Dissolution Of Magnetic Minerals Research Articles

Anti-phase variation of long eccentricity and precipitation in inland Asia during the Middle Miocene Climatic Optimum

The mechanisms and pace of orbital forcing on precipitation in inland Asia during the Cenozoic remain poorly understood. Many previous studies using magnetic proxies for precipitation have shown a consistent signal of long eccentricity (405 kyr) in hydrological records of central China that are younger than ca. 11 Ma. Most studies suggest that variations in rainfall amount were controlled by Northern Hemisphere summer insolation, and the peak of precipitation is associated with eccentricity maxima. Here, we report multiple magnetic records dating back to the Middle Miocene Climatic Optimum (MMCO, ∼14−17 m.y. ago), including a detailed record from a new section in the Qaidam Basin, which was dated using magnetostratigraphy, U-Pb geochronology, and apatite low-temperature thermochronology. Our records show the exact opposite: 405 kyr wet-dry cycles dominated, but the wetter intervals correspond to eccentricity minima and ice-volume maxima during the MMCO. Taken at face value, these results question the origin—monsoonal or westerly-derived—of the precipitation that reached central China during the middle Miocene and the mechanisms that enhanced monsoonal penetration of inland Asia. We also suggest that this anti-phase relationship could also reflect biases in magnetic proxies for precipitation during the wettest climatic phases, which can result in the dissolution of magnetic minerals and a significant underestimation of past rainfall.

Links Between Orbital Forcing, Antarctic Ice Volume, and the East Asian Hydrological Cycle Over the Pliocene

AbstractRevealing the evolution of monsoonal intensity through the Pliocene on orbital timescales is of potential utility for providing insights into the response of Asian monsoons to future high pCO2 scenarios. Here, we report a continuous Pliocene cyclostratigraphic record from lake deposits of the Xinding Basin, Shanxi Graben, North China, and reconstruct the regional hydrological cycle from this location during ∼5.2 to 2.56 Ma. Our results show that regional hydrological cycling was consistently dominated by long‐and short‐eccentricity (405‐and 100‐kyr) forcing over the Pliocene. Gamma‐ray (GR) data (reflecting hydrodynamic changes) show strengthened 100‐kyr eccentricity power after ∼3.5 Ma, whereas 100‐kyr eccentricity power preserved in magnetic susceptibility (MS; interpreted as a proxy of pedogenesis and magnetic mineral dissolution) slightly weakened after ∼3.5 Ma. This orbital power transition at the 100‐kyr eccentricity scale may link to expansion of Antarctic ice volume after ∼3.5 Ma, which enhanced East Asian summer monsoon intensity and thus increased summer rainfall in North China, resulting in changes to hydrological cycling and the expression of eccentricity climate forcing in East Asian basins. In addition, our results demonstrate that the orbital configuration at ∼4.2–4.4 Ma could have been a contributory factor in strengthening the intensity of the East Asian summer monsoon at this time.

The Effect of Early Diagenesis in Methanic Sediments on Sedimentary Magnetic Properties: Case Study From the SE Mediterranean Continental Shelf

Microbial respiration in marine sediment can affect the magnetic properties of the sediment through a complicated interplay between reductive dissolution and authigenic precipitation of iron-bearing magnetic minerals. However, a direct link between the main diagenetic zones in the upper sedimentary column and sedimentary magnetic properties using high resolution multi parameter profiles has been demonstrated only in few studies. Here, we directly correlate early diagenetic processes and sedimentary magnetism using a composite high-resolution sedimentary record of pore water chemistry, solid phase chemical measurements and mineral-magnetic parameters. Measurements along the profiles include the entire redox cascade, from the water-sediment interface, down through the deep methanic zone, on a six-meter sediment core collected from the Southern Eastern Mediterranean continental shelf. The uppermost part of the sediment core, associated with oxic, nitrous, manganous, ferruginous, and sulfate reduction zones, is characterized by high ferrous iron and sulfate concentrations and high values of the measured magnetic parameters (susceptibility, Isothermal remanent magnetization (IRM) and Anhysteretic remanent magnetization (ARM)). This layer is underlain by a sulfate-methane transition zone (SMTZ) that shows a significant decrease in magnetic parameters due to the dissolution of magnetic minerals. Below the SMTZ, the methanic zone has been assumed to be magnetically inactive under steady-state conditions. However, we observe in the upper methanic zone an increase in microbial iron reduction, coupled to an abrupt increase in magnetic parameters. Our data indicate that the observed increase in the magnetic signal is related to the precipitation of authigenic magnetic minerals. These diagenetic changes should be considered when interpreting paleomagnetic data, and highlight the potential to use high-resolution magnetic data as a proxy for identifying diagenetic processes.

