E-waste Recycling Facilities Research Articles

Concentrations and influencing factors of 17 elements in placenta, cord blood, and maternal blood of women from an e-waste recycling area

BackgroundThe effects of prenatal element exposure on mothers and fetuses have generated concern. Profiles of trace and toxic elements in biological material are urgently desired, especially for women who reside near e-waste recycling facilities. The aim of this study was to investigate elements concentrations in placenta, cord blood, and maternal blood of women and to evaluate the influencing factors. MethodsA group of 48 women from an e-waste recycling site and a group of 31 women from a non-e-waste recycling site were recruited. Basic characteristics were collected by questionnaire and the concentrations of 17 elements in placenta, cord blood, and maternal blood samples were analyzed by inductively coupled plasma mass spectrometry (ICP-MS). Finally, the generalized linear model regression analysis (GLM) was used to test the association between element concentrations and possible factors. ResultsCompared to the control group, the exposed group had significantly elevated cadmium (Cd), zinc (Zn), nickel (Ni), and antimony (Sb) in placenta, and higher lead (Pb) in maternal blood and cord blood (P<0.05). Sb concentration in maternal blood was significantly lower than in the control group (P<0.05). GLM analysis showed that element concentrations were mainly associated with maternal age [chromium (Cr), iron (Fe), selenium (Se), cobalt (Co), mercury (Hg) in placenta, copper (Cu) in maternal blood], education (Se, Sb in placenta), family income (Cu in maternal blood and Ni in placenta), passive smoking [Cu and Zn in placenta, Pb in maternal blood], and e-waste contact history (Hg in cord blood, Cu, Zn, and Cd in maternal blood). ConclusionsWomen in the e-waste recycling area had higher toxic element levels in the placenta and blood samples. More preventive measures were needed to reduce the risk of element exposure for mothers and fetuses in these areas.

Location of the Nearest E-Waste collection and Recycling Facility

The main purpose of online e-waste location system is to provide nearby e-waste locations to the user. The project integrates GPS mapping with real-time data to create a user-friendly. The project not only promotes environmental sustainability by diverting e-waste from landfills but also raises awareness about the importance recycling and environmental conservation. This abstract encapsulates a user-focused approach to solving the problem of e-waste disposal by combining geospatial technology and applications, thereby contributing to a cleaner environment and a more sustainable future.

HBM4EU E-waste study: Assessing persistent organic pollutants in blood, silicone wristbands, and settled dust among E-waste recycling workers in Europe

E-waste recycling is an increasingly important activity that contributes to reducing the burden of end-of-life electronic and electrical apparatus and allows for the EU's transition to a circular economy. This study investigated the exposure levels of selected persistent organic pollutants (POPs) in workers from e-waste recycling facilities across Europe.The concentrations of seven polychlorinated biphenyls (PCBs) and eight polybrominated diphenyl ethers (PBDEs) congeners were measured by GC-MS. Workers were categorized into five groups based on the type of e-waste handled and two control groups. Generalized linear models were used to assess the determinants of exposure levels among workers. POPs levels were also assessed in dust and silicone wristbands (SWB) and compared with serum.Four PCB congeners (CB 118, 138, 153, and 180) were frequently detected in serum regardless of worker's category. With the exception of CB 118, all tested PCBs were significantly higher in workers compared to the control group. Controls working in the same company as occupationally exposed (Within control group), also displayed higher levels of serum CB 180 than non-industrial controls with no known exposures to these chemicals (Outwith controls) (p < 0.05). BDE 209 was the most prevalent POP in settled dust (16 μg/g) and SWB (220 ng/WB). Spearman correlation revealed moderate to strong positive correlations between SWB and dust. Increased age and the number of years smoked cigarettes were key determinants for workers exposure. Estimated daily intake through dust ingestion revealed that ΣPCB was higher for both the 50th (0.03 ng/kg bw/day) and 95th (0.09 ng/kg bw/day) percentile exposure scenarios compared to values reported for the general population.This study is one of the first to address the occupational exposure to PCBs and PBDEs in Europe among e-waste workers through biomonitoring combined with analysis of settled dust and SWB. Our findings suggest that e-waste workers may face elevated PCB exposure and that appropriate exposure assessments are needed to establish effective mitigation strategies.

