Dissolved Organic Carbon Removal Research Articles

Valorization of Cherry By-Products as Coagulant/Flocculants Combined with Bentonite Clay for Olive Mill Wastewater Treatment

In this study, two by-products resulting from the processing of cherry (stems and pits) were used as natural coagulants to promote the valorization of these wastes and treat olive mill wastewater (OMW). The efficacy of the plant-based coagulants (PBCs) in the coagulation–flocculation–decantation process (CFD) was evaluated through the removal of turbidity, total suspended solids (TSS), total polyphenols (TPh), and dissolved organic carbon (DOC). The CFD process was demonstrated to be effective in turbidity and TSS reduction in OMW. Using cherry stems (CSs), these reductions were 65.2% of turbidity and 58.0% of TSS, while cherry pits (CPs) achieved higher reductions, 78.6% of turbidity and 68.2% of TSS. To improve the effectiveness of OMW treatment, mainly regarding the removal of TPh and DOC, the CFD process was complemented with the adsorption process (using bentonite clay). The adsorption capacity of bentonite was higher in acidic conditions (pH 3.0) and, with a dosage of 3.0 g L−1, reached 17.3 mg of DOC and 13.8 mg of TPh per gram of bentonite. Several adsorption isothermal models were assessed, and the Langmuir (r2 = 0.985), SIPS (r2 = 0.992), and Jovanovic models (r2 = 0.994) provided the best fittings. According to the optimal operational conditions defined throughout the present work, the combination of CFD and adsorption removals were as follows: (1) 98.0 and 91.3% of turbidity, (2) 80.8 and 81.2% of TSS, (3) 98.1 and 97.6% of TPh and (4) 57.9 and 62.2% of DOC, for CSs and CPs, correspondingly. Overall, the results suggest that cherry by-products can be used as low-cost natural coagulants and, when combined with another natural, abundant, and cheap material, such as bentonite clay, can be a sustainable alternative for treating OMW.

Seasonal Stream Water Chemistry Response To Long-Term Forestry Drainage And Wildfire: A Case Study In A Part Of The Great Vasyugan Mire

Recent research suggests that climate change is contributing to rising solute concentrations in streams. This study focuses on assessing the concentrations of major elements, nutrients, and dissolved organic carbon (DOC), and their release through the bog-river system in the taiga zone of Western Siberia. The research was carried out in the northeastern part of the Great Vasyugan Mire (GVM), the largest mire system that impacts the quality of river water in the Ob River basin. By using PCA and cluster analysis, we examined the long-term dynamics of the chemical composition of headwater streams of the GVM affected by drainage and wildfires. Our data from 2015-2022 revealed that the concentrations of Са2+, Mg2+, K+, Na+, and HCO3- in stream water from the drained area of the GVM were, on average, 1.3 times lower than those at the pristine site. Conversely, the concentrations of NH+4, Fetotal, Cl-, SO42-, NO-3, DOC, and COD were higher, indicating the influence of forestry drainage and the pyrogenic factor. Our findings also demonstrated that the GVM significantly impacts the water chemical composition of small rivers. We observed a close correlation in the concentrations of К+, Na+, Cl-, Fetotal, NH+4, HCO3-, and COD between the GVM and the Gavrilovka River waters. PCA analysis revealed that air temperature influences the concentrations of Са2+, Mg2+, NH4+, NO3-, HCO3-, Fetotal, and DOC in the studied streams, with an inverse correlation with river discharge. The removal of major elements, nutrients, and DOC from the drained area of the GVM was most pronounced in April, being twice as high as in the pristine area. However, the total export from the drainage area of the Gavrilovka in April-September 2022 was 1.3 times lower than in the pristine area, amounting to 8487 kg/km2, with DOC removal at 42%.

