Vertical profiles and lateral distribution patterns of heavy metals in Recent sediments are increasingly employed in the assessment of the major sources of pollution in coastal regions, including estuaries and marginal seas. After a general review of studies from typical locations, examples from New Bedford Harbor, Mass./U.S.A., and from the southern German Bight in the North Sea are described in more detail. Chemical extraction procedures are used to evaluate different forms of metal associations in aquatic sediments: (i) heavy metals are transported and deposited as major, minor and trace constituents in the natural rock detritus, mostly in inert positions; (ii) slight alkalinity in sea water results in the formation and precipitation of hydroxides, carbonates, sulphides and phosphates of heavy metals; (iii) sorption and cation exchanges takes place in particular on fine-grained substances with large surface areas, e.g. on manganese dioxide, humic acids, hydrous iron oxides and clay minerals; (iv) organic substances play an important role in the transfer of metals between dissoved and solid phases, particularly by the process of flocculation; (v) under oxidizing conditions, the redox-sensitive Fe- and Mn-hydroxides and -oxides are significant “sinks” of heavy metals in aquatic systems. The characteristic rise in the residual content of lead, copper and cadmium in the polluted samples points toward the strong influence of atmospheric dust particles. Heavy metals immobilized in the bottom sediment constitute a potential hazard to water quality and aquatic life since they may be released as a result of chemical changes. In relation to the marine environment, the following mechanisms should be taken into account: (i) increased salinities at the inflow of rivers into the sea water will affect the partial exchange of metal cations sorbed onto the surface of suspended particles; (ii) oxygen deficiency in the bottom sediments may lead to the dissolution of hydrous iron and manganese oxides and to a release of co-precipitated heavy metals; (iii) complexing substances of both natural and synthetic origin increases the solubilization of metals; (iv) microbial activities can convert inorganic metal compounds to organic molecules and may thereby increase toxicity, as exemplified in organo-mercurial transformations.
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