Assessment of Heavy Metal Pollution and Health Risks in a Government-Intervened Electronic Waste Dismantling Area in South China

ABSTRACT Efficient control of heavy metal pollution necessitates a comprehensive understanding of pollutant sources. In this study, we conducted a thorough investigation of 11 metals in the soil of an electronic waste (e-waste) recycling facility in South China. The sources of these metals were determined through a combination of statistical analysis and the UNMIX model. Despite government intervention, our findings reveal significant pollution of nickel, copper, zinc, cadmium, and lead in the study area. Primary contributors to heavy metal contamination in the soil were identified as demolition activities, transport emissions, and atmospheric deposition. Utilizing a source risk assessment model, we observed that children face higher noncarcinogenic and carcinogenic risks compared to adults. Remarkably, the total hazard index of the study area was found to be considerably lower than that of other e-waste dismantling cities. Moreover, the total carcinogenic risk was noted to be one order of magnitude lower than both other e-waste dismantling cities and industrial and mining cities. While acknowledging the government’s commendable achievements in the standardized management of e-waste dismantling activities, our study underscores the need for targeted measures to further reduce pollution and safeguard the health of residents. These results emphasize the importance of ongoing efforts to enhance environmental protection strategies and underscore the significance of tailored interventions for sustainable pollution control in e-waste recycling facilities.

Simultaneous targeted and non-targeted analysis of plastic-related contaminants in e-waste impacted soil in Agbogbloshie, Ghana

An LC-MS based analytical method was developed and validated for the simultaneous targeted analysis and suspect screening of plastic-related contaminants in e-waste impacted soils. Satisfactory recoveries (97 ± 13 %) were achieved using ultrasound-assisted extraction for 14/15 of the targeted analytes (7 bisphenols and 8 plasticizers) in a range of agricultural and non-agricultural soils. The method was applied to 53 soil samples collected in May 2015 in the region of Agbogbloshie (Ghana) at e-waste facilities (incl. Dump, trade, and burn sites), neighboring non-agricultural (incl. upstream, downstream, and community) and agricultural fields, and at two control agricultural sites away from e-waste recycling facilities. Bisphenol A (BPA) and bis(2-ethylhexyl) phthalate (DEHP) were the two dominant contaminants in e-waste soil (with concentrations up to 48.7 and 184 μg g−1, respectively), especially at the trade site, where e-waste was sorted and dismantled. The non-targeted workflow was successfully applied to identify additional plastic-related contaminants previously unreported in e-waste impacted soils, including bis(2-propylheptyl) phthalate, diisononyl phthalate, trioctyl trimellitate, 4-dodecylbenzenesulfonic acid, perfluorooctanesulfonic acid, perfluorobutanesulfonic acid, diphenyl phosphate, and triethylene glycol monobutyl ether. The agricultural soils surrounding the e-waste sites were also contaminated by plastic-related chemicals (especially DEHP), highlighting the impact of e-waste activities on the surrounding agricultural system.

Awareness, Safety Practices and Associated Factors Among E-Waste Recycling Workers in Bangladesh.

Awareness of electronic waste (e-waste) improves safety practices among workers, thereby reducing health risks associated with pollutants. Investigating the awareness and safe practices among these workers could help identify areas for improvement, a task not yet undertaken in Bangladesh. Consequently, this study aimed to examine the awareness, safety measures, and associated factors among e-waste workers in the country. In this cross-sectional study, 236 workers from an e-waste recycling facility located near Dhaka were interviewed using a semi-structured questionnaire from August to September 2022. Eight questions captured information on socio-demographics and work factors, 24 questions on e-waste awareness, and 11 questions on safety practices. Total awareness and safety scores were calculated and categorized as "good" and "poor" based on a cut-off point of 80% of the total score. Bivariate and regression analyses were done to determine associated factors. Only 25% of workers had good e-waste awareness; major knowledge gaps were regarding minimization, health hazards, and environmental impact. Good awareness was significantly associated with female gender, higher education, income, smoking, experience ⩾5 years, and training. About 58% followed good safety practices, but the use of boots and helmets was inadequate. Good safety practices were significantly associated with higher education, income, smoking, experience, training, and overtime work. On multivariable analysis, those with higher education had 12 times (95% CI 4.83-32.81) and 6 times (95% CI 2.94-12.81) higher odds of good awareness and practices, respectively. Trained workers had 3.6 times (95% CI 1.67-7.52) higher odds of good practices. There was a significant correlation between awareness and practices (r = .70, P < .001). The study found poor awareness and inadequate safety practices related to e-waste among the workers. Urgent interventions like training, the use of protective gear, and stringent policies are warranted to increase awareness and safety behaviors.

