Diurnal Variation Of Ozone Research Articles

Surface ozone characterization at Larsemann Hills and Maitri, Antarctica.

Data are analyzed in terms of daily average ozone, its diurnal variation and its relation with meteorological parameters like dry bulb temperature (T), wet bulb temperature (Tw), atmospheric pressure and wind speed based on measurement of these parameters at two Indian Antarctic stations (Larsemann Hills, and Maitri) during 28th Indian Scientific Expedition of Antarctica (ISEA) organized during Antarctic summer of the year 2008-09. The work has been carried out to investigate summer time ozone level and its day-to-day and diurnal variability at these coastal locations and to highlight possible mechanism of ozone production and destruction. The result of the analysis indicates that daily average ozone concentration at Larsemann Hills varied from ~13 and ~20ppb with overall average value of ~16ppb and at Maitri, it varied from ~16 and ~21ppb with overall average value of ~18ppb. Photochemistry is found to partially contribute occasionally to the surface layer ozone at both the stations. Lower concentration of ozone at Maitri during beginning of the observational days may be due to destruction of ozone through activated halogens, whereas higher ozone on latter days may be due to photochemistry and advective transport from east to south-east areas. Ozone concentration during blizzard episodes at both the stations is reduced due to slow photochemical production of ozone, its photochemical removal and removal through deposition of ozone molecules on precipitation particles. Diurnal variation of ozone at Larsemann Hills and Maitri has been found to be absent.

Numerical air quality forecasting over eastern China: An operational application of WRF-Chem

The Regional Atmospheric Environmental Modeling System for eastern China (RAEMS) is an operational numerical system to forecast near surface atmospheric pollutants such as PM2.5 and O3 over the eastern China region. This system was based on the fully online coupled weather research and forecasting/chemistry (WRF-Chem) model. Anthropogenic emissions were based on the multi-resolution emission inventory for China (MEIC), and biogenic emissions were online calculated using model of emissions of gases and aerosols from nature (MEGAN2). Authorized by the China Meteorological Administration (CMA), this system started to provide operational forecast in 2013. With a large domain covering eastern China, the system produces daily 72-hr forecast. In this work, a comprehensive evaluation was carried out against measurements for two full years (2014–2015). Evaluation results show that the RAEMS is skillful in forecasting temporal variation and spatial distribution of major air pollutants over the eastern China region. The performance is consistent in different forecast length of 24 h, 48 h, and 72 h. About half of cities have correlation coefficients greater than 0.6 for PM2.5 and 0.7 for daily maximum 8-h averaged (DM8H) ozone. The forecasted PM2.5 is generally in good agreement with observed concentrations, with most cities having normalized mean biases (NMB) within ±25%. Forecasted ozone diurnal variation is very similar to that of observed, and makes small peak time error for DM8H ozone. It also shows good capability in capturing ozone pollution as indicated by high critical success indexes (CSI). The modeling system also exhibits acceptable performance for PM10, NO2, SO2, and CO. Meanwhile, degraded performance for PM2.5 is found under heavy polluted conditions, and there is a general over estimation in ozone concentrations.

Diurnal variations and source apportionment of ozone at the summit of Mount Huang, a rural site in Eastern China

Comprehensive measurements were conducted at the summit of Mount (Mt.) Huang, a rural site located in eastern China during the summer of 2011. They observed that ozone showed pronounced diurnal variations with high concentrations at night and low values during daytime. The Weather Research and Forecasting with Chemistry (WRF-Chem) model was applied to simulate the ozone concentrations at Mt. Huang in June 2011. With processes analysis and online ozone tagging method we coupled into the model system, the causes of this diurnal pattern and the contributions from different source regions were investigated. Our results showed that boundary layer diurnal cycle played an important role in driving the ozone diurnal variation. Further analysis showed that the negative contribution of vertical mixing was significant, resulting in the ozone decrease during the daytime. In contrast, ozone increased at night owing to the significant positive contribution of advection. This shifting of major factor between vertical mixing and advection formed this diurnal variation. Ozone source apportionment results indicated that approximately half was provided by inflow effect of ozone from outside the model domain (O3-INFLOW) and the other half was formed by ozone precursors (O3-PBL) emitted in eastern, central, and southern China. In the O3-PBL, 3.0% of the ozone was from Mt. Huang reflecting the small local contribution (O3-LOC) and the non-local contributions (O3-NLOC) accounted for 41.6%, in which ozone from the southerly regions contributed significantly, for example, 9.9% of the ozone originating from Jiangxi, representing the highest geographical contributor. Because the origin and variation of O3-NLOC was highly related to the diurnal movements in boundary layer, the similar diurnal patterns between O3-NLOC and total ozone both indicated the direct influence of O3-NLOC and the importance of boundary layer diurnal variations in the formation of such distinct diurnal ozone variations at Mt. Huang.

