Dry Cycles Research Articles

Experimental investigation of influence of amide polymer on loess for subgrade

The effects of moisture and drying shrinkage can lead to uneven settlement, cracking, and other diseases in loess subgrade. The objective of this study was to investigate the effects of amide polymer (AP) on the permeability, mechanical properties and crack resistance of loess by orthogonal experiments. The basic properties of AP and the permeability, mechanical properties, and dry–wet variation properties of polymer-modified loess were tested, and a scale model verification and simulation analysis were conducted. In this paper, water migration in subgrade is regulated by improving the water sensitivity of loess. By reducing the variation range of subgrade water content, the stress accumulation in subgrade caused by water is weakened. The results show that the curing time and mechanical properties of AP are directly affected by the oxidant and reducing agent, and the mechanical properties of AP are compatible with the characteristics of loess. AP filled the grain gap and reduced the permeability of loess by 34.05–280.83%. The ductility of polymer-modified loess is significantly increased, and the strain of peak strength is increased by 17.21–126.36%. AP can regulate moisture change, reduce the surface tension between particles, and reduce stress concentration. The strength loss rate was reduced by 19.98–51.21% by enhancing the cracking resistance and weakening the strength loss caused by dry and wet cycling. The increase of upper layer moisture content in the scale model of polymer-modified loess subgrade is reduced by 31.38–36.11%.

Recovery and reuse of phosphogypsum: Effect of ternary cementitious materials on the performance of phosphogypsum pavement base layers

In this paper, the performance of a new type of phosphogypsum (PG) pavement material is studied under the joint action of ternary cementitious materials (cement, mineral powder, and fly ash), CaCl2 and gravel. The experimental results of mechanical properties and durability of the material system, including compressive strength, splitting strength, dry and wet cycle, freeze-thaw cycle, etc., confirm that the material system can meet the design standards for road base material design standards for highways and primary highway sub-base. The test results of SEM, XRD, EDS, contact angle, and solubility of trace elements show that the material system does not cause secondary pollution to the environment, and its strength mainly comes from the C-S-H gel and calcium alumina (AFt) generated by the reaction of the reactive substances in the cementitious materials with PG in an alkaline environment. Finally, the optimal ratio of modified PG: mineral powder: cement: fly ash: gravel: water: CaCl2 was 50:8:3:0:39:11:0.22, and its 7d compressive strength, splitting strength, loss of strength in dry and wet cycles, loss of strength in freezing and thawing cycles, and water absorption were 6.41 MPa, 6.84 MPa, 3.01%, 16.22%, and 8.87%, respectively.

Mathematical Modeling and Design of Parboiled Paddy-Impinging Stream Dryer Using the CFD-DEM Model.

Impinging stream dryers (ISDs) are effective for removing moisture from particulate materials because of the complex multiphase transport of air particles in ISDs. Nowadays, computational techniques are powerful to simulate multiphase flows, including dilute and dense-phase gas-solid flows and hence, the use of a reliable computational model to simulate the phenomena and design a dryer has recently received more attention. In this study, computational fluid dynamics, combined with the discrete element method (CFD-DEM) and falling drying rate model, were used to predict the multiphase transport phenomena of parboiled paddy in a coaxial ISD. The design of an impinging stream pattern for improving residence time in a drying chamber of ISD was also investigated. The results showed that the CFD-DEM, in combination with the falling drying model, could be well-utilized to predict the particle motion behavior and lead to more physically realistic results. The predicted change of moisture content in parboiled paddy was in good agreement with the experimental data for 17 cycles of drying. Although the prediction of mean residence time was lower than the experimental data, the predicted mean residence time was a similar trend to the experimental data. For ISD design, the simulation revealed that the use of two stages of impinging stream region (two streams collide at the top of the drying chamber at the first stage and then the gas particles flow on the incline floor to collide with the other stream at second stage) in a drying chamber could increase the residence time approximately 75% and reduce drying cycle from 17 to 10 cycles when it was considered at the same final moisture content.

