Fraction Of Dust Research Articles

Computational Mechanistic Analysis of the Formation of the Magnesium Silicate Monomers MgSiO3 and Mg2SiO4.

Silicate grains comprise a large fraction of cosmic dust, motivating a need to understand how they form. The current body of work on silicates generally reflects the abundance of silicate grains, yet models for their formation often do not consider silicate chemistry on the smallest scale, which can form species available for dust grain nucleation processes. In order to expand upon previous attempts to bridge this gap in silicate chemistry, novel gas-phase reaction pathways for the magnesium silicate monomers enstatite (MgSiO3) and forsterite (Mg2SiO4) from MgH, H2O, and SiO are presently computed using highly accurate quantum chemical calculations. MgSiO3 and Mg2SiO4 form through a series of reactions that initially excludes silicon addition, creating the elusive species MgOH and Mg2O prior to further reaction. The formation of the two silicate monomers is expected to be efficient with the primary bottleneck being the amount of MgH available for reaction. The addition of these reactions to cosmic chemical networks will add further clarity to the processes that govern dust formation, most significantly for those occurring within stellar outflows of asymptotic giant branch stars.

A new census of dust and polycyclic aromatic hydrocarbons at z = 0.7–2 with JWST MIRI

Aims. This paper utilises the James Webb Space Telescope (JWST) Mid-Infrared Instrument (MIRI) to extend the observational studies of dust and polycyclic aromatic hydrocarbon (PAH) emission to a new mass and star formation rate (SFR) parameter space beyond our local Universe. The combination of fully sampled spectral energy distributions (SEDs) with multiple mid-infrared (mid-IR) bands and the unprecedented sensitivity of MIRI allows us to investigate dust obscuration and PAH behaviour from z = 0.7 up to z = 2 in typical main-sequence galaxies. Our focus is on constraining the evolution of PAH strength and the dust-obscured luminosity fraction before and during cosmic noon, the epoch of peak star formation activity in the Universe. Methods. In this study, we utilise MIRI multi-band imaging data from the SMILES survey (5 to 25 μm), complemented with NIRCam photometry from the JADES survey (1 to 5 μm), available HST photometry (0.4 to 0.9 μm), and spectroscopic redshifts from the FRESCO and JADES surveys in GOODS-S for 443 star-forming (without dominant active galactic nucleus (AGN)) galaxies at z = 0.7 − 2.0. This redshift range was chosen to ensure that the MIRI data cover mid-IR dust emission. Our methodology involved employing ultraviolet (UV) to IR energy balance SED fitting to robustly constrain the fraction of dust mass in PAHs and dust-obscured luminosity. Additionally, we inferred dust sizes from MIRI 15 μm imaging data, enhancing our understanding of the physical characteristics of dust within these galaxies. Results. We find a strong correlation between the fraction of dust in PAHs (PAH fraction, qPAH) with stellar mass. Moreover, the sub-sample with robust qPAH measurements (N = 216) shows a similar behaviour between qPAH and gas-phase metallicity to that at z ∼ 0, suggesting a universal relation: qPAH is constant (∼3.4%) above a metallicity of Z ∼ 0.5 Z⊙ and decreases to < 1% at metallicities ≲0.3 Z⊙. This indicates that metallicity is a good indicator of the interstellar medium properties that affect the balance between the formation and destruction of PAHs. The lack of a redshift evolution from z ∼ 0 − 2 also implies that above Z ∼ 0.5 Z⊙ the PAH emission effectively traces obscured luminosity and the previous locally calibrated PAH-SFR calibrations remain applicable in this metallicity regime. We observe a strong correlation between the obscured UV luminosity fraction (ratio of obscured to total luminosity) and stellar mass. Above the stellar mass of M* > 5 × 109 M⊙, on average, more than half of the emitted luminosity is obscured, while there exists a non-negligible population of lower-mass galaxies with > 50% obscured fractions. At a fixed mass, the obscured fraction correlates with SFR surface density. This is a result of higher dust covering fractions in galaxies with more compact star-forming regions. Similarly, galaxies with high IRX (IR to UV luminosity) at a given mass or UV continuum slope (β) tend to have higher ΣSFR and shallower attenuation curves, owing to their higher effective dust optical depths and more compact star-forming regions.

