In this paper, a novel method for high-accuracy high temperature measurement is proposed, which is based on forward Brillouin scattering (FBS) of double-coated optical fiber with polyimide outer coating. The temperature variation changes the acoustic properties of polyimide-coated fiber that is suitable for high temperature measurement in the range of 120 ∼ 220 ℃. An interesting feature is that different radial acoustic modes have different frequency responses in the polyimide-coated fiber. Another interesting phenomenon is that the temperature linearly depends on the frequency shift of FBS spectrum with high sensitivity from 120 ℃ to 220 ℃. By using one acoustic mode with a high frequency shift-temperature sensitivity, we propose a novel high temperature measurement method based on FBS with high measurement accuracy. The experimental result shows that the low temperature measurement uncertainty of 0.02 ℃ can be achieved. The proposed method is expected to be used for high-accuracy temperature measurement applications within a temperature range of 100 ∼ 200 ℃, such as underground oil layer detection, power plant monitoring and high-power electrical systems monitoring.