Distinct Layers Research Articles

Unveiling the potential of lead-free Cs2AgBi0.75Sb0.25Br6 double perovskite solar cells with multilayer charge transport for 30% efficiency

The present study delves into the utilization of computer modeling techniques to analyze a photovoltaic (PV) design incorporating a lead (Pb)-free perovskite absorber material. This innovative structure employs a cesium-based double perovskite material, specifically Cs2AgBi0.75Sb0.25Br6, characterized by an energy bandgap of 1.80 eV. The Cs2AgBi0.75Sb0.25Br6 exhibits a range of advantageous properties, including heightened stability in ambient conditions and appropriately aligned bandgaps. Given these considerations, an extensive exploration of the FTO/CdS/Cs2AgBi0.75Sb0.25Br6 /HTL/Au configuration was undertaken to assess the impact of ten distinct hole transport layers (HTLs) on the solar cell's efficiency. The simulation and analysis of all devices were conducted employing the one-dimensional SCAPS-1D (Solar Cell Capacitance Simulator) tool. Furthermore, the efficiency of the FTO/ETL/Cs2AgBi0.75Sb0.25Br6 /MoO3/Au architecture was probed, employing six different electron transport layers (ETLs) (BaSnO3, PC61BM, SnS2, Ti2O3:Nb, CdS, ZnOS), to discern the optimal combination. Post-optimization, adjustments were made to the absorber and ETL thickness, as well as the acceptor doping and defect density of the absorber, and the donor and defect density of the ETL, for the six combinations assessed. These topologies were also examined for their impacts on series and shunt resistance, capacitance, the Mott-Schottky effect, generation and recombination processes, current–voltage density, and quantum efficiency. Eventually, the most efficient cell in this study achieved a power conversion efficiency (PCE) of 30.30 % and featured the FTO/ZnOS/Cs2AgBi0.75Sb0.25Br6/MoO3/Au configuration. The aforementioned findings hold significant potential for advancing lead-free, double perovskite solar cells (PSCs) that are both more efficient and environmentally sustainable, paving the way for their widespread adoption in the future.

Controls on Deep and Shallow Gas Hydrate Reservoirs in the Dongsha Area, South China Sea: Evidence from Sediment Properties

The Dongsha area, a key region in the northern South China Sea (SCS), features both diffusive deep and seepage shallow gas hydrate reservoirs. Utilizing sediment samples from gas hydrate reservoirs and adjacent layers at sites W08 and W16 in the Dongsha area, this study aims to uncover the sediment property differences between deep and shallow gas hydrate reservoirs and their impact on gas hydrate accumulation through grain size, X-ray diffraction, and specific surface area (SSA) analyses. The findings classify the study intervals into four distinct layers: shallow non-gas hydrate layer (shallow-NGHL), shallow gas hydrate reservoir (shallow-GHR), deep non-gas hydrate layer (deep-NGHL), and deep gas hydrate reservoir (deep-GHR). In the clayey silt sediment reservoirs, grain size has a minor influence on gas hydrate reservoirs. Both shallow and deep NGHLs, characterized by high smectite content and SSA, possess a complex structure that impedes gas and fluid migration and offers limited potential reservoir space. Consequently, both shallow and deep NGHLs function as sealing beds. The deep GHR, having low smectite content and SSA, exhibits a strong capacity for gas and fluid migration and greater potential reservoir space. As a result, sediment properties significantly influence the deep GHR. Seepage primarily controls the shallow GHR.