Effect of Moisture Content and Wet–Dry Cycles on the Strength Properties of Unsaturated Clayey Sand

Based on the actual situation of the project on the Weihai–Yanhai Expressway section of Rongwu Expressway, the effects of water content change and the dry–wet cycle on the mechanical behavior of unsaturated clayey sandy soil were analyzed in this study. In this study, ventilated undrained triaxial shear tests were carried out on unsaturated clayey sandy soils with different water contents (6%, 8%, 10%, 12%, 14% and 16%). Concurrently, the soil samples were subjected to three distinct wet and dry cycle pathways (2~22%, 2~12%, and 12~22%) to gain an understanding of how the mechanical features of the soil changed under the different conditions. The test findings demonstrate that when the water content increases, the unsaturated clayey sandy soil’s cohesiveness and shear strength diminish. The strength of shear decline exhibits a pattern of first being quick, followed by sluggish. The strength of shear and cohesiveness of clayey sandy soil declined under the influence of the dry and wet cycles, with the first cycle primarily affecting variations in cohesiveness and strength of shear. Furthermore, the strength of shear and cohesiveness of clayey sandy soil diminish more with increasing wet and dry cycle amplitude and upper water content limits. Lastly, the drying shrinkage and hygroscopic expansion of clay particles in clayey sandy soils during wet and dry cycles are not significant, resulting in less structural damage and deterioration of the mechanical properties of the soils. The study’s findings have a significant impact on the durability of roadbeds made of unsaturated clayey sandy soil in both wet and dry situations.

The effect of amorphous silica on soil–plant–water relations in soils with contrasting textures

This study investigates how amorphous silica (ASi) influences soil–plant–water interactions in distinct soil textures. A sandy loam and silty clay soil were mixed with 0 and 2% ASi, and their impact on soil retention and soil hydraulic conductivity curves were determined. In parallel, tomato plants (Solanum lycopersicum L.) were grown in experimental pots under controlled conditions. When plants were established, the soil was saturated, and a controlled drying cycle ensued until plants reached their wilting points. Soil water content, soil water potential, plant transpiration rate, and leaf water potential were monitored during this process. Results indicate a positive impact of ASi on the sandy loam soil, enhancing soil water content at field capacity (FC, factor of 1.3 times) and at permanent wilting point (PWP, a factor of 3.5 times), while its effect in silty clay loam was negligible (< 1.05 times). In addition, the presence of ASi prevented a significant drop in soil hydraulic conductivity (Kh\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${K}_{h}$$\\end{document}) at dry conditions. The Kh\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$${K}_{h}$$\\end{document} of ASi-treated sandy loam and silty clay at PWP were 4.3 times higher than their respective control. Transpiration rates in plants grown in ASi-treated sandy loam soil under soil drying conditions were higher than in the control, attributed to improved soil hydraulic conductivity. At the same time, no significant difference was observed in the transpiration of plants treated with ASi in silty clay soil. This suggests ASi boosts soil–plant–water relationships in coarse-textured soils by maintaining heightened hydraulic conductivity, with no significant effect on fine-textured soils.

Hydraulic conductivity of bentonite–polymer geosynthetic clay liners subject to wet–dry cycles used in landfill cover systems

This study evaluated the hydraulic conductivity of bentonite–polymer (B-P) geosynthetic clay liners (GCLs) subjected to wet-dry cycles that simulated seasonal conditions on a GCL installed in a landfill cover system. Hydraulic conductivity tests were conducted on B-P GCLs and NaB GCLs at 10 kPa in accordance with the ASTM D5084 standard. Two wet–dry methods were used to investigate the hydraulic conductivity of the GCLs under different field exposure conditions. The hydraulic conductivities of the NaB and B-P GCLs gradually increased during four wet–dry cycles. However, the hydraulic conductivity of the B-P GCL (K = 2.3 × 10-12 m/s) was lower than that of the NaB GCL (K = 6.3 × 10-11 m/s) by two orders of magnitude after four permeation–drying cycles. In addition, the hydraulic conductivity of the B-P GCL was lower (K = 5.8 × 10-12 m/s) than that of the NaB GCL (K = 7.8 × 10-10 m/s) by two orders of magnitude after four saturation–drying cycles. The results suggest that B-P GCLs can enhance the effectiveness of landfill cover systems compared to Na-B GCLs in managing conditions during wet and dry seasons.