Untargeted Screening of Per- and Polyfluoroalkyl Substances (PFASs) in Airborne Particulate of Three Italian E-Waste Recycling Facilities

Poly- and perfluorinated alkyl substances (PFASs) are widely used in the electrical and electronic appliance industry to the point that waste of electrical and electronic equipment (WEEE), also known as e-waste, creates significant potential for PFAS exposure (by inhalation, ingestion, or dermal exposure) for people handling and recycling e-waste. The aim of this work was the development of an untargeted analytical approach in order to detect the presence of possible unknown PFASs in particulate matter collected in three Italian e-waste facilities through liquid chromatography coupled to high-resolution tandem mass spectrometry (LC-HR-MS/MS) in negative ionization mode. By means of three acquisition experiments, nine compounds were detected as candidate PFASs, and three were definitively confirmed by comparison with their authentic standards. Among these, bistriflimide (bis (trifluoromethylsulfonyl) imide), an ionic liquid with several promising technological applications, was the most abundant compound detected in all three recycling plants. This is the first study associating the presence of fluorinated ionic liquids with e-waste, and as these chemicals are not only toxic and persistent but also highly mobile, our results indicate the need to include them in future PFAS research. Only further data on their actual environmental diffusion will determine whether they are emerging pollutants or not.

Planning of three-level facilities network for collection and recycling of E-waste: A MILP-based modelling approach

The collection and recycling of E-waste are vital for the economy, the environment, and public health. From a financial perspective, planning the necessary E-waste facilities, including the collection centres and recycling centres, can be a challenging and laborious undertaking. The E-waste recycling facilities network planning problem involves three types of facilities related to different stages. Firstly, E-waste generated from households is collected at a location known as a collection point, from where it is transported to collection centres where it is sorted into several product groups, and lastly, it is sent to relevant recycling facilities. The recovered materials in recycling facilities are then forwarded to original manufacturers for reuse, while hazardous waste is dumped in landfills. The capacity and location decisions of recycling facilities are strategic and important as it involves huge capital investment, and they should be far from residential areas. Furthermore, to reduce transportation costs, these facilities should be located nearby collection centres and landfills. So, to reduce the overall E-waste recycling cost, the decision regarding the number and location of all three facilities plays an important role.In this study, the planning problem of determining the optimal number and location of collection points, collection centres, and recycling centres, as well as the flow of E-waste to these facilities, has been tackled by proposing a mixed-integer linear programming (MILP) formulation. The objective is to minimise the overall cost associated with these operations. The costs include the transportation cost and the cost of establishing all types of E-waste facilities. The application of the model has been demonstrated using a numerical example. The numerical case has been solved using GUROBI 8.0.1 optimisation solver. This study provides a framework to plan an effective and efficient network of E-waste facilities at minimum cost and lesser environmental impact.

Are UK E-waste recycling facilities a source of environmental contamination and occupational exposure to brominated flame retardants?

Investigations into the impacts of regulated electrical and electronic waste (e-waste) recycling activities on urban environments in Europe remain rather scarce. In this study, dust samples taken both inside and outside of five UK e-waste recycling facilities were analysed for concentrations of polybrominated diphenyl ethers (PBDEs), novel brominated flame retardants (NBFRs), and hexabromocyclododecane (HBCDD). Average concentrations of ∑BFRs in dust inside and outside UK e-waste recycling facilities were 12,000 ng/g and 180 ng/g, with median concentrations of 7500 ng/g and 85 ng/g, respectively. BDE-209 and decabromodiphenyl ethane (DBDPE) were the most abundant BFRs in both indoor and kerb dust, making a combined contribution to ∑BFRs of ~90 % on average. While four out of the five studied e-waste facilities showed a lack of significant impact on BFR contamination in surrounding environment, one of the studied e-waste recycling facilities was identified as a likely source of BFR contamination to UK urban environments, with industrial activities as another potential source of NBFRs. Occupational exposure of UK e-waste recycling workers to BFRs via dust ingestion was generally lower than that estimated for e-waste recyclers from other countries, but was comparable to BFR exposure via dust ingestion of UK office workers. Our estimates suggested that health burdens posed by dust ingestion of BFRs were minimal for UK e-waste recycling workers.

