Downwind Regions Research Articles

Novel application of satellite and in-situ measurements to map surface-level NO<sub>2</sub> in the Great Lakes region

Abstract. Ozone Monitoring Instrument (OMI) tropospheric NO2 vertical column density data were used in conjunction with in-situ NO2 concentrations collected by permanently installed monitoring stations to infer 24 h surface-level NO2 concentrations at 0.1° (~11 km) resolution. The region examined included rural and suburban areas, and the highly industrialised area of Windsor, Ontario, which is situated directly across the US-Canada border from Detroit, MI. Photolytic NO2 monitors were collocated with standard NO2 monitors to provide qualitative data regarding NOz interference during the campaign. The accuracy of the OMI-inferred concentrations was tested using two-week integrative NO2 measurements collected with passive monitors at 18 locations, approximating a 15 km grid across the region, for 7 consecutive two-week periods. When compared with these passive results, satellite-inferred concentrations showed an 18% positive bias. The correlation of the passive monitor and OMI-inferred concentrations (R=0.69, n=115) was stronger than that for the passive monitor concentrations and OMI column densities (R=0.52), indicating that using a sparse network of monitoring sites to estimate concentrations improves the direct utility of the OMI observations. OMI-inferred concentrations were then calculated for four years to show an overall declining trend in surface NO2 concentrations in the region. Additionally, by separating OMI-inferred surface concentrations by wind direction, clear patterns in emissions and affected down-wind regions, in particular around the US-Canada border, were revealed.

Measurement of western U.S. baseline ozone from the surface to the tropopause and assessment of downwind impact regions

[1] Since 1997, baseline ozone monitoring from the surface to the tropopause along the U.S. west coast has been limited to the weekly ozonesondes from Trinidad Head, California. To explore baseline ozone at other latitudes, an ozonesonde network was implemented during spring 2010, including four launch sites along the California coast. Modeling indicated that North American pollution plumes impacted the California coast primarily below 3 km, but had no measurable impact on the average coastal ozone profiles. Vertical and latitudinal variation in free tropospheric baseline ozone appears to be partly explained by polluted and stratospheric air masses that descend isentropically along the west coast. Above 3 km, the dominant sources of ozone precursors were China and international shipping, while international shipping was the greatest source below 2 km. Approximately 8–10% of the baseline ozone that enters California in the 0–6 km range impacts the surface of the USA, but very little reaches the eastern USA. Within California, the major impact of baseline ozone above 2 km is on the high elevation terrain of eastern California. Baseline ozone below 2 km has its strongest impact on the low elevation sites throughout the state. To quantify ozone production within California we compared inland ozone measurements to baseline measurements. For average daytime conditions, we found no enhancements of lower tropospheric ozone in the northern Central Valley, but enhancements of 12–23% were found in the southern Central Valley. Enhancements above Joshua Tree were greater, 33–41%, while the greatest enhancements occurred over the LA Basin, 32–63%.

