Dissipative Processes Research Articles

Experimental and MD simulation study of surface residual stress and surface quality of SiCp/Al in pulsed laser-ultrasonic assisted grinding

The utilisation of aluminium-based silicon carbide composites (SiCp/Al) is on the rise. However, during the grinding process, where abrasive particles compel SiC particles into the aluminium matrix, stress concentration occurs near the interface between the two phases. This phenomenon results in adverse surface deformation accompanied by residual compressive stress (RCS). Consequently, a pulsed laser-ultrasonic-assisted grinding method (PL-UAG) has been proposed. The effectiveness of the method is verified through grinding experiments. Moreover, the influence process of the thermal effect of pulsed laser and the evolution mechanism of microscopic RS near the SiCp/Al two-phase interface are revealed through molecular dynamics simulation. The experimental results show that the surface RCS of SiCp/Al gradually decreases and transforms into residual tensile stress (RTS) with the increase of laser power. The RCS increases with the grinding depth. The RCS is reduced to 17 Mpa and the surface roughness Sa value is reduced to 0.110 μm with the laser power is 40 W and the grinding depth is 1 μm. The simulation results show that the energy dissipation process of pulsed laser helps to reduce thermal deformation and damage. The laser-induced thermal effect reduces the deformation of the aluminium matrix caused by particle extrusion and inhibits the formation and slip of dislocations in the aluminium matrix. In addition, the ultrasonic shock effect effectively weakens the RTS generated by the laser.

Energy Dissipation of Fast Electrons in Polymethylmethacrylate: Toward a Universal Curve for Electron-Beam Attenuation in Solids between ∼0 eV and Relativistic Energies.

Spectroscopy of correlated electron pairs was employed to investigate the energy dissipation process, as well as the transport and the emission of low-energy electrons on a polymethylmethacrylate surface, providing secondary electron spectra causally related to the energy loss of the primary. Two groups are identified in the cascade of slow electrons, corresponding to different stages in the energy dissipation process. The characteristic lengths for attenuation due to collective excitations and momentum relaxation are quantified for both groups and are found to be distinctly different: λ_{1}=(12±2) Å and λ_{2}=(62±11) Å. The results strongly contradict the commonly employed model of exponential attenuation with the electron inelastic mean free path as characteristic length, but they essentially agree with a theory used for decades in astrophysics and neutron transport, albeit with characteristic lengths expressed in units of angstroms rather than light-years.

Transfer film formation and dissipation and its effect on friction coefficient in NAO friction materials containing FeS2 lubricant

PurposeThe purpose of this study is to investigate the accumulation process of transfer film formation and dissipation and its effect on friction coefficients in non asbestos organic friction materials with various lubricant FeS2 contents.Design/methodology/approachIn total, 2.5%, 5% and 10% FeS2 were added as lubricating components to the friction materials. Friction tests composed of two stages were conducted for these friction materials, and the friction surfaces of the counterpart discs were examined using scanning electron microscopy.FindingsThe transfer film formation reduced the friction coefficients, and the transfer film dissipation influenced the recovery of the friction coefficients. The effect of a high content of FeS2 was to promote the transfer film formation at high temperatures and to hinder the transfer film dissipation at low temperatures, thus resulting in a decrease in the friction coefficients at high temperatures together with recovery retardation at low temperatures.Originality/valueFeS2 contributed to the transfer film formation at high temperatures in the fade test but hindered the transfer film removal in the recovery test, resulting in the retardation of friction coefficient recovery. The mechanism by which the FeS2 lubricant component affected the transfer film formation and dissipation was analyzed and attributed to the different levels of FeS2 pyrolysis at different temperature levels.

EPR Spin-Trapping for Monitoring Temporal Dynamics of Singlet Oxygen during Photoprotection in Photosynthesis.