Assessing Strategic Management of E-Waste in Developing Countries

E-waste is one of the fastest growing waste streams in the world, paradoxically containing both hazardous components and substances which can adversely impact on both the environment and public health, as well as valuable secondary resources and raw materials that could be recovered if e-waste is processed properly. Developing countries not only lack the infrastructure and technology required to manage e-waste appropriately, they largely rely on a fragmented informal sector for the management of a large fraction of e-waste that is either recognized by the state, or is marginalized and suppressed. This article examines the current situation with e-waste management in the developing countries, and assesses these countries’ challenges. The study highlights that there is an urgent need to design more better framework for e-waste that protect these countries from the problems caused by e-waste that are beyond repair and refurbishment, and to help these countries to advance their e-waste recycling and disposal facilities to prevent open burning on and dumping in the environment that can result in deleterious effects on communities at a local as well as at a global level.

Exposure to Organophosphate Ester Flame Retardants in the Occupational Environment

Rationale: Flame retardants (FR) are commonly used in consumer products, electronics, and safety equipment. Organophosphate esters (OPEs) are a sub-class of FRs and are widely used in various industries. Occupational risk of exposure is expected for many workers in various industries. However, the evidence of occupational exposure to OPE FRs is limited.&#x0D; Objectives: This study aimed to summarize evidence of occupational exposure to OPE FRs.&#x0D; Methods: A scoping review was conducted using Scopus (April-2022) and Google Scholar (January-2022). Search terms included ""occupational"", ""exposure"", ""flame retardants"", ""organophosphate"" and similar. Studies with quantitative measures of OPE exposure in workplaces were retained. Information on sample types, exposure levels, routes of exposure, and contextual information was extracted and summarized.&#x0D; Results: To-date, 15 studies have met the inclusion criteria. Groups most frequently assessed for OPE exposure include workers in e-waste recycling facilities and constructions. Published studies have described inhalation exposure, incidental ingestion, and dermal absorption routes. Sampling methods included active air sampling, passive air sampling, biological sampling, and dermal sampling. Triphenyl phosphate (TPhP), Tris(2-chloroisopropyl) phosphate (TCIPP), and Tris(2-chloroethyl) phosphate (TCEP) were the three most common sampled OPEs.&#x0D; Conclusions: There is evidence of OPE exposure in a limited number of industries and occupations at levels higher than the general population. The adverse health effects associated with OPE exposure included reproductive complications, endocrine disruption, and potential carcinogenicity. More research is needed to understand the prevalence and level of occupational exposure to OPE FRs and the potential work-related health impacts.

Insights into the long-term fates and impacts of polybrominated diphenyl ethers in sediment samples in Taiwan: The national project for background monitoring of the environmental distribution of chemical substances (BMECs)

This study aimed to evaluate the impact factors and effectiveness of management policies on the presence of polybrominated diphenyl ethers (PBDEs) in sediment samples in Taiwan from the last 10 years. Twenty-four PBDE congeners were detected in 838 sediment samples collected from 4 stages (2006–2019) in 30 principal rivers, based on the national project for background monitoring of the environmental distribution of chemical substances. The ΣPBDE concentrations in the 4 stages ranged from 30.00 to 147.10 ng/g dw, 6.03–15.30 ng/g dw, 4.99–7.00 ng/g dw, and 1.20–2.10 ng/g dw in the northern, southern, central, and eastern areas, respectively. The concentrations of PBDEs (e.g., penta-BDE and octa-BDE) in sediment samples notably decreased (−6 to −73%) as the Taiwan Environmental Protection Administration implemented policies banning PBDEs (except deca-BDE). The PBDEs levels of the sediment samples collected in the dry season were higher than those collected in the wet season. The levels of ΣPBDEs in sediment samples were affected by season, the amount of general waste present, and nearby PBDE-related factories and e-waste recycling facilities. Reducing the release of PBDEs, especially deca-BDE, through sound waste management and recycling practices is still needed to improve environmental sustainability in Taiwan.