Investigating combined effects of saturation–desaturation cycles and cyclic stress resistance of reinforced biopolymer-treated soil

Throughout their service life, subgrades endure significant stress from cyclic traffic and seasonal moisture fluctuations. This study aims to evaluate the moisture variation and cyclic stress resistance of reinforced and biopolymer-treated soils, which were treated with varying percentages (0.25%, 0.5%, 0.75%, and 1.0%) of xanthan gum (XG) and sisal fiber, to determine the level of tolerance a subgrade can sustain. Wetting–drying (W-D) cycle tests, unconfined compressive strength (UCS) tests, and dynamic resilient modulus (DRM) tests were conducted to assess the resistance of the treated soils to moisture variation and cyclic stress. The findings indicate that biopolymer-treated specimens retained over 95% of their original mass after 15 cycles, whereas fiber-reinforced soil exhibited a 9.1% loss in mass. Furthermore, the DRM of the reinforced soil improved, demonstrating greater resistance to cyclic stress compared to biopolymer-treated soils. Fiber-reinforced soils exhibited strain-hardening responses at low cyclic stress levels and maintained stress tolerance even at high cyclic stress levels without signs of strain deformation. Conversely, the UCS of the biopolymer-treated soil surpassed that of the fiber-reinforced soil due to the brittleness of the specimens.

Desiccation cracking behavior and its suppression methods in lateritic soil under drying and wetting cycles

In this study, the desiccation cracking behavior of lateritic soil caused by drying and wetting cycles was investigated and effective methods for mitigating crack development were proposed. Direct mixing and spray coating methods based on different additives were used to modify lateritic soil. Cyclic wet–dry tests were performed to analyze the influence of wet–dry cycles on the cracking behavior. Subsequently, uniaxial tensile tests were conducted to examine the strength degradation caused by crack formation and strength enhancement by additives. In addition, the modification mechanisms were revealed using electron microscopy. The results demonstrated that desiccation cracks developed significantly during the drying process, with some cracks closing upon wetting. However, most of the cracks reopened and expanded further during subsequent drying, leading to a steady increase in the crack rate during the wet-dry cycles. When using the direct mixing method, lignocellulose was the most effective additive for enhancing the crack resistance of lateritic soils. The optimal crack resistance was achieved with a lignocellulose content of 0.75%, resulting in an 18.2% increase in tensile strength. Conversely, when employing the spray coating method, PAC was found as the optimal additive, with a desirable concentration of 1.5–6.0%.

The Effect of Wet and Dry Cycles on the Strength and the Surface Characteristics of Coromandel Lacquer Coatings

Research on the degradation mechanism of coating materials is crucial for the preservation of cultural heritage. The purpose of this study was to evaluate the protective effect of Coromandel coatings on wooden substrates by analyzing their dimensions, weight, adhesion strength, hydrophobicity, and glossiness. The results indicate that after five cycles, the radial moisture expansion rate of the wood specimen is 0.332%, while that of the lacquer specimen is 0.079%, representing 23.8% of the radial moisture expansion rate of untreated wood specimens. This performance is superior to that of the ash and pigment specimens. Across different experimental conditions, the change in the mass of the Coromandel specimens aligns with the trend in their dimensional changes, indicating that moisture absorption and desorption are the primary reasons for dimensional changes. The influence of temperature on mass and dimensional stability is significant only in terms of dry shrinkage rate. After wet and dry cycles at 40 °C, the adhesion strength of the Coromandel specimens decreases the most, with the ash specimens decreasing by 7.2%, the lacquer specimens by 3.2%, and the pigment specimens by 4.5%. Following wet and dry cycles at three different temperatures, the contact angle of the lacquer layers changes by less than 5%, with their contact angle values exceeding 120°. These data indicate that among the Coromandel coatings, the lacquer layer provides the best protection for the wooden substrate, while the ash coating is the most fragile. The degradation rate of the Coromandel specimens increases with rising temperatures. These findings emphasize the critical roles of humidity and temperature in protecting wooden coatings and aim to provide theoretical insights and practical significance for the preservation of wooden artifacts and the assessment of coating performance.

