventional reservoir. But their lateral persistence is not as long as unconventional ones.

Chitosan-Cement Composite Mortars: Exploring Interactions, Structural Evolution, Environmental Footprint and Mechanical Performance.

The increasing environmental concerns about synthetic polymers as reinforcement in the construction industry have highlighted the need for eco-friendly, biodegradable fibers as potential alternative materials for cementitious composites. This study examines the influence of chitosan particle concentrations on the midterm compressive strength of mortars. Chitosan particles, derived from shrimp shells, were mixed with high early strength hydraulic cement at various percentages (0, 0.05, 0.25, 0.5, 1, and 2 wt %) and silica sand to prepare the mortar samples. The findings indicate that chitosan affects the hydration process through the distribution of chitosan particles within the mortar matrix and slightly improved midterm mechanical properties. A life cycle assessment (LCA) revealed a slight increase in greenhouse gas emissions and embodied energy for chitosan-modified mortars, likely due to the use of chemicals in the chitosan synthesis and purification process. In fact, the addition of 0.25 wt % of chitosan into the mortar only added 1.3% of the global warming potential of the sample when compared to the control sample. Incorporating chitosan into a mortar matrix does not significantly affect the resistance-mechanical properties of the composite. The hydration of the cement mortar appears to be slowed by the inclusion of chitosan particles in the cementitious matrix. This research lays the groundwork as one of the first studies for the development of high-performance, early strength cement using chitosan, contributing to a more sustainable construction industry.

Geomorphological features along the shelf of the southern Brazilian margin: Implications for shallow-water sediment transport induced by ocean currents

Chirp profiles collected on the southern Brazilian shelf were combined with sedimentological and hydrodynamic data to characterize shelf geomorphology, focusing on the development of outer shelf bedforms and their genetic links with major oceanic currents. Outer shelf sediment accumulations are interpreted as two scales of bedforms, such as dunes and sand ridges. In the São Paulo Bight, cuspate bedforms are bounded landward by a geomorphological scarp. The sector between Florianopolis and Mostardas also exhibits frequent asymmetric bedforms, whereas the inner- middle shelf is covered by semitransparent sheets. The southern Rio Grande Cone is characterized by stratified deposits covering vast outer shelf areas. Surficial sediment samples reveal a dominantly muddy composition and relatively high carbonate contents. Hydrodynamic data indicate a major influence of the Brazil Current over the São Paulo Bight. The prolific bedform outer-shelf environment is assumed to be mostly relict formed in a transgressive shallow-water setting. The sand ridges are believed to have evolved from a moribund stage characterized by morphological degradation to a relict stage, with preservation enhanced by fine-grained winnowing, coarse sediment armoring, and early cementation. Bedform migration seems to be occurring on the São Paulo Bight due to the presence of a nearly permanent meander of the Brazil Current. Over most of the inner shelf, the northward advection of sediments mainly led by the Brazilian Coastal Current has formed extensive fine-grained deposits. The occurrence of a relict shelf scarp may have conditioned the formation of the outer-shelf bedform environment. The vast spatial distribution of bedforms over most of the outer shelf seems comparable with other shelf areas, such as the south African shelf, dominated by the influence of unidirectional oceanic currents. Dune dimensions are lower on the Brazilian shelf, due to their relict character, the geomorphological configuration of the margin, and the scarcity of sand sources.

Diagenetic Genesis and Evolution of Coal-Bearing Tight Sandstone Reservoir in the Yangxia Formation, Northern Kuqa Depression, Tarim Basin.