Open-path measurement of ozone and methane gases using quartz-enhanced photoacoustic spectroscopy

ABSTRACTWe demonstrate a standoff system based on quartz-enhanced photoacoustic spectroscopy technique for the concentration measurements of atmospheric ozone and methane. The technique is a modified version of Photoacoustic spectroscopy. Two primary features of this technique are the employment of a tunable quantum cascade laser and a resonant quartz-crystal tuning fork detector. Both of these features facilitate simultaneous sensing of multiple molecular species. External-cavity quantum cascade laser having a spectral range from 7 to 10 micron is used. Diurnal concentration variations of methane and ozone are estimated for open-path up to 25 m. The ambient methane and ozone concentration maxima were observed to have values of 3.5 parts per million by volume and 140 parts per billion by volume, respectively. Finite-element mesh-based software is used to simulate the Eigen frequency of the tuning fork sensor. High-resolution transmission molecular spectroscopic database of atmospheric gases and the real-time gas concentration data from the Delhi Pollution Control Committee have been used as references.

Association between Diurnal Variation of Ozone Concentration and Stroke Occurrence: 24-Hour Time Series Study.

Background and PurposeIncreasing ozone concentrations have been known to damage human health and ecosystems. Although ozone tends to display diurnal variation, most studies have reported only on the association between daily ozone concentrations and ischemic stroke occurrence on the same day, or with a 1-day lag. We investigated the effect of the diurnal variation of ozone on ischemic stroke occurrence during the same day.MethodsWe included a consecutive series of 1,734 patients from January 1, 2008, to December 31, 2014, at a single tertiary hospital in Seoul, South Korea. We evaluated differences between temperature and pollutants at the time of stroke onset for each time interval and averaged those parameters across the 7-year study period.ResultsDuring the interval from 13:00 to 16:59, we found a positive association between ischemic stroke occurrence and ozone concentration relative to other time periods. Upper median ozone levels from 13:00 to 16:59 were positively correlated with ischemic stroke (odds ratio, 1.550; 95% confidence intervals, 1.220 to 1.970; P = <0.001) when compared with lower median levels.ConclusionsThe results show diurnal patterns of ischemic stroke occurrence based on upper and lower median ozone levels for a 24-hour period, which extends understanding of the association between stroke occurrence and environmental influences.

Ozone reaction with interior building materials: Influence of diurnal ozone variation, temperature and humidity

Abstract Elevated tropospheric ozone concentrations are associated with increased morbidity and mortality. Indoor ozone chemistry affects human exposure to ozone and reaction products that also may adversely affect health and comfort. Reactive uptake of ozone has been characterized for many building materials; however, scant information is available on how diurnal variation of ambient ozone influences ozone reaction with indoor surfaces. The primary objective of this study is to investigate ozone-surface reactions in response to a diurnally varying ozone exposure for three common building materials: ceiling tile, painted drywall, and carpet tile. A secondary objective is to examine the effects of air temperature and humidity. A third goal is to explore how conditioning of materials in an occupied office building might influence subsequent ozone-surface reactions. Experiments were performed at bench-scale with inlet ozone concentrations varied to simulate daytime (ozone elevated) and nighttime (ozone-free in these experiments) periods. To simulate office conditions, experiments were conducted at two temperatures (22 °C and 28 °C) and three relative humidity values (25%, 50%, 75%). Effects of indoor surface exposures were examined by placing material samples in an occupied office and repeating bench-scale characterization after exposure periods of 1 and 2 months. Deposition velocities were observed to be highest during the initial hour of ozone exposure with slow decrease in the subsequent hours of simulated daytime conditions. Daily-average ozone reaction probabilities for fresh materials are in the respective ranges of (1.7–2.7) × 10−5, (2.8–4.7) × 10−5, and (3.0–4.5) × 10−5 for ceiling tile, painted drywall, and carpet tile. The reaction probability decreases by 7%–47% across the three test materials after two 8-h periods of ozone exposure. Measurements with the samples from an occupied office reveal that deposition velocity can decrease or increase with time. Influence of temperature and humidity on ozone-surface reactivity was not strong.

