E-waste Dismantling Activities Research Articles

Informal E-waste dismantling activities accelerated the releasing of liquid crystal monomers (LCMs) in Pakistan: Occurrence, distribution, and exposure assessment

Liquid crystal monomers (LCMs) are emerging contaminants characterized by their persistence, bioaccumulation potential, and toxicity. They have been observed in several environmental matrices associated with electronic waste (e-waste) dismantling activities, particularly in China. However, there is currently no information on the pollution caused by LCMs in other developing countries, such as Pakistan. In this study, we collected soil samples (n = 59) from e-waste dismantling areas with different functions in Pakistan for quantification analysis of 52 target LCMs. Thirty out of 52 LCMs were detected in the soil samples, with the concentrations ranging from 2.14 to 191 ng/g (median: 16.3 ng/g), suggesting widespread contamination by these emerging contaminants. Fluorinated LCMs (median: 10.4 ng/g, range: 1.27–116 ng/g) were frequently detected and their levels were significantly (P < 0.05) higher than those of non-fluorinated LCMs (median: 6.11 ng/g, range: not detected (ND)–76.7 ng/g). The concentrations and profiles of the observed LCMs in the soil samples from the four functional areas varied. The informal dismantling of e-waste poses a potential exposure risk to adults and infants, with median estimated daily intake (EDI, ng/kg bw/day) values of 0.0420 and 0.1013, respectively. Calculation of the hazard quotient (HQ) suggested that some LCMs (e.g., ETFMBC (1.374) and EDFPB (1.257)) may pose potential health risks to occupational workers and their families. Considering the widespread contamination and risks associated with LCMs, we strongly recommend enhancing e-waste management and regulation in Pakistan.

A meta-analysis highlighting the increasing relevance of the hair matrix in exposure assessment to organic pollutants

Owing to a wide range of advantages, such as stability, non-invasiveness, and ease of sampling, hair has been used progressively for comprehensive biomonitoring of organic pollutants for the last three decades. This has led to the development of new analytical and multi-class analysis methods for the assessment of a broad range of organic pollutants in various population groups, ranging from small-scale studies to advanced studies with a large number of participants based on different exposure settings. This meta-analysis summarizes the existing literature on the assessment of organic pollutants in hair in terms of residue levels, the correlation of hair residue levels with those of other biological matrices and socio-demographic factors, the reliability of hair versus other biomatrices for exposure assessment, the use of segmental hair analysis for chronic exposure evaluation and the effect of external contamination on hair residue levels. Significantly high concentrations of organic pollutants such as pesticides, flame retardants, polychlorinated biphenyls and polycyclic aromatic hydrocarbon were reported in human hair samples from different regions and under different exposure settings. Similarly, high concentrations of pesticides (from agricultural activities), flame retardants (E-waste dismantling activities), dioxins and furans were observed in various occupational settings. Moreover, significant correlations (p < 0.05) for hair and blood concentrations were observed in majority of studies featuring pesticides and flame retardants. While among sociodemographic factors, gender and age significantly affected the hair concentrations in females and children in general exposure settings, whereas adult workers in occupational settings. Furthermore, the assessment of the hair burden of persistent organic pollutants in domestic and wild animals showed high concentrations for pesticides such as HCHs and DDTs whereas the laboratory-based studies using animals demonstrated strong correlations between exposure dose, exposure duration, and measured organic pollutant levels, mainly for chlorpyrifos, diazinon, terbuthylazine, aldrin, dieldrin and pyrethroid metabolites. Considering the critical analysis of the results obtained from literature review, hair is regarded as a reliable matrix for organic pollutant assessment; however, some limitations, as discussed in this review, need to be overcome to reinforce the status of hair as a suitable matrix for exposure assessment.