Coal seams of the Yangxia Formation are widespread in the northern part of the Kuqa Depression in the Tarim Basin. During the thermal evolution of the coal seams, the generated fluids of different periods and natures have a significant impact on tight sandstone reservoirs. To further investigate the diagenetic characteristics and reservoir genesis of the tight sandstones due to the influence of coal seams, an in-depth exploration of the causes of dissolution and cementation in the reservoirs was conducted through thin-section casting, cathode luminescence, scanning electron microscopy, carbon-oxygen isotopic analyses, and X-ray diffraction of whole rock and authigenic clay minerals, along with burial evolution history and fluid evolution history. It is suggested that two phases of acidic fluids are mainly produced during the thermal evolution process of coal seams, including an early humic acid and a late organic carboxylic acid. The early phase humic acid plays a purifying role in reservoirs with coarse particles, rigidity-rich particles, and good permeability conditions. It selectively dissolves sedimentary calcareous mud and calcite, and the dissolution products are completely migrated. At the same time, it inhibits early carbonate cementation. The late organic carboxylic acid will dissolve potassium feldspar and some volcanic rock debris, and the dissolution products are difficult to migrate under the sealing conditions caused by lithological differences, which often take the cementation form of siliceous overgrowth and kaolinite or illite. In addition to the cementation resulting from the dissolution products of acidic fluids produced by the coal seams, the CO2-rich fluids generated by the coal seam thermal evolution will combine with ions such as Ca2+ from different sources, resulting in two phases of carbonate cementation. Based on the above research, this study summarizes a set of diagenetic evolution models for coal-bearing reservoirs.

Investigation on the early proceeding of cement hydration containing dispersed nano Calcium Silicate Hydrated (CSH) seeds

Steam curing process is a traditional method for accelerating the progression of cement hydration to satisfy the rapid development of compressive strength in precast concrete industry. However, steam curing would release significant amount of CO2 into the atmosphere. In order to avoid the serious environmental pollution caused by the steam curing process, Calcium Silicate Hydrate (CSH) dispersed by comb-like polycarboxylate superplasticizer (PCE), shorted as dispersed nano CSH seed, was utilized to promote the early cement hydration at normal temperature. This investigation aims at disclosing the hydration process of cement and the microstructure evolution of cement paste in the presence of dispersed nano CSH seed during the early stage via setting time, ultrasonic pulse velocity (UPV), compressive strength, conductivity, pH, thermogravimetric (TG), 29Si NMR and nitrogen adsorption/desorption. The results demonstrated that with the dispersed nano CSH seed increasing, the setting process of cement paste was shortened dramatically, the compressive strength and UPV of cement mortar increased significantly especially at 12 h. The variation of conductivity and pH of cement suspension indicated that the ion dissolution process was promoted by dispersed nano CSH seed, which therefore conducive to the precipitation of cement hydration products. TG curves exhibited that the formation of cement hydration products, including CH (Calcium Hydrated), AFt and CSH gel were accelerated by dispersed nano CSH seed. The 29Si NMR (Nuclear Magnetic Resonance) and nitrogen adsorption/desorption results validated that the incorporating dispersed nano CSH seed promoted considerably the polymerization of CSH gel. The aforementioned results are correlated well with the fast formation of microstructure and in turn the rapid development of compressive strength at early age.

Depositional Setting, Diagenetic Processes, and Pressure Solution-Assisted Compaction of Mesozoic Platform Carbonates, Southern Apennines, Italy

Pressure solution processes taking place during diagenesis deeply modify the hydraulic properties of carbonates, affecting their mechanical layering and hence the dimension, distribution, and connectivity of high-angle fractures. The formation of stylolites is controlled by the texture of the host rock and therefore by the depositional environment and the diagenetic processes that involve it. This study reports the results of a multidisciplinary study carried out on a Jurassic–Cretaceous carbonate platform in southern Italy. The goal is to unravel the control exerted by single carbonate textures and specific diagenetic processes on the formation of bed-parallel stylolites. Microfacies analyses of thin sections are aimed at obtaining information regarding the composition and texture of the carbonates. Petrographic observations coupled with CL analyses are key to deciphering their diagenetic history. Results are consistent with carbonates originally deposited in a shallow-water realm in which carbonate mud is occasionally abundant. In this environment, early cementation inhibits their chemical compaction. In grain-supported facies, pressure solution is only localized at the grain contacts. During shallow burial diagenesis, precipitation of blocky calcite predates the formation of bed-parallel stylolites in the grain-supported facies. Contrarily, mud-supported facies favor chemical compaction, which results in stylolites showing a good lateral extension and thick sediment infill. A classification of different types of stylolite morphology is attempted in relation to facies texture. In detail, rougher morphology (sharp-peak) characterizes the stylolites nucleated in grain-supported facies, while smoother morphology (rectangular to wave-like) is observed in stylolites on mud-supported facies. Application of this knowledge can be helpful in constraining the diagenetic history of carbonate rocks cored from depth, and therefore predict the fracture stratigraphy properties of carbonates buried at depth.