Diurnal variation of surface ozone in mountainous areas: Case study of Mt. Huang, East China

To explore the variations in atmospheric environment over mountainous areas, measurements were made from an intensive field observation at the summit of Mt. Huang (30.13°N, 118.15°E, 1841m above sea level), a rural site located in East China, from June to August 2011. The measurements revealed a diurnal change of surface O3 with low concentrations during the daytime and high concentrations during the nighttime. The causes of diurnal O3 variations over the mountain peak in East China were investigated by using a fairly comprehensive WRF-Chem and HYSPLIT4 modeling approach with observational analysis. By varying model inputs and comparing the results to a baseline modeling and actual air quality observations, it is found that nearby ozone urban/anthropogenic emission sources were contributing to a nighttime increase in mountaintop ozone levels due to a regional transport lag and residual layer effects. Positive correlation of measured O3 and CO concentrations suggested that O3 was associated with anthropogenic emissions. Sensitivity modeling experiments indicated that local anthropogenic emissions had little impact on the diurnal pattern of O3. The diurnal pattern of O3 was mainly influenced by regional O3 transport from the surrounding urban areas located 100–150km away from the summit, with a lag time of 10h for transport.

Diurnal variations of ground-level ozone in three port cities in Malaysia

The diurnal variations of ground-level ozone (O3) concentrations along a gradient of three major port cities (Klang, Perai, and Pasir Gudang) in Malaysia were evaluated. Annual monitoring records (2009) of O3, nitrogen dioxide (NO2), nitric oxide (NO), carbon monoxide (CO), sulfur dioxide (SO2), and particulate matter (PM10) were obtained. Weather-influencing parameters such as incoming solar radiation, temperature, relative humidity, and wind speed were also analyzed. Although an overwhelming majority (99.9 %) of the recorded data are below the prescribed levels in the Malaysian Ambient Air Quality Guidelines (MAAQG), a number of exceedances (0.1 %) (>100 ppb) have been recorded in Klang and Pasir Gudang. The annual hourly average concentrations of O3 were 20.3 ± 18.2, 15.4 ± 15.8, and 14.4 ± 13.1 ppb for Klang, Perai, and Pasir Gudang, respectively. The diurnal cycles of ground-level O3 concentrations and cluster analysis suggest that a unimodal peak occurs between 1 p.m. and 3 p.m., and the highest O3 concentrations were observed during the first quarter of 2009 as a result of the higher rate of local photochemical production. Results of principal component analysis showed that the contributions to O3 level variation by meteorological variables (UVB, temperature, relative humidity, and wind speed) are higher at 47.7, 39.5, and 18.2 % than those of primary air pollutants (NOx, CO, SO2, PM10) at 28.9, 32.6, and 45 % for Perai, Pasir Gudang, and Klang, respectively. The exposure of the population in the three port cities to the elevated levels of ozone during January–May months validated the increasing threat and risks that ozone presents to humans. Result indicated that the concentration of O3 in the three ports was still below the maximum permissible values prescribed by the MAAQG, and expansion in shipping industries is possible in exaggerating O3 problems especially in Klang.

Microwave ground-based measurements of ozone diurnal variations in the upper stratosphere over Kirgizia

Results of ground-based microwave measurements of diurnal variations of the ozone content in the stratosphere and mesosphere over Central Asia are given. The increase in ozone concentration at night at a height level of 50 km on 30–40% and at a height level of 60 km on 50–80% in comparison with day values is observed. At heights below 50 km, diurnal variations of ozone are not revealed within the measuring error. It is shown that interdaily changes of the night ozone content in the upper stratosphere and in the lower mesosphere take place. A comparison of the results of ground-based microwave sounding with the data of the MLS AURA orbital tool is given.