Assessment of Heavy Metal Pollution and Health Risks in a Government-Intervened Electronic Waste Dismantling Area in South China

ABSTRACT Efficient control of heavy metal pollution necessitates a comprehensive understanding of pollutant sources. In this study, we conducted a thorough investigation of 11 metals in the soil of an electronic waste (e-waste) recycling facility in South China. The sources of these metals were determined through a combination of statistical analysis and the UNMIX model. Despite government intervention, our findings reveal significant pollution of nickel, copper, zinc, cadmium, and lead in the study area. Primary contributors to heavy metal contamination in the soil were identified as demolition activities, transport emissions, and atmospheric deposition. Utilizing a source risk assessment model, we observed that children face higher noncarcinogenic and carcinogenic risks compared to adults. Remarkably, the total hazard index of the study area was found to be considerably lower than that of other e-waste dismantling cities. Moreover, the total carcinogenic risk was noted to be one order of magnitude lower than both other e-waste dismantling cities and industrial and mining cities. While acknowledging the government’s commendable achievements in the standardized management of e-waste dismantling activities, our study underscores the need for targeted measures to further reduce pollution and safeguard the health of residents. These results emphasize the importance of ongoing efforts to enhance environmental protection strategies and underscore the significance of tailored interventions for sustainable pollution control in e-waste recycling facilities.

Bisphenol and analogues in indoor dust from E-waste recycling sites, neighboring residential homes, and urban residential homes: Implications for human exposure

The compound 4-hydroxyphenyl 4-isoprooxyphenylsulfone (BPSIP) has recently emerged as a novel alternative to bisphenol A (BPA) and has been found in various paper products. However, there is limited information available regarding the identification of BPSIP as a novel contaminant in the e-waste dismantling area. In our research, we conducted a comprehensive analysis of 16 bisphenol analogues (BPs), including BPSIP, within indoor dust samples obtained from a representative e-waste recycling facility, neighboring rural communities, and control urban communities. Out of the 16 target BPs, ten were found in both e-waste and local household dust, while only six BPs were identified in the control urban household dust. Bisphenol A (BPA) remained the predominant compound, followed by bisphenol F (BPF), bisphenol S (BPS), BPSIP and bisphenol AF (BPAF). The total concentrations of BPs in e-waste dust were notably higher compared to both local and urban household dust (p < 0.01), with BPA and BPF, in particular, exhibiting significantly elevated levels. Importantly, BPSIP was first identified in e-waste dust, and its concentration significantly exceeded that of the commonly used BPA alternative, BPAF, which justifiably merits increasing concern. Correlation analysis indicated that BPs were commonly used in the production of electronic products, and e-waste dismantling activities contributed significantly to their widespread emission. The daily intakes of BP through dust ingestion for these three population groups exceeded the recently established tolerable daily intake for BPA, especially among e-waste dismantling workers. This represents the first report indicating that e-waste recycling is causing substantial emissions of multiple bisphenol analogues, including a novel contaminant.

Soil heavy metal pollution from waste electrical and electronic equipment of repair and junk shops in southern Thailand and their ecological risk

The waste electrical and electronic equipment (WEEE) stream in Thailand shifted from exporting WEEE to recycling them in domestic enterprises after China's import restrictions on e-waste in 2018. This study aims to investigate the pollution status, pollution sources, and ecological risk of heavy metals from manual WEEE dismantling facilities (12 repair shops and 8 junk shops) in the Nakhon Si Thammarat province of southern Thailand by examining the concentrations of As, Cd, Ni, and Pb in the topsoil (0–15 cm) during the wet and dry seasons. The results revealed that the mean concentrations of all heavy metals were higher during the dry season than in the wet season. The concentrations of analyzed soil heavy metals decreased as the intensity of e-waste dismantling activities increased, with recycling sites > repair sites > control sites (no e-waste recycling activities). Only 10% of WEEE processing workshops (junk shops) had soil Pb and As concentrations that exceeded Thailand's residential soil quality standards. However, ecological indexing models based on the geo-accumulation index found that 75% of electric repair shops were contaminated with the analyzed heavy metals, particularly Pb. Moreover, the Nemerow integrated pollution index indicated that 16.7% of electric repair shops were on the pollution warning line. Our findings suggest that policymakers should promote ecological risk assessment as a method for mitigating the negative environmental impact of electronic repair businesses, which are widely dispersed in residential areas and tend to dominate the WEEE stream because of the circular economy concept of “right to repair”, and highlight the decline of junk shops and e-waste dismantling villages for waste export resulting from China's ban.

