Dominant Phase Research Articles

Photocatalytic Degradation of Paracetamol and Antibacterial Activity of La-Modified TiO2 Obtained by Non-Hydrolytic Sol–Gel Route

The current study aims to synthesize and analyze both pure and La-doped TiO2, and evaluate the photocatalytic and antibacterial activity of as-prepared samples. Doped and undoped samples were prepared by the non-hydrolytic sol–gel method from titanium(IV) chloride, benzyl alcohol, and lanthanum(III) nitrate followed by thermal treatment. Lanthanum content in synthesized samples was 0.4, 1, and 5 mol%. The resulting nanopowders’ structure and morphology were described using XRD, IR, and UV–Vis analysis. The average particle sizes of pure and doped TiO2 were about 6–15 nm and anatase was found to be a dominant crystalline phase in the samples. It was observed that particle sizes decreased on increasing La content. The photocatalytic activity of the pure and La-doped sol–gel powders was estimated in the decomposition of paracetamol in distilled water using ultraviolet light illumination. Doping with lanthanum ions has been shown to increase the photocatalytic properties on the degradation of paracetamol. Furthermore, the annealed catalysts (pure and La3+ doped) showed increased photocatalytic activity and degradation of the analgesic in comparison with non-annealed materials. In both cases, the highest photocatalytic efficiency is observed at the optimal La3+ (1 mol%) concentration. The antimicrobial activity of 1 mol% La/TiO2 was tested against a reference strain E. coli in the presence of ultraviolet light and in dark conditions. The number of viable bacterial cells was determined by a spread plate method, and kill curves were performed. The results showed that photoactivated 1 mol% La/TiO2 exhibited a strong bactericidal effect, and in concentration, 1 mg/mL efficiently killed bacteria at an initial cell density of about 105 colony forming units in 1 mL within 15 min.

Controllable Growth of Crystal Facets Enables Superb Cycling Stability of Anode Material for Potassium Ion Batteries

AbstractTo enrich the crystal growth strategies for the booming applications concerning lattice structure, a preferred facet‐growth method is proposed for solvothermal synthesis of target (BiO)2CO3 in the two‐phase system. The dominant crystal phase can be regulated from α‐Fe2O3 to (BiO)2CO3 by properly increasing dosage of Bi feedstock, and the optimized composite is composed of (BiO)2CO3 nanocrystal (≈10 nm) and amorphous iron oxide (defined as “FOB‐50”). Based on experimental characterizations and theoretical calculations, the highly matched lattice between (006)/(0012) facets of α‐Fe2O3 and {010} facet group of (BiO)2CO3 involving orientation of Fe─O─Fe bond and Bi─O─Bi bond is verified to facilitate the interaction between the above facets, resulting in preferred growth of {010} dominated by (040) facet in (BiO)2CO3 and its composites. The structural merits can not only enable the FOB‐50‐based electrodes to achieve a high capacity and unprecedentedly stable cyclic performances for 1500 cycles/a long time‐span of 32 months as anode materials, but also ensure the full‐cell to well inherit the electrochemical features of the cathode in potassium ion batteries (PIBs). This work can provide new insight into lattice regulation for bismuth‐based materials and expand their application as electrodes for high performance PIBs and lithium ion batteries.

Low-temperature stabilization of rutile in W-doped Titania thin films deposited by magnetron Co-Sputtering

Tungsten doped Titania thin films were sputtered on a silicon substrate by magnetron co-sputtering. The influence of tungsten on Vickers hardness and crystallographic changes was studied in films subjected to stepped annealing treatments. Rutile is the dominant phase with crystallite size ∼ 10 nm after 500 °C annealing. The films, doped with 1.79 % W, exhibit the highest hardness (20.88 GPa), a rutile-anatase mixture (80:20) and a preferential shift in crystallographic orientation from (101) to (110). The homogeneous distribution of tungsten in TiO2 stabilizes rutile at 500 °C, providing an innovative and simple strategy for its synthesis, thus expanding the options for substrate materials.