A central goal of photoprotective energy dissipation processes is the regulation of singlet oxygen (1O2*) and reactive oxygen species in the photosynthetic apparatus. Despite the involvement of 1O2* in photodamage and cell signaling, few studies directly correlate 1O2* formation to nonphotochemical quenching (NPQ) or lack thereof. Here, we combine spin-trapping electron paramagnetic resonance (EPR) and time-resolved fluorescence spectroscopies to track in real time the involvement of 1O2* during photoprotection in plant thylakoid membranes. The EPR spin-trapping method for detection of 1O2* was first optimized for photosensitization in dye-based chemical systems and then used to establish methods for monitoring the temporal dynamics of 1O2* in chlorophyll-containing photosynthetic membranes. We find that the apparent 1O2* concentration in membranes changes throughout a 1 h period of continuous illumination. During an initial response to high light intensity, the concentration of 1O2* decreased in parallel with a decrease in the chlorophyll fluorescence lifetime via NPQ. Treatment of membranes with nigericin, an uncoupler of the transmembrane proton gradient, delayed the activation of NPQ and the associated quenching of 1O2* during high light. Upon saturation of NPQ, the concentration of 1O2* increased in both untreated and nigericin-treated membranes, reflecting the utility of excess energy dissipation in mitigating photooxidative stress in the short term (i.e., the initial ∼10 min of high light).

In-situ rock shattering and strain localization along a seismogenic fault in dolostones (Monte Marine fault, Italian Central Apennines)

In-situ shattered rocks are often associated with seismogenic fault zones, but their mechanism of formation is still matter of debate, partly because of the limited number of field studies. Here we describe the characteristics of in-situ shattered rocks distribution along the NW-SE-striking seismogenic Monte Marine Fault (MMF) in the Italian Central Apennines. In the studied area, the MMF cuts through Mesozoic carbonates, is exhumed from <3 km depth and consists of two >5 km-long major hard-linked segments with normal kinematics. The linkage between the two fault segments occurs along a ∼2 km-long step-over zone with E-W trending faults and oblique-slip kinematics. To the northwest, fault-related shear deformation is localized in a ∼5 m-thick cataclastic fault core and off-fault deformation is dominated by in-situ shattered rocks up to ∼40 m-thick. Instead, in the step-over zone to the southeast, the in-situ shattered rocks are up to ∼500 m thick, particularly where MMF crosscuts older low-angle thrust faults.We integrated detailed field structural surveys with microstructural and grain size distribution analyses of the fault rocks to assess the mechanism of (1) formation of in-situ shattered rocks and, (2) progressive localization of shear deformation along the MMF. The obtained results, after the viability of several formation mechanisms (mechanical models) have been reviewed, support the hypothesis that the formation of in-situ shattered rocks was associated with the propagation of (multiple) seismic ruptures (mainshocks and aftershock sequences) within a mechanically heterogeneous fault zone. Heterogeneity is due to the occurrence of preexisting damage related to previous earthquakes, but also inherited from the older low-angle thrust faults. Therefore, we suggest that the origin of these shattered rocks is more compatible with seismic related processes than only with quasi-static fault growth models. On the other hand, the cataclastic fault core derived from the progressive accommodation of shear deformation within the in-situ shattered rock volumes during several seismic cycles. We conclude that the large volumes of in-situ shattered rocks are the result of seismic-related dissipative processes in a geometrically and mechanically heterogeneous fault zone. In this scenario, large volumes of in-situ shattered rocks are compliant low velocity zones which can influence the propagation of earthquake ruptures.

Stepwise Dissipative Control of Multimodal Motion in a Silver(I) Catenate

AbstractStepwise dissipative control of two distinct motions, i.e., shuttling and sliding, is demonstrated in a single multicomponent device. When [2]rotaxane 1, which acts as a biped, and deck 2 were treated with AgBF4/PhCH2Br+NEt3 as chemical fuel, the transient catenate [Ag(1)]+ ⋅ [Ag3(2)]3+ was instantly generated showing multimodal motion and autonomous return to 1 and 2. In the dissipative process, catenate [Ag(1)]+ ⋅ [Ag3(2)]3+ cleanly transformed into the follow‐up transient device (1) ⋅ [Ag3(2)]3+ exhibiting only sliding motion. Two interference‐free dissipative cycles proved the resilience and robustness of the process.

Stepwise Dissipative Control of Multimodal Motion in a Silver(I) Catenate.