STUDY OF FERROCHROME SMELTING TECHNOLOGY USING BRIQUETTES WITH VARIOUS CARBONACEOUS REDUCERS

This study explores the ferrochrome smelting technology using briquettes with various carbonaceous reducers. The research addresses the significant challenge of dust and fine fractions of raw materials generated during the metallurgical industry's crushing, beneficiation, storage, and transportation processes. Briquettes were produced and tested by agglomerating chrome ore dust with carbonaceous reducers for their mechanical properties and effectiveness in smelting processes. The study concludes that carbonaceous reducers' ash content significantly affects the chrome ore-containing briquettes' thermal stability and electrical conductivity. Low ash content was associated with better performance in the smelting process. Using briquettes with various carbonaceous reducers offers a flexible approach to charge composition, depending on specific production needs and the availability of reducers. The results highlight the potential for improved environmental impact, reduced material losses, and enhanced efficiency in ferrochrome production.

Impact Mill

An impact mill has been developed to produce powders from shavings of refractory metals using impact grinding method for reuse in electrometallurgy in devices with screw feed, for example, in 3D printers. The proposed device provides high uniformity of grinding with a minimum content of dust fraction and impurity content at low technical and economic costs. The result is achieved by using a Laval nozzle, which operates in the supersonic jet formation mode. In the area of the first Mach disk there are rod fenders arranged in a cascade, and the impact plate is located in the turbulence zone and is equipped with winglets with holes for separating crushed metal.

Energy valorization of solid residue from steam distillation of aromatic shrubs

The interest for essential oils is increasing, alongside ongoing scientific research into distillation techniques. This process generates significant solid residue that could be revalorized as energy source. This study explores the energy recovery of the solid fraction produced during the distillation of three aromatic plants: Cistus ladanifer, Juniperus communis and Rosmarinus officinalis. Two conventional energy recovery technologies were considered and compared through an energy balance: solid biofuel production and biogas generation. In case of solid biofuels, the fractionation of biomass allowed for generation of three different qualities that meet the regulation standards of solid fuels, except for the dust fraction. According to the energy balance, the alternative use of these substrates for biogas production showed competitive production in case of Cistus ladanifer and Juniperus communis, while Rosmarinus officinalis biomass presented inhibition of the anaerobic digestion and null energy recovery.

The Fraction of Dust Mass in the Form of Polycyclic Aromatic Hydrocarbons on 10–50 pc Scales in Nearby Galaxies

Polycyclic aromatic hydrocarbons (PAHs) are a ubiquitous component of the interstellar medium (ISM) in z ∼ 0 massive, star-forming galaxies and play key roles in ISM energy balance, chemistry, and shielding. Wide field-of-view, high-resolution mid-infrared (MIR) images from JWST provide the ability to map the fraction of dust in the form of PAHs and the properties of these key dust grains at 10–50 pc resolution in galaxies outside the Local Group. We use MIR JWST photometric observations of a sample of 19 nearby galaxies from the Physics at High Angular Resolution in Nearby GalaxieS (PHANGS) survey to investigate the variations of the PAH fraction. By comparison to lower-resolution far-infrared mapping, we show that a combination of the MIRI filters (R PAH = [F770W+F1130W]/F2100W) traces the fraction of dust by mass in the form of PAHs (i.e., the PAH fraction, or q PAH). Mapping R PAH across the 19 PHANGS galaxies, we find that the PAH fraction steeply decreases in H ii regions, revealing the destruction of these small grains in regions of ionized gas. Outside H ii regions, we find R PAH is constant across the PHANGS sample with an average value of 3.43 ± 0.98, which, for an illuminating radiation field of intensity 2–5 times that of the radiation field in the solar neighborhood, corresponds to q PAH values of 3%–6%.