Thermal Behavior of Clinoptilolite

Understanding the thermal properties of zeolites is crucial for their industrial applications. This study explores the thermal stability and dehydration process of clinoptilolite using high-temperature X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR). Clinoptilolite’s thermal decomposition was monitored from 25 °C to 1200 °C, with results analyzed based on its crystal structure. Principal components analysis (PCA) of the DRIFT spectra indicated progressive water removal and dehydration upon heating, leading to the formation of hydrogen bonds. Thermogravimetric analysis (TGA) revealed a two-step endothermic weight loss: initially, physically adsorbed water was lost up to 100 °C, followed by the removal of tightly bound water and hydroxyl groups until 800 °C. Clinoptilolite remained the dominant phase up to 800 °C, after which albite and cristobalite took over. Rietveld refinement showed that the sample initially contained 70% clinoptilolite, 24% albite, and 6% cristobalite. Above 800 °C, clinoptilolite disappeared, leaving 93% albite and 7% cristobalite. FT-IR spectra changes due to water loss were evident: drying of adsorbed water occurred up to 75 °C and minimal changes were observed from 75 °C to 135 °C, followed by further dehydration until 240 °C. Complete dehydration was confirmed by the disappearance of OH stretching vibration bands by 395 °C, consistent with TGA findings.

Laser-Induced Synthesis of Tin Sulfides.

Various polytypes of van der Waals (vdW) materials can be formed by sulfur and tin, which exhibit distinctive and complementary electronic properties. Hence, these materials are attractive candidates for the design of multifunctional devices. This work demonstrates direct selective growth of tin sulfides by laser irradiation. A 532nm continuous wave laser is used to synthesize centimeter-scale tin sulfide tracks from single source precursor tin(II) o-ethylxanthate under ambient conditions. Modulation of laser irradiation conditions enables tuning of the dominant phase of tin sulfide as well as SnS2/SnS heterostructures formation. An in-depth investigation of the morphological, structural, and compositional characteristics of the laser-synthesized tin sulfide microstructures is reported. Furthermore, laser-synthesized tin sulfides photodetectors show broad spectral response with relatively high photoresponsivity up to 4 AW-1 and fast switching time (τ rise = 1.8ms and τ fall = 16ms). This approach is versatile and can be exploited in various fields such as energy conversion and storage, catalysis, chemical sensors, and optoelectronics.

Unexpected contributions by carbonates and organic matter in a silicate-dominated tropical catchment: An isotope approach

The understanding of global carbon has rarely extended to small-scale tropical river basins. To address these uncertainties, this study aims to investigate the importance of rock weathering and organic matter turnover in the carbon cycle in a terrain dominated by crystalline silicate rocks. The geochemical composition of the dissolved and particulate carbon phases (DIC, DOC and POC) and their stable carbon isotopes were studied in the Deduru Oya River in Sri Lanka. Dissolved inorganic carbon (DIC) was the most dominant carbon phase and its contribution to the total carbon pool varied between 67 and 89 %. Furthermore, the δ13CDIC values in the river varied between −1.1 and −16.5 ‰. The lithological characteristics and molar ratios between Ca2+, Mg2+ and HCO3− indicated rock weathering mainly by CO2 and carbonic acid. The δ13CDIC values for groundwater input were −15.9 ‰, while for carbonate weathering, mainly due to fertiliser input, they reached a value of −12.7 ‰. This input was fed into an isotope mass balance to determine the relative contributions. However, the isotope mass balance was only plausible after correcting for the effects on δ13CDIC caused by degassing and photosynthesis. Our study demonstrated that carbonate weathering and organic matter turnover are essential components of the river carbon cycle even in a silicate dominated catchment. They can represent up to 60 % of the DIC pool. Combined with the higher organic matter turnover and high pCO2 in the river water, it can be suggested that the Deduru Oya River acts as a net source of CO2 in the atmosphere. Our study shows that CO2 degassing and in-stream photosynthesis in tropical river systems need to be considered along with chemical weathering to account for carbon transport and turnover in tropical rivers.

Effect of particle size distribution on the properties of celsian based glazes

AbstractThe microstructure and surface properties of ceramic glaze are influenced by chemical composition, particle size distribution, glaze application conditions, and firing parameters. This study specifically focused on the influence of glaze particle size distribution on the thermal behavior, microstructure, and surface appearance of barium frit based ceramic glaze in the floor tile firing process. The investigation involved examining the impact of four distinct particle size dimensions (d50: 5.7 μm, 6.8 μm, 7.5 μm, 10.9 μm) on the glaze properties by using hot stage microscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), color and gloss measurements. The studies indicated that celsian is the dominant phase in the glaze structure. The sintering and softening temperatures of glazes decreased with the increase of milling time. A decrease in the particle size of the glaze slurry increased the whiteness index. As the average particle size (d50) of the glaze decreased, the number of crystals was also increased. The investigation results also suggested a relation between specular reflection and milling time. As the milling time extended, there was a corresponding increase in the magnitude of glossiness.