Alternating wet and dry irrigation cycles enhance the nitrogen “cache” function of duckweed in a rice-duckweed system

In continuously-flooded paddies, the small, fast-growing aquatic plant duckweed (Lemna minor L.) considered to compete with rice for nitrogen, thereby having a negative impact on early rice growth. While duckweed overpopulation was known can be effectively overcome through field water management, the influence of such management on the N fate and its use efficiency in rice-duckweed systems is poorly documented. Accordingly, a three-year (2020–2022) field experiment was conducted to examine the combined impact on rice yield, as well as N loss and utilization, of two water management approaches (flood irrigation, FI vs. alternate wetting and drying irrigation, AWD), factorially combined with two rice production systems (rice-duckweed, +D, vs. duckweed-free rice, -D). In AWD+D fields, the density of duckweed generally remained below 250 g m−2 (about 85 % coverage), whereas in FI+D fields it reached 100 % coverage (300 g m−2) within 5 days after transplanting, with individual duckweeds overlapping one another. Following AWD irrigation, duckweed performed as a nitrogen “cache,” akin to a split fertilizer application, with the first of several splits occurring at the rice crop's early tillering stage. Within the first 2 days of a specific wet-dry cycle, duckweed can store 0.5–1.5 g N m−2, and then, within a further 3 days, release 0.3–1.0 g N m−2. In contrast, in FI+D paddies, this caching function occurred once under mid-season drainage, with further N being stored in the duckweeds during the remaining rice production season. As a result, at harvest the 0–0.10 m soil layer's N level increased significantly (p<0.05) in both FI+D (8.5–16.8 %) and AWD+D (14.9–20.8 %) compared to FI-D and AWD-D, respectively. Due to the coverage and storage-release function of duckweed, apparent N loss decreased in rice-duckweed system by 1.4–12.5 % in the FI field and 22.1–31.3 % in the AWD field compared to their respective duckweed-free systems. In FI fields, except for a 10 % relative reduction in nitrogen recovery efficiency (NRE) in 2020, duckweed didn't significantly affect rice yield or NRE. The yield reduction (3.5–6.7 %) and the NRE increase (0.8–7.4 %) under AWD-D (vs. FI-D) was, in the presence of duckweed, compensated for and overrun, resulting in a greater yield (5.3–6.7 %) and NRE (5.4–28.9 %) in the AWD+D vs. AWD-D field. When duckweed was present, AWD irrigation improved the by-path nitrogen cycling through duckweed, making the AWD+D system more beneficial for rice cultivation and the agroecosystem's environment health. The AWD+D system offers a promising measure for building an efficient and sustainable rice-duckweed agroecosystem.

Slake durability indices of shales from the Batu Arang Beds, Selangor Darul Ehsan