E-waste dismantling as a source of personal exposure and environmental release of fine and ultrafine particles

Electronic waste (WEEE; from TV screens to electric toothbrushes) is one of the fastest growing waste streams in the world. Prior to recycling, e-waste components (metals, wood, glass, etc.) are processed by shredding, grinding and chainsaw cutting. These activities generate fine and ultrafine particle emissions, containing metals as well as organics (e.g., flame retardants), which have high potential for human health impacts as well as for environmental release. In this work, release of fine and ultrafine particles, and their exposure impacts, was assessed in an e-waste recycling facility under real-world operating conditions. Parameters monitored were black carbon, particle mass concentrations, ultrafine particles, and aerosol morphology and chemical composition. Potential health impacts were assessed in terms of cytotoxicity (cell viability) and oxidative stress (ROS) on <2 μm particles collected in liquid suspension. Environmental release of WEEE aerosols was evidenced by the higher particle concentrations monitored outside the facility when compared to the urban background (43 vs.11 μgPM2.5/m3, respectively, or 2.4 vs. 0.2 μgCa/m3). Inside the facility, concentrations were higher in the top than on the ground floor (PM2.5 = 147 vs. 78 μg/m3, N = 15.4 ∗ 104 vs. 8.7 ∗ 104/cm3, BC = 12.4 vs. 7.2 μg/m3). Ventilation was a key driver of human exposure, in combination with particle emissions. Key chemical tracers were Ca (from plastic fillers) and Fe (from wiring and other metal components). Y, Zr, Cd, Pb, P and Bi were markers of cathode TV recycling, and Li and Cr of grinding activities. While aerosols did not evidence cytotoxic effects, ROS generation was detected in 4 out of the 12 samples collected, associated to the ultrafine fraction. We conclude on the need for studies on aerosol emissions from WEEE facilities, especially in Europe, due to their demonstrable environmental and human health impacts and the rapidly growing generation of this type of waste.

Release and Gas-Particle Partitioning Behavior of Liquid Crystal Monomers during the Dismantling of Waste Liquid Crystal Display Panels in E-Waste Recycling Facilities.

Liquid crystal monomers (LCMs) are a class of emerging chemical pollutants; however, their release and gas-particle partitioning remain unknown. This study performed the first comprehensive analysis of a wide range of 93 LCMs in the ambient air of liquid crystal display (LCD) dismantling facilities. A total of 53 of the 93 target LCMs were detected in the air samples. The total atmospheric concentrations (gas and particles) of LCMs (∑LCMs) ranged from 68,800 to 385,000 (median of 204,000) pg/m3. Most LCMs were predominant in the gas phase, implying that their atmospheric transport would be mainly governed by gas rather than particle diffusions. Differential distribution patterns of the LCMs were observed due to their different atmospheric partitioning behaviors. Significant linear correlations were found between the gas-particle partitioning coefficients (KP) and the predicted subcooled vapor pressures (PL) and octanol-air partitioning coefficients (Koa) (p < 0.01). Compared with two equilibrium-state models, the experimentally observed particulate fractions (ϕ) fit better with the predicted values based on the Li-Ma-Yang (L-M-Y) steady-state model, and Koa was identified as a key factor determining the atmospheric fate pathways of LCMs. Our study highlights another new class of chemicals significantly contributing to the chemical mixture in the ambient air at e-waste recycling areas.

A comparison of waste recycling facilities for their contribution of heavy metals and trace elements in ambient air.