Paleomagnetic secular variation records from Holocene sediments of Lake Victoria (0.5°S, 33.3°E)

We have conducted a paleomagnetic study of Holocene sediments from Lake Victoria in order to develop a high-resolution record of paleomagnetic secular variation (PSV). This study has recovered PSV records from two cores (V95-1P and V95-7P) in northern Lake Victoria (0.5°S). The PSV is recorded in fine-grained detrital magnetite/titanomagnetite grains, but the rock magnetic data suggest that significant magnetic mineral dissolution has occurred, which limits our paleomagnetic studies to the uppermost ~5 m of both cores. Detailed alternating field (af) demagnetization of the natural remanence (NRM) shows that a distinctive characteristic remanence (ChRM) is demagnetized from ~10 to 40 mT, which decreases simply toward the origin. The resulting directional PSV records for 1P and 7P are correlatable with 22 distinct inclination features and 19 declination features. Radiocarbon dating of the cores is based on eight radiocarbon dates from core 1P, which can be correlated into core 7P using both the PSV and rock magnetic/environmental measurements. The final PSV time series cover the last 11,000 years with an average sediment accumulation rate of ~40 cm/kyr. The Lake Victoria PSV records can be correlated with new PSV records from Lake Malawi. Comparison of the correlatable PSV feature ages between the two lakes indicates that the PSV records are not significantly different in age, although Lake Victoria PSV ages might average ~100 years younger. We think that the Lake Victoria and Lake Malawi PSV records, together, provide the most accurate, well-dated, and consistent record of Holocene PSV for Africa yet developed.

Spatial and seasonal variability in grain size, magnetic susceptibility, and organic elemental geochemistry of channel-bed sediments from the Mekong Delta, Vietnam: Implications for hydro-sedimentary dynamic processes

Understanding the relationship between depositional processes and their products in the fluvial–marine transition zone in tide-dominated depositional systems is fundamental to improving environmental and stratigraphic interpretations of long-term sedimentary records. The distributary channels of the Mekong Delta represent a typical example of a complex sedimentary environment characterized by strong fluvial and tidal interactions, and seasonal variability in hydro-sedimentary dynamic processes, particularly the migration of a salt wedge front linked to seasonal fluctuations in freshwater discharge. For this study, we analyzed grain size, magnetic susceptibility, and organic elemental geochemistry of channel-bed surficial sediments collected in 2015 from all distributary channels during the dry season and from the Mekong–Co Chien River during the flood season. This paper reports spatial and seasonal differences in the characteristics of channel-bed surficial sediments, which are closely linked to sediment sources and depositional processes during the dry and flood seasons.Distributary channels are characterized by coarse-grained sediments in the upper reaches and fine-grained sediments in the lower reaches, in both dry and flood seasons, reflecting the difference between the upstream fluvial-dominated environment and the downstream tide-dominated environment. Flood season samples from the Co Chien River show higher magnetic mineral contents and a terrestrial source of organic carbon compared with dry season samples, indicating sourcing from the drainage basin and trapping of suspended materials in the distributary channel due to the barrier effect of the saltwater wedge at the river mouth. Compared with the flood season, during the dry season the mud content was lower in the downstream reach close to the river mouth and higher in the upstream reach of the Co Chien River, and the content of magnetic minerals was lower in both reaches, indicating dissolution of magnetic minerals during early diagenesis. Furthermore, the lower C/N ratios (<10) and slightly enriched δ13C values of the dry season samples from the Co Chien River imply an additional contribution of organic carbon from a marine source. These various features imply a landward import of mud into the Co Chien River induced by stronger salinity intrusion during the dry season. Along the downstream tract of the Bassac River, two mud-dominated reaches were identified during the dry season. The magnetic mineral contents, C/N ratios and δ13C values indicate that the mud-dominated reach near the Bassac River mouth is also supplied from resuspended sediments by estuarine circulation and tidal pumping, whereas the mud in the reach that is transitional from fluvial to tide dominance has a riverine supply. The results suggest that the Mekong distributary channels are important sinks for suspended sediments during both the flood and dry seasons, controlled by a sediment trapping mechanism provided by either estuarine processes or the morphological configuration of the channels, both of which are controlled by fluvial–tidal dynamics. These depositional processes may be compensating for the incision of channels induced by sand mining in recent decades.