The Eocene to Oligocene Batu Arang Beds outcrop within an approximately triangular basin covering some 15 km2 and comprise stiff, structureless clays to well laminated and fissile shales inter-bedded with fine to coarse sandstones and several coal layers. The shales are often silty and even sandy and contain abundant carbonaceous material. The coal mostly occurs as thin laminae, though two thick seams, mined by open-cast and under-ground methods from 1915 to 1960, are found in the eastern part of the basin. To determine the weatherability characteristics of the shales, three samples (A, B and C) were collected at the western wall, and one sample (D) at the eastern wall, of an open-cast shale pit. Samples A and D are located some 10 m, and 5 m, below the ground surface, whilst samples B and C are 10 m, and 16 m, stratigraphically below sample A. Samples A, B and C, and D have average dry unit weights of 16.64, 14.49, and 15.40, kN/m3 and average apparent porosities of 26.2%, 35.7% and 31.7%, respectively. Slake durability indices of all samples for one standard cycle of wetting and drying (Id1) are between 98.3% and 99.3%, and for two standard cycles (Id2), between 96.7% and 98.9%. Durability indices for three standard cycles (Id3) are between 95.1% and 98.2%, and for four standard cycles (Id4), between 93.3% and 97.6%. The indices lead to the conclusion that the shales are of high to extremely high durability and suitable for use as highway embankment or construction material. The high durability classification is supported by recent excavations at an overburden dump where relatively fresh shale blocks with little disaggregation or disintegration are exposed even after being buried for 78 to 85 years.

Experimental Study of Macro- and Micro-Scopic Damage in Red Sandstone under Dry and Wet Cycling

The high-strength red sandstone in its natural state is subjected to significant strength deterioration under alternating wet and dry conditions, which can cause many catastrophic problems in the process of engineering construction. It is important to deeply understand the damage mechanism of red sandstone under the action of dry and wet cycles. Therefore, this paper explores the mechanism of red sandstone’s uniaxial deformation and failure through indoor uniaxial compression tests, studies the damage to the microstructure of red sandstone under wet–dry cycles using scanning electron microscopy, and establishes a damage variable based on fractal dimension. The results show that with the increase of wet–dry cycles, the peak stress of red sandstone shows a decreasing trend, and the minimum peak stress is 17.3 MPa, which is a 46.62% decrease compared to the sample with 0 wet–dry cycles. During the wet–dry cycle process, there are four deformation characteristics of red sandstone samples, namely, crack compression, crack extension, progressive fracture, and crack penetration. SEM images show that the porosity, pore area, and fractal dimension all show a nonlinear increase, and the maximum damage variable can reach 10.41%. The research results can provide guidance for engineering design and slope failure mechanism research in red sandstone areas.

Effects of biogenic sulfuric acid on simulated concrete septic tanks

Concrete is the major construction material for infrastructure development. Concrete sewer septic tanks are Constructed using the conventional ordinary portland cement (OPC) and the Portland pozzolana cement (PPC). However, OPC based concrete sewer systems are susceptible to biological, mechanical, and chemical degradation. Degradation of the concrete septic leads to their failure hence imposing tremendous environmental problems. The aftermath is the emergence of sanitation-related diseases. The wastewater from failing septic systems leads to contamination of the groundwater or the surface water resulting in the pollution of drinking water. Therefore, the need to explore other possibilities and potential construction materials to achieve sustainable sanitation is inevitable. The use of Limestone Calcined Clay Cement (LC3) in the construction of degradation-resistant concrete sewer septic systems has not been well explored in Kenya. LC3 concrete is resistant to the deterioration effects of aggressive media such as acids, chlorides, and sulfates. This paper presents experimental performance and findings of LC3 in aggressive media vis a vis OPC. The LC3 was formulated by mixing clinker, Calcined clay, limestone, and gypsum at percentages of 50 %, 30 %, 15 %, and 5 % respectively. Compressive strength, Sorptivity, and weight loss during the wet and dry cycles for both LC3 and OPC were evaluated. Simulated concrete septic tanks made of LC3 and OPC were made by casting cubes at water cement ratio of 0.5 and cured in fresh water at ambient temperature for 28 days. These cubes were passed through a regime of W-D cycles in the 3% concentration of Biogenic sulfuric acid. It was observed that after 28 days of curing OPC cubes had slightly higher compressive strength than LC3. However LC3 concrete cubes are expected to have higher compressive strength than the OPC. Cubes curing time increases due to increased pozzolanic activity. Biogenic sulphuric acid attacks on hydrated cement products cause a decrease in compressive strength. The water absorption profile of LC3 cubes was lower as compared to OPC cubes. In conclusion, LC3 cubes had a high potential of resisting degradation as compared to OPC cubes. LC3 show more impressive performance, hence LC3 It’s a potential binder for use in the construction of sewer system.&#x0D; Keywords: Septic tank, Sorptivity, compressive strength, wet-dry cycles, biological, mechanical, and chemical degradation, sustainable sanitation, LC3.