Removal of Anabaena by ultrasonic pretreatment enhancing-coagulation and water treatment processes

Cyanobacteria bloom brings great challenges to the safety of the drinking water process. Ultrasonic pretreatment can effectively enhance coagulation to remove algae cells from algae-laden water. However, due to the special chain-like structure of Anabaena, the removal characteristics of Anabaena in water treatment process are quite different from those of unicellular cyanobacteria. No study has yet systematic studied on the enhancement effect of ultrasonic enhanced water treatment process on Anabaena. Therefore, this paper studied the characteristics and mechanism of ultrasonic pretreatment to enhance the removal of Anabaena, and carried out pilot experiments. The results showed that ultrasound irradiation at 740 kHz and 1.12 MHz had a great effect on the destruction of the chain-like structure and cell structure of Anabaena. After 15 min, the removal rate of Anabaena cells reached 16.0% and 30.4%, respectively, and the release of intracellular organic matter (IOM) reached 4.3 and 6.0 mg/L, in which phycocyanin released more. The damage of dynamic ultrasound irradiation on algae cells is weak, which can avoid the influence of uneven ultrasound irradiation on algae cells. The enhanced coagulation effect was better after 740 kHz ultrasonic pretreatment for 1 min, and the removal rates of algal cells, turbidity and dissolved organic carbon (DOC) increased by 7%, 9.4% and 12.6%, respectively. Pilot scale experiments demonstrate that ultrasonic pretreatment leads to a notable enhancement in the removal efficiency during the coagulation and sedimentation stages. After 4 h of operation, the turbidity and algal cell removal in the sedimentation stage increased by 6.1% and 14.0%, respectively. In addition, the removal of DOC in the final treated water increased by 6.7%. Furthermore, the disinfection by-products (DBPs) concentration experiences a reduction exceeding 200 μg per liter. Together, these results show a substantial improvement in filtration efficiency and effluent quality. This study provides guidance for the ongoing study of ultrasonic pretreatment to remove chain-like cyanobacteria.

Efficient electrochemical oxidation of refractory organics in actual petrochemical reverse osmosis concentrates by Ti/SnO2-Sb mesh anode

The efficient treatment of refractory organics in reverse osmosis concentrate (ROC) is a critical issue for achieving emission reduction or even zero emission in the petrochemical industry. A simple and efficient electrocatalytic process was proposed for treating actual petrochemical ROC using a highly active self-assembling Ti/SnO2-Sb anode. The Ti/SnO2-Sb anode was prepared by using citric acid (CA) and ethylene glycol (EG) as precursors, with a mole ratio of Sn:Sb of 5:1 and a metal salts to CA to EG mole ratio of 1:3:16. The resulting electrode surface had a complete mesh pit structure after calcination at 550 ºC. Several key factors were found to affect the degradation of dissolved organic carbon (DOC), including current density, chloride ion concentration, Fe (II) concentration, and acidity. The presence of chloride ions on the anode surface significantly improved the conversion efficiency of hydroxyl radicals, which played a crucial role in the oxidation of the organics. Additionally, near the cathode, oxidative radicals such as H2O2 and O2-∙ were generated, while hydroxyl radicals were produced with the addition of Fe (II) and H+. Under a current density of 20 mA·cm−2, the Ti/SnO2-Sb anode achieved a COD removal rate of 94.5% and a DOC removal rate of 43.4%.

Organic matter biofiltration performance modeling: Influence of influent water quality, operating conditions, and biomass

The impact of source water dissolved organic matter (DOM) origin, empty bed contact time (EBCT), temperature, and pretreatment methods on biofiltration performance was evaluated and predictive models based on experimental data were developed. Three DOM source water types, terrestrial, microbial, and treated wastewater (WW) effluent, were utilized. A model was developed to predict biofilter performance for dissolved organic carbon (DOC) removal based on the influent biodegradable DOC (BDOC) fraction, a single active biomass measurement from the top of the filter and the filter EBCT. A biomass distribution model was developed to predict total active biomass throughout the filter based on a single biomass measurement from the top of the filter. The measured BDOC fractions were 21 % for the nonWW impacted source waters, 36 % for the WW effluents and 62 % for the ozonated WW effluents. At an EBCT of 15 min, biofilters removed between 7 and 21 % of the DOC (19 to 50 % for BDOC) depending on the DOM type and use of ozonation. When the EBCT decreased to 5 min DOC removal decreased by 40 % and when increased to 30 min removal increased by 42 %. When the temperature decreased from 22 °C to 6 °C DOC removal was 33 % lower and when increased to 28 °C removal was 42 % higher. ATP values were found to be a function of temperature and DOM origin, as the average ATP values from the WW effluent biofilters were almost double that of the non-WW impacted sources and pre-ozonation of the WW effluent yielded values three times higher. The model was applied to the results of 27 different biofilter runs at three EBCTs yielding one distinct rate constant for the non-WW impacted source waters and one rate constant for the WW effluents. The model was successfully applied to the results of 19 filter runs from the literature and to those from a pilot plant over 6 months of operation.