Ice chemistry modeling of active phase comets: Hale–Bopp

We present a chemical kinetics model of the solid-phase chemical evolution of a comet, beginning with a long period of cold-storage in the Oort Cloud, followed by five orbits that bring the comet close to the Sun. Current orbital parameters for Hale–Bopp are used for all orbits. The chemical model is based on an earlier treatment (Garrod 2019) that considered only the cold-storage phase, and which was based on the interstellar ice chemical kinetics model MAGICKAL. The comet is treated as 25 chemically distinct layers, whose thicknesses increase with depth; each layer has a dust component, and the chemical network includes a further 200 atomic/molecular species. The new model includes several key updates to the previous treatment: (i) Time- and depth-dependent temperature profiles based on heat transfer according to heliocentric distance; (ii) a rigorous treatment of back-diffusion (random walk) for species capable of diffusing through the thick bulk-ice layers; (iii) adoption of recent improvements in the kinetic treatment of nondiffusive chemical reaction rates in the ice and on the ice surface. Starting from an initially simple ice composition, interstellar UV photons drive a rapid chemistry in the upper micron of material, but diminished by absorption of the UV by the dust component. Galactic cosmic rays (GCRs) drive a much slower chemistry in the deeper ices over the long cold-storage period, to depths on the order of 10 m. The first solar approach drives off the upper layers of ice material via thermal desorption and/or dissociation (the model does not include a treatment for the more complex cometary outbursts), bringing closer to the surface the deeper material that previously underwent long-term processing by GCRs. Subsequent orbits are more uniform in their chemical behavior after the upper layers are lost. Loss of molecular material leads to concentration of the dust in the upper layers, with a large dust fraction extending to depths on the order of 10 cm after all orbits are complete. Substantial quantities of complex organic molecules (COMs) are formed in the upper 10 m during the cold storage phase, with some of this material released during solar approach; however, their abundances with respect to water appear too low to account for the observed gas-phase values for comet Hale–Bopp, indicating that the majority of complex molecular material observed, at least in comet Hale–Bopp, is an inheritance of primordial material.

Determination of the geophysical signature of soft-clay and hard lateritic soils and the implications on geotechnical works using electrical resistivity imaging

Understanding the geophysical signature of subsurface is quite essential in mapping site conditions for geotechnical engineering and simulating geophysical surveys, especially in coastal areas. This article presents a comparative geophysical study of topsoil (often refer as engineering layer) of soft clay deposit and hard lateritic soil to evaluate the implications on geotechnical work using electrical resistivity imaging (ERI). The results of the 2D ERI show that the hard lateritic soil produces three distinctive geological layers with the topsoil having high apparent electrical resistivity (AER) values varying between 300 Ωm–1000 Ωm and a thickness between 2.0 m – 10.0 m. The layer between the unsaturated and saturated regions has a moderate layer AER and thickness values ranging from 100 Ωm–300 Ωm and 2.5 m–9.5 m, respectively. In contrast, the saturated (weathered) layer has a low AER value (< 100Ω m), which represents the regional groundwater unit, located beneath the subsurface of a depth > 6.0 m. However, the soft clay soil shows no distinctive subsurface layers, as it is characterized by a nearly homogeneity subsurface of poor AER variability. The top-soft clay deposit has very AER values ranging from 11.0 Ωm–80 Ωm, which extends beyond 6.5 m. Higher and lower AER values noted within the overburdened topsoil of lateritic and clay extractions, respectively, were due to the accumulations of compacted clay and lateritic soil, which are very essential for geotechnical works. In addition, the geophysical signal was conspicuously attenuated in soft clay soil, which shows that soft clay soil is not a favourite target of geophysical investigation. However, the geophysical signals in hard lateritic generate a fine geo-electrical layer pattern. It was also noted that the existence of soft clay and lateritic soil decreases with depth. This kind of information is very essential in geotechnical works.

Developmental, Physiological and Phylogenetic Perspectives on the Expression and Regulation of Myosin Heavy Chains in Craniofacial Muscles.

This review deals with the developmental origins of extraocular, jaw and laryngeal muscles, the expression, regulation and functional significance of sarcomeric myosin heavy chains (MyHCs) that they express and changes in MyHC expression during phylogeny. Myogenic progenitors from the mesoderm in the prechordal plate and branchial arches specify craniofacial muscle allotypes with different repertoires for MyHC expression. To cope with very complex eye movements, extraocular muscles (EOMs) express 11 MyHCs, ranging from the superfast extraocular MyHC to the slowest, non-muscle MyHC IIB (nmMyH IIB). They have distinct global and orbital layers, singly- and multiply-innervated fibres, longitudinal MyHC variations, and palisade endings that mediate axon reflexes. Jaw-closing muscles express the high-force masticatory MyHC and cardiac or limb MyHCs depending on the appropriateness for the acquisition and mastication of food. Laryngeal muscles express extraocular and limb muscle MyHCs but shift toward expressing slower MyHCs in large animals. During postnatal development, MyHC expression of craniofacial muscles is subject to neural and hormonal modulation. The primary and secondary myotubes of developing EOMs are postulated to induce, via different retrogradely transported neurotrophins, the rich diversity of neural impulse patterns that regulate the specific MyHCs that they express. Thyroid hormone shifts MyHC 2A toward 2B in jaw muscles, laryngeal muscles and possibly extraocular muscles. This review highlights the fact that the pattern of myosin expression in mammalian craniofacial muscles is principally influenced by the complex interplay of cell lineages, neural impulse patterns, thyroid and other hormones, functional demands and body mass. In these respects, craniofacial muscles are similar to limb muscles, but they differ radically in the types of cell lineage and the nature of their functional demands.