Experimental Study on Erosion Modeling of Architectural Red Sandstone under the Action of the Natural Environment

When buildings are exposed to erosion from the natural environment, erosion behaviors such as surface damage and structural instability occur, which greatly affect the aesthetic value and service life of the buildings. The study of erosion behaviors and the establishment of a suitable erosion model are constructive references for the protection and restoration of buildings. In order to establish a suitable erosion model for architectural red sandstone, two types of red sandstone specimens were selected in this paper to carry out dry and wet cycle tests. Combining the theoretical analysis and the actual erosion situation, a unidirectional corrosion model is proposed to describe the erosion of buildings by the natural environment. In this model, it is assumed that only the outer surface of the building is in contact with external erosion factors for a long period of time, so this situation can be considered a unidirectional erosion process. The paper uses XRD, SEM, and ultrasonic methods to record changes in the properties of the red sandstone samples. Finally, the rationality of the unidirectional erosion model was verified numerically. The test results show that the red sandstone specimens subjected to erosion by the natural environment will be accompanied by the development of defects, such as cracks, fissures, and holes, as well as the generation of fresh material. The demarcation point of different erosion stages exists in both the in-service red sandstone specimens and the fresh red sandstone specimens, which is consistent with the results of the unidirectional erosion model. In this paper, a calculation model for the demarcation point of different erosion stages is established, and the model estimation shows that the demarcation point of different erosion stages of the in-service red sandstone sample is 1.1528 cm from the erosion surface, and the demarcation point of different erosion stages of the fresh red sandstone sample is 1.67 cm.

High salinity prolongs water processes required for soil structure stability during drying–wetting cycles

AbstractClimate events, such as drought and rainfall, can lead to a cycle of drying and wetting that may cause changes in soil structure, leading to deteriorations in the health of saline soils. However, little is known about the extent and behavior of soil structure degradation under the combined influences of salinity and drying–wetting (D‐W) cycles. Thus, we systematically investigated the effects of salinity (0, 5, 30, and 100 g/L, labeled as CK, T5, T30, and T100) and D‐W cycles on soil structure by determining soil volume, shrinkage, and swelling potentials along with soil pore character obtained from soil shrinkage characteristics curve, intending to explore how D‐W cycles and salinity affect soil structure. The results showed that soil deformation behaviors in saline and non‐saline soils varied with the number of D‐W cycles. Irreversible deformation of the soil was observed during continual D‐W cycles. The soil volume increased by 3.75%–15.73% after three D‐W cycles. In vertical direction, the maximum expansion magnitude for each treatment was reached with the value of 29.03%, 23.42%, 34.23%, and 35.87% in CK, T5, T30, and T100, respectively. The magnitudes of shrinkage and expansion were equal in the horizontal direction since the soil samples consistently returned to their original dimensions. Furthermore, the decrease was observed in the micropores and capillary pores affected by salinity, with values of 50%, 58.6%, and 70.4% in CK, T5, T30, and T100, respectively. However, the D‐W cycles primarily affected large pores. High salinity levels enhanced swelling potential and inhabit shrinkage potential, prolonging the water processes required for the soil structure to achieve stability. The results of this study underscore the necessity of understanding the hysteresis of soil volume change and elucidate the mechanisms of soil structure deterioration driven by salinity and D‐W cycles. These findings provide a valuable reference for healthier soil management.