Co-occurrence and distribution of organophosphate tri- and di-esters in dust and hand wipes from an e-waste dismantling plant in central China

Electronic waste (e-waste) dismantling facilities are a well-known source of emerging contaminants including organophosphate esters (OPEs). However, little information is available regarding the release characteristics and co-contaminations of tri- and di-esters. This study, therefore, investigated a broad range of tri- and di-OPEs in dust and hand wipe samples collected from an e-waste dismantling plant and homes as comparison. The median ∑tri-OPE and ∑di-OPE levels in dust and hand wipe samples were approximately 7- and 2-fold higher than those in the comparison group, respectively (p < 0.01). Triphenyl phosphate (median: 11,700 ng/g and 4640 ng/m2) and bis(2-ethylhexyl) phosphate (median: 5130 ng/g and 940 ng/m2) were the dominant components of tri- and di-OPEs, respectively. The combination of Spearman rank correlations and the determinations of molar concentration ratios of di-OPEs to tri- OPEs revealed that apart from the degradation of tri-OPEs, di-OPEs could originate from direct commercial application, or as impurities in tri-OPE formulas. Significant positive correlations (p < 0.05) were found for most tri- and di-OPE levels between the dust and hand wipes from dismantling workers, whereas this was not observed in those from the ordinary microenvironment. Our results provide robust evidence that e-waste dismantling activities contribute to OPEs contamination in the surroundings and further human exposure pathways and toxicokinetics are needed to be elucidated.

E-waste in Vietnam: a narrative review of environmental contaminants and potential health risks.

Informal electronic waste (e-waste) dismantling activities contribute to releasing hazardous compounds in the environment and potential exposure to humans and their health. These hazardous compounds include persistent organic pollutants (POPs), polycyclic aromatic hydrocarbons (PAHs) and heavy metals. This review searched papers addressing hazardous compounds emitted from e-waste recycling activities and their health effects in Vietnam. Based on the keywords searched in three electronic databases (PubMed, Psych Info, and Google scholar), we found 21 relevant studies in Vietnam. The review identifies extensive e-waste dismantling activities in Vietnam in the northern region. To measure the environmental exposure to hazardous compounds, samples such as e-waste recycling workshop dust, soil, air, and sediments were assessed, while human exposure levels were measured using participants' hair, serum, or breast milk samples. Studies that compared levels of exposure in e-waste recycling sites and reference sites indicated higher levels of PBDEs, PCBs, and heavy metals were observed in both environmental and human samples from participants in e-waste recycling sites. Among environmental samples, hazardous chemicals were the most detected in dust from e-waste recycling sites. Considering both environmental and human samples, the highest exposure difference observed with PBDE ranged from 2-48-fold higher in e-waste processing sites than in the reference sites. PCBs showed nearly 3-fold higher levels in e-waste processing sites than in reference sites. In the e-waste processing sites, age-specific higher PCB levels were observed in older recycler's serum samples. Among the heavy metals, Pb was highly detected in drinking water, indoor soil and human blood samples. While high detection of Ni in cooked rice, Mn in soil and diet, Zn in dust and As in urine were apparent. Exposure assessment from human biomonitoring showed participants, including children and mothers from the e-waste processing areas, had higher carcinogenic and non-carcinogenic risks than the reference sites. This review paper highlights the importance of further comprehensive studies on risk assessments of environmentally hazardous substances and their association with health outcomes at e-waste processing sites.