New Life in the Countryside: Conservation and Sustainability of Vernacular Architectural Facade Characteristics in the Jiangnan Region, China

The facade form of vernacular architecture is an outward manifestation of the building structure, which can easily give people an intuitive impression of the building. Most of the existing studies focus on analyzing the construction process and building materials of vernacular architecture in detail, but there are few studies on the characteristic elements in the form of architectural facades. The main objective of this study is to propose a new methodology for objectively analyzing the morphological characteristics of architectural facades with complex networks to support the sustainable development of vernacular architecture. The results of the study show that the vernacular architectural facades in the Jiangnan region are characterized by the richness of details and distinctive layers and that the formal elements that can show the regional characteristics are preserved in the process of the sustainable development of vernacular architecture. The most crucial part of this is the roof shape, followed by the simplification of the detailing and how the vertical form elements are laid out horizontally. The article addresses the protection and continuity of vernacular architectural facade characteristics and proposes a strategic plan to strengthen the vernacular architectural facade characteristics in the Jiangnan region, aiming to protect the traditional characteristics and continue the traditional culture.

Ten-moment fluid model with heat flux closure for gasdynamic flows

The gasdynamic 10-moment equations are revisited, applying a Chapman-Enskog type expansion to achieve the closure for heat flux. The resulting gradient-based closure performs favorably against previously employed closures in regions of shocks when compared to the kinetic results obtained from Direct Simulation Monte Carlo simulations. The 10-moment model can capture finite kinetic effects due to non-Maxwellian velocity distribution functions, as compared to the 5-moment Navier-Stokes equations, and remains hyperbolic-parabolic with real wave speeds under all initial conditions. Self-consistent kinetic boundary conditions are derived without consideration of a distinct Knudsen layer. The model is applied to a number of canonical gasdynamics problems in one and two dimensions such as steady normal and oblique shocks, as well as the Sod shock tube problem.

Deciphering layer formation in Red Heart Qu: A comprehensive study of metabolite profile and microbial community influenced by raw materials and environmental factors

Environmental-origin microbiota significantly influences Red Heart Qu (RH_Qu) stratification, but their microbial migration and metabolic mechanisms remain unclear. Using high-throughput sequencing and metabolomics, we divided the stratification of RH_Qu into three temperature-based stages. Phase I features rising temperatures, causing microbial proliferation and a two-layer division. Phase II, characterized by peak temperatures, sees the establishment of thermotolerant species like Bacillus, Thermoactinomyces, Rhodococcus, and Thermoascus, forming four distinct layers and markedly altering metabolite profiles. The Huo Quan (HQ), developing from the Pi Zhang (PZ), is driven by the tyrosine-melanin pathway and increased MRPs (Maillard reaction products). The Hong Xin evolves from the Rang, associated with the phenylalanine-coumarin pathway and QCs (Quinone Compounds) production. Phase III involves the stabilization of the microbial and metabolic profile as temperatures decline. These findings enhance our understanding of RH_Qu stratification and offer guidance for quality control in its fermentation process.

