Dominant Charge Carriers Research Articles

Preparation, electrical and thermal properties of new anode material based on Ca-doped perovskite CeAlO3

Tetragonal perovskite phase Ce0.9Ca0.1AlO2.95 + x was obtained for the first time. Such phase, containing cerium in the oxidation state of 3+, can be promising anode materials for a solid oxide fuel cells (SOFCs). Ce0.9Ca0.1AlO2.95 + х (space group I4/mcm) was synthesized by the solid-phase method at 1400°С in a nitrogen flow with using ammonium oxalate (NH4)2C2O4 to create a reducing atmosphere. Thermogravimetry results showed that Ce0.9Ca0.1AlO2.95 + x was stable to oxidation up to 500°С in air and up to 700°С in argon (partial pressure of oxygen рО2 = 10−4 bar). The thermal expansion coefficient measured by dilatometry was equal to 11.16·10−6 К−1. The temperature dependences of the electrical conductivity (for undoped phase CeAlO3σ ≈ 1·10−3 S/cm and for doped Ce0.9Ca0.1AlO2.95 + xσ ≈ 3·10−2 S/cm at 500°С in air) were obtained by the electrochemical impedance spectroscopy measurements). The electrical conductivity of these samples at the temperatures range of 350–500°С was almost independent of the partial pressure of oxygen рО2 from 10−18 to 0.21 bar, however, there was a slight negative slope at T > 500 °C (рО2). The total ionic transport numbers measured by the EMF method were close to 1·10−3, which indicated the dominance of electronic conductivity. The measurement of the sign of the thermal-EMF showed that positive charge carriers (holes) were dominant charge carriers.

Solid-State Electron Transport Through Carbon Dots Junctions: The Role of Boron and Phosphorus Doping.

Carbon dots (CDs) are a new class of nanoparticles that gained widespread attention recently because of their easy preparation, water solubility, biocompatibility, and bright luminescence, leading to their integration in various applications. Despite their nm-scale and proven electron transfer capabilities, the solid-state electron transport (ETp) across single CDswasnever explored. Here, a molecular junction configuration is used to explore the ETp across CDs as a function of their chemical structure using both DC-bias current-voltage and AC-bias impedance measurements. CDs are used with Nitrogen and Sulfur as exogenous atoms and doped with small amounts of Boron and Phosphorous. It is shown that the presence of P and B highly improves the ETp efficiency across the CDs, yet without an indication of a change in the dominant charge carrier. Instead, structural characterizations reveal significant changes in the chemical species across the CDs: the formation of sulfonates and graphitic Nitrogen. Temperature-dependent measurements and normalized differential conductance analysis reveal that the ETp mechanism across the CDs behaves as tunneling, which is common to all CDs used here. The study shows that the conductivity of CDs is on par with that of sophisticated molecular wires, suggesting CDs as new 'green' candidates for molecular electronics applications.

Electric properties of anorthite ceramics prepared from illitic clay and oil shale ash

Electrical properties during firing of anorthite ceramic prepared from mixtures of illitic clay (from Northeastern Hungary) and fly ashes (obtained from circulating fluidized bed combustion – IA4 and pulverized firing – ID4) with high content of CaO were investigated. Mixtures were prepared with 60 wt% of illitic clay and 40 wt% of oil shale ash. The ashes were hydrated prior to mixing, to prevent the reaction of free lime with water during sample preparation. The mixtures were subjected to thermal and structural analyses to describe the processes induced by thermal treatment. The contraction of the IA4 and ID4 samples reached 1.8% and 2.5%, respectively, at 1100 °C, which is significantly lower than that of the illitic clay (7%). X-ray diffraction (XRD) analysis revealed a presence of diopside, gehlenite, cristobalite, and leucite minerals as additional mineral phases in the prepared anorthite ceramics. Measurement of AC conductivity showed that after the decomposition of the CaCO3 at ∼880 °C, Ca2+ ions became the dominant charge carriers, and the electrical current was carried by a hopping mechanism throughout the studied temperature region. The electrical conductivity and the relative dielectric constant of the ID4 sample was higher compared to that of the IA4 sample. The relative dielectric constant reached values of 6 (sample IA4) and 8 (sample ID4) at 140 °C (after drying).