Time-Resolved Measurements of PM2.5 Carbonaceous Aerosols at Gosan, Korea

ABSTRACT In order to better understand the characteristics of atmospheric carbonaceous aerosol at a background site in Northeast Asia, semicontinuous organic carbon (OC) and elemental carbon (EC), and time-resolved water-soluble organic carbon (WSOC) were measured by a Sunset OC/EC and a PILS-TOC (particle-into-liquid sampler coupled with an online total organic carbon) analyzer, respectively, at the Gosan supersite on Jeju Island, Korea, in the summer (May 28–June 17) and fall (August 24–September 30) of 2009. Hourly average OC concentration varied in the range of approximately 0.87–28.38 μgC m−3, with a mean of 4.07 ± 2.60 μgC m−3, while the hourly average EC concentration ranged approximately from 0.04 to 8.19 μgC m−3, with a mean of 1.35 ± 0.71 μgC m−3, from May 28 to June 17, 2009. During the fall season, OC varied in the approximate range 0.9–9.6 μgC m−3, with a mean of 2.30 ± 0.80 μgC m−3, whereas EC ranged approximately from 0.01 to 5.40 μgC m−3, with a mean of 0.66 ± 0.38 μgC m−3. Average contributions of EC to TC and WSOC to OC were 26.0% ± 9.7% and 20.6% ± 7.4%, and 37.6% ± 23.5% and 57.2% ± 22.2% during summer and fall seasons, respectively. As expected, clear diurnal variation of WSOC/OC was found in summer, varying from 0.22 during the nighttime up to 0.72 during the daytime, mainly due to the photo-oxidation process. In order to investigate the effect of air mass pathway on the characteristics of carbonaceous aerosol, 5-day back-trajectory analysis was conducted using the HYSPLIT model. The air mass pathways were classified into four types: Continental (CC), Marine (M), East Sea (ES) and Korean Peninsula (KP). The highest OC/EC ratio of 3.63 was observed when air mass originated from the Continental area (CC). The lowest OC/EC ratio of 0.79 was measured when air mass originated from the Marine area (M). A high OC concentration was occasionally observed at Gosan due to local biomass burning activities. The contribution of secondary OC to total OC varied approximately between 8.4% and 32.2% and depended on air mass type. IMPLICATIONS Organic material contributes approximately 20–90% of the total fine particulate mass concentration at different sites over the world depending on location and season. Organic carbon consists of hundreds of compounds with a wide range of chemical and optical properties. A better understanding of the chemical characteristics of carbonaceous aerosol influenced by increasing anthropogenic pollution in the downwind regions of the East Asian continent is needed in order to determine their impacts on regional air quality and climate change.

Mercury in cloud water collected on Mt. Bamboo in northern Taiwan during the northeast monsoon season

Cloud water was sampled on Mt. Bamboo in northern Taiwan in January–March 2009 for total mercury (Hg) analysis. This was the first cloud water Hg measurement reported from the downwind region of East Asia, which is the major Hg emission source region globally. A total of 11 cloud events were encountered, and 129 and 316 cloud water samples were collected for Hg and major ion analyses, respectively. The mean cloud water pH was 4.14. Cl− and Na+ were the major ions in cloud water. About 2/3 of the samples had molar ratios of Cl−/Na+ close to the seawater ratio of 1.12, demonstrating a significant impact of sea salt aerosols on cloud water chemistry. On the other hand, 90% of the measured SO42− was non-sea-salt-SO42− (nss-SO42−), highlighting the influence of human activities. Concentrations of Hg ranged between 0.5 and 165.5 ng L−1, with a mean of 9.6 ng L−1. Elevated Hg concentrations were usually associated with highly acidic samples. Hg concentrations were well correlated with major ion concentrations, especially with NO3−, K+, nss-SO42−, and NH4+. The results of element ratio calculations, correlation analyses and trajectory analyses indicated that, in addition to sea salt aerosols, coal combustion, industrial activities, and biomass/biofuel burning in the East Asian continent could have contributed to the measured Hg in the cloud water. The contribution of below-cloud scavenging to rainwater Hg was evaluated by comparing the cloud water Hg concentrations to the rainwater Hg concentrations sampled at a nearby mountain site and at an urban site. The mean rainwater Hg values at the mountain site (11.6 ng L−1) and at the urban site (19.2 ng L−1) were all higher than the cloud water value, demonstrating the below-cloud scavenging contribution. Nonetheless, the below-cloud scavenging contribution was more significant in the urban area than in the mountain area. About 28% and 91% of the rainwater Hg at the mountain and urban sites could be attributed to the below-cloud scavenging, respectively.

Simulated variations of eolian dust from inner Asian deserts at the mid-Pliocene, last glacial maximum, and present day: contributions from the regional tectonic uplift and global climate change