Isolated left ventricular non-compaction cardiomyopathy: case report and brief review on diagnostic imaging methods

Left ventricular non-compaction cardiomyopathy (LVNC) is a rare congenital heart disease with an estimated incidence of 0.014-0.045% in a general population. It occurs due to a morphogenetic abnormality during embryogenesis that inhibits myocardial compaction and determines prominent trabeculae with deep intertrabecular spaces and thickening of the adjacent myocardium in two distinct layers. Diagnosis is generally established via transthoracic echocardiogram (TTE) with further confirmation with cardiac magnetic resonance (CMR). A 57-year-old male patient previously diagnosed with systemic arterial hypertension and chronic obstructive pulmonary disease reported chest pain and dyspnea upon exertion, headache, and dizziness. During outpatient investigation, the patient was submitted to a stress electrocardiogram that was positive for ischemia and led to a cineangiocoronariography with no signs of coronary artery obstruction. At the echocardiography lab, several trabeculations were detected in the apical region of the left ventricle. A diagnosis of LVNC was established and the results were confirmed via CMR. Management was initiated with the goal of symptom relief. LVNC is a relatively unknown pathology that is frequently underdiagnosed at earlier stages. As presented, we highlight the importance of multimodality imaging, especially TTE and CMR, in the diagnosis of this congenital heart condition.

Alloying on the high-temperature oxidation behavior of Nb-Ti-Si-based alloy additively manufactured by laser directed energy deposition

Nb-Si-based alloys have important application prospects in the new generation of high-thrust-to-weight ratio aero-engines hot-end components. Understanding how alloying affects the microstructure and oxidation resistance of Nb-Si-based alloys is crucial for their applications. In this work, the effects of Zr, Cr and Mo on the microstructure and high-temperature oxidation resistance of Nb-23Ti-14Si-based alloys prepared by laser directed energy deposition (LDED) were investigated. Results showed that the oxidation resistance at 1250 °C of as-deposited Nb-23Ti-14Si-based alloys enhanced by Zr, Cr and Mo alloying, of these, Cr is the most significant, followed by Zr and Mo. The oxide film of Nb-23Ti-14Si-based alloys have three distinct oxide layer: the inner, middle, and outer oxide layer. The formation of SiO2 layer in the Nb-23Ti-14Si-based alloys' outer oxide layer when Zr and Cr alloying, respectively. Furthermore, following oxidation at 1250 °C for 20 h, and the weight gain per unit area is around 32.52 mg/cm2, and the creation of CrNbO4 layer when Cr content is up to 10 at.%.

Reversible Constrained Dissociation and Reassembly of MXene Films.

Enabling materials to undergo reversible dynamic transformations akin to the behaviors of living organisms represents a critical challenge in the field of material assembly. The pursuit of such capabilities using conventional materials has largely been met with limited success. Herein, the discovery of reversible constrained dissociation and reconfiguration in MXene films, offering an effective solution to overcome this obstacle is reported. Specifically, MXene films permit rapid intercalation of water molecules between their distinctive layers, resulting in a significant expansion and exhibiting confined dissociation within constrained spaces. Meanwhile, the process of capillary compression driven by water evaporation reinstates the dissociated MXene film to its original compact state. Further, the adhesive properties emerging from the confined disassociation of MXene films can spontaneously induce fusion between separate films. Utilizing this attribute, complex structures of MXene films can be effortlessly foamed and interlayer porosity precisely controlled, using only water as the inducer. Additionally, a parallel phenomenon has been identified in graphene oxide films. This work not only provides fresh insights into the microscopic mechanisms of 2D materials such as MXene but also paves a transformative path for their macroscopic assembly applications in the future.

Mathematical modelling for groundwater management for multilayers aquifers (Erbil basin)