Polarons in Conjugated Polyelectrolytes: A First‐Principles Perspective

AbstractConjugated polyelectrolytes (CPEs) comprised of conjugated backbones and pendant ionic functionalities are versatile organic semiconductors with myriad optoelectronic applications. Although polarons are dominant charge carriers in conducting CPEs owing to strong electron‐phonon coupling, their properties are not well understood, especially from a first‐principles perspective. In this study, a comprehensive study on the stability, structural deformation, electronic structure, and optical absorption of positive (or hole)/negative (or electron) polarons and bi‐polarons in CPEs is conducted. It is explored how these properties depend on the electrostatic interaction between the polarons and ionic functionalities, including alkyl chains, ionic groups, and counterions. It is then examined how the bandgap, polaron binding energy, and optoelectronic structure of CPEs can be tuned by various combinations of the donor and acceptor units in their backbones. Finally, electrochemical stability of CPEs is studied and light is shed on the absence of negative polarons in CPEs. The strategy to improve the electrochemical stability of n‐doped CPEs is also discussed.

Electronic transport studies of Ag-doped Bi2Se3 topological insulator

The structural, magnetotransport, and angle-resolved photoemission spectroscopy (ARPES) of Ag-doped Bi2Se3 single crystals are presented. Temperature dependent resistivity exhibits metallic behavior with a slope change above 200 K for Ag-doped Bi2Se3. The magnetoresistance shows positive quadratic dependence at low fields satisfying Kohler's rule. Hall resistivity measurement shows that electrons are dominant charge carriers. Furthermore, these results agree well with the ARPES spectra observed at T = 20 K, where the Fermi level lies inside the bulk conduction band. The Dirac point of the topological surface states is shifted toward higher binding energy (∼0.12 eV) for Ag-doped samples as compared to pristine Bi2Se3.

Spin-selected electron transfer in liquid–solid contact electrification

Electron transfer has been proven the dominant charge carrier during contact electrification at the liquid–solid interface. However, the effect of electron spin in contact electrification remains to be investigated. This study examines the charge transfer between different liquids and ferrimagnetic solids in a magnetic field, focusing on the contribution of O2 molecules to the liquid–solid contact electrification. The findings reveal that magnetic fields promote electron transfer at the O2-containing liquid–solid interfaces. Moreover, magnetic field-induced electron transfer increases at higher O2 concentrations in the liquids and decreases at elevated temperatures. The results indicate spin-selected electron transfer at liquid–solid interface. External magnetic fields can modulate the spin conversion of the radical pairs at the O2-containing liquid and ferrimagnetic solid interfaces due to the Zeeman interaction, promoting electron transfer. A spin-selected electron transfer model for liquid–solid contact electrification is further proposed based on the radical pair mechanism, in which the HO2 molecules and the free unpaired electrons from the ferrimagnetic solids are considered radical pairs. The spin conversion of the [HO2• •e−] pairs is affected by magnetic fields, rendering the electron transfer magnetic field-sensitive.

Strong Fermi-Level Pinning in GeS-Metal Nanocontacts.

Germanium sulfide (GeS) is a layered monochalcogenide semiconductor with a band gap of about 1.6 eV. To verify the suitability of GeS for field-effect-based device applications, a detailed understanding of the electronic transport mechanisms of GeS–metal junctions is required. In this work, we have used conductive atomic force microscopy (c-AFM) to study charge carrier injection in metal–GeS nanocontacts. Using contact current–voltage spectroscopy, we identified three dominant charge carrier injection mechanisms: thermionic emission, direct tunneling, and Fowler–Nordheim tunneling. In the forward-bias regime, thermionic emission is the dominating current injection mechanism, whereas in the reverse-bias regime, the current injection mechanism is quantum mechanical tunneling. Using tips of different materials (platinum, n-type-doped silicon, and highly doped p-type diamond), we found that the Schottky barrier is almost independent of the work function of the metallic tip, which is indicative of a strong Fermi-level pinning. This strong Fermi-level pinning is caused by charged defects and impurities.