Occurrence, spatial distributions, and temporal trends of bisphenol analogues in an E-waste dismantling area: Implications for risk assessment

The environmental occurrences of bisphenol analogues (BPs) have been extensively reported, whereas their concentration profile, spatial distribution, and temporal trend in e-waste dismantling area are still poorly understood. Herein, typical BPs (BPA, BPS, TBBPA, TBBPA-DHEE, and TBBPA-MHEE) were investigated in water, soil, and biological samples from three representative regions (FJT, JJP, and RIB) in e-waste recycling area in Taizhou, Zhejiang Province. Overall, the detection frequency of BPs in all samples was 100 %, confirming widespread presence of BPs in e-waste recycling area. Wherein, BPA was the predominant BPs in water (33.3 %) and soil samples (34.9 %), but TBBPA accounted for the largest proportion (41.3 %) in biological samples. In addition, the concentration of BPs in FJT was lower than that in JJP and RIB owing to the renovations on FJT by the local government in recent years, whereas the higher BPs level in RIB implied that elevated BPs contents was related to massive e-waste dismantling activities. From 2017 to 2021, a decreased trend of BPs concentration was observed in FJT, but aggravation of BPs levels in RIB was caused by the ongoing e-waste dismantling. The risk assessment revealed that the BPs in e-waste recycling area posed a low ecological and human health risk. Our finding could provide a valuable reference for the development of strict legislation systems related to e-waste management in China.

First Evidence of Prenatal Exposure to Emerging Poly- and Perfluoroalkyl Substances Associated with E-Waste Dismantling: Chemical Structure-Based Placental Transfer and Health Risks.

Limited information is available about prenatal exposure to per- and polyfluoroalkyl substances (PFAS) in electronic waste (e-waste) recycling sites. In this study, we determined 21 emerging PFAS and 13 legacy PFAS in 94 paired maternal and cord serum samples collected from an e-waste dismantling site in Southern China. We found 6:2 fluorotelomer sulfonate (6:2 FTSA), 6:2 chlorinated polyfluorinated ether sulfonate (6:2 Cl-PFESA), and perfluorooctanephosphonate (PFOPA) as the major emerging PFAS, regardless of matrices, at median concentrations of 2.40, 1.78, and 0.69 ng/mL, respectively, in maternal serum samples, and 2.30, 0.73, and 0.72 ng/mL, respectively, in cord serum samples. Our results provide evidence that e-waste dismantling activities contribute to human exposure to 6:2 FTSA, 6:2 Cl-PFESA, and PFOPA. The trans-placental transfer efficiencies of emerging PFAS (0.42-0.94) were higher than that of perfluorooctanesulfonic acid (0.37) and were structure-dependent. The substitution of fluorine with chlorine or hydrogen and/or hydrophilic functional groups may alter trans-placental transfer efficiencies. Multiple linear regression analysis indicated significant associations between maternal serum concentrations of emerging PFAS and maternal clinical parameters, especially liver function and erythrocyte-related biomarkers. This study provides new insights into prenatal exposure to multiple PFAS in e-waste dismantling areas and the prevalence of emerging PFAS in people living near the sites.

Is e-waste a source of phthalate and novel non-phthalate plasticizers? A comparison study on indoor dust

Nine traditional phthalate plasticizers and 33 novel non-phthalate plasticizers were determined in indoor dust from a typical e-waste recycling area. The median concentrations ranged from <LOQ to 22,700 ng/g for phthalates and from <LOQ to 1250 ng/g for non-phthalates. Bis-(2-ethylhexyl) phthalate (DEHP) and di-isononyl phthalate (DINP) were the two major phthalates in dust, while glycerol monooleate (GMO) and methyl oleate (MO) were the predominant non-phthalates. Different pollutant patterns among different sites implied multiple sources of the plasticizers. Using the ratio of DINP/DEHP as an indicator, we evaluated the impact of e-waste source emission on the sampling sites, resulting in an impact rank of Matou > Dakeng > Baihetang > Shiding > Jieyang, which was consistent with the local e-waste dismantling activities and supported by polybrominated diphenyl ethers (PBDEs) levels. The correlations between chemical levels and the indicators indicated that most phthalates and non-phthalate plasticizers in the dust, might not be primarily influenced by e-waste emission sources. Additionally, the estimated median human exposures of phthalates and non-phthalates via dust ingestion were 30.6 and 1.82 ng/kg/day for adults, and 299 and 17.8 ng/kg/day for toddlers respectively, indicating negligible health risks.