This study addresses the pressing issues of groundwater depletion and drought problems in the Erbil basin, a vital resource region in the Middle East. Focused on an area of strategic importance due to its large size and critical water resources, the study employs the Groundwater Modeling System (GMS) software to create a detailed 3D hydrogeological model based on extensive borehole data. With over 240 boreholes analyzed, the study strategically selects 70 accurate wells drilled by the Groundwater Directorate. The construction of the 3D stratigraphic models for the Erbil basin relies on three main historical data including boreholes, geological formations and a comprehensive approach, incorporating deep well logging data and the definition of distinct geological layers. By discerning the presence of previous and impervious layers, the model effectively categorizes the aquifer types within the Erbil basin. The aquifer system is delineated based on stratigraphic units, designating materials with high conductivity (silt, sand, and gravel) as aquifers and clay (or claystone) as aquitards. A 3D steady-state groundwater flow model is successfully executed, employing PEST pilot point for automated parameter estimation. The model, validated with a coefficient of determination (R2) of 0.9998, reveals hydraulic conductivity values ranging from 0.000980705 to 100 m/day and a recharge value of 0.000976443 m/day. The study classifies Erbil's aquifer types as unconfined, confined, and semi-confined, providing a valuable foundation for groundwater management. The primary objective of this study is to construct a calibrated numerical groundwater model for the multi-aquifer system in the Erbil basin. The model aims to serve as a robust tool for analyzing the sustainability of diverse groundwater infrastructure development strategies within the region. The Erbil basin poses unique challenges for groundwater modeling, marked by a scarcity of critical data such as monitoring well information, pumping rates, recharge rates, and flow budgets. In response to these limitations, the study adopts an innovative approach by integrating in situ data with earth observation data. The integration of these datasets seeks to overcome data constraints and enhance the accuracy of the groundwater model. By achieving calibration and validation of the numerical model, this research strives to provide a valuable resource for decision-makers, planners, and stakeholders involved in groundwater management in the Erbil basin. Ultimately, the study aims to contribute to the development of sustainable and effective strategies for the utilization and preservation of groundwater resources in this vital region and also to enhance practical management strategies for the Erbil groundwater basin, ensuring sustainable utilization of the crucial sub-surface water resources, an objective successfully achieved through this research.

Theoretical analysis and numerical study of natural convection inside combined solar chimney

AbstractSolar chimneys may induce natural ventilation through solar radiation. However, sufficient theoretical studies are needed as a basis to fully exploit passive design in practical green building design. In this work, we investigate the heat transfer properties of turbulent natural convective flows in a combined solar chimney with a thermal flux at the absorption wall by means of theoretical analysis and numerical simulations. Two different flow patterns have been found, one with a clear thermal boundary layer flow pattern and the other without, based on high Rayleigh numbers. For flow development in these two flow regimes, the transient scaling analysis is performed separately and the control mechanism for each phase is presented. Some new scale relationships are established to characterize the ventilation performance of solar chimneys, including thermal boundary layer thickness δT, velocity vT, mass flow m, and so on. For the distinct thermal boundary layers, δT,s ~ HΓ2/5/Bo1/5κ2/5, vT,s ~ Bo2/5κ4/5Γ1/5/H, m ~ ρBo1/5κ2/5Γ3/5. For nonobvious thermal boundary layers, vT,f ~ Bo1/3κ/H2/3W1/3, m ~ ρBo1/3κ/A2/3. The important scale relationships are validated using corresponding numerical simulation data, such as the mass flow rate scale M ~ (Γ/κ)3/5Bo1/5 in the distinct thermal boundary layer flow state, and so on. The air changes per hour and heat exchange efficiencies are calculated for a solar chimney with a fixed height‐to‐width ratio to provide a basis for the design of a solar chimney.

Prenatal and postnatal development of New Zealand white rabbit (Oryctolagus cuniculus) teeth: histological and computed tomography aspects

The study reveals a lack of histomorphogenesis in New Zealand white rabbit teeth. The teeth development was examined through sequential histological segments in 24 rabbits from prenatal ages (E19, E21, E23, E25, and E28), neonates (E30), and postnatal age (1 week and 2 weeks); (three animal specimens at each age stage). Rabbit teeth first appeared at 19 days of prenatal life (E19) as an ectodermal epithelial thickening on each side of the mouth opening. At E21, the bud of upper incisor tooth appeared as an epithelial bud, which composed of many condensed epithelium cells, was simply identified from the larger with less condensed vestibular lamina, and was surrounded by mesenchymal connective tissue while the lower incisor took the cap stage. At (E23), tooth regular construction is formed from enamel, dentine, and pulp cavity. Peg incisor appearance (supplementary and assistant incisors) is visible at the lingual surface of the upper major incisor. Teeth prenatal development went through successive stages like initiation, bud, cap, late bell, maturation, and crown stages. The first initiation phase of tooth formation was seen as ectodermal epithelial cell collection at (E19). Bud stage saw on upper incisor tooth, while in cap structure in lower incisor teeth at (E19). A cap-formed tooth is composed of the enamel organ and fundamentally dense mesenchymal tissue. Enamel organs are segmented into three distinct layers: the external tooth enamel epithelial, the internal tooth enamel epithelial, and finally the stellate reticular layer. The cement layer covered teeth all around on enamel on both the labial and lingual sides while not contacting the dentine on the lateral side, forming enamel space. Teeth develop consistently all through life; they have expanded enamel thickness; they are diphyodont teeth; they have two continuous dentitions; they are deciduous and perpetual, with long crown teeth and an open root.