Stepwise dissipative control of two distinct motions, i.e., shuttling and sliding, is demonstrated in a single multicomponent device. When [2]rotaxane 1, which acts as a biped, and deck 2 were treated with AgBF4/PhCH2Br+NEt3 as chemical fuel, the transient catenate [Ag(1)]+ ⋅ [Ag3(2)]3+ was instantly generated showing multimodal motion and autonomous return to 1 and 2. In the dissipative process, catenate [Ag(1)]+ ⋅ [Ag3(2)]3+ cleanly transformed into the follow-up transient device (1) ⋅ [Ag3(2)]3+ exhibiting only sliding motion. Two interference-free dissipative cycles proved the resilience and robustness of the process.

Mechanism of tartaric acid mediated dissipation and biotransformation of tetrabromobisphenol A and its derivatives in soil

Biotransformation is a major dissipation process of tetrabromobisphenol A and its derivatives (TBBPAs) in soil. The biotransformation and ultimate environmental fate of TBBPAs have been widely studied, yet the effect of root exudates (especially low-molecular weight organic acids (LMWOAs)) on the fate of TBBPAs is poorly documented. Herein, the biotransformation behavior and mechanism of TBBPAs in bacteriome driven by LMWOAs were comprehensively investigated. Tartaric acid (TTA) was found to be the main component of LMWOAs in root exudates of Helianthus annus in the presence of TBBPAs, and was identified to play a key role in driving shaping bacteriome. TTA promoted shift of the dominant genus in soil bacteriome from Saccharibacteria_genera_incertae_sedis to Gemmatimonas, with a noteworthy increase of 24.90–34.65% in relative abundance of Gemmatimonas. A total of 28 conversion products were successfully identified, and β-scission was the principal biotransformation pathway for TBBPAs. TTA facilitated the emergence of novel conversion products, including 2,4-dibromophenol, 3,5-dibromo-4-hydroxyacetophenone, para-hydroxyacetophenone, and tribromobisphenol A. These products were formed via oxidative skeletal cleavage and debromination pathways. Additionally, bisphenol A was observed during the conversion of derivatives. This study provides a comprehensive understanding about biotransformation of TBBPAs driven by TTA in soil bacteriome, offering new insights into LMWOAs-driven biotransformation mechanisms.

Dissipative potential flow models and energy evolution characteristics for curtain-wall caisson breakwaters under wave action

Curtain-wall caisson breakwaters are a kind of coastal protection structure, which is composed of semi-submersible vertical thin curtain walls, a rear vertical caisson, and wave chambers formed by the curtain walls and rear caisson. When water waves interact with the curtain-wall caisson breakwater, the wave energy may be partially dissipated owing to the flow separation and vortex formation near the edges of curtain walls. The conventional potential flow solution without considering wave energy dissipation gives unreasonable results of full wave reflection by the curtain-wall caisson breakwater. To address this issue, this study develops a dissipative potential flow model for predicting the hydrodynamic performance of the curtain-wall caisson breakwaters. The wave energy dissipation near the breakwater is considered by introducing a quadratic pressure loss condition at the entrances of wave chambers. By adopting appropriate dimensionless dissipation coefficients, the analytical predictions of the reflection coefficient and the wave amplitude inside chambers are in good agreement with published experimental results. The differences in the hydrodynamic quantities predicted by the dissipative and conventional potential flow solutions are examined, and further discussion based on the dissipative analytical solution is performed. Moreover, viscous numerical simulations based on a meshless particle method are carried out to clarify the characteristics of wave energy evolution, wave energy dissipation, and local fluid motion near the curtain-wall caisson breakwaters. The results show that the front curtain wall plays the leading role in the wave energy dissipation process of the whole double-chamber curtain-wall breakwater.