A multi-elemental analysis, including heavy metals and trace elements in ambient air samples, was conducted for computers, wires, lead batteries, and iron extraction facilities in Lahore by proton-induced X-ray emission (PIXE) spectroscopy. The data obtained from PIXE analysis revealed the presence of Mg, Al, Zn, S, Pb, K, Ti, Fe, Si, K, and Cr elements at e-waste recycling facilities. The computer dismantling site revealed a higher concentration of Fe (634.7 μg/m3), Al (176.8 μg/m3), Pb (135.4 μg/m3) and Zn (122.5 μg/m3) in the air samples. The decreasing order of heavy metals and trace elements contribution at the computer dismantling site was as Si > Fe > Al > Pb > Zn > Mg > Ca > Cr > K > S > Ti. Similarly, at wires/cables burning site, a higher concentration of Fe, Al, and Pb (829.8 μg/m3, 184.5 μg/m3 and 115.6 μg/m3, respectively) were observed, and the elements revealed a descending trend as Si > Fe > Al > Zn > Pb > Mg > Ca > Cr > Ti > K > S. The lead batteries dismantling site showed the highest Pb concentration (141.2 μg/m3) due to the disassembling of lead acid batteries. Al, Zn, Fe, and Cr also revealed higher concentration in air samples and exhibited a declining trend as Si > Fe > Al > Pb > Zn > Cr > Ca > Mg > Ti > K > S. However, the highest concentration of Fe (865.7 μg/m3) was detected in air samples of iron extraction sites besides Al and Zn. The descending order of trace elements contribution was Si > Fe > Al > Zn > Mg > K > Ca > Ti > S. Furthermore, the correlation between workers' awareness and their possible health impacts were also examined in the study. Most of the workers were less aware of the hazardous impacts. Majority of workers and residents were suffering from a respiratory illness (27.5% and 32.5%), kidney failure (15% and 22.5%), and neurological disorders (15% and 7.5%), respectively, due to exposure of airborne particulate matter which could be correlated with the higher concentration of heavy metals such as Pb, Cr, Zn, and Fe in the ambient air at the e-waste recycling sites.

Analyzing the intention of the households to drop off mobile phones to the collection boxes: empirical study in Malaysia

PurposeTo achieve proper waste management, the disposal of electronic waste (e-waste) is one suitable method. Most developing countries, including Malaysia, are facing lack of e-waste recycling facilities and low household participation. Using a survey method using a questionnaire, this study aims to examine the intention of Malaysian households to drop-off their mobile phones to the nearest collection boxes (n= 600).Design/methodology/approachThis study expanded the theory of planned behavior by adding environmental awareness and knowledge. In addition, the cost of disposal and the convenience of the available disposal infrastructure were measured as two parts of the perceived behavioral control.FindingsThe results of this study show that environmental knowledge and awareness have a significant impact on attitudes toward recycling intention of the households. In addition, it was also found that the attitude and cost of disposal infrastructure is positively related to household intention.Originality/valueThese results show that if e-waste collection boxes are provided to the nearest community and e-waste management information is distributed, this will increase household participation in e-waste management.

Occurrence of multiple classes of emerging photoinitiators in indoor dust from E-waste recycling facilities and adjacent communities in South China and implications for human exposure

Photoinitiators (PIs) are indispensable additives in photopolymerization. PI-containing consumables, such as adhesives, coatings, UV-cured inks and light-sensitive materials, are widely used in various electronic products. Nevertheless, there is no information concerning the identification of PIs as emerging contaminants from e-waste recycling. In this study, 25 PIs, including 9 benzophenones (BZPs), 8 amine coinitiators (ACIs), 4 thioxanthones (TXs) and 4 phosphine oxides (POs), were analyzed in indoor dust from typical e-waste recycling facilities and adjacent rural communities, as well as from control urban communities. All 25 target PIs were detected in e-waste dust, while only 17 and 15 of the 25 target PIs were detected in local home dust and urban home dust, respectively. The PIs detected in all dust samples were dominated by BZPs and POs, followed by ACIs and TXs. Most PIs exhibited significantly higher levels in e-waste dust than local or urban home dust. The influence of PI contamination on the local household environment by dust diffusion and transport from near e-waste recycling facilities may be lower due to the low volatility of most PIs. Characteristic composition profiles of PIs for indoor dust from the e-waste recycling area were identified and compared to those from the control area. Significant correlations were found among almost all the frequently detected PIs in the e-waste dust, indicating their similar application in electronic products and common emission from e-waste recycling. The estimated daily intakes of PIs via dust ingestion for the e-waste dismantling workers, as determined by using Monte Carlo analysis, were several times higher than those for the local adult residents and the general urban adult residents, which should be an emerging concern. To the best of our knowledge, this is the first report showing that e-waste dismantling/recycling activities lead to largely common releases of a wide range of multiple classes of PIs.