Microbial dominated Ca‐carbonates in a giant Pliocene cold‐seep system (Crotone Basin – South Italy)

AbstractThe Pliocene cold‐seep carbonate of the Crotone Basin (South Italy) represents a key site for dimension, outcropping exposure and quality. These deposits form a large carbonate (calcite) body (350 m long, 100 m wide and 40 m thick), and are characterized by a conduit facies made of authigenic calcite interpreted as previously active gas/fluid escape pipes and by a pavement facies, depicted as the surrounding early calcite‐cemented bioclastic and siliciclastic sediments. Pavement facies are commonly colonized by chemosymbiotic and non‐chemosymbiotic macrofauna (Lucinid and Solemyid bivalves, gastropods and serpulids). The conduit microfacies is characterized by the inward accretion of dark micritic laminae alternating with whitish sparitic layers. The micritic laminae show a microbial peloidal to dendrolitic fabric, which commonly incorporates planktonic foraminifera and coprolites, whereas the crystalline layers consist of microsparitic and sparitic crusts of prismatic zoned calcite crystals. The pavement facies shows more variability, because it is typified by laminated microbial boundstones, chemosymbiotic–bivalves packstone, foraminiferal packstone/wackestone and hybrid arenites. The stratigraphic constraint coupled with the foraminiferal assemblage (planktonic taxa) suggest a deep‐water setting occasionally affected by siliciclastic sedimentary flows. The pavement facies also shows common brecciation features, suggesting the establishment of post‐depositional overpressure conditions due to the early cementation of the conduits, which triggered localized rock failure. Stable isotope analysis of the different facies reveals overall negative δ13C values (−6.8 to −37.4‰ Vienna PeeDee Belemnite), indicating the presence of a complex mixture of methane with other hydrocarbons consumed microbially via anaerobic oxidation of methane; whereas δ18O is relatively positive (0.0 to 3.4‰ Vienna PeeDee Belemnite) suggesting the possible dehydration of clay minerals and/or destabilization of gas hydrates. This study, besides helping in the definition of the migration pathways and modality of accumulation of hydrocarbon‐rich fluids, can also help in building more and more realistic models for the complex genesis of cold‐seep carbonates.

Modelling diagenetic reactions and secondary porosity generation in sandstones controlled by the advection of low‐molecular‐weight organic acids

AbstractHigher secondary porosity was observed in the centre of a sandstone unit in the Eocene Shahejie Formation fan delta front sandstones from the Bozhong Depression, Bohai Bay Basin. This differs from past studies showing secondary porosity mainly in the marginal parts of sandstones adjacent to shales. This study utilized reactive transport models involving low‐molecular‐weight organic acids (LMWOA) to discuss potential processes resulting in the contrary distribution of secondary porosity. An interface model simulating LMWOA diffusion from adjacent shales to the sandstone resulted in secondary porosity in sandstones adjacent to shales. In contrast, an advection model simulating advective transport of LMWOA parallel to the sandstone bedding successfully generated higher secondary porosity in the central part. The central part of the sandstone exhibited better grain sorting (greater depositional porosity) and significantly less early carbonate cements compared to the marginal sandstone parts. Consequently, the central part had greater porosity prior to the dissolution through LMWOA. The initially higher porosity in the central part allowed for a higher advective flux of LMWOA‐rich water and associated lower pH, resulting in decreased oligoclase saturation, higher oligoclase dissolution rates and ultimately higher secondary porosity. This study indicates that grain sorting during sediment deposition, early carbonate cementation, LMWOA production in adjacent shales, and advection processes collectively control the diagenetic reactions and the distribution of secondary porosity in sandstones.