Evaluation of Water Treatment Efficiency of Full-Scale Slow Sand Filtration Process: Comparison of Summer and Winter Season

Objectives : The objective of this study is to evaluate the feasibility of sustainable operation in a conventional full-scale slow sand filter process.Methods : A slow sand filtration process was operated in small scale water treatment plants for valley water. The water quality such as particle matter, dissolved organic matter, the number of bacteria, and disinfection by-product (DBP) were monitored at four designated points once a week and was compared during summer (July-August) and winter season (December-January).Results and Discussion : Although the number of particle matter in summer was higher than in winter by 39% (2.91×10<sup>4</sup> /mL), particle matter in slow sand filter process was removed by 99% regardless of season (temperature). The removal efficiency of dissolved organic carbon (DOC) and UV<sub>254</sub> was higher in summer than in winter by 15% and 21%, respectively. In addition, concerning the organic fraction, higher molecular weight led to higher removal efficiency in the following sequence: BP (biopolymer, MW: 20,000 g/mol) > HS(humic substances, MW : 1,000~20,000 g/mol) > BB(building blocks, MW : 300~500 g/mol) > LMWs(low molecular weights, MW : 350 g/mol. The concentration of trihalomethanes (THMs) and haloacetic acids (HAAs), indicator of DBP, were detected at 12.2 and 9.4 μg/L in summer and 8.1 and 6.3 μg/L in winter, respectively, which would be considered very low concentration related to the drinking water regulation of 100 μg/L. Finally, the active bacteria was removed up to 93 and 92% in summer and winter, respectively.Conclusion : The feasibility of a slow filtration process was evaluated to compare particle and dissolved matter in summer and winter operation. Despite a 39% increase in particle matter in summer, the removal efficiency was maintained at 98% in summer and winter. Due to the increased activation of biofilm in summer, the removal of DOC and UV<sub>254</sub> was higher in summer than winter by 15 and 21%, respectively. The significant low concentration of THMs and HAAs, regardless of season, would be negligible. In addition, achieving over 92% removal of activated bacteria secured the biological safety. These stable operations ensure that slow filtration process is effective in controlling of water quality.

Tri-protonated ferrate: A novel electro-synthesised pre-oxidant/coagulant for NOM and DBP precursors removal in drinking water production

The generation of tri-protonated form of ferrate (H3FeVIO4+) in acidic media offers unique opportunities for drinking water treatment. Compared to the more conventional deprotonated ferrate form (FeVIO42−), H3FeVIO4+ is an extremely strong oxidant rendering it both an effective pre-oxidant and coagulant for water treatment applications. In this work, the treatment performance of H3FeVIO4+ at removing natural organic matter (NOM) and disinfection by-product (DBP) precursors was evaluated and compared against FeVIO42− and the most commonly-used iron-based coagulant: ferric chloride (FeCl3) when treating the water from two drinking water reservoirs in Australia. Results demonstrate that FeVIO42− and H3FeVIO4+ react with organic matter in intrinsically different ways, influencing the removal of dissolved organic carbon (DOC) and the formation potentials of carbonaceous-DBPs upon subsequent disinfection with chlorine or chloramine. H3FeVIO4+ dosing achieved the highest DOC removal observed: 77 % for water from site A and 60 % for water from B, both significantly superior to FeVIO42− (water A: 22 % and water B:18 %) and FeCl3 (water A: 40 % and water B: 41 %) dosing. Moreover, H3FeVIO4+ pre-oxidation of water A and subsequent chlorination reduced trihalomethanes (THMs), iodo-trihalomethanes (I-THMs), haloketones (HKs) and chloral hydrate (CH) precursors by 81 %, 92 %, 53 % and 61 %, respectively, whereas for water B the THMs, I-THMs, HKs and CH precursors were reduced by 60 %, 52 %, 20 % and 58 %, respectively, heavily outperforming the performance of FeVIO42− and FeCl3 in the removal of all measured DBPs. Finally, the formation of bromate was not observed when either ferrate(VI) forms were applied, thus rendering H3FeVIO4+ an interesting alternative pre-oxidant/coagulant, even for high bromide-containing waters (such as water B: 240 μg L−1).

