Continuous Phase Research Articles

A Polarization‐Insensitive and Adaptively‐Blazed Meta‐Grating Based on Dispersive Metasurfaces

AbstractThe diffraction efficiency of blaze gratings is optimized only at a specific frequency due to a fixed blaze angle, resulting in reduced and variable diffraction efficiencies over the working frequency band. Additionally, blazed gratings demonstrate polarization dependence due to their groove structures and the interaction of light with their surfaces. Consequently, designing gratings with constant diffraction efficiencies across a wide frequency bandwidth while maintaining polarization independence remains a challenge. Here, a design paradigm of dispersion engineerable meta‐grating inspired by orthogonal harmonic oscillations (OHO) is presented. Utilizing the OHO model, the phase dispersion of a metasurface can be precisely controlled, which applies to any unit cell featuring two orthogonal electromagnetic resonances. As a proof of concept, a polarization‐insensitive meta‐grating is showcased, where the blazed angle adapts with the incident frequency, ensuring broadband performance. In the experiment, the adaptively‐blazed grating measured an optimized and constant diffraction efficiency of ≈80% over the working wavelength range, i.e., 8.7–12.2 µm. The difference in diffraction efficiency between the two perpendicular linear polarization states remains within 4.6%. The proposed paradigm paves the way for meta‐device design based on precise dispersion engineering, which has potential applications in spectrometers, broadband beam forming and steering, hyperspectral imaging, etc.

MATHEMATICAL MODELING OF THE PROCESS OF SEPARATION OF MIXTURES BY LIQUID EXTRACTION

While designing liquid-phase extraction processes, one of the main conditions is to determine the kinetic characteristics of the exchange processes necessary to determine the flows and masses of the components. Existing mass transfer models describe mass transfer processes on a semi-empirical and empirical basis with a limited range of applications, simplifying the real picture in most cases. In this regard, the development of models that more widely describe the processes of liquid-phase extraction and allow their application is considered one of the important tasks. Based on the generalization of the Chilton-Colborne hydrodynamic analogy in gradient flows and further development of the Landau-Levich boundary layer model, a mathematical model has been developed to determine the mass transfer coefficients in the extraction process in continuous and dispersed phases using minimal experimental data obtained at the stage of hydrodynamic studies

Jammed Pickering Emulsion Gels.

Emulsion gels with specific rheological properties have widespread applications in foods, cosmetics, and biomedicines. However, the constructions of water-in-oil emulsion gels are still challenging, due to the limited interactions available in the continuous oil phase. Here, a versatile strategy is developed to prepare a new type of emulsion gels, called Jammed Pickering emulsion gels (JPEGs). In the JPEG system, SiO2 NPs in the oil phase serve as colloidal surfactants to stabilize water-in-oil Pickering emulsions, while positively-charged NH2-PEG-NH2 molecules in the water phase cross-link negatively-charged SiO2 NPs at the water/oil interface, making NP-stabilized water droplets hard to deform and thus jamming the emulsion system to form emulsion gels. The strategy to prepare JPEGs is versatile and applicable to diverse oil phases. The designed JPEGs possess many advantages, including good biocompatibility for widespread applications, shear-thinning rheological properties for easy processing, good stability Over a wide temperature range and Against centrifugation, good adhesion to wet tissues for tissue engineering, and well-controlled sustained release Under intestinal conditions. The developed JPEGs are demonstrated to be a promising delivery platform and the strategy to achieve JPEGs will trigger more innovations of material design.

Modified Abelian and SU(2) Wilson theories on a lattice from a noncompact regularization

Multiflavor gauge theories of matter systems on a three-dimensional lattice have recently been widely investigated especially in connection with a possible symmetry enlargement at a continuous phase transition. Abelian models were studied both with compact gauge fields and in a mixed formulation in which the coupling with matter fields is in compact form while the gauge fields Lagrangian is written in terms of noncompact gauge fields, getting quite different results. Such a mixed formulation is not permissible for non-Abelian theories, for which however there exists an entirely noncompact formulation (in which exact gauge invariance is enforced by help of auxiliary fields), which for SU(2) was shown to yield in the scaling window a larger physical volume than Wilson’s one. The corresponding U(1) noncompact regularization is derived in the present work. In both Abelian and SU(2) cases there is only one auxiliary field that for a large mass has a linear coupling with the other fields and it can be integrated out yielding a negative definite correction. The coupling with the auxiliary field might make the inversion of the fermion matrix easier. Published by the American Physical Society 2024