Magnetic mineral dissolution recorded in a lacustrine sequence from the Heqing Basin, SW China, and its relationship with changes in the Indian monsoon

The dissolution of magnetic oxides is an important process in many lake environments. Understanding this phenomenon is crucial for the paleoenvironmental interpretation of the magnetic properties of lake sediments. In order to reveal its effects on sedimentary magnetic properties, and to assess the possible associated paleoenvironmental implications, we carried out detailed rock magnetic analyses of the selected samples from a 920-kyr lacustrine sequence from the Heqing Basin, SW China. The results indicate that the sedimentary magnetic properties are controlled by the concentration and grain size of magnetite and maghemite. High magnetic susceptibility (χ) intervals contain more fine-grained magnetite and maghemite, while low χ intervals contain only minor amounts of residual magnetite. The decreased content of fine-grained maghemite from high χ to low χ intervals reflects the dissolution of magnetic oxides during deposition. Intervals affected by strong magnetic dissolution have a high TOC content and correspond to times of high Antarctic temperatures, suggesting that magnetic mineral dissolution intensity was associated with variations in the strength of the Indian Summer Monsoon (ISM). Notably, the ISM is sensitive to Southern Hemisphere warming. Weak magnetic dissolution indicates a dry climate occurred since ~320 kyr in the Heqing Basin. This dry/cool event was widespread across the Eastern Bay of Bengal, Equatorial Indian Ocean and Northern Australia, and was linked to a strengthened Indian Ocean Dipole (IOD). Since the moisture source of the Heqing Basin was mainly from the above regions, we infer that the influence of the IOD extended northwards to SW China.

Gradual late stage deepening of Gega ice-dammed lake, Tsangpo gorge, southeastern Tibet, indicated by preliminary sedimentary rock magnetic properties

Gega lake, in southeastern Tibet, was formed by the blocking of Yarlung Tsangpo gorge by a glacier and is a well-known example of geomorphological damming. However, the evolution of the damming process at the site is still not understood in detail. Here, we use measurements of multiple magnetic parameters of the sediments from the Yusong (YS) 3 section, which is well-dated by optically stimulated luminescence, to provide a detailed history of the late stage of Gega dammed lake since 17.0 ka. Low-frequency field magnetic susceptibility (chi(lf)) increases upwards gradually from 25 to 79 x 10(-8) m(3)/kg above 5.5 m, but other magnetic properties, such as frequency-dependent magnetic susceptibility (chi(fd)% and (fd)), susceptibility of anhysteretic remanent magnetization (chi(ARM)), and saturation isothermal remanent magnetization (SIRM) did not show a similar degree of enhancement. The magnetic grain size indicators of chi(ARM)/chi(lf), chi(ARM)/SIRM, and chi(lf)/SIRM all indicate a trend of increasing magnetic grain size from the 5.5 m to the top of section; however, the bulk sediment grain size decreases gradually within the same interval. The total organic carbon is very low (0.2-0.7%), and thus, it is unlikely that the sedimentary environment is sufficiently strongly reducing to lead to the dissolution of magnetic minerals. Therefore, we infer that the coarsening-upwards of the magnetic grain size, and the increasing magnetic susceptibility from 5.5 m, reflect the gradual preferential preservation of magnetic minerals, caused by the deepening of the lake. Thus, we interpret the magnetic record of the section as reflecting the gradual deepening of the late stage of Gega ice-dammed lake. Last, the abrupt disappearance of the lake may have resulted in an outburst flood.