Northern Tibetan Plateau uplift and global climate change are regarded as two important factors responsible for a remarkable increase in dust concentration originating from inner Asian deserts during the Pliocene–Pleistocene period. Dust cycles during the mid-Pliocene, last glacial maximum (LGM), and present day are simulated with a global climate model, based on reconstructed dust source scenarios, to evaluate the relative contributions of the two factors to the increment of dust sedimentation fluxes. In the focused downwind regions of the Chinese Loess Plateau/North Pacific, the model generally produces a light eolian dust mass accumulation rate (MAR) of 7.1/0.28 g/cm2/kyr during the mid-Pliocene, a heavier MAR of 11.6/0.87 g/cm2/kyr at present, and the heaviest MAR of 24.5/1.15 g/cm2/kyr during the LGM. Our results are in good agreement with marine and terrestrial observations. These MAR increases can be attributed to both regional tectonic uplift and global climate change. Comparatively, the climatic factors, including the ice sheet and sea surface temperature changes, have modulated the regional surface wind field and controlled the intensity of sedimentation flux over the Loess Plateau. The impact of the Tibetan Plateau uplift, which increased the areas of inland deserts, is more important over the North Pacific. The dust MAR has been widely used in previous studies as an indicator of inland Asian aridity; however, based on the present results, the interpretation needs to be considered with greater caution that the MAR is actually not only controlled by the source areas but the surface wind velocity.

Temporal and Spatial Variations of NOx and Ozone Concentrations in Seoul during the Solar Eclipse of 22 July 2009

Abstract The temporal and spatial variations of NO, NO2, and O3 concentrations in Seoul, South Korea, during the solar eclipse of 22 July 2009 are investigated by analyzing data measured at 25 environmental monitoring stations. The NO2 concentration increases and the NO and O3 concentrations decrease because the efficiency of NO2 photolysis decreases during the solar eclipse. About an hour after the maximum obscuration, the reduction in the average O3 concentration over Seoul is estimated to be 45%. The maximum reduction in the O3 concentration downwind of the NOx source area is higher and occurs later than that in the downtown region. Deviations from the NO–NO2–O3 photostationary state in the downwind region are larger than those in the downtown region. This result implies that, in addition to the photochemical effect, the effect of transport by winds increases the reduction potential of the O3 concentration in the downwind region during the solar eclipse.

Coastal Atmospheric Circulation around an Idealized Cape during Wind-Driven Upwelling Studied from a Coupled Ocean–Atmosphere Model

Abstract The study analyzes atmospheric circulation around an idealized coastal cape during summertime upwelling-favorable wind conditions simulated by a mesoscale coupled ocean–atmosphere model. The domain resembles an eastern ocean boundary with a single cape protruding into the ocean in the center of a coastline. The model predicts the formation of an orographic wind intensification area on the lee side of the cape, extending a few hundred kilometers downstream and seaward. Imposed initial conditions do not contain a low-level temperature inversion, which nevertheless forms on the lee side of the cape during the simulation, and which is accompanied by high Froude numbers diagnosed in that area, suggesting the presence of the supercritical flow. Formation of such an inversion is likely caused by average easterly winds resulting on the lee side that bring warm air masses originating over land, as well as by air warming during adiabatic descent on the lee side of the topographic obstacle. Mountain leeside dynamics modulated by differential diurnal heating is thus suggested to dominate the wind regime in the studied case. The location of this wind feature and its strong diurnal variations correlate well with the development and evolution of the localized lee side trough over the coastal ocean. The vertical extent of the leeside trough is limited by the subsidence inversion aloft. Diurnal modulations of the ocean sea surface temperatures (SSTs) and surface depth-averaged ocean current on the lee side of the cape are found to strongly correlate with wind stress variations over the same area. Wind-driven coastal upwelling develops during the simulation and extends offshore about 50 km upwind of the cape. It widens twice as much on the lee side of the cape, where the coldest nearshore SSTs are found. The average wind stress–SST coupling in the 100-km coastal zone is strong for the region upwind of the cape, but is notably weaker for the downwind region, estimated from the 10-day-average fields. The study findings demonstrate that orographic and diurnal modulations of the near-surface atmospheric flow on the lee side of the cape notably affect the air–sea coupling on various temporal scales: weaker wind stress–SST coupling results for the long-term averages, while strong correlations are found on the diurnal scale.