Ultra-high strength metal matrix composites (MMCs) with extended ductility manufactured by size-controlled powder and spherical cast tungsten carbide

The main challenge of particle reinforced metal matrix composites (MMCs) is balancing strength and ductility. This research uses type 420 stainless steel and spherical cast tungsten carbide (WC/W2C) with a similar powder size and range as raw powders to manufacture laser powder bed fusion (LPBF) 420 + 5 wt% WC/W2C MMCs. LPBF 420 + 5 wt% WC/W2C MMCs contain austenite, martensite, and W-rich carbides (WC/W2C, FeW3C, M6C, and M7C3) from nanometre to micrometre scale. The well-balanced composition creates a crack-free reaction layer between the reinforced particles and matrix. This reaction layer consists of two distinct layers, depending on the element concentration. The LPBF 420 + 5 wt% WC/W2C MMCs achieved an excellent compressive strength of ∼5.5 GPa and a considerable fracture strain exceeding 50 %. The underlying mechanisms for the improved mechanical properties are discussed, providing further insight to advance the application of MMCs via additive manufacturing.

Steroids-producing nodules: a two-layered adrenocortical nodular structure as a precursor lesion of cortisol-producing adenoma

The human adrenal cortex consists of three functionally and structurally distinct layers; zona glomerulosa, zona fasciculata (zF), and zona reticularis (zR), and produces adrenal steroid hormones in a layer-specific manner; aldosterone, cortisol, and adrenal androgens, respectively. Cortisol-producing adenomas (CPAs) occur mostly as a result of somatic mutations associated with the protein kinase A pathway. However, how CPAs develop after adrenocortical cells acquire genetic mutations, remains poorly understood. We conducted integrated approaches combining the detailed histopathologic studies with genetic, RNA-sequencing, and spatially resolved transcriptome (SRT) analyses for the adrenal cortices adjacent to human adrenocortical tumours. Histopathological analysis revealed an adrenocortical nodular structure that exhibits the two-layered zF- and zR-like structure. The nodular structures harbour GNAS somatic mutations, known as a driver mutation of CPAs, and confer cell proliferative and autonomous steroidogenic capacities, which we termed steroids-producing nodules (SPNs). RNA-sequencing coupled with SRT analysis suggests that the expansion of the zF-like structure contributes to the formation of CPAs, whereas the zR-like structure is characterised by a macrophage-mediated immune response. We postulate that CPAs arise from a precursor lesion, SPNs, where two distinct cell populations might contribute differently to adrenocortical tumorigenesis. Our data also provide clues to the molecular mechanisms underlying the layered structures of human adrenocortical tissues. KAKENHI, The Uehara Memorial Foundation, Daiwa Securities Health Foundation, Kaibara Morikazu Medical Science Promotion Foundation, Secom Science and Technology Foundation, ONO Medical Research Foundation, and Japan Foundation for Applied Enzymology.

P53 rapidly restructures 3D chromatin organization to trigger a transcriptional response

Activation of the p53 tumor suppressor triggers a transcriptional program to control cellular response to stress. However, the molecular mechanisms by which p53 controls gene transcription are not completely understood. Here, we uncover the critical role of spatio-temporal genome architecture in this process. We demonstrate that p53 drives direct and indirect changes in genome compartments, topologically associating domains, and DNA loops prior to one hour of its activation, which escort the p53 transcriptional program. Focusing on p53-bound enhancers, we report 340 genes directly regulated by p53 over a median distance of 116 kb, with 74% of these genes not previously identified. Finally, we showcase that p53 controls transcription of distal genes through newly formed and pre-existing enhancer-promoter loops in a cohesin dependent manner. Collectively, our findings demonstrate a previously unappreciated architectural role of p53 as regulator at distinct topological layers and provide a reliable set of new p53 direct target genes that may help designs of cancer therapies.