Paleomagnetic record for the past 80 ka from the Mahanadi basin, Bay of Bengal

High resolution paleomagnetic investigations were performed on a 50.08 m long sediment core (MD161/20) from Mahanadi basin, Bay of Bengal. Core yielded reliable paleomagnetic results for top 20 m below seafloor (mbsf) which spans about 80 ka. Based on the analysis of rock magnetic data, the core is subdivided into five distinct Zones: Zone 1 and Zone 2 cover top 20 mbsf and do not show any abrupt change in magnetic mineralogy, concentration and grain size. Zones 3 and 5 show significant reduction in χLF, χARM and SIRM due to dissolution of magnetic minerals. Zone 4 shows moderate values of χLF and SIRM. The low value of χARM suggests that magnetic signal is mostly carried by magnetic grains in PSD/MD state. The paleomagnetic data for the top 20 mbsf show four prominent geomagnetic excursions at ∼9 mbsf, ∼13.5 to 15 mbsf, ∼16.3 mbsf and ∼18 to 18.2 mbsf. The age-depth relationship is established using stratigraphic correlation between well-dated sedimentary core NGHP-01-19B and the core MD161/20. The ages of the observed excursions correspond to ∼18 to 20 ka, ∼42 to 49 ka, ∼54 to 57 ka and ∼69 to 70 ka. The excursions at ∼42 to 49 ka, ∼54 to 57 ka, and ∼67 to 70 ka is similar to the known excursions the Laschamp and the split Norwegian-Greenland Sea events (NGS-I and NGS-II). The excursion at 18–20 ka is not observed globally and may be related to lithological/sedimentological changes occurring during last glacial maxima (LGM). The virtual geomagnetic path (VGP) of Laschamp excursion traces clockwise loop. All excursions identified in present study fall in the periods of relatively low paleointensity.

Magnetic mineral diagenesis in anoxic laminated sediments from the Southern Gulf of California

Diagenetic effects on the magnetic mineralogy in marine sediments have long been investigated, including oxidation/reduction reactions, magnetic dilution, formation of iron sulfides and oxides, magnetization acquisition mechanisms and reliability of the paleomagnetic record. This study investigates diagenetic effects in low-oxygen depositional environments characterized by recent and past magnetic mineral dissolution zones. We analyze a marine sequence from the Alfonso Basin in the southern Gulf of California in which the topmost sediments show diagenetic effects marked by high magnetic enhancement factors. The susceptibility logs show high values at the top sediments with well-defined small amplitude low frequency fluctuations down core. Magnetic hysteresis loops indicate low coercivity saturation, characteristic of magnetites and low-tititanomagnetites with varying paramagnetic contributions. Intensity of natural remanent, isothermal and anhysteretic magnetizations and coercivity parameters show similar variation patterns with depth. The anhysteretic remanence intensity-susceptibility ratio shows an inverse correlation to magnetic susceptibility, indicating varying concentration of fine grained single domain and superparamagnetic particles. The magnetic logs record diagenetic changes and magnetite authigenesis, with preserved recent and old dissolution zones marked by enriched single-domain/pseudo-singledomain/multi-domain magnetite in between the dissolution fronts. The oxidation/reduction processes relate to climatic and water/sediment interface factors controlling the dissolution processes, which occur in the Alfonso Basin anoxic conditions.