Comparison of the effects of carbon-based and inorganic nanomaterials on early cement hydration

This study delves into the impact of nanomaterials on early cement hydration, aiming to elucidate their mechanism of action. Four nanomaterials were selected, including carbon-based nanomaterials (multi-walled carbon nanotubes (CNT) and graphene oxide (GO)) and inorganic nanomaterials (nano-SiO2 and nano-CaCO3). Initially, the zeta potential was employed to examine nanomaterial adsorption on relevant ions in simulated solutions. Subsequently, SEM NMR, XRD, and TGA were utilized to assess the influence of different nanomaterials on hydration product morphology, content, and structure. Utilizing the Krstulovic-Dabic model, the hydration kinetics based on the heat of hydration in cement paste containing nanomaterials was simulated. Results revealed nanomaterials exhibited stronger Ca2+ ion adsorption than cement particles, with CNT and GO particles displaying weaker adsorption relative to SO42- ions. Conversely, nano-SiO2 and nano-CaCO3 particles exhibited a stronger adsorption capacity for Ca2+ ions than SO42- ions. This robust adsorption facilitated hydration product generation, yielding fine and regular C-S-H particles in carbon-based nanomaterial-containing cement pastes, contrasting with coarse and irregular particles in inorganic nanomaterial-containing pastes. Nanomaterial introduction increased polymerization and the average chain length of hydration products. Furthermore, it heightened exothermic peak intensity and total exothermic amount, while reducing the induction period and exothermic peak length. Hydration kinetics, simulated through the Krstulovic-Dabic model, aligned with the nucleation and growth (NG)-phase boundary reaction (I)-diffusion (D) process. In the NG stage, nanomaterials accelerated hydration by reducing reaction stages (n) and increasing the rate constant (K1'). In the I stage, hindered Ca2+ ion migration led to decreased K2', slowing hydration. Stage D witnessed a rapid decline in K3'.

Effect of calcium nitrate on hydration properties and strength development of calcium sulfoaluminate cement

Global lithium salt price surges drive up costs for high-performance repair materials, creating demand for cost-effective alternatives. Calcium nitrate (CN), with its low production costs and capacity to enhance early cement strength, emerges as a preferred choice. Limited knowledge on combining calcium sulfoaluminate (CSA) cement and CN prompts further exploration for a potentially cost-effective solution in repair materials. This study investigated the impact of varied CN contents on fluidity, setting time, compressive strength, electrical resistivity, heat of hydration, hydration products, and pore structure of CSA cement. The results show that CN can enhanced fluidity, significantly reduced setting time, accelerated hydration process, shortened the hydration induction period, and promoted the nucleation and growth of ettringite. When CN content was 8%, the compressive strength of samples reached its peak at 40.8 MPa, 44.9 MPa, and 47.3 MPa at 3 d, 7 d, and 28 d, respectively. Exceeding 8% CN content will increase the cumulative heat release which reach the maximum of 314.5 J·g−1 at 72 h. The addition of CN will generate the NO3-AFm phase and improve the stability of ettringite, as well as refine the pore structure of the samples but increase their total porosity.

Upper Jurassic–lowermost Cretaceous hybrid build-ups of the Western Tethys Realm: Cement-rich microencruster-microbialite-calcified sponge framework