Analysis of dominant phases inhibiting dissociation of smelting slags and the alkali depolymerization mechanism

Analysis of dominant phases inhibiting dissociation of smelting slags and the alkali depolymerization mechanism

Hydrogen isotope effects on recombination dominant plasmas in NAGDIS-II

The detachment processes of the hydrogen (H) and deuterium (D) plasmas are comparatively investigated in the linear plasma device NAGDIS-II. The laser Thomson scattering measurements demonstrate that the recombination rate of the H plasma is greater than that of the D plasma as the neutral pressure increases in the molecular activated recombination (MAR) dominant detachment phase. As the recombination process by MAR is strongly dependent on the vibrational and rotationally excited states of the molecule, the rovibrational quantum state populations of the H and D molecules are measured using the Fulcher-α band spectroscopy. The results indicate that the vibrational temperature in the electronic ground state is considerably higher than the rotational temperature during detachment. The reaction rate coefficients for MARs due to charge exchange chains (CX-MAR) and dissociative attachment chains (DA-MAR) are calculated by the collision-radiation model under the measured temperature conditions. It can be observed that the CX-MAR is larger than the DA-MAR for both H and D, and that the CX-MAR of H is larger than the CX-MAR of D at electron temperatures T e above 1 eV. In consideration of the experimentally observed vibrational and rotational excitation temperatures, the reaction rate coefficients of CX-MAR and DA-MAR are increasing in the low T e region. These calculations are in accordance with the experimental results, which indicate that recombination processes due to MAR are more predominant in the H plasma compared to the D plasma. Furthermore, a transition from MAR to electron–ion recombination processes is observed in the D plasma at T e below 0.5 eV.

SEM/Raman spectroscopy of clathrites as analogs of authigenic carbonates in ocean worlds

AbstractThere is evidence from the near‐infrared observations of space missions of the presence of carbonates on the surface of several ocean worlds. However, their genesis remains unresolved. We investigate the hypothesis that these carbonates may be in the form of clathrites assuming that clathrate hydrates are stable phases in the crust and ocean of these ocean worlds. In order to support this, we studied a sample of a potential clathrite from the Hydrate Ridge cold seep (Cascadia Subduction Zone), the carbonate rock fossil of clathrate hydrates, as a terrestrial analogue. We characterised the mineralogy and texture of the sample by using a coupled confocal Raman microscope and scanning electron microscopy instrument with the aim of identifying possible geo‐ and biosignatures, which could be relevant for future missions of exploration to ocean worlds and Mars. Our results show that aragonite is the dominant mineral phase in the clathrite sample, but Mg‐calcite and dolomite were also identified. These three carbonates constitute a pattern related to clathrate hydrate formation and dissociation processes. Dolomite was defined as a biosignature of gas hydrate microbiomes because it was integrated within Mg‐calcite grains precipitated after clathrate hydrate dissociation. Nevertheless, no spectral changes were observed in Raman bands of carbonate minerals that would indicate the influence of clathrate hydrates in their genesis. We also observed that Raman band positions of the associated framboidal pyrites are a characteristic signature of the associated framboid‐like texture because its potential as biosignature may only be attributed by biochemical analysis.

Pupillometry indexes ocular dominance plasticity

Short-term monocular deprivation in normally sighted adult humans produces a transient shift of ocular dominance, boosting the deprived eye. This effect has been documented with both perceptual tests and through physiological recordings, but no previous study simultaneously measured physiological responses and the perceptual effects of deprivation. Here we propose an integrated experimental paradigm that combines binocular rivalry with pupillometry, to introduce an objective physiological index of ocular dominance plasticity, acquired concurrently with perceptual testing. Ten participants reported the perceptual dynamics of binocular rivalry, while we measured pupil diameter. Stimuli were a white and a black disk, each presented monocularly. Rivalry dynamics and pupil-size traces were compared before and after 2 h of monocular deprivation, achieved by applying a translucent patch over the dominant eye. Consistent with prior research, we observed that monocular deprivation boosts the deprived-eye signal and consequently increases ocular dominance. In line with previous studies, we also observed subtle but systematic modulations of pupil size that tracked alternations between exclusive dominance phases of the black or white disk. Following monocular deprivation, the amplitude of these pupil-size modulations increased, which is consistent with the post-deprivation boost of the deprived eye and the increase of ocular dominance. This provides evidence that deprivation impacts the effective strength of monocular visual stimuli, coherently affecting perceptual reports and the automatic and unconscious regulation of pupil diameter. Our results show that a combined paradigm of binocular rivalry and pupillometry gives new insights into the physiological mechanisms underlying deprivation effects.

