We discuss black hole solutions of Einstein-Λ gravity in the presence of nonlinear electrodynamics in dS spacetime. Considering the correlation of the thermodynamic quantities respectively corresponding to the black hole horizon and cosmological horizon of dS spacetime and taking the region between the two horizons as a thermodynamic system, we derive effective thermodynamic quantities of the system according to the first law of thermodynamics, and investigate the thermodynamic properties of the system under the influence of nonlinearity parameter α. It is shown that nonlinearity parameter α influences the position of the black hole horizon and the critical state of the system, and along with electric charge has an effect on the phase structure of the system, which is obvious, especially as the effective temperature is below the critical temperature. The critical phase transition is proved to be second-order equilibrium phase transition by using the Gibbs free energy criterion and Ehrenfest equations.