Microwave Ground-Based Measurements of Ozone Diurnal Variations in the Upper Stratosphere over Kirgizia

Microwave Ground-Based Measurements of Ozone Diurnal Variations in the Upper Stratosphere over Kirgizia

Reevaluation of stratospheric ozone trends from SAGE II data using a simultaneous temporal and spatial analysis

Abstract. This paper details a new method of regression for sparsely sampled data sets for use with time-series analysis, in particular the Stratospheric Aerosol and Gas Experiment (SAGE) II ozone data set. Non-uniform spatial, temporal, and diurnal sampling present in the data set result in biased values for the long-term trend if not accounted for. This new method is performed close to the native resolution of measurements and is a simultaneous temporal and spatial analysis that accounts for potential diurnal ozone variation. Results show biases, introduced by the way data are prepared for use with traditional methods, can be as high as 10%. Derived long-term changes show declines in ozone similar to other studies but very different trends in the presumed recovery period, with differences up to 2% per decade. The regression model allows for a variable turnaround time and reveals a hemispheric asymmetry in derived trends in the middle to upper stratosphere. Similar methodology is also applied to SAGE II aerosol optical depth data to create a new volcanic proxy that covers the SAGE II mission period. Ultimately this technique may be extensible towards the inclusion of multiple data sets without the need for homogenization.

Diurnal variations of stratospheric ozone measured by ground-based microwave remote sensing at the Mauna Loa NDACC site: measurement validation and GEOSCCM model comparison

Abstract. There is presently renewed interest in diurnal variations of stratospheric and mesospheric ozone for the purpose of supporting homogenization of records of various ozone measurements that are limited by the technique employed to being made at certain times of day. We have made such measurements for 19 years using a passive microwave remote sensing technique at the Mauna Loa Observatory (MLO) in Hawaii, which is a primary station in the Network for Detection of Atmospheric Composition Change (NDACC). We have recently reprocessed these data with hourly time resolution to study diurnal variations. We inspected differences between pairs of the ozone spectra (e.g., day and night) from which the ozone profiles are derived to determine the extent to which they may be contaminated by diurnally varying systematic instrumental or measurement effects. These are small, and we have reduced them further by selecting data that meet certain criteria that we established. We have calculated differences between profiles measured at different times: morning–night, afternoon–night, and morning–afternoon and have intercompared these with like profiles derived from the Aura Microwave Limb Sounder (Aura-MLS), the Upper Atmosphere Research Satellite Microwave Limb Sounder (UARS-MLS), the Superconducting Submillimeter-Wave Limb-Emission Sounder (SMILES), and Solar Backscatter Ultraviolet version 2 (SBUV/2) measurements. Differences between averages of coincident profiles are typically &lt; 1.5% of typical nighttime values over most of the covered altitude range with some exceptions. We calculated averages of ozone values for each hour from the Mauna Loa microwave data, and normalized these to the average for the first hour after midnight for comparison with corresponding values calculated with the Goddard Earth Observing System Chemistry Climate Model (GEOSCCM). We found that the measurements and model output mostly agree to better than 1.5% of the midnight value, with one noteworthy exception: The measured morning–night values are significantly (2–3 %) higher than the modeled ones from 3.2 to 1.8 hPa (~39–43 km), and there is evidence that the measured values are increasing compared to the modeled values before sunrise in this region.

A climatology of the diurnal variations in stratospheric and mesospheric ozone over Bern, Switzerland