Elemental composition of household dusts extracted in simulated body fluids and their impact on culturable pathogenic bacteria responses

In the last decade, a great deal of research has focused on the determination of potential toxic elements by total concentration and identification the microorganisms in dust. However, determining bio-relevant (e.g., inhalable) forms of elements instead of total contents in acids is necessary for human health. Moreover, examination of the behavior of microorganism under these bio-relevant conditions and revealing the interaction between elements and pathogens is vital and necessary for deeper understanding. However, previous studies have ignored these topics. Therefore, the present study aimed to (i) investigate elements in household dusts extracted in simulated lung fluids, (ii) examine the total concentration of culturable bacteria and their biochemical responses with exposure to bio-fractions of household dusts, and (iii) assess their relations and risks using the model approaches by inhalation. Here, settled dusts were collected in 25 houses, and extracted in four simulated body fluids to determine bio-fractions of elements. Moreover, total count of potentially pathogenic and heterotrophic bacteria, and four clinically important culturable pathogens were incubated in the presence of household-dusts extracted in simulated body fluids. The activity, biofilm, biochemical and oxidative responses of pathogens were measured following household-dust exposures. Afterward, the relationship between elements and pathogen responses were evaluated, and model and derived approaches were used for risk assessments of elements and pathogens. The higher daily intake of elements obtained in artificial lysosomal fluid fraction of household dust mimicking the inflammatory condition compared to other body fluids. Moreover, bacterial responses were mainly influenced from bio-fractions of household dusts and their elemental contents.

The oxidative stress-dependent pulmonary inflammation of inhalable multi-walled carbon nanotube-containing nano-concrete dust and its comparison with conventional concrete dust and DQ12

Nano-concrete, which is an admixture of nanomaterials in concrete recipes, has been investigated to overcome the limitations of existing concrete, such as its stability and strength. However, there is no information on the human health effects of broken-down dust released during the construction and demolition efforts. In this study, we prepared an inhalable fraction of multi-walled carbon nanotube-containing nano-concrete dust and performed comparative toxicity studies with conventional concrete dust and DQ12 using a rat intratracheal instillation model. Although the recipes for concrete and nano-concrete are entirely different, the pulverized dust samples showed similar physicochemical properties, such as 0.46–0.48 µm diameter and chemical composition. Both concrete and nano-concrete dust exhibited similar patterns and magnitudes, representing acute neutrophilic inflammation and chronic active inflammation with lymphocyte infiltration. The toxicity endpoints of the tested particles at both time points showed an excellent correlation with the reactive oxygen species levels released from the alveolar macrophages, highlighting that alveolar macrophages are the primary target cells and that the oxidative stress paradigm is the main toxicity mechanism of the tested particles. In addition, the toxicity potentials of both concrete and nano-concrete dust were more than 10 times lower than that of DQ12.

Hubungan komunitas moluska dengan parameter lingkungan di kawasan mangrove Pulau Penyu, Tanjung Benoa, Bali

Mangroves are plants in coastal and estuary areas that are influenced by tides. Mangroves provide essential habitats as spawning, nursery and food sources for various biota, including mollusks. Mollusks have a reciprocal relationship with mangrove plants, play an important role in maintaining the balance of the food chain in mangrove ecosystems. The objective of the research is to establish the structure of the mollusk community and its correlation with environmental conditions in the Pulau Penyu mangroves. The study was carried out in September 2023. The method employed the 1x1m quadrat transect with 15 points per station. Salinity, pH, temperature and substrate type are all measurements of environmental conditions. The research revealed 24 species, including 20 gastropod species and 4 bivalvia species from 12 mollusk families. Families found include Potamididae, Cerithiidae, Batillariidae, Ellobiidae, Mitridae, Neritidae, Littorinidae, Naticidae, Muricidae, Veneridae, Cyrenidae and Corbulidae. Mollusk abundance ranged from 0,07 to 13,07 ind/m2 at the research site, with Cerithium coralium being the most abundant species and Corbula macgillivrayi being the least abundant. The results of diversity index is 1,90 to 2,25; evenness index is 0,68 to 0,78; dominance index is 0,18 to 0,25; indicating moderate species diversity, high individual numbers each species, and no dominant species. The range of environmental parameter values obtained were; temperature ranges from 34,1 to 35,37 oC; pH ranges from 6,43 to 6,68; and salinity ranges from 35,2 to 36,3 ppt. The substrate type at the research site was sandy clay and clayey sand. PCA analysis results indicate a strong relationship between mollusk abundance and pH, salinity and sand fraction, but very weak relationship with temperature, dust and clay fraction.