The impact of anthropogenic and biogenic emissions on surface ozone concentrations in Istanbul

Surface ozone concentrations at Istanbul during a summer episode in June 2008 were simulated using a high resolution and urban scale modeling system coupling MM5 and CMAQ models with a recently developed anthropogenic emission inventory for the region. Two sets of base runs were performed in order to investigate for the first time the impact of biogenic emissions on ozone concentrations in the Greater Istanbul Area (GIA). The first simulation was performed using only the anthropogenic emissions whereas the second simulation was performed using both anthropogenic and biogenic emissions. Biogenic NMVOC emissions were comparable with anthropogenic NMVOC emissions in terms of magnitude. The inclusion of biogenic emissions significantly improved the performance of the model, particularly in reproducing the low night time values as well as the temporal variation of ozone concentrations. Terpene emissions contributed significantly to the destruction of the ozone during nighttime. Biogenic NMVOCs emissions enhanced ozone concentrations in the downwind regions of GIA up to 25 ppb. The VOC/NO x ratio almost doubled due to the addition of biogenic NMVOCs. Anthropogenic NO x and NMVOCs were perturbed by ± 30% in another set of simulations to quantify the sensitivity of ozone concentrations to the precursor emissions in the region. The sensitivity runs, as along with the model-calculated ozone-to-reactive nitrogen ratios, pointed NO x-sensitive chemistry, particularly in the downwind areas. On the other hand, urban parts of the city responded more to changes in NO x due to very high anthropogenic emissions.

Impacts of aerosols on summertime tropospheric photolysis frequencies and photochemistry over Central Eastern China

Abstract Aerosols in the troposphere influence photolysis frequencies and hence the concentrations of chemical species. We used a three-dimensional regional chemical transport model (NAQPMS) coupled with an accurate radiative transfer model to examine the impacts of aerosols on summertime photochemistry in Central Eastern China (CEC) via changing photolysis frequencies. In addition to looking at changes in concentrations as previous studies have done, we examined the changes in ozone (O3) budgets and the uncertainties related to our estimations. The 1st–12th June 2006 was selected as the simulation period when high aerosol optical depth at 550 nm (AOD550) and O3 were found. A comparison of measurements showed that the model was capable of reproducing the spatial and temporal variations in photolysis frequencies, ultraviolet (UV) radiation, AOD550, cloud optical depth, O3 and other chemical constitutes in CEC. Aerosols have important impacts on atmospheric oxidation capacity in CEC. On a regional scale, aerosols decreased the average O3→O (1D) photolysis frequency by 53%, 37% and 21% in the lower, middle and upper troposphere in CEC. The uncertainties of these estimations were 37%, 25% and 14%, respectively. Mean OH concentrations decreased by 51%, 40% and 24% in layers below 1 km, 1–3 km and 3–10 km, with uncertainties of 39%, 28% and 9%, respectively. The changes in HO2 concentrations were smaller but significant. In contrast, NOx showed a significant increase at 0–1 km and 1–3 km in CEC, with magnitudes of 6% and 8%. The largest relative enhancement occurred in downwind regions below 1 km. Summertime boundary layer O3 (below 1 km and 1–3 km) was reduced by 5% with a maximum of 9% in highly polluted regions. The reduced ozone production (P (O3)) was responsible for this reduction below 3 km.

Effects of an Apartment Complex on Flow and Dispersion in an Urban Area

The effects of an apartment complex on flow and pollutant dispersion in an urban area are numerically investigated using a computational fluid dynamics (CFD) model. The CFD model is based on the Reynolds-averaged Navier-Stokes equations and includes the renormalization group k- turbulence model. The geographic information system (GIS) data is used as an input data of the CFD model. Eight numerical simulations are carried out for different inflow directions and, for each inflow direction, the effects of an apartment complex are investigated, comparing the characteristics of flow and dispersion before and after construction of the apartment complex in detail. The observation data of automatic weather system (AWS) is analyzed. The windrose analysis shows that the wind speed and direction after the construction of the complex are quite different from those before the construction. The construction of the apartment complex resulted in the decrease in wind speed at the downwind region. It is also shown that the wind speed increased partially inside the apartment complex due to the channeling effect to satisfy the mass continuity. On the whole, the wind speed decreased at the downwind region due to the drag effect by the apartment complex. As a result, the passive pollutant concentration increased (decreased) near the downwind region of (within) the apartment complex compared with that before the construction.