Distribution characteristics and risks assessment of brominated flame retardants in surface soil from both a legacy and a new e-waste dismantling site

Brominated flame retardants (BFRs) are widely used in diverse industries, resulting in extensive environmental contamination. Although many legacy BFRs have been banned and replaced with novel brominated flame retardants (NBFRs), these NBFRs have also been found to exhibit toxicity and persistence. In this study, 55 soil samples were collected from areas surrounding an abandoned (FJ) and a newly built (TZ) e-waste dismantling zone which represent the traditional and modern e-waste dismantling practice in China, respectively, to examine and compare the occurrence of BFRs and their potential ecological and health risks. The concentrations of novel brominated flame retardants (NBFRs) ranged from 10.0 to 2,390 ng/g dw, and those of polybrominated diphenyl ethers (PBDEs) ranged from 78.0 to 13,300 ng/g dw. Decabromodiphenyl ethane (DBDPE) to BDE-209 ratios were greater than one in 6.8% and 25% of samples in FJ and TZ, respectively. BFRs concentrations in FJ soils significantly decreased with increasing distance to the center of FJ, indicating that the soil in the FJ region was strongly affected by the e-waste dismantling activities in FJ. For TZ, only DBDPE exhibited similar regulation, indicating that the newly built e-waste dismantling zone has already impacted on the surrounding environment. The Mann–Whitney test showed that the concentrations of most PBDE congeners were higher in FJ (P < 0.01/0.05) than those in TZ, while there was no significant difference in the concentrations of most NBFRs between FJ and TZ. A low abundance of BDE-209 in soils suggests that its degradation process and DBDPE was the predominant NBFRs in soils from both FJ and TZ. It was found that low-brominated PBDE congeners posed high ecological risks to terrestrial animals, which the ecological risks may increase in the future due to the debromination process of high PBDE congeners. The health hazard of BFRs via soil exposure in FJ was generally higher than in TZ, although both were acceptable. Despite much greater average daily doses for BDE-209 and DBDPE, the oral hazard quotients of BDE-47 and BDE-99 were much higher. Toddlers were found to face a higher health risk due to soil exposure than teenagers and children. The carcinogenic effect of BDE-209 was also acceptable in FJ and TZ. With the continuous operation of the TZ site, the further accumulation of BFRs in soils and health hazard via BFRs exposure are expected, and the results suggest that ongoing monitoring and further research is necessary. We believe that our work could help researchers investigate and reveal the harmful impacts of NBFRs and PBDEs.

Exposure, risk and predictors of hexabromocyclododecane and Tetrabromobisphenol-A in house dust from urban, rural and E-waste dismantling sites in Thailand.

In this study, for the first time, we determined concentrations of hexabromocyclododecane (HBCDD) and tetrabromobisphenol-A (TBBPA) in house dust and estimated human exposure to these substances in houses located in an e-waste dismantling site and in urban and rural residential areas of Thailand. The median HBCDD concentration in urban residential houses (2.10ngg-1) was similar to that in houses in an e-waste dismantling site (2.05ngg-1, p>0.05) and slightly higher than that in rural residential houses (1.11ngg-1, p>0.05). In contrast, significantly higher TBBPA concentrations were present in house dust from an e-waste dismantling site (median=720ngg-1; range=44-2300ngg-1) compared to those in urban (68.6ngg-1; 3.5-300ngg-1, p<0.001) and rural residential areas (17ngg-1; 2.0-201ngg-1, p<0.001). TBBPA concentrations increased with the increasing presence of electronic devices and a decreasing distance to the e-waste dismantling site. These results suggest that e-waste dismantling activities may contribute to TBBPA contamination of house dust. The median estimated daily intake (EDI) of HBCDD and TBBPA through dust ingestion for toddlers exceeded that for children and adults. However, EDI values for HBCDD and TBBPA from all age groups were below the oral reference dose guideline value suggested by the US National Research Council and National Toxicology Program (NTP).