Magnetic properties and load of potentially toxic heavy metals carried by the coarse and fine fractions of indoor dust

The granulometric fractions of indoor dust, categorized as coarse (grain size of 1.00–0.071 mm) and fine (grain size <0.071 mm), were investigated to discern variations in their magnetic properties and contents of potentially toxic heavy metals. Monthly dust samples were gathered from January 2021 to December 2022 from a private apartment situated on the outskirts of a large urban agglomeration (Warsaw, Poland). To assess indoor dust, several magnetic parameters, including mass-specific magnetic susceptibility, were employed. Portable X-ray fluorescence measurements were utilized to evaluate the enrichment of granulometric fractions in harmful heavy metals. The study reveals a comparable composition of magnetic minerals irrespective of grain size (magnetite and metallic iron), with variations observed in the domain state of magnetic particles (contribution of single-domain (SD) grains to multi-domain (MD)). Seasonal fluctuations were predominantly noted in the distribution of the fine fraction's mass during the warm season (May–July). A notable increase was observed in the fine fraction's mass contribution to the total dust mass compared to the winter season (December and February). The fine fraction was highly enriched in toxic metals, including Pb, Cr, Cu, Mn, Fe, and Sr. Pollution Load index is 6–8 for the fine fraction and 2–8 for the coarse fraction. The increase in the fine fraction mass induces linear changes in magnetic susceptibility, likely associated with the rise in anthropogenic magnetic particles. This finding holds significant implications for human health, as fine particles laden with toxic heavy metals can enter the human respiratory tract causing adverse health effects.

Contribution of Saharan dust to chemical weathering fluxes and associated phosphate release in West Africa

Huge amounts of mineral dust are produced in northern Africa, representing the largest source of aerosols worldwide. Transatlantic dust transport is known to fertilize soils as far as in the Amazon Basin. Yet, the influence of Saharan dust on chemical weathering fluxes and associated nutrient release in West Africa remains largely overlooked. To address this issue, we analysed clay fractions (<2 µm) of river sediments (n = 37) from across the Niger River basin - the largest river system in West Africa - using neodymium and hafnium isotope compositions as proxies for provenance (εNd) and chemical weathering (ΔεHf CLAY).Compared to previously published data for corresponding sand fractions, measured εNd values indicate significant size-dependent decoupling for Nd isotopes in most samples, with εNd differences between clay and sand fractions yielding values as great as ∼26 ε-units. Using mixing models, we show that this discrepancy reflects the overwhelming presence in the studied clay fractions of Harmattan dust blown from the Bodélé Depression in Chad, which we estimate to account for about 40 % of the fine-grained sediment load exported to the Gulf of Guinea. Additionally, significant ΔεHf CLAY variability occurs across the Niger catchment, partly explained by the presence of zircon in clay-size fractions, but also by preferential alteration of dust-borne accessory phosphate minerals in the subtropical regions of the watershed.Based on these results, we propose that Saharan dust plays a major role in controlling regional patterns of chemical weathering in West Africa, suggesting that enhanced wet deposition of mineral dust in shield areas dominated by transport-limited weathering regime can result in a large increase in weatherability and associated release of phosphorus. These findings have general implications for the importance of mineral aerosols in controlling sediment yield and the supply of weathering-derived nutrients to continental areas bordering large subtropical deserts worldwide.

Novel granular bentonite-carbon sorbents: textural characterization, adsorption-desorption isotherm, kinetics, and cost estimation.

This research focuses on the synthesis of novel low-cost granular sorbents based on bentonite clay of the Navbahor deposit, dust fraction of Angren brown coal, and agricultural wastes such as straw and sawdust to meet the internal needs of the Republic of Uzbekistan. The impact of the initial mixture ingredients on the structural and textural properties of bentonite-coal sorbents (BCSs) has been studied using X-ray diffraction, Raman spectroscopy, Fourier-transform infrared spectroscopy, optical microscopy, and nitrogen adsorption-desorption analysis. For determining the sorption capacity of BCSs, a standard model substance methylene blue (MB), was applied. It was revealed that the maximum adsorption amount of MB was 5.3 mg∙g-1 during 2 h of contact. Prolonging the contact time to 24 h allowed for more extensive diffusion of dye molecules into the sorbent's pores, increasing the adsorption capacity to 13 mg∙g-1. It was demonstrated that BCSs could be regenerated by strong oxidizing agents such as sulfuric acid and hydrogen peroxide, with sulfuric acid proving more effective. Regeneration fully restores sorption properties, particularly at low dye concentrations (up to 0.2 mg∙ml-1). Despite slight reductions in adsorption capacity over multiple regeneration cycles, the sorbents maintain their structural integrity and durability. It is shown that compared to imported expensive activated carbon, the gross profitability of the in-house production of such granular BCSs within the territory of Uzbekistan increases from 48 to 78%, while the net income increases almost three times.