Non‐conservation and conservation for different formulations of moist potential vorticity

AbstractPotential vorticity (PV) is one of the most important quantities in atmospheric science. In the absence of dissipative processes, the PV of each fluid parcel is known to be conserved, for a dry atmosphere. However, a parcel's PV is not conserved if clouds or phase changes of water occur. Recently, PV conservation laws were derived for a cloudy atmosphere, where each parcel's PV is not conserved but parcel‐integrated PV is conserved, for integrals over certain volumes that move with the flow. Hence a variety of different statements are now possible for moist PV conservation and non‐conservation, and in comparison to the case of a dry atmosphere, the situation for moist PV is more complex. Here, in light of this complexity, several different definitions of moist PV are compared for a cloudy atmosphere. Numerical simulations are shown for a rising thermal, both before and after the formation of a cloud. These simulations include the first computational illustration of the parcel‐integrated, moist PV conservation laws. The comparisons, both theoretical and numerical, serve to clarify and highlight the different statements of conservation and non‐conservation that arise for different definitions of moist PV.

Understanding earthquake precursors: from subcritical instabilities to catastrophic events

The collapse of man-made and natural structures is a complex phenomenon that has been studied for centuries. Existing models often focus on a ‘critical point’ where failure becomes imminent. This work presents a radically different perspective: large earthquakes may not arise from critical states, but instead develop dynamically from the subcritical regime as rare, extreme events. Our approach hinges on an extension of Onsager’s reciprocal theorem, allowing us to delve into this subcritical realm. We demonstrate that within such a regime, excitable systems, like those underlying earthquakes, are dynamically renormalised towards a nonlocal equilibrium. For these systems, the maximum entropy production of at least two interacting phases is used to replace the local equilibrium assumption for the subcritical state. Typically, dissipative processes at larger scales arrest these self-amplifying feedbacks. However, in rare instances, they can morph into intricate tensor networks of instabilities that ripple from microscopic scales to the entire system, culminating in an extreme event like a catastrophic earthquake. This novel framework offers a potentially deeper understanding of earthquake precursors and paves the way for exploring earthquake prediction based on the statistics of subcritical dynamics.

Surface State Dissipation in Confined ^{3}He-A.

We have studied the power dependence of superfluid Helmholtz resonators in flat (750 and 1800nm) rectangular channels. In the A phase of superfluid ^{3}He, we observe a nonlinear response for velocities larger than a critical value. The small size of the channels stabilizes a static uniform texture that eliminates dissipative processes produced by changes in the texture. For such a static texture, the lowest velocity dissipative process is due to the pumping of surface bound states into the bulk liquid. We show that the temperature dependence of the critical velocity observed in our devices is consistent with this surface-state dissipation. Characterization of the force-velocity curves of our devices may provide a platform for studying the physics of exotic surface bound states in superfluid ^{3}He.

Ultrafast piezocapacitive soft pressure sensors with over 10 kHz bandwidth via bonded microstructured interfaces

Flexible pressure sensors can convert mechanical stimuli to electrical signals to interact with the surroundings, mimicking the functionality of the human skins. Piezocapacitive pressure sensors, a class of most widely used devices for artificial skins, however, often suffer from slow response-relaxation speed (tens of milliseconds) and thus fail to detect dynamic stimuli or high-frequency vibrations. Here, we show that the contact-separation behavior of the electrode-dielectric interface is an energy dissipation process that substantially determines the response-relaxation time of the sensors. We thus reduce the response and relaxation time to ~0.04 ms using a bonded microstructured interface that effectively diminishes interfacial friction and energy dissipation. The high response-relaxation speed allows the sensor to detect vibrations over 10 kHz, which enables not only dynamic force detection, but also acoustic applications. This sensor also shows negligible hysteresis to precisely track dynamic stimuli. Our work opens a path that can substantially promote the response-relaxation speed of piezocapacitive pressure sensors into submillisecond range and extend their applications in acoustic range.