Abstract. The ground-based radiometer GROMOS, stationed in Bern (47.95° N, 7.44° E), Switzerland, has a unique data set: it obtains ozone profiles from November 1994 to present with a time resolution of 30 min and equivalent quality during night- and daytime. Here, we derive a monthly climatology of the daily ozone cycle from 17 years of GROMOS observation. We present the diurnal ozone variation of the stratosphere and mesosphere. Characterizing the diurnal cycle of stratospheric ozone is important for correct trend estimates of the ozone layer derived from satellite observations. The diurnal ozone cycle from GROMOS is compared to two models: the Whole Atmosphere Community Climate Model (WACCM) and the Hamburg Model of Neutral and Ionized Atmosphere (HAMMONIA). Generally, observation and models show a good agreement: in the lower mesosphere, daytime ozone is for both GROMOS and models around 25% less than midnight ozone. In the stratosphere, ozone reaches its maximum in the afternoon showing values several percent larger than the midnight value. Further, GROMOS and models indicate a seasonal behaviour of the diurnal ozone variations in the stratosphere with a larger afternoon maximum during daytime in summer than in winter. Using the 17 years of ozone profiles from GROMOS, we find strong interannual variations in the diurnal ozone cycle for both the stratosphere and the mesosphere. Interannual variability in temperature, atmospheric circulation and composition may explain the observed interannual variability of the diurnal ozone cycle above Bern.

Spatial Patterns of Seasonal Level Diurnal Variations of Ozone and Respirable Suspended Particulates in Hong Kong

In this study we analyzed the diurnal spatial patterns of cycles of ozone (O3) and respirable suspended particulate (RSP) matter in Hong Kong between 2001 and 2011. We used harmonic analysis to reveal the diurnal cycle in the seasonal-level spatial patterns. The diurnal cycle of O3 is stronger in the northeast rural areas of Hong Kong than in the urban center due to the lower titration effects of nitric oxide in the rural areas. For RSP, the southern sections show the strongest diurnal cycle and the northeastern sections show the weakest diurnal cycle, which could be explained by the heavy vehicular traffic in the southern urban areas and light vehicular traffic in the northeast rural areas. The diurnal patterns of O3 and RSP both show stronger cycles in the summer months, which might be related to the diurnal rainfall pattern. The time of maximum for O3 is around 1400 Local Standard Time (LST) in the afternoon in summer, whereas a wider range in the time of maximum, between 1100 and 1400 LST, was observed in winter. The spatial pattern of the time of maximum for RSP showed a gradual progression from the center of the city to the west, between 1300 and 1700 LST, which is consistent with rush hour traffic.

Diurnal and Seasonal Variations of Surface Ozone and Its Precursors in the Atmosphere of Yanbu, Saudi Arabia

Surface ozone (O3) and its precursor’s gases (nitrogen monoxide (NO), nitrogen dioxide (NO2), nitrogen oxides (NOx), carbon monoxide (CO), methane (CH4) and non-methane hydrocarbons (NMHCs), and sulfur dioxide (SO2) were measured in Yanbu, Saudi Arabia from January 2004-December 2004. The annual average concentrations of O3, NO, NO2, NOx, SO2, CO, CH4, TNMHCs and THC were 22.51 ppb, 15.58 ppb, 17.25 ppb, 23.84 ppb, 6.66 ppb, 165.13 ppb, 3.44 ppm, 0.56 ppm and 3.88 ppm, respectively. The SO2/NOx and SO2/NO2 concentration ratios during the period of study indicate that the mobile emissions are the predominant sources in yanbu. The diurnal cycles of O3 concentrations revealed highest levels in the daytime and lowest levels in night time. The diurnal variations of NO, NO2, NOx, SO2, CO, NMHCs concentrations were similar and showed peaks concentrations linked to traffic density, boundary layer mixing processes and chemical processes in the atmosphere. The mean concentrations of O3 in different seasons follow the order of summer > spring > autumn > winter. In contrary to O3, NO has higher concentrations in autumn and winter than those in summer and spring seasons. The highest concentrations of NO2, NOx, SO2, CO, and TNMHCs were found in autumn and spring, whereas the lowest concentrations were found in summer and winter. THC and CH4 have no significant change over winter, autumn and summer seasons, while their concentrations decrease sharply in spring. Although the studied area does not suffer from NO2, O3, SO2 and CO pollution and no health risk, comprehensive and long-term air quality management programmes are needed in order to keep air quality in a good condition.