Asian monsoon modulation of nonsteady state diagenesis in hemipelagic marine sediments offshore of Japan

AbstractWe have identified millennial‐scale variations in magnetic mineral diagenesis from Pacific Ocean sediments offshore of Japan that we correlate with changes in organic carbon burial that were likely driven by Asian monsoon fluctuations. The correlation was determined by identifying offsets between the positions of fossil diagenetic fronts and climatically induced variations in organic carbon burial inferred from magnetic and geochemical analyses. Episodes of intense monsoon activity and attendant sediment magnetic mineral diagenesis also appear to correlate with Heinrich events, which supports the existence of climatic telecommunications between Asia and the North Atlantic region. Several lines of evidence support our conclusions: (1) fluctuations in down‐core magnetic properties and diagenetic pyrite precipitation are approximately coeval; (2) localized stratigraphic intervals with relatively stronger magnetic mineral dissolution are linked to enhanced sedimentary organic carbon contents that gave rise to nonsteady state diagenesis; (3) down‐core variations in elemental S content provide a proxy for nonsteady state diagenesis that correlate with key records of Asian monsoon variations; and (4) relict titanomagnetite that is preserved as inclusions within silicate particles, rather than secondary authigenic phases (e.g., greigite), dominates the strongly diagenetically altered sediment intervals and are protected against sulfidic dissolution. We suggest that such millennial‐scale environmental modulation of nonsteady state diagenesis (that creates a temporal diagenetic filter and relict magnetic mineral signatures) is likely to be common in organic‐rich hemipelagic sedimentary settings with rapidly varying depositional conditions. Our work also demonstrates the usefulness of magnetic mineral inclusions for recording important environmental magnetic signals.

Diagenetic disturbances of marine sedimentary records from methane‐influenced environments in the Fram Strait as indications of variation in seep intensity during the last 35 000 years

The effect of seeping of methane on marine sediment records has been studied in four gravity cores from Vestnesa Ridge, Svalbard margin. The area shows acoustic signs in the form of flares indicating active methane gas seepage. For a better understanding of the timing and variability of the flux of methane in the past and the effects on potential proxies, a detailed study of the diagenetic processes that may affect the composition and structure of both sediments and foraminiferal shells is needed. Here we discuss deep‐sea records from methane‐influenced environments in three cores from an active and very heterogeneous seep‐area (pockmark) and one core from outside the pockmark for background. The results include the distribution and stable isotopes of authigenic carbonates and of benthic and planktonic foraminifera, magnetic susceptibility, AMS‐14C dates, sedimentary data and biostratigraphy. Extremely low δ13C values recorded in both benthic and planktonic foraminifera during the Bølling‐Allerød interstadials indicate possible increased methane flux beginning at late Heinrich event H1. The recorded low values are mainly a result of diagenetic overprint by methane‐derived authigenic carbonates. The δ18O signals of authigenic carbonates are close to those of foraminiferal calcite and thus the δ18O records remain a valid stratigraphical tool in methane seep sites, except in the case of severely encrusted samples. In addition, the records from the active pockmark show nearly constant values of low magnetic susceptibility in contrast to higher and more variable magnetic susceptibility values from the control station and other published records from normal sediments west of Svalbard. This phenomenon is probably caused by dissolution of magnetic minerals in the reducing environmental conditions of methane seep sediments, associated with anaerobic oxidation of methane and formation of paramagnetic minerals (pyrite). This process enables magnetic susceptibility to be used as a common diagnostic tool for identifying methane‐related palaeo‐reductive environments.