Polycyclic Aromatic Hydrocarbon emission model in photodissociation regions – I. Application to the 3.3, 6.2, and 11.2 μm bands

ABSTRACT We present a charge distribution based model that computes the infrared spectrum of polycyclic aromatic hydrocarbon (PAH) molecules using recent measurements or quantum chemical calculations of specific PAHs. The model is applied to a sample of well-studied photodissociation regions (PDRs) with well-determined physical conditions (the radiation field strength, G0, electron density ne, and the gas temperature, Tgas). Specifically, we modelled the emission of five PAHs ranging in size from 18 to 96 carbon atoms, over a range of physical conditions characterized by the ionization parameter $\gamma = G_{0}\times T_{\rm gas}^{1/2}/n_{e}$. The anions emerge as the dominant charge carriers in low γ (<2 × 102) environments, neutrals in the intermediate γ (103 – 104) environments, and cations in the high γ (>105) environments. Furthermore, the PAH anions and cations exhibit similar spectral characteristics. The similarity in the cationic and anionic spectra translates into the interpretation of the 6.2/(11.0+11.2) band ratio, with high values of this ratio associated with large contributions from either cations or anions. The model’s predicted values of 6.2/(11.0+11.2) and 3.3/6.2 compared well to the observations in the PDRs NGC 7023, NGC 2023, the horsehead nebula, the Orion bar, and the diffuse interstellar medium, demonstrating that changes in the charge state can account for the variations in the observed PAH emission. We also reassess the diagnostic potential of the 6.2/(11.0+11.2) versus 3.3/(11.0+11.2) ratios and show that without any prior knowledge about γ, the 3.3/(11.0+11.2) can predict the PAH size, but the 6.2/(11.0 + 11.2) cannot predict the γ of the astrophysical environment.

First-principles calculations to investigate transport properties of non-trivial fermions of CoSi

Recently, the electronic topology of CoSi has been reported to be present at three nodal points (two at Γ (G1, G2) and one at R (R1)) in the band structure. Considering this, we present a study where various transport coefficients are investigated by using first-principle based DFT method for the temperature (T) range 40-300 K. For the chemical potential (μ) corresponding to energies of these nodal points and at the Fermi level (EF), 3D constant energy surfaces are constructed. They have shown that the number of states available at energies of these nodal points and the EF is largest for R1 point and least for G1 point at T = 0 K. Electrical conductivity per unit relaxation time(σ/τ) and electronic thermal conductivity per unit relaxation time(κ0) have also shown similar results at different μ with rise in T. For instance, at T = 100 K, σ/τ∼0.13×1020Ω−1m−1s−1 at G1 whereas its value reaches ∼0.18×1020Ω−1m−1s−1 at R1 nodal point. However, Seebeck coefficient (S) is largest for G2 and least for G1 nodal point at any given T. The values of S are obtained to be positive at the μ corresponding to the G2, R1 and EF (except G1) which is increasing with the rise in T. Also, the dominant charge carriers at G1 point are found to be electrons for T < 225 K whereas for T > 225 K, the charge carriers are obtained to be dominated by holes. Furthermore, the doping concentrations have also been calculated for G1 (electron doping ∼2.25×1022 cm−3), G2 and R1 points (hole doping ∼4.10×1020 cm−3 and 7.22 × 1022 cm−3, respectively).

Experimental Research on Electrical Conductivity of the Olivine-Ilmenite System at High Temperatures and High Pressures

Ilmenite is a common metallic oxide distributed in the mafic rocks from the Earth’s upper mantle, and thus the effect of ilmenite contents on the electrical structures of the Earth’s upper mantle should be investigated in detail. Electrical conductivities of the olivine–ilmenite systems with various contents of ilmenite (VIlm = 4, 7, 10, 11 and 15 vol%) and pure ilmenite aggregates were measured using a complex impedance spectroscopic technique at 1.0–3.0 GPa and 773–1273 K. Electrical conductivities of the olivine–ilmenite systems increased with increasing temperatures in different degrees, conforming to the Arrhenius law. With the rise of pressure, the conductivities of the olivine–ilmenite systems slightly increased. According to the significant change of the conductivities, the percolation threshold of ilmenite grains in the olivine–ilmenite systems was proposed to be ∼ 11 vol%. Isolated ilmenites moderately influence the conductivities of olivine aggregates, but the interconnected ilmenites dramatically enhanced the conductivities of the olivine–ilmenite systems. The conductivities of the olivine aggregates with 11 vol% ilmenites were about 1.5–3 orders magnitude higher than those of 10 vol% ilmenites-bearing olivine aggregates. Small polarons were proposed to be the dominant charge carriers for olivine aggregates with isolated ilmenites (activation enthalpies: 0.62–0.89 eV) and interconnected ilmenites (activation enthalpies: 0.15–0.20 eV). Furthermore, the conductivity–depth profiles of olivine–ilmenite systems in the Earth’s upper mantle were constructed, providing an important constraint on the electrical structures of the Earth’s interior.