Krótka charakterystyka ochry ze sztolni Marta (Nižná Slaná, Spiš-Gemer Ore Mts

The contribution deals with the study on composition of ochre sample from the Marta adit at Nižná Slaná. Three samples were prepared from ochre by hand picking and screening, which were subjected to GA, AAS, XRF and XRD. Salts precipitated on surface at drying contain 17.7 % S (53 % as SO4), 16.5 % MgO, 13.6 % Fe2O3, 3.54 % CaO and 1 % MnO. As to mineral composition, sulphates such as gypsum, starkeyite and rozenite are dominant. The fraction of grain size under 250 micron contains 30 % Fe2O3, 28.6 % SiO2, 8 % Al2O3, 6.6 % CaO, 2.9 % MgO and 1.95 % S. Notable is content of arsenic in this fraction, which attain as high as 1.84 %. Quartz and gypsum occur as dominant crystalline phases. As to coarser fraction, i.e. under 150 microns, 44.5 % SiO2, 16.8 % Fe2O3, 11.3 % Al2O3, 6.9 % CaO, 2.4 % MgO a 2.3 % C were assayed. Dominant quartz is accompanied by mica, plagioclase, ankerite and dolomite. It was shown that arsenic is bonded in finer grain size fraction.

Evolution of technology investment and development of robotaxi services

Using artificial intelligence and autonomous driving technologies, robotaxis are expected to provide more intelligent, efficient, sustainable, and convenient services as technology advances and market penetration increases. This requires attention to technology investment and market competition at the different stages of robotaxi development. This study aims to reveal the changing rules of R&D investment and market competition for robotaxi services at various stages, considering subsidies, passenger preferences (i.e. walking aversion, safety, additional convenience), and the volatility of benefits from congestion reduction. We developed models to capture the competition between robotaxis and traditional taxis in the three phases of market development — namely, introduction, development, and dominance. The results of this study show that the optimal level of R&D investment is affected by factors such as R&D subsidies, passenger preferences, and the volatility of congestion reduction benefits and that it decreases during the development phase and may further decline during the dominance phase. Additionally, government R&D subsidies should be maintained at a reasonable level to avoid potential strategic conflicts with companies in technology investment and adoption of robotaxi services during the introduction phase. The transition from R&D subsidies to usage subsidies will depend on reaching the perceived safety threshold for robotaxi services. Reducing congestion can play a role similar to the deployment of usage subsidies to promote robotaxi services during the development phase, and can promote R&D investment, robotaxi services, and firm profits in the dominance phase. However, these benefits may be reduced by the volatility of congestion reduction. Policy recommendations and strategies are provided to promote future technological progress and market competition.

Study the variation of current density & corrosion behavior of modified M2 tool steel: Simulation & experimental

In this study, the simulation of the current density was carried out through COMSOL Multiphysics on surface-modified M2 high-speed tool steel. The results demonstrated that in the presence of the nitride layer on the surface of M2, the current density was increased remarkably in the nitride layer and M2 was immune, and consequently, it can be predicted that the corrosion resistance was increased. For verification, the surface modification through plasma nitriding was applied on the M2 steel corrosion resistance and was evaluated through polarization and electrochemical impedance spectroscopy (EIS) in the 3.5 wt% of NaCl solution. The results confirmed the simulation outcomes; therefore, optimization of the parameters was performed. The impression of the variation of the process parameter of plasma nitriding such as temperature (500, 550, and 600 °C), time (4, 6, and 8 h), and ratio of inserted gases (N2/H2: 1:3, 1:1, 3:1) on the growth of the diffusive layer was assessed by X-Ray Diffractometry (XRD). Outcomes illustrated that applying plasma nitriding causes the formation of the different nitride phases on the top surfaces of the M2 substrate and Fe3N is the dominant phase. The diffusive nitride layer has a higher current density based on simulation results. The microhardness of the surface increased remarkably and 2414 HV was reached as a maximum surface hardness. By considering the obtained results, 500 °C, 6 h, and a ratio of 1:1 of N2/H2 were chosen as optimum conditions of the plasma nitriding of M2 high-speed tool steel, and a corrosion rate of 1.62 mpy was calculated.