Seasonal heterogeneity in ozone and its precursors (NOx) by in-situ and model observations on semi-arid station in Anantapur (A.P), South India

The continuous measurements of surface ozone (O3) and oxides of nitrogen (NOx) present in the ambient air were carried out on a semi-arid rural area in Anantapur [14.62° N, 77.65° E], South India during the period beginning from March 2012 to February 2013. The diurnal variation of surface ozone (O3) showed a minimum at sun rise and late evenings and maximum at noon time, due to slow titration of O3 with oxides of nitrogen (NOx). The monthly average minimum/maximum of O3 observed in August/March was 19.9 ± 0.3/55.8 ± 2.9 ppbv. The monthly average variation of NOx was found to be high (6.67 ± 0.8) in November and noticed low (2.07 ± 0.2) concentrations in May. The monthly mean maximum of O3 during day time (night time) was observed as 64.9 ± 5.3 (45.3 ± 4.1) ppbv in March, and mean low concentration was about 19.9 ± 1.02 (12.8 ± 0.9) ppbv in August. The monthly mean enhanced concentration of NOx during the day time/night time was about 5.0 ± 0.6/8.7 ± 0.9 in November and the fallen concentration was noticed 1.5 ± 0.2/2.7 ± 0.3 in May. The spatial distribution of O3 was associated with the air flow pattern, air mass trajectories and boundary layer heights. The water vapor content also played a significant role in the diurnal variation of O3 in addition to photo chemistry. The diurnal variation of UV radiation with O3 and NOx has been analyzed and the results are reported. And the diurnal and seasonal variations in boundary layer height have also been discussed. The monthly mean variation of aerosol optical depth (AOD) is similar to that of tropospheric ozone, with a correlation coefficient of r = 0.60. The diurnal and seasonal patterns of ozone were simulated using the chemical box model (NCAR Mater Mechanism) and when compared with the observed ones, the results are found to be in good agreement with the observed ones.

Results of surface ozone monitoring in the atmosphere over Ulan-Ude

Presented are the results of surface ozone monitoring in the atmosphere over Ulan-Ude during the period from 2000 to 2012. Revealed are seasonal and diurnal variations of surface ozone. The analysis of the seasonal variability of surface ozone concentration indicates the presence of the clearly pronounced maximum in spring-summer period. A statistical model of forecasting single concentrations of the surface ozone is considered using the multiple regression analysis. Temperature, relative humidity, wind direction, wind speed, turbulence factor, temperature gradient, velocity of vertical flow, and concentrations of minor gas admixtures such as nitrogen oxides are used as predictors. Analyzed are statistical relationships, where observed ozone values are presented in the form of the regression function of the most significant predictors.

Combined SAGE II–GOMOS ozone profile data set for 1984–2011 and trend analysis of the vertical distribution of ozone

Abstract. We have studied data from two satellite occultation instruments in order to generate a high vertical resolution homogeneous ozone time series of 26 yr. The Stratospheric Aerosol and Gas Experiment (SAGE) II solar occultation instrument and the Global Ozone Monitoring by Occultation of Stars (GOMOS) instrument measured ozone profiles in the stratosphere and mesosphere from 1984–2005 and 2002–2012, respectively. Global coverage, good vertical resolution, and the self-calibrating measurement method make data from these instruments valuable for the detection of changes in vertical distribution of ozone over time. As both instruments share a common measurement period from 2002–2005, it is possible to inter-calibrate the data sets. We investigate how well these measurements agree with each other and combine all the data to produce a new stratospheric ozone profile data set. Above 55 km, SAGE II measurements show much less ozone than the GOMOS nighttime measurements as a consequence of the well-known diurnal variation of ozone in the mesosphere. Between 35–55 km, SAGE II sunrise and sunset measurements differ from GOMOS' measurements to different extents. Sunrise measurements show 2% less ozone than GOMOS, whereas sunset measurements show 4% more ozone than GOMOS. Differences can be explained qualitatively by the diurnal variation of ozone in the stratosphere recently observed by SMILES and modeled by chemical transport models. Between 25–35 km, SAGE II sunrise and sunset measurements and GOMOS measurements agree within 1%. The observed ozone bias between collocated measurements of SAGE II sunrise/sunset and GOMOS night measurements is used to align the two data sets. The combined data set covers the time period 1984–2011, latitudes 60° S–60° N, and the altitude range of 20–60 km. Profile data are given on a 1 km vertical grid, and with a resolution of 1 month in time and 10° in latitude. The combined ozone data set is analyzed by fitting a time series model to the data. We assume a linear trend with an inflection point (so-called "hockey stick" form). The best estimate for the point of inflection was found to be the year 1997 for ozone between altitudes 35 and 45 km. At all latitudes and altitudes from 35 to 50 km we find a clear change in ozone trend before and after the inflection time. From 38 to 45 km, a negative trend of 4% per decade (statistically significant at 95% level) at the equator has changed to a small positive trend of 0–2% per decade. At mid-latitudes, the negative trend of 4–8% per decade has changed to to a small positive trend of 0–2% per decade. At mid-latitudes near 20 km, the ozone loss has still increased whereas in the tropics a recovery is ongoing.