Analysis of a Severe Dust Storm Event over China: Application of the WRF-Dust Model

ABSTRACTA severe dust storm (SDS) event occurred during March-20 to March-22, 2010 in China. A regional dynamical model coupled with a dust model (WRF-Dust) is used for analyzing this SDS event. The distribution of API (air pollution index) values in China and satellite (moderate-resolution imaging spectroradiometer—MODIS) AOD (aerosol optical depth) data are used to trace the dust storm and to compare with the model result. Several model sensitive studies are performed to analyze the roles of physical processes (such as dust source, transport, and deposition) in controlling the SDS event. The result suggests that the Gobi Desert is a major dust source of the SDS event. By contrast, the Taklamakan Desert plays minor roles for affecting the high dust concentrations in eastern/southern China during the SDS event. This study also suggests that a large amount of dust particles was deposited at the surface during the transport pathway between the Gobi Desert and eastern/southern China, and the high surface concentrations of dust particles can be considered as a new dust source region, which produced dust air pollution when surface winds were strong. In this study, we define this process as a propagate dust source (PDS). The calculation shows that the calculated dust concentrations were considerably lower than the measured values in the downwind regions of deserts when the PDS process was not included in the model. By including the PDS process, the calculated dust pollution in eastern and southern China is considerably improved. The further detailed analysis shows that the PDS played important roles in controlling the long-range transport of dust particles during the SDS event. This study suggests that this regional dust model (WRF-Dust) is a useful tool to analyze the important processes of dust storms that are often occurred in China.

The Trend of Atmospheric Ozone Concentration in Taiwan, 1996–2009

PP-30-015 Background/Aims: Taiwan's small landmass and dense population, coupled with increasing numbers of motor vehicles caused all sorts of respiratory problems in Taiwan's population. In 1995, the Taiwan government established a limitation policy on the amount of primary pollutants; however, secondary pollutants such as ozone were still on the rise. Methods: To utilize the statistical values taken during 1996–2009 from the monitoring stations in the downwind regions of the Northern, Central, and Southern parts of Taiwan, operated by Taiwan's environmental protection agency, and doing an analysis. Results: From 1996 to 2009 monitoring stations situated in the North, Central, and South of Taiwan showed increasing ozone concentration, and significant difference (P = 0.7 × 10−3, P = 1.73 × 10−5, P = 0.4 × 10−2). During April–May and October, noticeable peaks were observed in the maximum hourly and maximum 8 hours moving average ozone concentration in a day. From 1996 to 2009, the maximum hourly value of ozone concentration did not show significant difference, with the maximum value being in the range of 55–62 ppb, 64–83 ppb, 71–87 ppb in the North, Central, and Southern parts of Taiwan. From 1996 to 2009, a decrease in the concentration of NOx has been observed. Conclusion: The decreasing concentration of NOx and increasing concentration of ozone could be a result of decreasing NO titration effect. The ozone concentration is increasing yearly, especially during the spring and autumn seasons. Ozone causes respiratory health problems, and by reducing motor vehicle pollution, we can lower the concentration of ozone in our air and bring better health to the citizens of Taiwan.

Climatological aspects of the optical properties of fine/coarse mode aerosol mixtures

Aerosol mixtures composed of coarse mode desert dust combined with fine mode combustion generated aerosols (from fossil fuel and biomass burning sources) were investigated at three locations that are in and/or downwind of major global aerosol emission source regions. Multiyear monitoring data at Aerosol Robotic Network sites in Beijing (central eastern China), Kanpur (Indo‐Gangetic Plain, northern India), and Ilorin (Nigeria, Sudanian zone of West Africa) were utilized to study the climatological characteristics of aerosol optical properties. Multiyear climatological averages of spectral single scattering albedo (SSA) versus fine mode fraction (FMF) of aerosol optical depth at 675 nm at all three sites exhibited relatively linear trends up to ∼50% FMF. This suggests the possibility that external linear mixing of both fine and coarse mode components (weighted by FMF) dominates the SSA variation, where the SSA of each component remains relatively constant for this range of FMF only. However, it is likely that a combination of other factors is also involved in determining the dynamics of SSA as a function of FMF, such as fine mode particles adhering to coarse mode dust. The spectral variation of the climatological averaged aerosol absorption optical depth (AAOD) was nearly linear in logarithmic coordinates over the wavelength range of 440–870 nm for both the Kanpur and Ilorin sites. However, at two sites in China (Beijing and Xianghe), a distinct nonlinearity in spectral AAOD in logarithmic space was observed, suggesting the possibility of anomalously strong absorption in coarse mode aerosols increasing the 870 nm AAOD.