Performance of biological ion exchange resin and gravity-driven ceramic membrane hybrid process for surface water treatment

In this study, the performance of a biological ion exchange (BIEX) resin and gravity-driven ceramic membrane (GDCM) filtration hybrid process in terms of membrane permeate quality, flux, and membrane biofilm characteristics during river water treatment for drinking water was investigated. The hybrid process results were compared with those of the GDCM process without the BIEX pre-treatment. Three types of previously synthesized microfiltration membranes were used: M1 (100 wt% kaolin), M2 (75 wt% kaolin + 25 wt% alumina), M3 (50 wt% kaolin + 50 wt% alumina), and M4 (commercial ceramic microfiltration membrane). In terms of permeate quality, the BIEX column removed approximately 74 % of the dissolved organic carbon (DOC) compared with the influent water, followed by 27 % DOC removal using M3 compared with the BIEX column effluent on day 65 (6,240 BV), which was mainly due to the removal of humic and fulvic acids. BIEX removed turbidity of the influent water from 2.20 NTU to 0.77 NTU, which was further decreased to 0.09 NTU by membranes. The maximum stabilized flux of the membranes was approximately 5.7 LMH, which was almost doubled compared to GDCM without pre-treatment. The membrane biofilm showed lower thickness and roughness in the hybrid process than that in GDCM without pre-treatment. Higher extracellular polymeric substance (EPS) concentration and biological activity were observed for M3, the membrane with the highest stabilized flux and highest DOC removal efficiency. The results indicate that the hybrid BIEX + GDCM is a robust, high-performance, and easy-to-use process that can increase the flux and permeate quality of GDCM systems.

Vacuum ultraviolet irradiation for reduction of the toxicity of wastewater towards mammalian cells: Removal mechanism, changes in organic compounds, and toxicity alternatives

Vacuum ultraviolet (VUV, 185 + 254 nm) irradiation performs well for oxidation of model pollutants. However, oxidation of pollutants does not necessarily lead to a reduction in toxicity. Currently, a comprehensive understanding of the effect of VUV irradiation on the toxicity of real wastewater is still lacking. In this study, the influence of VUV irradiation on the toxicity of secondary effluents to Chinese hamster ovary (CHO) cells was investigated. The induction units of endogenous reactive oxygen species (ROS) and 8-hydroxyguanosine (8-OHdG) in cells continuously decreased with prolonged irradiation time. After 36 min of irradiation, the cytotoxicity and the genotoxicity of the secondary effluents were reduced by 57%–63% and 56%–61%, respectively. The UV (254 nm), •OH, and other substances generated during the VUV irradiation directly drive toxicity changes of wastewater. The contribution of •OH generated during VUV irradiation to the reductions in cytotoxicity and genotoxicity of the secondary effluents reached 72%–78% and 77%–84%, respectively. Hydroxyl radicals generated during VUV irradiation played an important role in the detoxification. The relative signal intensity of dissolved organic carbon (DOC) > 500 Da was partially removed, whereas that of DOC < 500 Da was small changed. Since the content of DOC > 500 Da in the samples was much lower than that of DOC < 500 Da, the removal of total DOC was only 15.8%-20.0% after 36 min of irradiation. The UV254 values and the fluorescence intensity values for different molecular weights (MWs) were all reduced effectively by VUV irradiation. Electron-rich organic compounds of all MWs were all sensitive to VUV irradiation. There were mono-linear relationships between changes in chemical indexes and changes in cytotoxicity or genotoxicity. The total fluorescence intensity (Ex: 220–420 nm, Em: 280–560 nm) was identified as the best indicator of the reduction in toxicity.