Polycyclic aromatic hydrocarbons in PM2.5 from an e-waste source site and a receptor site in Southern China: Atmospheric transport and process implications

Polycyclic aromatic hydrocarbons (PAHs) are potential contaminants released from informal electronic waste (e-waste) recycling. PAHs in PM2.5 collected at a rural e-waste (source) site and a background (receptor) site in Southern China were measured. Seasonal variations and regional transport of PAHs were investigated, and their sources and atmospheric processes were implied. The median concentrations of ∑18PAHs at the e-waste site (13.7 ng/m3) were one order of magnitude higher than those at the background site (median = 1.54 ng/m3), indicating the informal e-waste dismantling was a significant source. The seasonal variations of PAH concentrations at the two sites were similar, exhibiting noticeably unimodal distributions in winter, predominantly associated with the strengthened e-waste dismantling activities. Three molecular diagnostic ratios (MDRs) can be collectively used as potential markers of field informal e-waste burning sources. The dispersion model revealed that regional atmospheric transport from this e-waste site was a source of PAHs in the background air. Some MDRs significantly changed at the background site compared to the source site but could not be explained by the lifetime and/or gas-particle partition of the isomers. The differences complied with recent theories about the multiphase reactivity and evaporation of PAHs on aerosols. It was proposed that in warm and humid climates, the losses of PAHs from PM2.5 were dominated by their phase separation or diffusion, which was n-octanol/water partition coefficient (KOW) dependent. This hypothesis was further supported by data in the literature.

Ecological and human health risk assessment of heavy metals based on their source apportionment in cropland soils around an e-waste dismantling site, Southeast China

An accurate understanding of soil heavy metal (HM) pollution characteristics and source apportionment, and a recognition of the major factors influencing ecological and human health risks (HHRs) are essential for soil HM pollution control and remediation. In this study, 212 surface soils (0–20 cm) and 15 profile soils (0–100 cm) were collected from cropland soils around an e-waste dismantling site in Taizhou city, Zhejiang Province, China. Spatial analysis was used to evaluate the pollution characteristics of HMs (Cd, Cu, Pb, Zn, Cr and Ni). Principal component analysis (PCA) and positive matrix factorization (PMF) were also conducted to quantify their source contributions. A modified source-oriented HHR assessment integrated source-oriented ecological risk and source-oriented HHR assessment was developed to describe the major factors that influenced HHR. Results showed that 94.81 %, 88.21 %, 36.79 % and 47.17 % of Cd, Cu, Pb and Zn, respectively, in surface soils exceeded their screening values in the soil environmental quality standard for agricultural soils (GB 15618–2018). Spatial analysis indicated that high values of Cd, Cu, Pb and Zn were distributed near the e-waste dismantling site. The results of PCA and PMF showed that the primary sources of HMs in the study area are e-waste dismantling activities, natural sources and atmospheric deposition, which contribute 27 %, 46 % and 27 % of HM pollutants, respectively. The results of source-oriented ecological risk and HHR assessment indicated that e-waste dismantling activities and natural sources were primary sources for ecological risk and HHR. However, source-oriented HHR assessment may underestimate the contribution of e-waste dismantling activities by ignoring HM pollution levels. The modified source-oriented HHR assessment highlights that e-waste dismantling activities were major factor that affect noncarcinogenic risk. This study could provide important data support for subsequent environmental remediation of soil HM pollution in cropland soils around e-waste dismantling sites.

Spatial variation of heavy metals and their ecological risk and health risks to local residents in a typical e-waste dismantling area of southeastern China.

There is an increasing concern that soils in e-waste recycling regions are severely contaminated by unregulated e-waste dismantling activities. Hence, it is urgent to reveal the spatial variation of hazardous elements in arable lands close to e-waste stacking and dismantling areas and their potential risks to human beings. We collected 349 topsoil samples based on an intensive grid of 100m × 100m in southeastern China. The average concentrations of heavy metals were 1.25 (Cd), 35.44 (Ni), 77.68 (Cr), 77.38 (Pb), 122.14 (Cu), 203.39 (Zn), 0.21 (Hg), and 4.74 (As) mg kg-1, respectively. Compared to the risk screening values of hazardous elements in Chinese agricultural land, Cd and Cu were severely accumulated in the soils. The results of ecological risk analysis revealed that Cd posed the crucial risk among the studied elements. However, the levels of non-carcinogenic and carcinogenic risk were still within the acceptable quantity for adults. Spatial distribution by kriging interpolation displayed that the heavy metals were mainly distributed close to e-waste dismantling sites.