Serum concentrations of bisphenol A and its alternatives in elderly population living around e-waste recycling facilities in China: Associations with fasting blood glucose

In the present study, concentrations of bisphenol A (BPA) and its six alternatives were quantified in serum samples collected from elder population living around an e-waste recycling facilities as well as an reference area in China. BPA, bisphenol AF (BPAF), and bisphenol F (BPF) were frequently detected (detection rates: > 65%) in serum samples collected from residents living near e-waste dismantling facilities, with geometric mean (GM) concentrations of 3.2, 0.0074, and 0.062 ng/mL, respectively. The detection frequencies of other four bisphenols (BPs) in serum samples were lower than 25%, regardless of the sampling areas. Significant difference (Mann−Whitney U−test, p < 0.05) was observed in the serum concentration of BPA, but not BPAF and BPF, between the e-waste recycling and reference areas. This finding indicated e-waste dismantling activities are correlated with human BPA exposure. Significant higher (p < 0.05) detection rates of donors who had abnormal fasting blood glucose (FBG) levels were found in e-waste recycling areas (45%) than those found in reference area. Our results suggested BPA and BPAF exposure might associated with abnormal FBG in participants living in e-waste sites. To our knowledge, this study is first determination of BPs in serum samples and assessment of health risk of elderly people from BPs exposure in e-waste dismantling area.

Tri(2,4-di- t-butylphenyl) Phosphate: A Previously Unrecognized, Abundant, Ubiquitous Pollutant in the Built and Natural Environment.

Using high-resolution mass spectrometry, we identified tri(2,4-di- t-butylphenyl) phosphate (TDTBPP) in e-waste dust. This is a previously unsuspected pollutant that had not been reported before in the environment. To assess its abundance in the environment, we measured its concentration in e-waste dust, house dust, sediment from the Chicago Ship and Sanitary Canal, Indiana Harbor water filters, and filters from high-volume air samplers deployed in Chicago, IL. To provide a context for interpreting these quantitative results, we also measured the concentrations of triphenyl phosphate (TPhP), a structurally similar compound, in these samples. Median concentrations of TDTBPP and TPhP were 14 400 and 41 500 ng/g, respectively, in e-waste dust and 4900 and 2100 ng/g, respectively, in house dust. TDTBPP was detected in sediment, water, and air with median concentrations of 527 ng/g, 3700 pg/L, and 149 pg/m3, respectively. TDTBPP concentrations were generally higher or comparable to those of TPhP in all media analyzed, except for the e-waste dust. Exposure from dust ingestion and dermal absorption in the e-waste recycling facility and in homes was calculated. TDTBPP exposure was 571 ng/kg bw/day in the e-waste recycling facility (pro-rated for an 8-h shift), and 536 ng/kg bw and 7550 ng/kg bw/day for adults and toddlers, respectively, in residential environments.

Passive Samplers for the Assessment of Occupational Exposure to Flame Retardants among Canadian E-Waste Dismantlers

The mass of e-waste produced globally is growing dramatically. One hazard, especially for e-waste handlers, are flame retardants (FRs) which are added to electronic and electrical equipment in order to meet flammability standards. FR air concentrations can be measured using active air sampling equipment, but this sampling train can be cumbersome for workers. Passive samplers made from polydimethylsiloxane (PDMS) or silicone rubber, are one option for simplifying the measurement process. Here, we compared PDMS passive air samplers (PDMS-PASs) with active air samplers for the assessment of FR air levels at an e-waste dismantling facility in Ontario, Canada for the purpose of estimating occupational exposure.Sampling was conducted daily over a five days in February 2017. PDMS-PASs were hung at 4 workbenches and a central workplace, and were co-deployed with an active low-volume air sampler which consisted of a GFF followed by a PUF/XAD/PUF sandwich. Each PDMS and low-volume sampler was harvested after 24 hours. Samples were extracted and analysed for 13 FRs, including novel brominated flame retardants (NFRs), polybrominated diphenyl ethers (PBDEs) and organophosphate esters (OPEs), using gas chromatography mass spectrometry (GC-MS).The most abundant FRs were the now-banned PBDEs (BDE-209 accounted for ~70-98 % of FRs collected by PDMS-PASs). Total median concentrations of PBDEs in PDMS-PASs at the central workplace and workbenches were 1930 and 2900 ng/m3, respectively. PDMS-PASs provided comparable estimates of air concentrations to active samplers. The chemical profiles from the PDMS matched those from active sampling, indicating that differences in compound gas-particle partitioning did not affect the sampling efficiency of PDMS.Levels of FRs in air collected from this Canadian e-waste recycling facility suggest PDMS-PASs can be used to estimate occupational exposure to FRs, even for short deployment times at workplaces with elevated levels of these chemicals.