Denitrifying stormwater biofiltration systems that include submerged zones containing organic carbon sources can alleviate eutrophication by reducing nitrogen loadings from stormwater runoff. The objective of this research was to evaluate performance of denitrifying biofilters containing wood chip medium under varying dynamic loading rates and antecedent dry conditions (ADCs). Results showed that during ADCs, dissolved organic carbon (DOC) concentrations increased in pore water due to dissolution of the wood chip medium. During a storm event, nitrate (NO3−) removal was enhanced due to high pore water DOC concentrations and mixing of NO3− from the influent with pore water; however, as DOC was gradually flushed out of the biofilter, higher effluent NO3− concentrations were observed over time. At lower hydraulic loading rates, effluent NO3− concentrations were low due to sufficient hydraulic residence time for denitrification. For all storm events tested, an overall NO3− mass removal efficiency of 85% was achieved. Sulfate reduction was observed at long ADCs (up to 30 days). Phosphate release was observed when NO3− was absent from the effluent, possibly due to dissolution of iron oxyhydroxides under low redox conditions. Findings from this study are being used to develop a mathematical model of nitrogen removal in denitrifying stormwater biofilters.
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