Legacy and alternative flame retardants in indoor dust from e-waste industrial parks and adjacent residential houses in South China: Variations, sources, and health implications

Many studies have elucidated health concerns of informal e-waste recycling activities, yet few has evaluated the effectiveness of the regulations as well as the human exposure risks to adjacent residents. Herein, legacy polybrominated diphenyl ethers (PBDEs), hexabromocyclododecane (HBCDs), and alternative organophosphate esters (OPEs) were investigated in indoor dust collected from three e-waste industrial parks and five adjacent villages located in south China. The levels and composition patterns varied significantly between workshop and home dust. BDE209 showed much higher (p < 0.01) concentrations in workshop dust versus home dust, while relatively comparable levels were found for OPEs and HBCDs. Principal component analysis revealed that OPEs and PBDEs were mainly related to home and workshop dust, respectively. Results strongly indicated that e-waste dismantling activities still contribute to a high burden of BDE209 to surrounding residents, whilst the sources of OPEs may also originated from household products, especially for TCEP. The estimated daily intakes (EDIs) via dust ingestion and dermal absorption for occupational worker and nearby toddlers were below available reference dose (RfD) values even at worst case scenario. This study highlights the significance of deca-BDEs rather than alternative OPEs in e-waste generated in China, which could provide scientific suggestions for policy formulation.

Atmospheric occurrences of nitrated and hydroxylated polycyclic aromatic hydrocarbons from typical e-waste dismantling sites

Primitive electronic waste (e-waste) dismantling activities have been shown to be an important emissions source for a variety of toxic organic compounds, including carcinogenic polycyclic aromatic hydrocarbons (PAHs). Previous studies have found that some nitrated PAHs (NPAHs) are more toxic than their parent PAHs, however, little attention has been paid to the formation of PAH derivatives during e-waste processing and there is a lack of comprehensive data from field observations. In this study, the spatial distribution, temporal trends and atmospheric fate of NPAHs and hydroxylated PAHs (OH-PAHs) were investigated at typical e-waste dismantling sites, with monitoring data collected over three consecutive years. Compared to background levels, higher levels of NPAHs and OH-PAHs were found in air samples from an e-waste dismantling industrial park, with their seasonal and annual changes shown to be affected by e-waste dismantling activities. Atmospheric PM2.5 particles were found to have high relative abundances of NPAHs (76.9%–95.1%) and OH-PAHs (73.3%–91.6%), with particle-bound concentrations ranging from 20.1 to 88.8 and 37.1 to 107 pg m−3, respectively. The most abundant NPAH isomers were found to be 9-Nitroanthracene and 2-Nitrofluoranthene, while OH-PAH isomers containing 2–4 rings were predominant. Source identification was performed based on the specific diagnostic ratios of NPAH isomers, confirming that NPAH and OH-PAH emissions have multiple sources, including emissions related to the e-waste dismantling process, atmospheric photochemical reactions and traffic emissions. Further research on the fate of such derivatives and their potential use as markers for source identification, is urgently required.

Novel insights into probabilistic health risk and source apportionment based on bioaccessible potentially toxic elements around an abandoned e-waste dismantling site