Groundwater Exploration using Geoelectric Technique in Oru-Ijebu, South-West Nigeria

Forty Vertical Electrical Soundings (VES) were carried out using Allied Ohmega resistivity meter with schlumberger configuration in parts of Oru-Ijebu to determine the necessary geoelectrical parameters for delineating the aquiferous zones. Four to five distinct geoelectric layers were delineated from the survey area except for VESORU21 which exhibited six geoelectric layers namely the top soil, clayey sand/laterite, clay and granite gneiss. The first layer serves as the topsoil with high variable resistivity ranging from 11.2Ωm (VESORU7) to 153.8Ωm (VESORU25) with their corresponding thickness of 0.9m to 3.8m respectively. The thickness of the entire top soil of the investigated area ranges from 0.4m to 3.8m. The second layer is composed of sand, clay sand, laterite and partly sandy clay. The resistivity of clay/clayey sand overburden varying from 16.2Ωm with a thickness of 8.7m in VESORU17 and 484.3Ωm with a thickness of 3m VESORU6. The highest resistivity exhibited by the second layer is 974 Ωm in VESORU30 while its lowest resistivity is 21.9Ωm in VESORU34. The resistivity of the third layer which stands as a weathered lithology ranges from 17.2Ωm with a thickness of 10.3m at VESORU7 to 233.2Ωm at VESORU23 whose thickness is indeterminate due to current termination in the field to 196 Ωm; typically diagnostic of clay/clayey sand horizon except beneath VESORU1, VESORU2, VESORU11, VESORU30, VESORU32, VESORU34, and VESORU36 where the inferred lithology is sandstone, fresh basement and partly sandy-clay. The fourth and fifth layers are composed of fresh basement formation notably granite-gneiss rocks with resistivity values ranging from 88.5Ωm VESORU20 to 384Ωm in VESORU15. The maximum aquifer thickness is encountered beneath VESORU25. The weathered layer for the study area is thick enough for groundwater accumulation making it a very prolific one. VESORU1, VESORU2 and VESORU23 are marked by a low groundwater yield due to the dip and the thickness.

Synergistic Effects of Carbon Vacancies in Conjunction with Phosphorus Dopant across Bilayer Graphene for the Enhanced Hydrogen Evolution Reaction.

Bilayer graphene (BLG) exhibits distinct physical properties under external influences, such as torsion and structural defects, setting it apart from monolayer graphene. In this study, we explore the synergistic effects of carbon vacancies, in conjunction with phosphorus dopants, across BLG, focusing on their impact on structural, magnetic, electrical, and hydrogen adsorption properties. Our findings reveal that the substitutional doping of a phosphorus atom into a single carbon vacancy in a graphene layer induces substantial structural distortion in BLG. In contrast, doping phosphorus into a double vacancy maintains the flat structure of graphene layers. These distinct layer structures affect the electron distribution and spin arrangement, leading to varied electronic configurations and intriguing magnetic behaviors. Furthermore, the presence of abundant unsaturated electrons around the vacancy promotes the capture and bonding of hydrogen atoms. Hydrogen adsorption on BLG results in substantial orbital hybridization, accompanied by significant charge transfer. The calculated Gibbs free energies for hydrogen adsorption on BLG range from -0.08 to 0.09 eV, indicating exceptional catalytic activity for the hydrogen evolution reaction. These findings carry implications for optimizing the properties of graphene layers, making them highly desirable for applications such as catalysis.

Graph convolutional collaborative filtering recommendation method based on temporal information during node aggregation process

Graph Convolutional Networks (GCN) are prevalent techniques in collaborative filtering recommendations. However, current GCN-based approaches for collaborative filtering recommendation have limitations in effectively embedding neighboring nodes during node and neighbor information aggregation. Furthermore, weight allocation for the user (or item) representations after convolution of each layer is too uniform. To resolve these limitations, we propose a new Graph Convolutional Collaborative Filtering recommendation method based on temporal information during the node aggregation process (TA-GCCF). The method aggregates and propagates information using Gated Recurrent Units, while dynamically updating features based on the timing and sequence of interactions between nodes and their neighbors. Concurrently, we have developed a convolution attention coefficient to ascertain the significance of embedding at distinct layers. Experiments on three benchmark datasets show that our method significantly outperforms the comparison methods in the accuracy of prediction.