Winery and olive mill wastewaters treatment using nitrilotriacetic acid/UV-C/Fenton process: Batch and semi-continuous mode

In this work, both red and white winery wastewaters (WW) and olive mill wastewater (OMW) were submitted to a treatment by Fenton-based processes (FBPs). The main aim was to evaluate the most efficient and economic process. Initial tests, resorting to a batch reactor, demonstrated that UV-C/Fenton (λ = 254 nm) was the most effective process. Operational conditions such as pH, H2O2 and Fe2+ concentrations revealed to have a superior influence within dissolved organic carbon (DOC) removal as well as regarding the reactor's energy consumption. As a means to prevent iron precipitation, the addition of nitrilotriacetic acid (NTA) was tested. With experimental conditions pH = 3.0, [H2O2] = 194 mM, [Fe2+] = 1.0 mM, [NTA] = 1.0 mM, radiation UV-C (254 nm), time = 240 min, the kinetic rate related with DOC removal showed a kredWW = 0.0128 min−1 > kOMW = 0.0124 min−1 > kwhiteWW = 0.0104 min−1 and both the WW and OMW achieved the Portuguese legal limit values for wastewater discharge. Furthermore, comparative experiments were performed in a semi-continuous reactor, being that the results put in evidence that the concentration of H2O2 added and the flow rate of reagents' addition (F) had a significant effect on the efficiency of the reactor. Under an optimum experimental procedure pH = 3.0, [H2O2] = 97 mM, [Fe2+] = 1.0 mM, [NTA] = 1.0 mM, radiation UV-C (254 nm), F = 1 mL min−1, time = 240 min, there were observed higher DOC removal kinetic rates (kOMW = 15.20 × 10−3 min−1 > kredWW = 11.64 × 10−3 min−1 > kwhiteWW = 11.57 × 10−3 min−1) and a cost ranging between 0.0402 and 0.0419 €/g.DOC. These results showed that semi-continuous reactors have the potential to be applied to large scale treatments, with low reagents consumption and reduced energy requirements.

Dynamics of chromophoric dissolved organic matter in a highly productive Amundsen Sea polynya

Dissolved organic carbon (DOC) is the largest organic carbon pool in the ocean, and is the most active component in respect to the ocean carbon cycling. However, its study in Antarctica has been limited due to challenges associated with sample collection. In this study, we conduct an investigation on the chromophoric dissolved organic matter (CDOM) in a highly productive Amundsen Sea Polynya (ASP), where phytoplankton blooms occur annually during the austral summer, serving as the primary source of DOC and CDOM. The relative abundances of CDOM, as indicated by the absorption coefficient at 254 nm (a254), exhibit significant variability, reaching up to 6.34 m−1. Four fluorescent components, including two humic-like components (C1 and C4) and two protein-like components (C2 and C3), are identified by excitation emission matrix coupled with parallel factor analysis (EEM-PARAFAC). Our findings suggest that heterotrophic metabolism primarily contributes to the formation of humic-like fluorescent components and DOC removal. Water mass, solar radiation, primary productivity as well as microbial degradation are identified as the main factors influencing CDOM dynamics in ASP. This study bears significant implications for advancing our understandings of the CDOM and DOC dynamics in the coastal polynyas of Antarctica, thus facilitating improved evaluation of carbon cycle in the Antarctica.

Thermal evolution of biochar in nature: A potential mode to enhance the self-cleaning of environmental DOC

Biochar often undergoes multiple thermal processes. Thermal evolution is described in this study as the process by which biochar in the environment changes again in a thermal environment. In this study, the thermal evolution process of biochar was studied by characterization test. The results showed that the oxygen content in biochar increased after thermal evolution, mainly due to functional groups such as O-H and C-O, while the functional groups of CO did not change significantly. Micro-pores will be generated in biochar after thermal evolution, which will increase the surface area and significantly enhance the adsorption capacity. The biochar was added to natural water to observe how biochar enhanced the removal of dissolved organic carbon (DOC). The concentration of DOC was reduced by about 6.68 mg/L by SB 800, and most of the components were humus, which indicated that the thermal evolution of biochar promoted the removal of DOC. The Electron spin resonance (ESR) test shows that after thermal evolution, biochar has more oxygen-containing carbon center persistent free radicals due to the increase of C-O functional groups in biochar. Under visible light, persistent free radicals in oxygen center are formed by electron transition, which can undergo a variety of reactions with water to form reactive oxygen species.