Influence of synthesis conditions and raw materials on the properties of N‐chlorosulfonamides immobilized on granular styrene–divinylbenzene polymer carriers

AbstractPolymer materials with immobilized functional groups–donors of active chlorine are widely used to create products with a microbiocidal effect and increased resistance to microbial contamination. In this work, various methods for the synthesis of granular styrene–divinylbenzene polymers with N‐chlorosulfonamide groups were investigated. It has been shown that the synthesis of polymers with chlorine‐active SO2NNaCl groups from a non‐functionalized styrene–divinylbenzene polymer matrix through the stage of its sulfochlorination with chlorosulfonic acid in dichloromethane for 6–7 h is optimal. These products contain approximately 11% of active chlorine and maintain a stable particle size distribution. When cation exchangers such as Purolite C100 are used as the initial polymer carrier, the content of chlorine‐active groups in the target product is approximately 9%, and an increase in the content of the dust fraction is observed. The obtained samples, regardless of the synthesis method, are capable of releasing active chlorine into solutions containing amino compounds. The microbial impurities in water also cause the emission of active chlorine in an amount that does not depend on the loading of the polymer, but is determined by the concentration of microbes, due to which a pronounced antimicrobial effect is observed. In this case, the resulting products do not cause further decomposition of the functional groups of the polymer, which indicates the high service life of the latter. The availability of raw materials, relative ease of synthesis, stability, possibility of regeneration and microbiocidal properties of the studied polymers make them promising for use as components of water and air purification systems and other products for medical and industrial purposes. © 2024 Society of Chemical Industry.

Dust dynamics: distribution patterns of semi-volatile organic chemicals across particle sizes in varied indoor microenvironments.

An extensive analysis of the distribution patterns of three distinct classes of semi-volatile organic chemicals (SVOCs)-phthalates (PAEs), organophosphate flame retardants (OPFRs), and polycyclic aromatic hydrocarbons (PAHs)-across four distinct size fractions of dust (25, 50, 100, and 200μm) was conducted. The dust samples were sourced from AC filter, covered car parking lots, households, hotels, mosques, and car floors. To generate the four fractions, ten dust samples from each microenvironment were pooled and sieved utilizing sieving apparatus with the appropriate mesh size. Selected SVOCs were quantified utilizing gas chromatography-mass spectrometry in electron impact (EI) mode. Results unveiled diverse contamination levels among dust fractions, showcasing car parking lot dust with the lowest chemical contamination, while car floor dust displayed the highest levels of PAHs and OPFRs, peaking at 28.3µg/g and 43.2µg/g, respectively. In contrast, mosque and household floor dust exhibited the highest concentrations of phthalates, with values of 985µg/g and 846µg/g, respectively. Across the analyzed microenvironments, we observed a trend where concentrations of SVOCs tended to rise as dust particles decreased in size, forming a visually striking pattern. This phenomenon was particularly pronounced in dust samples collected from car floors and parking lots. Among SVOCs, PAEs emerged as the predominant contributors with > 90% followed by OPFRs and PAHs. The high levels of OPFRs in car floor dust align logically with the fact that numerous interior components of cars are treated with OPFRs, within a compact indoor microenvironment, to comply to fire safety regulations. Furthermore, petroleum products are a major source of PAHs in the environment and all the sampled cars in the study had combustion engines. Consequently, car dust is more likely to be polluted with PAHs stemming from petroleum combustion. Although previous investigations have noted an increase in heavy metals and brominated flame retardants with decreasing dust particles, this is the first study analyzing these SVOCs in different fractions of dust from various microenvironments. However, aside from two specific microenvironments, the observed pattern of escalating SVOC concentrations with smaller dust particle sizes was not corroborated among the examined microenvironments. This divergence in concentration trends suggests the potential involvement of supplementary variables in influencing SVOC distributions within dust particles.