Characterization of Odin-OSIRIS ozone profiles with the SAGE II dataset

Abstract. The Optical Spectrograph and InfraRed Imaging System (OSIRIS) on board the Odin spacecraft has been taking limb-scattered measurements of ozone number density profiles from 2001–present. The Stratospheric Aerosol and Gas Experiment II (SAGE II) took solar occultation measurements of ozone number densities from 1984–2005 and has been used in many studies of long-term ozone trends. We present the characterization of OSIRIS SaskMART v5.0× against the new SAGE II v7.00 ozone profiles for 2001–2005, the period over which these two missions had overlap. This information can be used to merge OSIRIS with SAGE II into a single ozone record from 1984 to the present, if other satellite ozone measurements are included to account for gaps in the OSIRIS dataset in the winter hemisphere. Coincident measurement pairs were selected for ±1 h, ±1° latitude, and ±500 km. The absolute value of the resulting mean relative difference profile is &lt;5% for 13.5–54.5 km and &lt;3% for 24.5–53.5 km. Correlation coefficients R &gt; 0.9 were calculated for 13.5–49.5 km, demonstrating excellent overall agreement between the two datasets. Coincidence criteria were relaxed to maximize the number of measurement pairs and the conditions under which measurements were taken. With the broad coincidence criteria, good agreement (&lt; 5%) was observed under most conditions for 20.5–40.5 km. However, mean relative differences do exceed 5% for several cases. Above 50 km, differences between OSIRIS and SAGE II are partly attributed to the diurnal variation of ozone. OSIRIS data are biased high compared with SAGE II at 22.5 km, particularly at high latitudes. Dynamical coincidence criteria, using derived meteorological products, were also tested and yielded similar overall results, with slight improvements to the correlation at high latitudes. The OSIRIS optics temperature is low (&lt;16 °C) during May–July, when the satellite enters the Earth's shadow for part of its orbit. During this period, OSIRIS measurements are biased low by 5–12% for 27.5–38.5 km. Biases between OSIRIS ascending node (northward equatorial crossing time ~18:00 LT – local time) and descending node (southward equatorial crossing time ~06:00 LT) measurements are also noted under some conditions. This work demonstrates that OSIRIS and SAGE II have excellent overall agreement and characterizes the biases between these datasets.

Diurnal ozone variations in the stratosphere revealed in observations from the Superconducting Submillimeter‐Wave Limb‐Emission Sounder (SMILES) on board the International Space Station (ISS)

AbstractConsiderable uncertainties remain in the global pattern of diurnal variation in stratospheric ozone, particularly lower to middle stratospheric ozone, which is the principal contributor to total column ozone. The Superconducting Submillimeter‐Wave Limb‐Emission Sounder (SMILES) attached to the Japanese Experiment Module (JEM) on board the International Space Station (ISS) was developed to gather high‐quality global measurements of stratospheric ozone at various local times, with the aid of superconducting mixers cooled to 4K by a compact mechanical cooler. Using the SMILES dataset, as well as data from nudged chemistry‐climate models (MIROC3.2‐CTM and SD‐WACCM), we show that the SMILES observational data have revealed the global pattern of diurnal ozone variations throughout the stratosphere. We also found that these variations can be explained by both photochemistry and dynamics. The peak‐to‐peak difference in the stratospheric ozone mixing ratio (total column ozone) reached 8% (1%) over the course of a day. This variation needs to be considered when merging ozone data from different satellite measurements and even from measurements made using one specific instrument at different local times.