A comparison of micro-flocculation and ozonation as pretreatments for ultrafiltration: organic removal and membrane fouling.

Micro-flocculation and ozone were applied as pretreatments of ultrafiltration to treat sodium alginate (SA) and humic acid (HA) simulated water, respectively, to investigate the effects of different pretreatments of ultrafiltration (UF) on filtration flux and removal of organic matters. Regarding the SA simulated water, micro-flocculation helped to improve the dissolved organic carbon (DOC) removal efficiency highly, maximum DOC removal efficiency reached to 79.77%, due to the rejection of gel layer introduced by the alginate-aluminum complexes, but the gel layer had a negative impact on membrane flux. Compared with micro-flocculation, ozone as pretreatments had better ability to enhance the membrane specific flux, the maximum final specific flux remained as 0.786, larger than that of MF-UF process (0.574). Ozonation oxidizing SA into small organic molecules significantly reduced membrane fouling and filtration resistance, but also produced some dissolved organic matters hindering DOC removal of effluent. As for HA simulated water, both the micro-flocculation and ozone could effectively improve the specific flux, the final specific flux of MF-UF and ozone-UF were about 0.930, but MF-UF exhibited better DOC removal than ozone-UF, which avoided the introduction of additional dissolved organic matters.

Design considerations for biological ion exchange drinking water filters: Resin selection, backwash, and regenerations

AbstractTwo pilot studies provide insights into the design and operations of biological ion exchange (BIEX) drinking water filters. A lab‐scale pilot with strong‐base anionic (SBA) and weak‐base anionic (WBA) resins demonstrated 35% and 31% removal of dissolved organic carbon (DOC) up to 30 months, until secondary ion exchange exhaustion. While the WBA resins exhibited 14% less removal of DOC, their larger capacity doubled the duration until filter exhaustion. WBA filters were less affected than their SBA counterparts by sulfate‐containing inlet waters. In a second pilot, while water with high DOC yielded rapid exhaustion of SBA resins, air scouring increased the breakup of filter media and improved solids removal by 30× compared to hydraulic backwash alone. Significantly, DOC removal improved by 36% for a week following air scour. Key recommendations include the use of WBA resins to extend operating life while implementing air scouring can dramatically improve short‐term DOC removal.

Effect of marine sediment on the phase partitioning and isotopic content of riverine DOC

AbstractRivers discharge significant quantities of dissolved organic carbon (DOC) to the ocean, yet biomarker and isotope studies suggest that terrigenous DOC makes up only a small amount DOC in the ocean. One of the removal pathways proposed for riverine DOC is sorption to marine sediments. This process is chemically selective, but whether sorption alters the isotopic composition of riverine DOC is unknown. Because there is isotopic variability across different organic compound classes, sorptive removal of DOC could also alter the isotopic composition of DOC. As a first step in addressing this question, we examined phase partitioning and isotopic composition of a riverine DOC standard in the presence of marine sediment particles. In a series of controlled experiments, the standard was mixed with marine sediment in 35‰ NaCl solution, then separated into particulate and dissolved phases for analyses of mass, δ13C, and ∆14C of organic carbon (OC). Across a range of sediment OC to DOC mass ratios (from &lt; 0.1 to ~ 3), we found that: (1) sediment sorbed 0.8 μg OC per mg of sediment; and (2) DOC compounds with higher ∆14C and lower δ13C values relative to the bulk DOC was preferentially removed from solution. In effect, mixing a riverine DOC standard with marine sediment resulted in increased ∆14C and decreased δ13C of the DOC that remained in solution. These results show that sorption of DOC to sediment can alter the isotopic content of riverine DOC.