Synthesis and Study of Superhigh-Concentrated Organosols of Silver Nanoparticles

Abstract Due to their unique properties, organosols of silver nanoparticles are widely used in optical and semiconductor devices, to produce electrically and thermally conductive films, as catalysts, antibacterial materials, etc. This work proposes a simple and highly productive method for the preparation of silver organosols, which have a metal concentration as high as 1800 g/L and contain spherical nanoparticles with low polydispersity and a median size of 9.1 nm. The method consists in the initial preparation of silver nanoparticle hydrosols with a concentration of higher than 30 g/L followed by the transfer of the NPs into an organic phase of o-xylene. A set of physical research methods has been employed to study the regularities of the extraction of silver nanoparticles with o-xylene in the presence of cetyltrimethylammonium bromide (CTAB) and ethanol and to determine the optimal process conditions, under which the extraction degree is as high as 62.5%. It has been found that bromine anions contained in CTAB molecules cause the aggregation of some amount of silver nanoparticles with the formation of silver metal sediment in the aqueous phase. According to X-ray photoelectron spectroscopy data, the sediment contains bromide ions (up to 4 at %) on the particle surface. Organosols synthesized under optimal conditions are stable for more than 7 months and withstand repeated cycles of drying and redispersing. Silver organosols have been used to obtain metal films with an electrical conductivity of about 68 500 S/cm, which increases to 412 000 and 509 500 S/cm (87.8% of the electrical conductivity of bulk silver) after thermal treatment at 150 and 250°C, respectively.

Biochar from cashew residue enhances silicon adsorption and reduces cohesion and mechanical resistance at meso- and micro-structural scales of soil with cohesive character

Horizons with cohesive character impose physical restraints on plant development, particularly when it occurs near the soil surface. Howbeit, the genesis of cohesive character in soils is associated with temporary and reversible cementation by amorphous silica. Thus, we hypothesized that the biochar obtained from residues from cashew processing would improve soil porosity and promotes silicon adsorption, consequently reducing cohesion and mechanical resistance while improving the physical quality of soils with cohesive character. We collected soil samples with deformed structure from the Bt1 horizon of a Typic Haplustult with cohesive character in northeast Brazil. These samples were used to prepare test substrates by combining air-dried and sieved soil samples and biochar at application rates of 0, 5, 10, 20, and 40 Mg ha−1. All the samples in each treatment underwent ten cycles of wetting and drying (one cycle per week) to allow the manifestation of the cohesive character. Subsequently, we assessed silicon adsorption capacity, soil bulk density, porosity, soil penetration resistance, tensile strength, and rheometric properties. In the 5 and 10 Mg ha−1 doses, the physical quality remained like the control treatment (0 Mg ha−1). The 20 and 40 Mg ha−1 doses resulted in increased soil silicon adsorption capacity (+7.6 and +15.3%, respectively), total porosity (+2.0 and +1.9%, respectively), and macroporosity (+14.6 and +15.3%, respectively), compared to the treatment without biochar. Conversely, these doses led to a reduction in soil bulk density (-0.1 and −0.8%, respectively), penetration resistance (-16.2 and −16.1%, respectively), tensile strength (-24.2 and −36.5%, respectively), deformation at the end of the linear viscoelastic range (-6.3 and −10.5%, respectively), shear stress at the end of the linear viscoelastic range (-16.4 and −26.9%, respectively), and maximum shear stress (-13.7 and −22.3%, respectively). In conclusion, the application of biochar improved soil porosity and promoted silicon adsorption, thus reducing the bulk density, cohesion, and mechanical resistance, enhancing the physical quality of soils with cohesive character, especially for doses of 20 and 40 Mg ha−1.