Dynamic adjustment of climatological ozone boundary conditions for air-quality forecasts

Abstract. Ten different approaches for applying lateral and top climatological boundary conditions for ozone have been evaluated using the off-line regional air-quality model AURAMS, driven with meteorology provided by the GEM weather-forecast model. All ten approaches employ the same climatological ozone profiles, but differ in the manner in which they are applied, via the inclusion or exclusion of (i) a dynamic adjustment of the climatological ozone profile in response to the model-predicted tropopause height, (ii) a sponge zone for ozone on the model top, (iii) upward extrapolation of the climatological ozone profile, and (iv) different mass consistency corrections. The model performance for each approach was evaluated against North American surface ozone and ozonesonde observations from the BAQS-Met field study period in the summer of 2007. The original daily one-hour maximum surface ozone biases of about +15 ppbv were greatly reduced (halved) in some simulations using alternative methodologies. However, comparisons to ozonesonde observations showed that the reduction in surface ozone bias sometimes came at the cost of significant positive biases in ozone concentrations in the free troposphere and upper troposphere. The best overall performance throughout the troposphere was achieved using a methodology that included dynamic tropopause height adjustment, no sponge zone at the model top, extrapolation of ozone when required above the limit of the climatology, and no mass consistency corrections (global mass conservation was still enforced). The simulation using this model version had a one-hour daily maximum surface ozone bias of +8.6 ppbv, with small reductions in model correlation, and the best comparison to ozonesonde profiles. This recommended and original methodologies were compared for two further case studies: a high-resolution simulation of the BAQS-Met measurement intensive, and a study of the downwind region of the Canadian Rockies. Significant improvements were noted for the high resolution simulations during the BAQS-Met measurement intensive period, both in formal statistical comparisons and time series comparisons of events at surface stations. The tests for the downwind-Rockies region showed that the coupling between vertical transport associated with troposphere/stratosphere exchange, and that associated with boundary layer turbulent mixing, may contribute to ozone positive biases. The results may be unique to the modelling setup employed, but the results also highlight the importance of evaluating boundary condition and mass consistency/correction algorithms against three-dimensional datasets.

Sensitivity of the NOy budget over the United States to anthropogenic and lightning NOx in summer

We examine the implications of new estimates of the anthropogenic and lightning nitrogen oxide (NOx) source for the budget of oxidized nitrogen (NOy) over the United States in summer using a 3‐D global chemical transport model (Model of Ozone and Related Tracers‐4). As a result of the Environmental Protection Agency (EPA) State Implementation call, power plant NOx emissions over the eastern United States decreased significantly, as reflected by a 23% decrease in summer surface emissions from the 1999 U.S. EPA National Emissions Inventory to our 2004 inventory. We increase the model lightning NOx source over northern midlatitude continents (by a factor of 10) and the fraction emitted into the free troposphere (FT, from 80% to 98%) to better match the recent observation‐based estimates. While these NOx source updates improve the simulation of NOx and O3 compared to the Intercontinental Chemical Transport Experiment‐North America aircraft observations, a bias in the partitioning between nitric acid (HNO3) and peroxyacetylnitrate (PAN) remains especially above 8 km, suggesting gaps in the current understanding of upper tropospheric processes. We estimate a model NOy export efficiency of 4%−14% to the North Atlantic in the FT, within the range of previous plume‐based estimates (3%−20%) and lower than the 30% exported directly from the continental boundary layer. Lightning NOx contributes 24%−43% of the FT NOy export from the U.S. to the North Atlantic and 28%−34% to the NOy wet deposition over the United States, with the ranges reflecting different assumptions. Increasing lightning NOx decreases the fractional contribution of PAN to total NOy export, increases the O3 production in the northern extratropical FT by 33%, and decreases the regional mean ozone production efficiency per unit NOx (OPE) by 30%. If models underestimate the lightning NOx source, they would overestimate the background OPE in the FT and the fractional contribution of PAN to NOy export. Therefore, a model underestimate of lightning NOx would likely lead to an overestimate of the downwind O3 production due to anthropogenic NOx export. Better constraints on the lightning NOx source are required to more confidently assess the impacts of anthropogenic emissions and their changes on air quality over downwind regions.