Thermal tides in neutrally stratified atmospheres: Revisiting the Earth’s Precambrian rotational equilibrium

Rotational dynamics of the Earth, over geological timescales, have profoundly affected local and global climatic evolution, probably contributing to the evolution of life. To better retrieve the Earth’s rotational history, and motivated by the published hypothesis of a stabilized length of day during the Precambrian, we examined the effect of thermal tides on the evolution of planetary rotational motion. The hypothesized scenario is contingent upon encountering a resonance in atmospheric Lamb waves, whereby an amplified thermotidal torque cancels out the opposing torque generated by the oceans and solid interior, driving the Earth into rotational equilibrium. With this scenario in mind, we constructed an ab initio model of thermal tides on rocky planets describing a neutrally stratified atmosphere. The model takes into account dissipative processes with Newtonian cooling and diffusive processes in the planetary boundary layer. We retrieved, from this model, a closed-form solution for the frequency-dependent tidal torque, which captures the main spectral features previously computed using 3D general circulation models. In particular, under longwave heating, diffusive processes near the surface and the delayed thermal response of the ground prove to be responsible for attenuating, and possibly annihilating, the accelerating effect of the thermotidal torque at the resonance. When applied to the Earth, our model prediction suggests the occurrence of the Lamb resonance in the Phanerozoic, but with an amplitude that is insufficient for the rotational equilibrium. Interestingly, though our study was motivated by the Earth’s history, the generic tidal solution can be straightforwardly and efficiently applied in exoplanetary settings.

Skin transcriptome analysis in Brangus cattle under heat stress

Heat stress is a major factor that negatively affects animal welfare and production systems. Livestock should adapt to tropical and subtropical areas and to meet this, composite breeds have been developed. This work aimed to evaluate gene expression profiles in the skin of Brangus cattle under heat stress using a case-control design, and to correlate this with skin histological characteristics. Two groups of bulls were set using rectal temperature as a criterion to define stress conditions: stressed (N = 5) and non-stressed (N = 5) groups. Skin transcriptomics was performed and correlations between breed composition, phenotypic and skin histological traits were evaluated. Results showed 4309 differentially expressed genes (P < 0.01), 2113 downregulated and 2196 upregulated. Enrichment and ontology analyses revealed 132 GO terms and 67 pathways (P < 0.01), including thermogenesis, glycolysis, gluconeogenesis, mitochondrial activity, antioxidant and immune response, and apoptosis. The identity of the terms and pathways indicated the diversity of mechanisms directed to relieve the animals' suffering, acting from simple passive mechanisms (conduction, convection and radiation) to more complex active ones (behavioural changes, evaporation, vasodilation and wheezing). Furthermore, significant differences between phenotypic and skin histological traits and correlations between pairs of traits suggested a direction towards heat dissipation processes. In this sense, number of vessels was positively correlated with number of sweat glands (P < 0.001) and both were positively correlated with zebuine genetic content (P < 0.05 and P < 0.01, respectively), gland size was positively correlated with epidermal thickness and negatively with hair length (P < 0.05), and epidermal thickness was negatively correlated with gland-epidermis distance (P < 0.0005). These results support the notion that response to heat stress is physiologically complex, producing significant changes in the expression of genes involved in several biological pathways, while the animal's ability to face it depends greatly on their skin features.

An atomistic study of sticking, bouncing, and aggregate destruction in collisions of grains with small aggregates

Molecular dynamics simulations are used to study central collisions between spherical grains and between grains and small grain aggregates (up to 5 grains). For a model material (Lennard-Jones), grain–grain collisions are sticking when the relative velocity v is smaller than the so-called bouncing velocity and bouncing for higher velocities. We find a similar behavior for grain–aggregate collisions. The value of the bouncing velocity depends only negligibly on the aggregate size. However, it is by 35% larger than the separation velocity needed to break a contact; this is explained by energy dissipation processes during the collision. The separation velocity follows the predictions of the macroscopic Johnson–Kendall–Roberts theory of contacts. At even higher collision velocities, the aggregate is destroyed, first by the loss of a monomer grain and then by total disruption. In contrast to theoretical considerations, we do not find a proportionality of the collision energy needed for destruction and the number of bonds to be broken. Our study thus sheds novel light on the foundations of granular mechanics, namely the energy needed to separate two grains, the difference between grain–grain and grain–aggregate collisions, and the energy needed for aggregate destruction.

Energy evolution mechanism of structural surfaces in sandstones with different dips based on the energy principle.

