Reconfigurable intelligent surfaces (RISs) have recently emerged as effective solutions for providing massive connectivity. However, an effective RIS user selection method that can support massive devices remains undeveloped. In this study, a power method (PM)-based RIS user selection algorithm for RIS-assisted massive multiple-input multiple-output systems is proposed. It is proven that minimizing the condition number (CN) of the aggregated downlink channel matrix results in the same performance as maximizing the sum rate. Based on this analysis, a PM-based RIS user selection algorithm that utilizes a CN as an RIS user selection metric is proposed here. Although the complexity of conventional user selection algorithm is proportional to the square of the number of base station (BS) antennas ( M 2 ), that of the proposed algorithm is linearly proportional to the number of BS antennas ( M ). Simulation results demonstrate that, under a practical RIS control link, the proposed PMUS algorithm achieves better performance and lower complexity than the conventional user selection algorithm.