Research on the Electrochemical Properties of Al2−x Zn x O3−α

To understand the electrochemical properties of the Al2O3 based proton conductor in more detail, a solid-state electrolyte Zn-doped Al2O3 was successfully prepared using the solid-state reaction method at the temperatures of 1873 K for 10 h. The phase structure and microscopic morphology of these materials are thoroughly investigated. The structural analysis results revealed that the electrolyte has a pure perovskite phase structure. The crystal grains are relatively uniform, the ceramic material is dense, and the relative density is greater than 97 percent, according to microscopic morphology analysis. The electrical conductivity of the specimen was measured using the two-terminal AC method to clarify the electrochemical properties of Zn-doped Al2O3. The H/D isotope effect of electrical conductivity was studied, and it was discovered that protons are the dominant charge carrier at temperatures ranging from 1073 to 1473 K in hydrogen-rich atmospheres. The electrochemical impedance spectroscopy test showed that in the temperature range of 1073K–1473 K, the conductivity of the sample increases with the increase of temperature, and the electrochemical performance of the sample is the best when the doping amount is x = 0.012. The conductance activation energy () is in the range of 1.01–1.62 eV in hydrogen-rich atmospheres. From the point of view of electromotive force measurement, the theoretical (computational) electrical potential matches the measured potential very well. In a hydrogen-rich atmosphere of 1073–1473 K, the proton mobility of Al2−x Zn x O3−α exceeds 0.90. In this work, we proved that Al2−x Zn x O3−α sample is a proton conductor.

Constraints on fluids in the continental crust from laboratory-based electrical conductivity measurements of plagioclase

Aqueous fluids are regarded as the crucial origin of high conductivity and low velocity anomalies observed by magnetotelluric and seismic surveys in the middle to lower continental crust. Integration of field geophysical methods with experimental conductivity data is essential to accurately constrain the fluid fraction and salinity. Studies of fluid content and salinity in the crust from the experimental or theoretically calculated conductivity of fluid–minerals systems and saline-bearing fluid have demonstrated that crustal constituent minerals play a prominent role in the conductivity of fluid–mineral systems. We performed systematic measurements on electrical conductivity of dry and hydrous plagioclase solid solutions at high temperature and pressure. A positive dependence of electrical conductivity on Na contents is observed in dry samples, and discontinuous variation in conductivity is associated with the degree of Al/Si order–disorder. For hydrous samples, trace amounts of water considerably enhance the electrical conductivity. The dominant charge carriers in dry and hydrous plagioclase are Na ions and hydrogen, respectively, both of which migrate via the Frenkel mechanism. If there are no free fluids present in minerals, the crustal major constituent minerals containing structure water cannot account for the high-conductivity anomalies in the middle to lower crust based on our model of the rock conductivity–depth profiles in the continental crust. The calculated bulk conductivities of fluid–rock systems further suggest that at least 1 vol% of fluid with seawater salinity (3.5 wt%) is necessary in the middle to lower crust to interpret the high conductivity anomalies.

From p- to n-Type Mixed Conduction in Isoindigo-Based Polymers through Molecular Design.

Organic mixed ionic and electronic conductors are of significant interest for bioelectronic applications. Here, three different isoindigoid building blocks are used to obtain polymeric mixed conductors with vastly different structural and electronic properties which can be further fine-tuned through the choice of comonomer unit. This work shows how careful design of the isoindigoid scaffold can afford highly planar polymer structures with high degrees of electronic delocalization, while subtle structural modifications can control the dominant charge carrier (hole or electron) when probed in organic electrochemical transistors. A combination of experimental and computational techniques is employed to probe electrochemical, structural, and mixed ionic and electronic properties of the polymer series which in turn allows the derivation of important structure-property relations for this promising class of materials in the context of organic bioelectronics. Ultimately, these findings are used to outline robust molecular-design strategies for isoindigo-based mixed conductors that can support efficient p-type, n-type, and ambipolar transistor operation in an aqueous environment.

Origin of Interface Limitation in Zn(O,S)/CuInS2-Based Solar Cells.