A uniaxial compression test was conducted on sandstone specimens at various inclination angles to determine the energy evolution characteristics during deformation and damage. Based on the principle of minimum energy dissipation, an intrinsic model incorporating the damage threshold was developed to investigate the mechanical properties of sandstone at different inclination angles, and the energy damage evolution during deformation and damage. This study indicated that when the inclination angle of the structural surface remained below 40°, sandstone exhibited varying mechanical properties based on different inclination angles. The peak strain was positively correlated with the inclination angle, whereas the compressive strength and modulus of elasticity showed negative correlations. From an energy perspective, the deformation and damage of sandstone under external loading entail processes of energy input, accumulation, and dissipation. Moreover, higher inclination angles of the structural surface resulted in a smaller absorbed peak strain and a reduced proportion of dissipated energy relative to the energy input, thereby affecting the evolution of energy damage throughout the process. As the inclination angle of the structural surface increased, the absorbed total strain at the peak value decreased, whereas the proportion of the dissipated energy increased. Additionally, the damage threshold and critical value of the rock specimens increased with the inclination angle. The critical value, a composite index comprising the peak strain, compressive strength, and elastic modulus, also increased accordingly. These findings can offer a novel perspective for analyzing geological disasters triggered by fissure zones within underground rock formations.

Marangoni Convection Velocity in Nonlinear Hanging-Droplet Vibration Phenomena

The Marangoni effect involves a mass transfer along an interface between two phases owing to the gradient of the interfacial tension. The flow caused by this phenomenon is called Marangoni convection, a complex phenomenon that involves mass transfer processes, such as surfactant adsorption/desorption processes, solvent dissolution phenomena, and viscous dissipation processes. Therefore, the strength of the convection depends on the various thermodynamic and physical properties of the fluids. In this study, we experimentally investigated the relationship between the Marangoni convection generated inside a hanging oil droplet and the interfacial tension of the oil droplet in an aqueous phase by the particle image velocimetry method. This convection velocity depended on the initial value of the interfacial tension in the oil–water interfacial tension oscillation phenomenon accompanied by the expansion and contraction of the hanging drop. Additionally, the droplet oscillation frequency decreased as the Marangoni convection velocity increased. Furthermore, continuous convection, which is unlike Marangoni convection, was observed within this spontaneously expanding and contracting hanging-droplet system. This buoyant convection was caused by the mutual dissolution of the hanging-droplet oil phase and the surrounding aqueous phase.

How Variable Are Cold Pools?

AbstractCold pools formed by precipitating convective clouds are an important source of mesoscale temperature variability. However, their sub‐mesoscale (100 m–10 km) structure has not been quantified, impeding validation of numerical models and understanding of their atmospheric and societal impacts. We assess temperature variability in observed and simulated cold pools using variograms calculated from dense network observations collected during a field experiment and in high‐resolution case‐study and idealized simulations. The temperature variance in cold pools is enhanced for spatial scales between ∼5 and 15 km compared to pre‐cold pool conditions, but the magnitude varies strongly with cold pool evolution and environment. Simulations capture the overall cold pool variogram shape well but underestimate the magnitude of the variability, irrespective of model resolution. Temperature variograms outside of cold pool periods are represented by the range of simulations evaluated here, suggesting that models misrepresent cold pool formation and/or dissipation processes.

Wetting dynamics and adhesion of polyether ether ketone

Better understanding of how thermoplastics like polyether ether ketone (PEEK) spread on fiber surfaces within a composite, or themselves during fused filament fabrication is crucial for high-quality part production. Yet, due to its high melting temperature, the properties of molten PEEK have been rarely investigated. In this study, the viscosity, surface tension, and spreading dynamic behavior of molten PEEK on different substrates (glass, silicon wafer, and steel) were systematically explored. The analysis of the contact angle dynamics showed that both the classical hydrodynamics approach (HD) and molecular-kinetic theory (MKT) could model the experimental data satisfactorily. The relative contribution of the viscosity, as depicted by the MKT, to the energy dissipation process was found to dominate the contact-line friction contribution. In addition, a good agreement was found when calculating the physical work of adhesion between PEEK and the substrates in three different ways: at high temperatures (molten state), at room temperature (solid state), and using a combination of both states. This is a promising result indicating that the bonding ability of PEEK during processing could be predicted by characterizing its surface properties in the solid state.