Rock Magnetism of the Offshore Sediments of Lake Qinghai in the Western China

Lake Qinghai is the largest lake in China and situated in an important climate-sensitive zone on the northeastern margin of the Tibetan Plateau, making it an ideal place to study the environmental evolution of the northwest China as well as the interplay between the Asian monsoon and the westerlies in late Quaternary. In this study, detailed rock magnetic measurements were carried out on the offshore soils of Lake Qinghai. The dry grassland samples have higher magnetic susceptibility than that of the wet grassland samples, which suggests a higher concentration of magnetic minerals in the dry grassland and lower concentration of magnetic minerals in the wet grassland near the lake edge. The high concentration of the superparamagnetic (SP) magnetic minerals related to pedogenesis may also contribute to the high magnetic susceptibility of the dry grassland. The low magnetic susceptibility of the wet grassland may result from the conversion of strongly to weakly magnetic minerals and/or the dissolution of magnetic minerals. In addition, the Hm/(Gt+Hm) value has a positive correlation with the water content, thus can be taken as an effective proxy for the soil moisture.

The magnetic record of inorganic fly ash deposition in lake sediments and ombrotrophic peats

Interest in identifying a geological marker signifying the starting point for the Anthropocene has prompted an exploration of the stratigraphic record of inorganic particulates generated by industrial activities. Magnetic measurements of recent lake sediments and ombrotrophic peats are here used to reconstruct the history of deposition of inorganic fly-ash spheres resulting mainly from solid fuel combustion and metal smelting. The chronologies used have been based on moss-increment counting, radioisotope dating and pollen analysis. The sites come from the United Kingdom, Scandinavia and North America. In several cases where detailed chronologies of both fly-ash deposition and local industry can be compared, the sequence of concentration-linked magnetic measurements appears to capture accurately the record of industrial development despite incontrovertible evidence from other peat-based records for some selective dissolution of magnetic minerals. The dates at which magnetic concentration increases begin range from the 16th century in the peat profiles around the head of Morecambe Bay, South Cumbria, in North-West England where early iron manufacture using charcoal-fuelled bloomery hearths is well documented, to the mid-20th century at the remotest sites in Arctic Scandinavia. The lake sediment profiles used here come mainly from the United Kingdom and, in most cases, they date increases to the late 19th century or the first decades of the 20th century. Any attempt to use the magnetic record of fly-ash deposition in lake sediments and/or peats to mark the date chosen as the onset of the Anthropocene would require careful choice of site location and archive, bearing in mind the issue of selective magnetic mineral dissolution.

Can the magnetic signatures from inorganic fly ash be used to mark the onset of the Anthropocene?

Three possible candidates are considered as markers in lake sediments and peat for the onset of the Anthropocene. The artificial radioisotopes Americium 241 and Caesium 137, as well as Spherical Carbonaceous Particles, the by-product of fossil fuel combustion, are considered only briefly. They are possible markers for the onset of the Great Acceleration in the mid 20th century. More attention is given to Inorganic Ash Spheres which are mainly by-products of solid fuel combustion, iron and steel manufacture and metal smelting. Their changing contributions to the stratigraphic record can be detected by means of magnetic measurements. The date at which the deposition of inorganic fly ash is recorded varies from the 16th to the mid 20th centuries, depending mainly on location. In evaluating the prospects for using the magnetic record in recent peat and lake sediments as a marker for the start of the Anthropocene, special attention is given to the importance of developing and testing chronologies of deposition, the choice of appropriate locations and the problems posed by dissolution of magnetic minerals over time especially in acid peat.