Pilot-scale study on the performance of high-rate DAF based on removal of organic precursors and formation characteristics of disinfection by-products

In recent years, there has been an increased focus on the design and development of dissolved air flotation (DAF) with a high surface loading rate (SLR), but little research has been conducted using advanced natural organic matter characterization techniques. This research thus investigates the performance of pilot-scale DAF (10–30 m h–1) and compares them with those for a full-scale coagulation–flocculation–sedimentation (CFS) system based on the reduction of organic precursors, different molecular weight (MW) fractions characterized by liquid chromatography with organic carbon detection, and disinfection by-products. The removal of dissolved organic carbon (DOC) decreased with increasing SLR, ranging from 29 % to 38 %. This may be because of the short flocculation retention time for high SLR. Thus, achieving a similar removal of DOC by high SLR required higher coagulant doses. Furthermore, the organic precursors were measured lower in the high-rate DAF effluent than the CFS, maybe because of the high coagulation pH of the CFS effluent (7.5–8). Similarly, the concentration of different MW fractions, especially biopolymers and building blocks, was lower in the high-rate DAF effluent than in the CFS. The removal of biopolymers was 74.64 % and 87.20 % for the CFS and high-rate DAF, respectively. Likewise, 2.78 % and 27.09 % for the CFS and high-rate DAF, respectively, for building blocks. The normalized trihalomethanes/DOC and chloralhydrate/DOC were higher for the CFS than the high-rate DAF. Coagulation chemistry (pH, coagulant doses, and retention time) strongly influences the DAF and CFS unit performance and should not be neglected.

Fluorescence-based indicators predict the performance of conventional drinking water treatment processes: Evaluation based on the changes in the compositions of dissolved organic matter

This study investigated the treatability of dissolved organic matter (DOM) by the selected lab-scale drinking water treatment processes using fluorescence excitation-emission matrix (EEM) analysis. The fluorescence ratio Peak 3/Peak 2 was established from well-defined fluorescence peak intensity of humic-like components (Ex/Em: 225 nm/425 nm) and protein-like components (Ex/Em: 230 nm/345 nm). Peak 3/Peak 2 predicted the aromatic characteristics of DOM and their origins in the different natural surface water feeding the different drinking water treatment plants. The drinking water treatment processes confirmed the treatability of DOM using Peak 3/Peak 2 and was well-confirmed by specific UV260 absorbance relative to dissolved organic carbon (DOC) (SUVA) and fluorescence-based indices. Peak 3/Peak 2 was demonstrated to have a strong correlation with SUVA and DOC removal for the water after treatment by coagulation, adsorption, and chlorination. Compared to the humification index and fluorescence index, Peak 3/Peak 2 is better for indicating the DOM composition in terms of treatability. These findings can broaden the use of fluorescence spectroscopy in water treatment applications, by developing the fluorescence ratio to evaluate the performance of drinking water treatment plants.

DOC signal-based alum dose control for drinking water treatment plants

This paper describes a model, based on dissolved organic carbon (DOC) input data, developed for prediction of alum dosage for targeted removal of DOC from raw surface waters. DOC, UV absorbance at 254 nm/cm (A254), colour and turbidity data were acquired for raw and treated water samples. The results show that for 17 samples jar tested, only ~57 % ± 13 % (mean ± SD) of the DOC content was coagulable. For the range of samples studied, it was found that 85 % (±8 %) removal of coagulable DOC fraction was achieved at enhanced coagulation (EnC) based on ΔDOC/ΔAlum = −0.015 mg/mg. The 85 % value was then used as a basis to develop an alum dose prediction model for application over the wide range of water qualities of the samples studied. The model outputs were compared with EnC doses (EnD) obtained through jar testing, as well as predicted EnD values obtained through mEnCo© software, that uses input data of A254 and colour. Trials of the model predictions were conducted for five drinking water treatment plants (DWTPs) over a four-month period. The results show the potential of the model for alum dose predictions with correlation coefficients of predicted alum doses versus 1) actual alum doses and 2) estimated EnD from the mEnCo© software ranging from 0.72 to 0.98 and 0.92 to 0.99, respectively. It is suggested that the DOC model has potential to be deployed for online feedforward alum dose control.