Larger Dust Cooling Effect Estimated From Regionally Dependent Refractive Indices

AbstractThe dust direct radiative effect (DRE) depends strongly on the dust particle size distribution (PSD) and complex refractive index (CRI). Although recent studies constrained the dust PSD in the models, its CRI uncertainties are still large. As a result, whether dust warms or cools the climate system remains unclear. Here, we estimate the dust DRE by employing the regionally‐dependent dust CRI based on global measurements. We find that new dust CRI significantly enhances the scattering of dust in the shortwave while reduces its absorption in the longwave, which is opposite to that caused by increasing the coarse and giant dust fraction via constraining the PSD. Constraining both PSD and CRI ultimately leads to a net dust DRE of −0.68 W m−2, a cooling stronger than current model estimates.

Ice chemistry modeling of active phase comets: Hale–Bopp

We present a chemical kinetics model of the solid-phase chemical evolution of a comet, beginning with a long period of cold-storage in the Oort Cloud, followed by five orbits that bring the comet close to the Sun. Current orbital parameters for Hale–Bopp are used for all orbits. The chemical model is based on an earlier treatment (Garrod 2019) that considered only the cold-storage phase, and which was based on the interstellar ice chemical kinetics model MAGICKAL. The comet is treated as 25 chemically distinct layers, whose thicknesses increase with depth; each layer has a dust component, and the chemical network includes a further 200 atomic/molecular species. The new model includes several key updates to the previous treatment: (i) Time- and depth-dependent temperature profiles based on heat transfer according to heliocentric distance; (ii) a rigorous treatment of back-diffusion (random walk) for species capable of diffusing through the thick bulk-ice layers; (iii) adoption of recent improvements in the kinetic treatment of nondiffusive chemical reaction rates in the ice and on the ice surface. Starting from an initially simple ice composition, interstellar UV photons drive a rapid chemistry in the upper micron of material, but diminished by absorption of the UV by the dust component. Galactic cosmic rays (GCRs) drive a much slower chemistry in the deeper ices over the long cold-storage period, to depths on the order of 10 m. The first solar approach drives off the upper layers of ice material via thermal desorption and/or dissociation (the model does not include a treatment for the more complex cometary outbursts), bringing closer to the surface the deeper material that previously underwent long-term processing by GCRs. Subsequent orbits are more uniform in their chemical behavior after the upper layers are lost. Loss of molecular material leads to concentration of the dust in the upper layers, with a large dust fraction extending to depths on the order of 10 cm after all orbits are complete. Substantial quantities of complex organic molecules (COMs) are formed in the upper 10 m during the cold storage phase, with some of this material released during solar approach; however, their abundances with respect to water appear too low to account for the observed gas-phase values for comet Hale–Bopp, indicating that the majority of complex molecular material observed, at least in comet Hale–Bopp, is an inheritance of primordial material.

East Asian monsoon and westerly jet driven changes in climate and surface conditions in the NE drylands of China since the Late Pleistocene

The East Asian summer monsoon (EASM) is a major component of the global climate yet, the causes for the past spatiotemporal variability of EASM rainfall, its interactions and impacts remain unresolved. Here we use the Sr–Nd isotopes and rare earth elements composition of dust in a peat record from northeast (NE) China to investigate the relationship between aeolian dust, the East Asian monsoon and Westerly Jet (WJ) over East Asia since the Late Pleistocene (14 cal ka BP). The NE drylands of China dominate the dust fraction (Hunshandake, Horqin; 44–88%) with a contribution from the deserts of NW China (Badain Jaran, Tengger, Taklamakan; 10–44%), suggesting an influence of the WJ. Dust deposition varied during the Holocene, displaying a minimum between 8.0 and 6.0 cal ka BP and two peaks at 5.8–3.8 and 1.7–0.3 cal ka BP. Changes in dust flux are opposite to the East Asian winter monsoon intensity profile, suggesting a limited influence of the winter monsoon. The EASM appears to have played a more significant role in the dust cycle, with increasing dust fluxes corresponding with lower EASM precipitation. Variations in dust flux from NE drylands display shifts reflecting changes in EASM precipitations and dune activity along the EASM margin, where the dust originates from. To account for the influence of the WJ, we propose that the meridional position and intensity of the WJ also affected dust emission in the drylands’ region. A more northward position of the WJ allows the EASM front further north, generating more precipitations over the NE drylands, reducing the extent of arid areas, and resulting in less dust emission from dune activity, while the opposite occurs with a strong, more southerly WJ. Anthropogenic activities are likely to have had an increasing impact on the dust cycle over the late Holocene. Nevertheless, the presence of inconsistencies in records, coupled with a simultaneous decline in climatic conditions (mainly precipitations) during the same timeframe, hinders the precise assessment of the influence of human activities on dust emissions in the region.