Diagenesis of magnetic minerals in a gas hydrate/cold seep environment off the Krishna–Godavari basin, Bay of Bengal

We carried out detailed magnetic measurements of the core (MD161/8) located in the vicinity of Site NGHP-01-10, where ~128 m of hydrate is confirmed by drilling/coring, to understand the diagenesis of magnetic minerals in a gas hydrates/cold seep environment. The rock magnetic measurements along with SEM-EDS and XRD analyses show a zone of reduced magnetic susceptibility (zone 2) where most of the magnetic minerals are dissolved. The enhanced concentration of chromium reducible sulfur (CRS) in this zone suggests an intense pyritization process while isotopically depleted authigenic carbonates indicate sulfate reduction via anaerobic oxidation of methane (AOM). Therefore, the dissolution of magnetic minerals is attributed to the HS - released during AOM that has resulted in the reduction in the magnitude of magnetic parameters. Within zone 2, a zone of enhanced susceptibility (zone 2a) is observed between 17.68 and 23.6 mbsf, and is located beneath the present day sulfate-methane transition zone (SMTZ). The frequencydependent magnetic susceptibility and low temperature magnetic measurements suggest the abundance of fine grained superparamagnetic (SP) sized ferrimagnetic particles. The SEM-EDS and XRD analyses show the presence of greigite which occurs in interstices between the pyrite crystals. Such occurrence of greigite in sediments has important implications in the interpretation of paleomagnetic records. We evaluated the likely mechanism for the greigite formation in KG offshore basin and our data suggest that the formation of greigite may be related to either paleo-SMTZ or anaerobic oxidation of pyrite. It is unlikely that the formation of greigite can be explained by the downward diffusion of sulfide below the current depth of SMTZ. However, further investigations are required to ascertain the mechanism for the

Mineral magnetic studies of the vermiculated red soils in southeast China and their paleoclimatic significance

Vermiculated red soil, the main pedostratigraphical unit of the red soil sequences widespread in subtropical and tropical China, has experienced a higher degree of pedogenesis than loess/paleosols and the underlying red clays in the Loess Plateau of northern China. Previous studies suggested that magnetic properties of the vermiculated units of the red soils are significantly degraded compared to those of the non-vermiculated counterparts. The mechanism for this magnetic decrease, however, has not been well determined. In order to resolve this problem, this study has investigated two red soil sequences of different origin in southeast China by integrating environmental and mineral magnetic research. The results show that the magnetic depletion in the vermiculated units was probably caused by both dissolution of magnetic minerals in the white veins and transformation of highly magnetic maghemite to weakly magnetic hematite. It appears that stronger pedogenesis favors the transformation of more maghemite to hematite and magnetic properties associated with the relative concentration of maghemite to hematite can be used as climate indicator in the vermiculated red soils. The variation trends of the magnetic parameters of the vermiculated red soils prior to 0.85–0.9Ma suggest a strengthening of the East Asian summer monsoon. The reverse trend of these parameters after 0.85–0.9Ma may correlate with a significant strengthening of the East Asian winter monsoon since 0.85Ma.

Interplay between detrital and diagenetic processes since the last glacial maximum on the northwest Iberian continental shelf

Integrated analyses of magnetic, geochemical and textural data on six cores from the northwestern Iberian continental shelf allowed the reconstruction of the paleoenvironmental evolution of this area since the last glacial maximum (LGM). Four sedimentary units were identified, representing a succession from fluvial and subaerial settings to high and finally low-energy marine deposits subsequent to the post-LGM sea-level rise. The uppermost unit was deposited during the Holocene and its magnetic properties were controlled by the interplay between detrital input and early diagenetic reductive dissolution of magnetic minerals. Identification of a primary steady-state early diagenetic signal allowed the recognition of periods of increased detrital input, bounded by intervals of lower detrital input and intensified reductive diagenesis related to intensified upwelling in the area. These paleoenvironmental alternations are consistent with the climatic evolution of the late Holocene. During the Roman Warm Period and Medieval Warm Period, the combined effect of greater humidity and intense agricultural and mining activities led to a greater erosion and transport of detrital sediments to the shelf. In contrast, enhanced diagenetic reduction intervals, caused by upwelling intensification, were roughly coincident with the colder Dark Ages and the Little Ice Age.