Transformation of organic carbon through medium pressure (polychromatic) UV disinfection of wastewater effluent during wet weather events

An observed decrease in total organic carbon (TOC) and dissolved organic carbon (DOC) concentrations following wastewater disinfection with medium pressure (MP, polychromatic) ultraviolet (UV) irradiation during wet weather flows is investigated. When antecedent rainfall in the previous 7-days was >2 in (5 cm), TOC and DOC concentrations decreased dramatically following MP-UV disinfection. Organic carbon surrogate measurements of biological oxygen demand (BOD), TOC, DOC, turbidity, UVA – 254 nm, SUVA (specific UVA), scanning UV–Visible spectra (200–600 nm), fluorescence excitation-emission matrix (EEM) spectra, and light scattering data are presented for wastewater resource recovery facility (WRRF) influent, secondary effluent (pre-UV-disinfection), and MP-UV-disinfected (final effluent) samples. TOC and DOC in wastewater influent and secondary effluent (i.e., pre-UV disinfection) correlated with antecedent rainfall conditions. The percent TOC and DOC removal through secondary treatment (i.e., from influent to effluent pre-UV) and the percent TOC and DOC removal through MP-UV disinfection (i.e., from effluent pre-UV to effluent post-UV) were compared and the latter approached 90 % through MP-UV disinfection during high antecedent rainfall conditions. Spectroscopy (UV, visible, or fluorescence) was performed on samples after filtration through 0.45 μm filters, i.e., the operationally defined DOC fraction of aquatic carbon. Scanning UV–visible spectra indicated transformation of an unidentified wastewater component into light-scattering entities regardless of antecedent rainfall conditions. The types of organic carbon (diagenetic, biogenic, or anthropogenic) and the significance of wet weather are discussed. An organic carbon contribution via infiltration and inflow was attributed as a source-of-interest in this research.

Using 224Ra/228Th disequilibrium to quantify carbon transformation and export from intertidal sandy and muddy sediments

The intertidal zone is an important pathway for the transport of dissolved carbon across the land–ocean interface. Quantifying carbon transformation and export from the intertidal zone remains large uncertainties due to the natural heterogeneity and various driving mechanisms. Here, we used the 224Ra/228Th disequilibrium method to quantify porewater exchange and dissolved carbon export from intertidal sandy and muddy sediments, two main intertidal wetland types in the coast. Porewater exchange fluxes from sandy sediments ranged from 1.4 ± 0.1 to 1084 ± 53 L m−2 h−1, which gradually increased in the landward direction. Porewater exchange fluxes from mangrove muddy sediments ranged from 0 to 4.4 ± 0.7 L m−2 h−1. Advective porewater exchange was recognized as the dominant solute transport process in sandy sediments, whereas bioturbation may be the key process in mangrove muddy sediments. Furthermore, marine dissolved organic carbon (DOC) was removed in sandy sediments, indicating that the sandy sediment acted as a sink of DOC, likely via aerobic remineralization. DOC consumption fluxes ranged from 3.7 ± 0.2 to 206 ± 9 mmol C m−2 d−1. The total consumption flux of DOC in the entire sandy beach was one order of magnitude higher than the globally maximum DOC removal flux in the upper ocean. Porewater-derived dissolved inorganic carbon (DIC) export fluxes from sandy sediments ranged from 5.6 ± 0.3 to 883 ± 43 mmol C m−2 d−1. Nearly 50% of DIC export originated from the consumption of DOC. The rate constants for DOC transformation ranged from 0.009 to 0.155 h−1. In comparison, porewater-derived DOC and DIC export fluxes from muddy sediments were 25 ± 4 and 206 ± 30 mmol C m−2 d−1, respectively. Porewater-derived DIC export from sandy sediments was comparable or even higher than those from muddy sediments. These results showed that sandy sediments acted as a fast lane for marine DOC remineralization. Overall, both organic-poor sandy and organic-rich mangrove muddy sediments play important roles in the delivery of dissolved carbon to the ocean.