Regional-scale relationships between aerosol and summer monsoon circulation, and precipitation over northeast Asia

We investigated the regional-scale relationships between columnar aerosol loads and summer monsoon circulation, and also the precipitation over northeast Asia using aerosol optical depth (AOD) data obtained from the 8-year MODIS, AERONET Sun/sky radiometer, and precipitation data acquired under the Global Precipitation Climatology Project (GPCP). These high-quality data revealed the regional-scale link between AOD and summer monsoon circulation, precipitation in July over northeast Asian countries, and their distinct spatial and annual variabilities. Compared to the mean AOD for the entire period of 2001–2008, the increase of almost 40–50% in the AOD value in July 2005 and July 2007 was found over the downwind regions of China (Yellow Sea, Korean peninsula, and East Sea), with negative precipitation anomalies. This can be attributable to the strong westerly confluent flows, between cyclone flows by continental thermal low centered over the northern China and anticyclonic flows by the western North Pacific High, which transport anthropogenic pollution aerosols emitted from east China to aforementioned downwind high AOD regions along the rim of the Pacific marine airmass. In July 2002, however, the easterly flows transported anthropogenic aerosols from east China to the southwestern part of China in July 2002. As a result, the AOD off the coast of China was dramatically reduced in spite of decreasing rainfall. From the calculation of the cross-correlation coefficient between MODIS-derived AOD anomalies and GPCP precipitation anomalies in July over the period 2001–2008, we found negative correlations over the areas encompassed by 105–115°E and 30–35°N and by 120–140°E and 35–40°N (Yellow Sea, Korean peninsula, and East Sea). This suggests that aerosol loads over these regions are easily influenced by the Asian monsoon flow system and associated precipitation.

2006년 오존 고농도 사례 시 부산권 지역 isoprene 배출이 오존 농도에 미치는 영향 분석

The estimation of a biogenic volatile organic compound (BVOC, especially isoprene) and the influence of isoprene emissions on ozone concentrations in the Greater Busan Area (GBA) were carried out based on a numerical modeling approach during a high ozone episode. The BVOC emissions were estimated using a biogenic emission information system (BEIS v3.14) with vegetation data provided by the forest geographical information system (FGIS), land use data provided by the environmental geographical information system (EGIS), and meteorological data simulated by the MM5. Ozone simulation was performed by two sets of simulation scenarios: (1) without (CASE1) and (2) with isoprene emissions (CASE2). The isoprene emission (82 ton day -1 ) in the GBA was estimated to be the most dominant BVOC followed by methanol (56) and carbon monoxide (28). Largest impacts of isoprene emissions on the ozone concentrations (CASE2-CASE1) were predicted to be about 4 ppb in inland locations where a high isoprene was emitted and to be about 2 ppb in the downwind and/or convergence regions of wind due to both the photochemical reaction of ozone precursors (e.g., high isoprene emissions) and meteorological conditions (e.g., local transport).

The Dynamic Response of the Hurricane Wind Field to Spiral Rainband Heating

Abstract The response of the hurricane wind field to spiral rainband heating is examined by using a three-dimensional, nonhydrostatic, linear model of the vortex–anelastic equations. Diabatic heat sources, which are designed in accordance with previous observations of spiral rainbands, are made to rotate with the flow around the hurricane-like wind field of a balanced, axisymmetric vortex. Common kinematic features are recovered, such as the overturning secondary circulation, descending midlevel radial inflow, and cyclonically accelerated tangential flow on the radially outward side of spiral rainbands. Comparison of the responses to the purely convective and stratiform rainbands indicates that the overturning secondary circulation is mostly due to the convective part of the rainband and is stronger in the upwind region, while midlevel radial inflow descending to the surface is due to the stratiform characteristics of the rainband and is stronger in the downwind region. The secondary horizontal wind maximum is exhibited in both convective and stratiform parts of the rainband, but it tends to be stronger in the downwind region. The results indicate that the primary effects of rainbands on the hurricane wind field are caused by the direct response to diabatic heating in convection embedded in them and that the structure of the diabatic heating is primarily responsible for their unique kinematic structures. Sensitivity tests confirm the robustness of the results. In addition, the response of the hurricane wind field to the rainband heating is, in the linear limit, the sum of the asymmetric potential vorticity and symmetric transverse circulations.