The Cosmic Ultraviolet Baryon Survey (CUBS). VII. On the Warm-hot Circumgalactic Medium Probed by O vi and Ne viii at 0.4 ≲ z ≲ 0.7

This paper presents a newly established sample of 103 unique galaxies or galaxy groups at 0.4 ≲ z ≲ 0.7 from the Cosmic Ultraviolet Baryon Survey (CUBS) for studying the warm-hot circumgalactic medium (CGM) probed by both O vi and Ne viii absorption. The galaxies and associated neighbors are identified at <1 physical Mpc from the sightlines toward 15 CUBS QSOs at z QSO ≳ 0.8. A total of 30 galaxies or galaxy groups exhibit associated O vi λ λ 1031, 1037 doublet absorption within a line-of-sight velocity interval of ±250 km s−1, while the rest show no trace of O vi to a detection limit of logNOVI/cm−2≈13.7 . Meanwhile, only five galaxies or galaxy groups exhibit the Ne viii λ λ 770, 780 doublet absorption, down to a limiting column density of logNNeVIII/cm−2≈14.0 . These O vi- and Ne viii-bearing halos reside in different galaxy environments with stellar masses ranging from logMstar/M⊙≈8 to ≈11.5. The warm-hot CGM around galaxies of different stellar masses and star formation rates exhibits different spatial profiles and kinematics. In particular, star-forming galaxies with logMstar/M⊙≈9–11 show a significant concentration of metal-enriched warm-hot CGM within the virial radius, while massive quiescent galaxies exhibit flatter radial profiles of both column densities and covering fractions. In addition, the velocity dispersion of O vi absorption is broad with σ υ > 40 km s−1 for galaxies of logMstar/M⊙>9 within the virial radius, suggesting a more dynamic warm-hot halo around these galaxies. Finally, the warm-hot CGM probed by O vi and Ne viii is suggested to be the dominant phase in sub-L* galaxies with logMstar/M⊙≈9–10 based on their high ionization fractions in the CGM.

Elasticity of Single‐Crystal Clinohumite at High Pressures and Temperatures: Implication for the H2O and F Circulation in the Earth's Mantle

AbstractIn this study, we have determined the single‐crystal elasticity of clinohumite [Mg8.85Ti0.19Si3.93O16(OH1.11F0.89)] using Brillouin measurement up to 21 GPa at 300 K and 1 bar at 750 K, respectively. The elasticity of clinohumite was determined to be KS0 = 126.2(3) GPa, G0 = 79.7(2) GPa with pressure derivatives KS′ = 4.2(1), G′ = 1.3(1), pressure derivatives ∂KS/∂T = −0.024(1) GPa/K, and ∂G/∂T = −0.011(1) GPa/K). We comprehensively examined the effects of varying H2O, fluorine content and thermal states, on the velocity and density structures of the subducted harzburgite layer. Assuming a typical H2O content of 2 wt.% within harzburgite, our modeling has shown that hydrous harzburgite with clinohumite as the decomposition product of serpentine along a hot slab geotherm even has the VP and VS 0.4–0.8(6)% greater than it dry counterpart at 250–380 km depth. Yet in the top transition zone, the addition of H2O and F can effectively lower the sound velocities and density. The F‐bearing hydrous harzburgite has the VP and VS 1.1(5)–1.3(3)% lower than its dry counterpart, and only 0.6(5)% and 2.3(5)% greater than the pyrolitic mantle. Along cold slab geotherm, phase A will replace clinohumite as the dominant hydrous phase in the harzburgite, the VP and VS are 4.8(5)–5.3(3)% and 5.9(5)–6.0(3)% greater than the pyrolitic mantle in the upper mantle. In the top transition zone, the difference is approximately 3% in VP and 5% in VS. Our results provide crucial experimental evidence for future assessments of the seismic signals of subducted slabs with different hydrous minerals and thermal states.