OBSERVATIONS OF MAGNETITE DISSOLUTION IN POORLY DRAINED SOILS

Dissolution of strongly magnetic minerals is a common and relatively rapid phenomenon in poorly drained soils of the central United States, resulting in low magnetic susceptibility (MS). Low Eh reducing conditions are primarily responsible for magnetic mineral dissolution; a process likely mediated

Rock-magnetic changes with reduction diagenesis in Japan Sea sediments and preservation of geomagnetic secular variation in inclination during the last 30,000 years

A rock-magnetic and paleomagnetic study was conducted on a sediment core of about 4.4 m long taken from the northeastern part of the Japan Sea. The core covers the last about 30 kyrs, which was dated by nineteen radiocarbon (14C) ages. Remanent magnetization is carried dominantly by magnetite. Reductive dissolution of magnetic minerals occurs between 1.2 and 1.6 m in depth (about 5–8 ka in age). A rapid downcore decrease of anhysteretic remanent magnetization (ARM) begins at the shallowest depth. Saturation isothermal remanent magnetization (SIRM) follows, and a decrease of magnetic susceptibility (k) takes place at the deepest. Within this zone, coercivity of natural remanent magnetization (NRM) and the ratios of ARM to k and SIRM to k also decreases with depth. These observations indicate that finer magnetic grains were lost earlier than larger grains. A decrease of S ratios, wasp-waisted hysteresis curves, and a deviation from a mixing trend of single-domain and multi-domain grains in a Day plot occur as the dissolution proceeds, which suggests that high coercivity minerals like hematite are more resistive to dissolution than low coercivity minerals like magnetite. The start of the dissolution at 1.2 m in depth is synchronous with increases in organic-carbon and total-sulfur contents, but the horizon does not coincide with the present Fe-redox boundary at about 0.02 m below the sediment-water interface. From low-temperature magnetometry, it is estimated that magnetites with maghemite skin are reduced to pure magnetites prior to dissolution. There is no evidence for precipitation of secondary magnetic phases and acquisition of chemical remanent magnetization (CRM). Neither pyrrhotite nor greigite was detected. Information of paleomagnetic directions have survived the reductive dissolution. Inclination variations of this core resembles closely to the secular variation records available around Japan. Well-dated records older than 10 ka are still very rare, and hence our new record could be useful for establishing regional secular variations.

Selective dissolution of magnetic iron oxides in the acid-ammonium oxalate/ferrous iron extraction method-I. Synthetic samples

SUMMARY In soil magnetism, the magnetic parameters alone are not always sufficient to distinguish the lithogenic from the pedogenic magnetic fractions. Sequential extraction techniques have therefore been incorporated into magnetic studies to constrain the environmental interpretation. Here we report on the dissolution behaviour of magnetite and maghemite in the acid‐ammonium oxalate method to see whether the method is suitable for specific dissolution of magnetic minerals from soils and sediments. To prevent changes in the extraction mechanism during the experiments (see Appendix A), we used an adapted version of the acid‐ammonium oxalate (AAO) method, in which Fe 2+ is added to the extraction solution prior to the experiment [the AAO-Fe(II) method]. The procedure was divided into several 30 min extraction steps to check the dissolution progress. Synthetic samples containing a quartz matrix with 0.1 wt per cent of iron oxides were extracted with the AAO-Fe(II) method. The iron oxides consisted of either magnetite or maghemite with grain sizes of <0.5 mm (fine grained or SD/PSD) and <5 mm (coarse grained or MD/PSD), or a 1 : 1 mixture of both minerals. Because only magnetite and maghemite were studied, the changes in magnetic characteristics could be monitored after each extraction step by analysis of the bulk susceptibility and hysteresis parameters measured at room temperature. The AAO-Fe(II) method preferentially dissolved the smaller iron oxides from the samples. For samples containing iron oxides with coarse grain size there is a preference for dissolving maghemite rather than magnetite. Extractions of the samples containing mixtures of two different grain sizes or with different mineralogy show that the method preferentially dissolves the smaller grains before attacking the coarse grains in the sample.