Temporal distribution and potential sources of atmospheric mercury measured at a high-elevation background station in Taiwan

Measurements of gaseous elemental mercury (GEM), reactive gaseous mercury (RGM), and particulate mercury (PHg) have been conducted at Lulin Atmospheric Background Station (LABS) in Taiwan since April 2006. This was the first long-term free tropospheric atmospheric Hg monitoring program in the downwind region of East Asia, which is a major Hg emission source region. Between April 13, 2006 and December 31, 2007, the mean concentrations of GEM, RGM, and PHg were 1.73 ng m −3, 12.1 pg m −3, and 2.3 pg m −3, respectively. A diurnal pattern was observed for GEM with afternoon peaks and nighttime lows, whereas the diurnal pattern of RGM was opposite to that of GEM. Spikes of RGM were frequently observed between midnight and early morning with concurrent decreases in GEM and relative humidity and increases in O 3, suggesting the oxidation of GEM and formation of RGM in free troposphere (FT). Upslope movement of boundary layer (BL) air in daytime and subsidence of FT air at night resulted in these diurnal patterns. Considering only the nighttime data, which were more representative of FT air, the composite monthly mean GEM concentrations ranged between 1.06 and 2.06 ng m −3. Seasonal variation in nighttime GEM was evident, with lower concentrations usually occurring in summer when clean marine air masses prevailed. Between fall and spring, air masses passed the East Asian continent prior to reaching LABS, contributing to the elevated GEM concentrations. Analysis of GEM/CO correlation tends to support the argument. Good GEM/CO correlations were observed in fall, winter, and spring, suggesting influence of anthropogenic emission sources. Our results demonstrate the significance of East Asian Hg emissions, including both anthropogenic and biomass burning emissions, and their long-range transport in the FT. Because of the pronounced seasonal monsoon activity and the seasonal variation in regional wind field, export of the Asian Hg emissions to Taiwan occurs mainly during fall, winter, and spring.

Asian dust over northern China and its impact on the downstream aerosol chemistry in 2004

TSP and PM2.5 aerosol particles were synchronously sampled at six sites along the transport pathway of dust storms from desert regions to coastal areas in the spring of 2004 to investigate the regional characteristics of Asian dust and its impact on aerosol chemistry over northern China. Factor analysis of daily PM10 concentrations in 17 cities showed that northern China can be basically divided into five regions: (1) Northern Dust Region, (2) Northeastern Dust Region, (3) Western Dust Region, (4) Inland Passing Region, and (5) Coastal Region. Northern Dust Region was characterized by a high content of Ca. Northeastern Dust Region was a relatively clean area with a low concentration of pollutants and secondary ions in comparison to other regions. Inland Passing Region and Coastal Region showed high concentrations of anthropogenic pollutants. The impact of Asian dust on aerosol chemistry decreased in the order Yulin/Duolun > Beijing > Qingdao/Shanghai as transport distance increased. The ratio of Ca/Al, which showed significant differences in different regions over northern China, is suggested to be a tracer to identify the sources of dust storms. Asian dust either mixes pollutants on the pathway and carries them to the downwind regions or dilutes the pollutants over northern China, which affects the aerosol composition more in coarse particles in those areas near source regions and more in fine particles in downwind areas. The ratio of NO3−/SO42− during dust storms was significantly reduced and the lowest generally appeared after the peak of dust. Our results showed that Asian dust plays a critical role in buffering the acidity of aerosols over northern China by a potential increase of ∼1 unit pH for the aerosol particles in spring.