Impact of sand media continuous drying and rewetting cyclic on nutrients transformation performance from reclaimed wastewater effluent at soil aquifer treatment

Reusing reclaimed wastewater became a practical resource for water utilization in groundwater recharge and irrigation activities. However, the quality of reclaimed wastewater needs improvement to meet the environmental regulations and reduce contamination risks. A laboratory-scale study simulated a soil aquifer treatment (SAT) system, exploring the synergistic effects of wet and dry cycles alongside key physicochemical parameters on pollutant removal efficiency using a glass column filled with quartz sand as the filtration medium. The investigation focused on the cyclic wetting and drying phases to unravel their impact on removing NH4+, NO3−, and PO43−. The synthetic wastewater introduced into the system exhibited varying pollutant concentrations during wet and dry periods, influenced by dynamic soil water content (WC%), pH, dissolved oxygen (DO), and oxidation–reduction potential (ORP). The high removal rates of 93% for PO43− and 43% for Total N2 demonstrate the system’s capability to reduce concentrations significantly under dynamic alternating between wet and dry conditions. Results unveiled that the wet period consistently yielded higher removal rates for N2 species. Interestingly, for PO43−, the dry periods demonstrated a higher removal efficiency. Moreover, the study identified an average NO3− production during the experimental phases as a byproduct of nitrification. The average NO3− production in wet periods was 2.5 mg/L, whereas it slightly decreased to 2.2 mg/L in dry periods. These findings underscore the nuanced influence of wet and dry conditions on specific pollutants within SAT systems. Applying the logistic regression model and principal component analysis demonstrated the statistical significance of WC, pH, DO, and ORP in predicting wet/dry conditions, providing quantitative insights into their influential roles on the nutrient dynamic concentrations. This study contributes valuable data to our understanding of SAT systems, offering practical implications for designing and implementing sustainable wastewater treatment practices and pollution management across diverse environmental contexts.

Hygroscopicity in Epoxy Powder Composites

Epoxy powders offer a low-cost way of manufacturing thick-section composite parts, such as those found in wind and tidal turbines. Currently, their processing cycle includes a lengthy drying stage (≥15 h) to remove ambient moisture. This drying stage prevents void defect formation and, thereby, a reduction in mechanical properties; however, it constitutes up to 60% of the processing time. Little research has been published which studies the drying stage or its optimisation. In the present work, experimental and simulated analyses are used to investigate the effects of hygroscopicity in epoxy powder composites. Tests are performed to quantify the void content of dried and undried laminates and to measure its impact on transverse flexural strength. Dynamic vapour sorption analysis is used to study the sorption behaviour of the epoxy powder. It is shown that the epoxy powder is slightly hygroscopic (1.36 wt%) and exhibits sorption behaviour that is characteristic of glassy polymers. This results in up to 4.8% voids (by volume) if processed in an undried state, leading to a 43% reduction in transverse flexural strength. A modified linear driving force model is fitted to the desorption data and then implemented in existing process-simulation tools. The drying of a thick epoxy powder composite section is simulated to investigate the influence of powder sintering on the duration of the drying stage. Process simulations reveal that a standard drying cycle prematurely sinters the powder, which inhibits moisture release. By maintaining the powder state, simulations show that the drying cycle can be reduced to 5 h.

Evaluation of water treatments on surfaces to inhibit bacterial spore resuspension

AbstractThe impact of water and the wet–dry cycle was examined as a potential mitigation solution to pathogenic bacterial spore transport and inhalation risk via resuspension of spores from surfaces due to human activities. In this study, a fine mist of water was distributed onto a hydrophilic surface to represent conditions during a dew cycle or fog. Resuspension experiments were conducted on clean and dusty surfaces while they were wet and after drying. These resuspension results were directly compared to surfaces that had not been subjected to any surface water treatment to determine an absolute resuspension rate reduction ratio that could be treated as independent of resuspension technique. A minimum of a 3‐log reduction in resuspension was observed for dusty wet coupons and a maximum reduction of 4‐logs was observed after the clean coupons had dried. Water treatments have been demonstrated to inhibit spore resuspension under certain laboratory conditions while under an air‐generated shear stress similar in magnitude to shear forces generated by human interaction. This research has demonstrated that treating surfaces with water to inhibit spore resuspension could be a valuable tool in exposure minimization and remediation after a bioterrorism event.