The study of potentially toxic element (PTE) hazards around e-waste recycling areas has attracted increasing attention but does not consider elemental bioaccessibility. Here, the respiratory and oral bioaccessibilities were incorporated into probabilistic health risk evaluation and source contribution apportionment. The results showed that soil Cd yielded the highest respiratory and oral bioaccessibility, whereas Cr in soils and vegetables attained the lowest oral bioaccessibility. When incorporating metal bioaccessibility into health risk assessment, a 48.3%–55.7% overestimation of non-cancer and cancer risks can be avoided relative to the risk assessment based on the total concentrations of PTEs. More importantly, priority control metals were misidentified without consideration of bioaccessibility. Cadmium, As, and Cr were screened as the priority metal(loid)s for targeted risk control based on the total PTEs, whereas Cd, Zn, and Cu were the priority metal(loid)s based on the bioaccessible PTEs. Furthermore, source apportionment revealed that >50% of oral bioaccessible Cd, Cu, Ni, Pb, and Zn in farmland were contributed by e-waste dismantling activities, whereas bioaccessible As and Cr mainly originated from agrochemical applications and natural sources, respectively. This study emphasizes the refinement of risk estimation and source apportionment through metal bioaccessibility adjustment, which facilitates the realistic assessment of adverse health effects in humans and the precise identification of high-risk sources.

Brominated flame retardants (BFRs) in sediment from a typical e-waste dismantling region in Southern China: Occurrence, spatial distribution, composition profiles, and ecological risks

Our study evaluated the current occurrence, composition, and spatial distribution of eight congeners of polybrominated diphenyl ethers (PBDEs) and seven novel brominated flame retardants (NBFRs) in sediment from Guiyu, a typical e-waste dismantling region in China. PBDEs levels ranged from 0.345 to 401,000 ng/g dw and NBFRs levels ranged from 0.581 to 73,100 ng/g dw. Almost all sediment samples contained high levels of BDE-209 and DBDPE, and the ratio of DBDPE/BDE-209 in sediments ranged from 0.0814 to 2.80 (mean: 0.879). The concentration and composition profiles for BFRs in sediments from both mainstream and tributaries of two major rivers in Guiyu reach (and adjacent downstream locations) differed significantly from those far from Guiyu town. Whereas the high presence of BFRs in Guiyu reflected the historical crude e-waste dismantling activities in the region; the locations far from Guiyu town were likely to receive BFRs from atmospheric deposition, not originated from the region, as BFRs in water-sediment are known to be able to migrate a limited distance along the river. Ecological risk assessment revealed that the low brominated congeners of PBDEs and BDE-209 posed an unacceptable risk to the sedimentary life at multiple locations. Our results updated our knowledge of BFRs contamination in Guiyu, suggesting the necessity of continuous source monitoring, control procedures, and sediment cleanup for BFRs.

Changes in levels of legacy and emerging organophosphorus flame retardants and plasticizers in indoor dust from a former e-waste recycling area in South China: 2013-2017.

To assess the impacts of e-waste regulations on environmental pollution, the levels, compositions, and human exposure assessment of organophosphorus flame retardants (PFRs), emerging PFRs (ePFRs), phthalate esters (PAEs), and alternative plasticizers (APs) were investigated in indoor dust samples collected from homes in a former e-waste dismantling area in 2013 and in 2017, 4 years after the implementation of legislation and regulations governing e-waste dismantling activities in this area. The median concentrations of ΣPFRs, ΣePFRs, ΣPAEs, and ΣAPs in dust decreased from 5680, 1650, 167,200, and 140,600 ng/g in 2013 to 1210, 476, 95,000, and 45,300 ng/g in 2017, respectively, suggesting that the national and local regulations prohibiting primitive e-waste dismantling activities is effective in mitigating the pollution status for these chemicals. In the analyzed dust samples, tris(1-chloro-2-propyl) phosphate (TCIPP), triphenyl phosphate (TPHP), resorcinol bis(diphenylphosphate) (RDP), and bisphenol A-bis(diphenyl phosphate) (BDP) were the major PFRs/ePFRs, contributing to 77% and 76% of the total PFRs/ePFRs in 2013 and 2017, respectively. Di(2-ethylhexyl) phthalate (DEHP), di-iso-nonyl phthalate (DINP), di-iso-decyl phthalate (DIDP), and di-n-butyl phthalate (DNBP) were the major PAEs/APs, with contributions of 89% and 95% for the total PAEs/APs in 2013 and 2017, respectively. The results of the human exposure assessment demonstrated that exposure to these levels of the target chemicals via dust ingestion and dermal contact was unlikely to cause health concerns for local residents.