Measuring Respirable Crystalline Silica (Quartz) from Powdery Materials through Sedimentation and X-ray Diffractometry.

When possible, choosing materials with a low quartz content is the most effective and cost-efficient way to prevent the respirable quartz exposure of workers and other end users of powdery products. Therefore, methods are needed to analyze low amounts of quartz from powdery products, such as sand, gravel, plaster, cement, and concrete. To this end, we present a method to analyze respirable dust and quartz from powdered materials, such as construction products. The method includes separation of the respirable dust fraction by liquid sedimentation, followed by gravimetric analysis and determination of the crystalline silica content by X-ray diffractometry. While also aiding in the development of less harmful products, analysis of the quartz concentration of powdery products is statutory in Eu countries, excluding natural products not chemically modified. According to EU Regulation No. 1272/2008, products must be classified if they contain harmful substances in concentrations above 0.1 wt.%, and clauses pertaining to cancerous properties and harmfulness to lungs should be included. Also, mineral producers in the EU recommend that products containing respirable quartz should be labelled based on their quartz concentration, provided the concentration exceeds 1 wt.%. The present method meets these needs. The analysis can be performed in parallel from 50 to 1000 mg (dry weight) of powdery materials. The quantitative limit of determination was 10 µg per sample, corresponding to 0.01 wt.%, and the linear range 0.02-10 wt.% (10-5000 µg quartz per sample, Pearson correlation coefficient 0.99). The accuracy of the method was 82% and the repeatability 11%.

An implicit algorithm for simulating the dynamics of small dust grains with smoothed particle hydrodynamics

ABSTRACT We present an implicit method for solving the diffusion equation for the evolution of the dust fraction in the terminal velocity approximation using dust-as-mixture smoothed particle hydrodynamics. The numerical scheme involves casting the dust diffusion equation into implicit form, rearranging into its resolvent cubic equation and solving analytically. This method is relevant for small grains that are tightly coupled to the gas, such as sub-micron dust grains in the interstellar medium or millimetre-sized dust grains in protoplanetary discs. The method avoids problems with the variable used to evolve the dust fraction becoming negative when evolved explicitly and is fast and accurate, avoiding the need for dust stopping time limiters and significantly reducing computational expense. Whilst this method is an improvement over using the explicit terminal velocity approximation method, as with any dust-as-mixture method it still fails to give accurate solutions in the limit of large (weakly coupled) grains.

Characteristics of Soil Chemical Properties in Several Types of Oil Palm (Elaeis guineensis Jacq.) Land and Shrubs in Negeri Lama Seberang Village (Case Study of Lower Bilah Watershed)

The Bilah Sub-Watershed area includes areas that have somewhat critical or semi-critical land so that land use is the result of human efforts in managing the available resources to meet their various needs. This often results in land use not being in accordance with its capabilities. This research aims to examine the chemical properties of several vegetation in Negeri Lama Seberang Village, Bilah Hilir District, Labuhanbatu Regency. The research was carried out from December to March 2024 using a survey method. Soil samples were taken at 3 points for each vegetation and different slopes at depths of 1-10 cm and 10-20 cm using a simple random method. The soil parameters measured were soil acidity (electrometry), soil organic carbon content (Walkley and Black), and soil texture (bouyoucos hydrometer). Soil analysis was carried out at the Laboratory of the Faculty of Agriculture, University of North Sumatra. The results of this research show that on a slope of 0-8% the average soil pH value is 4.61% and organic C is 1.04%, while on a slope of 8-15% the average soil pH value is 4.46% and C -organic 0.91%. On a slope of 0-8% the average value of the clay fraction is 20.27%, the dust fraction is 15.02% and the sand fraction is 64.41%, while on a slope of 8-15% the average value of the clay fraction is 27.48%, the dust fraction 19.87%, and sand fraction 52.63%.