Copper indium disulfide (CuInS2) grown under Cu-rich conditions exhibits high optical quality but suffers predominantly from charge carrier interface recombination, resulting in poor solar cell performance. An unfavorable "cliff"-like conduction band alignment at the buffer/CuInS2 interface could be a possible cause of enhanced interface recombination in the device. In this work, we exploit direct and inverse photoelectron spectroscopy together with electrical characterization to investigate the cause of interface recombination in chemical bath-deposited Zn(O,S)/co-evaporated CuInS2-based devices. Temperature-dependent current-voltage analyses indeed reveal an activation energy of the dominant charge carrier recombination path, considerably smaller than the absorber bulk band gap, confirming the dominant recombination channel to be present at the Zn(O,S)/CuInS2 interface. However, photoelectron spectroscopy measurements indicate a small (0.1 eV) "spike"-like conduction band offset at the Zn(O,S)/CuInS2 interface, excluding an unfavorable energy-level alignment to be the prominent cause for strong interface recombination. The observed band bending upon interface formation also suggests Fermi-level pinning not to be the main reason, leaving near-interface defects (as recently observed in Cu-rich CuInSe2) as the likely reason for the performance-limiting interface recombination.

Photoelectrical properties of flexible quasi-interdigitated back-contact perovskite solar cells

Perovskites are a promising class of solution-processed semiconductor materials that are intensively investigated for their application in flexible solar cells and other optoelectronic devices. In this work, the fabrication and characterization of flexible quasi-interdigitated back-contact perovskite solar cells (FQIBC PSCs) are presented. The performance of fabricated devices on illumination direction (front-side or rear-side) and illumination intensity are studied. The current–voltage characteristics of the devices reveal that the performance of devices is better when illuminated from the rear-side. The quantum efficiency measurements show that the front-side illumination allows to avoid the light transmission losses and achieve a wide-spectral response in the devices. The dependence of the device open-circuit voltage on the illumination intensity is investigated to determine the dominant charge carrier recombination mechanism in the devices.

Ion conducting methylcellulose‐polyvinyl alcohol blend based electrolytes incorporated with ammonium thiocyanate for electric double layer capacitor application

AbstractSolid polymer electrolytes (SPEs) have received numerous attention for application in energy storage devices due to their safety performance and mechanical flexibility. However, further improvement of amorphousness and electrochemical performance is needed to realize the commercial potential of SPEs. In this work, a series of methylcellulose (MC) – polyvinyl alcohol (PVA) blend‐based electrolyte doped with ammonium thiocyanate (NH4SCN) salt has been prepared using solvent casting technique. MC‐PVA‐NH4SCN electrolytes have been characterized and the most amorphous sample has been used as electrolyte in an electric double layer capacitor (EDLC). Thermogravimetric analysis is carried out to analyze the thermal stability of the electrolytes. From X‐ray diffraction analysis, the addition of salt up to 40 wt% decreases the percentage of crystallinity and crystallite size indicating the improvement in amorphousness of the polymer electrolytes. From transference number measurements analysis, it is revealed that ions are the dominant charge carriers. Linear sweep voltammetry shows that the most amorphous electrolyte is electrochemically stable in the potential range of −1.97 V to +1.90 V. Using the most amorphous MC‐PVA‐NH4SCN electrolyte, an EDLC has been fabricated and characterized using impedance technique, cyclic voltammetry and galvanostatic charge–discharge.

Effect of Light Irradiation on the Diffusion Rate of the Charge Carrier Hopping Mechanism in P3HT–ZnO Nanoparticles Studied by μ+SR

Blended regio-regular P3HT–ZnO nanoparticles are a hybrid material developed as an active layer for hybrid solar cells. The study of the hopping mechanisms and diffusion rates of regio-regular P3HT–ZnO nanoparticles is significant for obtaining intrinsic charge transport properties that provide helpful information for preparing high-performance solar cells. The temperature dependences of the parallel and perpendicular diffusion rates in regio-regular P3HT–ZnO nanoparticles determined from muon spin relaxation measurements were investigated by applying various longitudinal fields. We investigated the effect of light irradiation on the diffusion rates in regio-regular P3HT–ZnO nanoparticles. We found that with increasing temperature, the parallel diffusion rate decreased, while the perpendicular diffusion rate increased. The ratio of the parallel to perpendicular diffusion rate (D‖/D⊥) can be used to indicate the dominant charge carrier hopping mechanism. Without light irradiation, perpendicular diffusion dominates the charge carrier hopping, starting at 25 K, with a ratio of 1.70×104, whereas with light irradiation, the perpendicular diffusion of the charge carrier starts to dominate at the temperature of 10 K, with a ratio of 2.40×104. It is indicated that the additional energy from light irradiation affects the diffusion, especially the charge diffusion in the perpendicular direction.