Diffused Aesthetics or the Globalization of the Aesthetic

Diffused aesthetics is the formula by which the pervasiveness of aesthetic phenomena in the current scenario is summarized: having overcome the long phase of the exclusive dominance of art as the parameter of aesthetic values, contemporaneity has recognized itself in a plurality of practices in which even the non-aesthetic is thought and experienced as aesthetic. The essay aims to probe the theoretical aspects of this process in which material consumption and immaterial consumption converge into a single, everyday and pervasive scenario. This definition of a globalized aesthetics, in which the role of the aesthetic in consumer culture is fully activated, has configured first of all the opposition between the aestheticization and the aesthetics of the everyday, one approach ideological and critic and another more constrained to the aesthetic experience of the practices of the contemporary life-world.

Antioxidant activity and cytotoxicity of greigite nanoparticles synthesized by hydrothermal technique.

The effects of 180, 210, and 230°C reaction temperatures on the structural and magnetic properties of synthesized iron sulfide nanoparticles were studied. The Rietveld refinement analysis result of the X-ray diffraction data indicated that greigite was the dominant phase in all samples. The sample was prepared at 210°C for 18h and had a greater wt% ratio of the greigite phase. The crystallite and particle sizes increased with increasing reaction temperatures. Scanning electron microscope images confirmed the presence of aggregation of synthesized rod-shaped nanoparticles. The magnetic hysteresis curves of all samples showed ferromagnetic behavior at room temperature. The magnetic saturation of three samples increases with increased reaction temperature, but the coercive force has the opposite behavior. Antioxidant activity and cytotoxicity of the sample synthesized at 210°C were investigated. This sample killed cancer cells at relatively moderate and high concentrations with high viability of normal cells, demonstrating the sample's suitability for use in killing cancer cells while avoiding normal cells.

Microbially-mediated reductive dissolution of Fe-bearing minerals during freeze-thaw cycles

Constraining the role of microbes in the structural iron (Fe) reduction of iron-bearing minerals improves our understanding of sediments and ice sheets as a source of dissolved Fe (dFe) to the oceans. However, bio-mediated structural Fe-reduction has yet to be studied in cryospheric environments. Here, we show that the Fe reducing psychrophile bacterium Shewanella vesiculosa, isolated from sea ice in Antarctica, reduced structural Fe in nontronite (NAu-2) and maghemite (γ-Fe2O3), common mineral phases in glacial ice, and marine sediments in Antarctica, during two freeze–thaw cycles (−10 °C to +15 °C), resulting in the release of dFe. The modification of turbostratically disordered nontronite (ferric iron dominant phase) to discrete ordered illite-like structure (ferrous iron dominant phase), and the aggregation of altered small maghemite particles with neoformation of vivianite (Fe3(PO4)2·nH2O) indicated the microbially induced reductive dissolution of nontronite and maghemite, respectively. The biotic Fe-reduction gradually decreased and ceased as the temperature approached freezing (−8 °C), however the rection reactivated in the thawing cycle (−7 to +15 °C). No discernable biotic Fe-reduction was measured for either mineral under freezing conditions, suggesting that temperature limits the activity of the microbes. Further, and regardless of temperatures during two freeze–thaw cycles, Fe-reduction was not observed in abiotic control. Overall, these results highlight the importance of microbially induced Fe reduction during seasonal freeze–thaw cycles of ice and sediments in continuous supplying bioavailable dFe to cryospheric environments and the often Fe-limited polar oceans.

Microstructural and mechanical properties of microwave sintered bulk titanium nitride nanoceramics

In the present work nano-sized TiN powders were consolidated and sintered in nitrogen, argon and air using microwave power of 900 W at frequency 2.45 GHz. Green compacts were exposed to microwave energy, and heated at an in-situ temperature of 1500 °C without holding time. The relative density achieved was ∼92 %. X-ray diffraction analysis showed presence of TiN as the dominant major phase. The microstructures indicate that the sintered samples retained their nanocrystallinty, though aggregates comprising clusters of nanoparticle was noticed with size in the range of 80–400 nm due to high heating rate. Micro indentation assessment indicates average Vickers hardness of 15.2 ± 0.5 GPa. The lengths of cracks originating from the indentation edges were measured; the indentation fracture toughness were obtained between 4.0 and 4.5 MPa.m1/2. The observed properties indicate the suitability of the sintered material in tribological applications.