This study summarizes and provides new data concerning the composition, fabrics, depositional environment and palaeogeographic distribution of Upper Jurassic–lowermost Cretaceous (Kimmeridgian–Berriasian) upper slope build-ups with complex microencruster-microbialite-calcified sponge frameworks associated with large amount of early marine cement crusts. The focus is on reef carbonates from the Štramberk-type limestones from the Carpathians (Getic Carbonate Platform) and Apuseni Mountains in Romania, with additional data from the Plassen Carbonate Platform (Northern Calcareous Alps, Austria) and the Štramberk Carbonate Platform (Western Carpathians, Czech Republic and Poland). The microencrusters, often of problematic biological affinity, are mainly Crescentiella morronensis (Crescenti 1969), Labes atramentosa Eliášová 1986 and Radiomura cautica Senowbari-Daryan & Schäfer 1979. Specialized encrusting calcified sponges are also common, with Perturbatacrusta leini Schlagintweit & Gawlick 2011 as the most abundant and characteristic form. Light-dependent microencrusters (e.g., “Lithocodium-Bacinella”) that are abundant in coeval overlying coral-dominated reefs, are rare, as are corals (microsolenids adapted to low-light level). Three dominant types of fabric-based framework varieties are considered for the studied build-ups. The main differences between these types reflect a bathymetric zonation in their development. The abundance of Crescentiella, microbialites, massive radiaxial fibrous cement crusts, and poorly diversified microencruster/sponge assemblages, are all suggesting that Type I framework variety is characteristic for build-ups formed in the deepest parts of an upper slope environment. Type II most probably developed at slightly lower depths than Type I, as revealed by its main features (clusters of calcified sponges and microencrusters associated with less extensive cement crusts) and distribution between the other two types in the sedimentary sequences. Type III, the most common, characterizes build-ups formed at the shallowest depths of the upper slope environment and is composed of alternating layers of diverse microencrusters (including several light-dependent species), calcified sponges, rare microsolenid corals, microbialites and early marine cement crusts. The distribution patterns of these framework varieties (Type I to Type III) together with their associated facies, strengthen this depositional interpretation. From a process-based perspective, these upper slope build-ups exemplify triple hybrid carbonates which are intimate combinations of microbial and skeletal components (microencrusters/microbialites and calcified sponges), associated with abiotic precipitates (early marine cement crusts). Their palaeogeographic importance is reflected in their formation on the slopes of rimmed carbonate platform systems facing open oceanic domains, predominantly within the central Western Tethys Realm. Such hybrid build-ups appear to have been absent on the southern European shelf where other reef frameworks commonly developed on carbonate ramps and ramp-type carbonate platforms.

Variations of sedimentary environment under cyclical aridification and impacts on eodiagenesis of tight sandstones from the late Middle Jurassic Shaximiao Formation in Central Sichuan Basin

Understanding eodiagenesis is essential to decoding the diagenetic pathways of tight sandstones that act as excellent unconventional oil & gas reservoirs. Great paleoclimate change is capable of influencing eodiagenetic processes of tight sandstones through variations of sedimentary environment. However, it is less noted how climate gradients between the greenhouse and the hothouse conditions impact the eodiagenesis of tight sandstones. We examined eodiagenetic processes that has been operated in the Shaximiao Formation sandstones using petrographic observation, scanning electron microscopy, geochemistry, and XRD analysis to reveal impacts of the transitional climate changes on the differential eodiagenesis and implications for the diagenesis-porosity evolution. Based on sequence stratigraphy, the Shaximiao Formation is divided into four sub-members SXM1, SXM2, SXM3, and SXM4, respectively. Dark sandstones and mudstones mainly occurred in the SXM1 and the SXM2. Grey-green clastic rocks are dominant in the SXM3, whereas red mudstones frequently appear in the SXM4. Paleoclimate indices denote that a cyclical aridification from the warm-humid to hot-semiarid conditions took place from the SXM1 to the SXM4. It could have been caused by the megamonsoon effect and the paleogeographic shift along with the breakup of the Pangaea supercontinent. Combined with the migration of depocenters, the paleoclimate change resulted in transformation of sediment provenances from mafic igneous rocks to quartzose sedimentary rock along with the decreasing textural maturity. Therefore, sedimentary environments varied from the high-saline to low-saline and from low-oxygen to high-oxygen conditions respectively, which had a crucial impact on eodiagenetic cements which were formed in the Shaximiao Formation. Chlorite and laumontite cement precipitation was promoted by high-saline alkaline fluids. Chlorite proportions show an arched trend from the SXM1 to the SXM4, compatible with those of primary and secondary porosities. In contrast, laumontite proportions exhibit a decreasing variation from the SXM1 to the SXM4. High percentages of early cements are favorable to improving resistance to the compaction and preservation of primary pores. However, high chlorite (>5%) and laumontite (>10%) proportions are destructive for the reservoir quality. Large quantities of laumontite cements occupy primary pores and impede diagenetic fluids flowing and are not favorable to the dissolution. By contrast, an excess of chlorite cements can be dissolved to produce secondary pores during the organic acid release. Thus, the SXM2 is potential as a reservoir for oil & gas. Therefore, those eodiagenetic cements can control the late diagenetic evolution and the reservoir quality. Observations made here have implications for understanding tight sandstone reservoirs elsewhere in the world.