The existence of five new ternary compounds with Gd1.33Pt3Al8-type structure (Pearson symbol hR51, space group R-3m) was established by means of X-ray powder diffraction and energy-dispersive X-ray spectroscopy: Tb1.33Ni3Ga8 (а = 4.2056(1), с = 37.8913(9) Å), Ho1.33Ni3Ga8 (а = 4.19666(9), с = 37.7882(9) Å), Er1.33Ni3Ga8 (a = 4.19290(8), c = 37.7446(8) Å), Tm1.33Ni3Ga8 (a = 4.18819(7), c = 37.6980(7) Å), and Lu1.33Ni3Ga8 (a = 4.1826(1), c = 37.647(1) Å). The structures of the ternary R1.33Ni3Ga8 compounds belong to a family of linear-intergrowth structures with the general formula R0.67TnM2n + m and are built from atom layers of the composition R0.67Ga (R0.67M), separated by single or double NiGa2 slabs (TM2). The layers containing the rare-earth metal atoms are characterized by a disordered distribution of rare-earth metal atoms and Ga-atom triangles.
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