Influence of Br-/S2- site-exchange on Li diffusion mechanism in Li6PS5Br: a computational study.

We investigate how low degrees of [Formula: see text] site-exchange influence the [Formula: see text] diffusion in the argyrodite-type solid electrolyte [Formula: see text] by ab initio molecular dynamics simulations. Based on the atomic trajectories of the defect-free material, a new mechanism for the internal [Formula: see text] reorganization within the [Formula: see text] cages around the [Formula: see text] sites is identified. This reorganization mechanism is highly concerted and cannot be described by just one rotation axis. Simulations with [Formula: see text] defects reveal that [Formula: see text] interstitials ([Formula: see text]) are the dominant mobile charge carriers and originate from Frenkel pairs. These are formed because [Formula: see text] defects on the [Formula: see text] sites donate one or even two [Formula: see text] to the neighbouring cages. The [Formula: see text] then carry out intercage jumps via interstitial and interstitialcy mechanisms. With that, one single [Formula: see text] defect enables [Formula: see text] diffusion over an extended spatial area explaining why low degrees of site-exchange are sufficient to trigger superionic conduction. The vacant sites of the Frenkel pairs, namely [Formula: see text], are mostly immobile and bound to the [Formula: see text] defect. Because [Formula: see text] defects on [Formula: see text] sites act as sinks for [Formula: see text] they seem to be beneficial only for the local [Formula: see text] transport. In their vicinity T4 tetrahedral sites start to get occupied. Because the [Formula: see text] transport was found to be rather confined if [Formula: see text] and [Formula: see text] defects are direct neighbours, their relative arrangement seems to be crucial for effective long-range transport. This article is part of the Theo Murphy meeting issue 'Understanding fast-ion conduction in solid electrolytes'.

Anomalous Electronic and Protonic Conductivity of 2D Titanium Oxide and Low‐Temperature Power Generation Using Its Protonic Conduction

AbstractIn this study, a titanium‐oxide film is fabricated by stacking 2D nanosheets with a thickness of 1 nm layer‐by‐layer. The electrical properties of the titanium‐oxide film are investigated under various temperatures (25–300 °C) and a water vapor atmosphere. As a result, it is found that protonic conduction is dominant at low temperatures (&lt;100 °C), while electronic conduction is highest at high temperatures (&gt;200 °C). The electrical conductivity is about one billion times higher than that of conventional 3D titanium‐oxide. Protons, dominant charge carriers at low temperature, are transported along the pathway between layers of nanosheets. The protonic conductivity is as high as 10−4−5 S cm−1 due to the increased interfacial density of the film. This anomalous electronic and protonic conduction is expected to be available in various applications. In this study, the developed 2D titanium‐oxide with high protonic conductivity is employed in the solid electrolyte of a solid oxide fuel cell using water as a fuel. A competitive power density of ≈0.22 mW cm−2 is obtained at low temperature (75 °C) under a water concentration gradient.

Structural, electrical and electrochemical characterization of hybrid morphological LiNi0.5Mn1.5O4 cathode material

Spinel LiNi0.5Mn1.5O4 (LNMO) cathode are effectively obtained by one-pot hydrothermal synthesis. Scanning electron microscopy (SEM) reveals the hybrid morphological of LNMO, featuring cotton-like structures (400–800 nm) and rod-like structures (90–150 nm). The equivalent circuit well describes the Nyquist plot to separate the grain and grain boundary effects. According to the Maxwell-Wagner model, the complex permittivity confirms non-homogenous layers' existence; highly conducting grains and poorly conducting grain boundaries. Non-overlapping polar tunneling (NSPT) and correlated barrier hopping (CBH) are two responsible models for the conduction mechanism at low and high temperatures. Further, identical activation energy values are observed for hopping frequency, and peak frequency from normalized parameters Z’’/Z’’ max and M’’/M’’ max, suggesting Li+ ions are the dominant charge carriers. The LNMO/Li cell delivers higher discharge capacity than commercial LNMO/Li cell from prior study, credits from the bridging features between rod-like and cotton-like particles.