Dissolution Thermodynamics Research Articles

Chemical kinetics of water‐rock interactions

The recent literature on the kinetics of water‐rock interactions is reviewed. The data are then extended to provide a quantitative framework for the description of weathering and alteration. The available experimental data on dissolution of silicates verifies quantitatively the usual mineral stability series in sedimentary petrology. The rate of hydration of carbonic acid is shown to be a possible limiting factor in water‐rock interactions. The framework is developed to enable use of laboratory dissolution experimental results and thermodynamics to arrive at a rate law applicable up to equilibrium and therefore applicable to natural systems. The kinetic justification for the significance of a water‐rock ratio is discussed. With a proper treatment of fluid flow, the equations are applied to the weathering profile leading to the development of bauxites from nepheline syenites.