Preferential Migration Of Carbon Black In Nr/Epdm Blend: An Investigation Through Microscopic Approach

Abstract This study focuses on the segregation of carbon black within a blend of NR/EPDM rubber at different mixing proportions (especially 70/30, 30/70). The research was exclusively conducted using microscopic techniques such as TEM, STEM-Mapping, FESEM, and AFM. Despite the challenges typically encountered in microscopy, these methods were extensively utilized to analyze the characteristics of the rubber matrix, from pristine rubber to the final filled blend. The investigation spans from the unfilled rubber to ultimate filled blends with low (25 phr) and high (50 phr) carbon black content. The use of osmium tetraoxide (OsO4) for selective chemical staining, in conjunction with microscopy, has made it possible to distinctly understand each rubber phase within the blend, greatly aiding in the identification of filler migration to the preferred rubber phase. In addition, the STEM-mapping confirmed the phase distribution by identifying the continuous and dispersed phase through precise detection and validation of the stained areas. Ultimately, the combined outcome of the microscopic study (TEM, FESEM, and AFM) revealed that the carbon black filler is more inclined to move towards the unsaturated NR phase due to its active graphitic edges, making it more compatible with the NR phase, which has a higher degree of unsaturation compared to EPDM.

Egg White-Based Gels with Candelilla Wax: A Study of Rheological, Mechanical, Calorimetric and Microstructural Properties

Bigels (BGs) are innovative composite systems that integrate oleogel and hydrogel structures, and are gaining increasing attention for their unique textural and functional properties in food applications. This study evaluated the rheological and mechanical properties of egg white-based bigels incorporating candelilla wax (CW) as an oleogelator. The results indicate that different egg white protein (EWP) (5–10%) concentrations and hydrogel-to-oleogel ratios (20:80 to 80:20) significantly influenced the structural and functional properties of the bigels. Compression testing revealed no significant differences in strength across the tested range; however, higher EWP concentrations enhanced the stability of the BGs. Furthermore, increased candelilla wax oleogel (CWO) content (60%) markedly improved emulsion stability, resulting in superior strength, as confirmed by dynamic light scattering. Rheological studies demonstrated shear-thinning behavior, particularly at higher hydrogel content related to the oleogel (W/O), which exhibited the highest yield stress. Microstructural investigations confirmed the presence of a continuous oleogel phase within the bigels (W/O) and revealed the formation of a complex structure. These findings suggest that a reduced hydrogel-to-oleogel ratio can be utilized across various food systems, opening new possibilities for creating customized food structures with desirable textural and functional attributes.

Ibuprofen encapsulation inside non-conventional O/W Pickering emulsions stabilized with partially hydrophobized silica

The encapsulation of active ingredients is an important process in various industrial sectors including pharmaceutics, foods and cosmetics. For the first time, the capacity of non-conventional anti-Bancroft oil-in-water Pickering emulsions stabilized by partially hydrophobized silica to encapsulate an apolar active is addressed. A dispersed phase volume of paraffin oil of 50% coupled to 0.5 wt.% of silica has been employed to avoid excess of silica in the continuous phase and encapsulate higher amount of ibuprofen (the model drug). Three ibuprofen contents ranging from 100 mg (1.6 mg/mL of paraffin) to 420 mg (6 mg/mL of paraffin) have been tested. The encapsulation efficiency as well as the emulsions properties are investigated by the means of light diffusion, microscopy, rheology, and HPLC coupled to mass balance. The Pickering emulsion is very efficient for the encapsulation of ibuprofen with encapsulation rates of 99% obtained inside droplets of 30 µm for all the 3 ibuprofen concentrations. This encapsulation ability is perfectly maintained, whether during ageing (during 90 days), or when the emulsion is diluted by a factor 100 inside physiological media at basic and acidic pH.

Sustainability assessment in food analysis: the application of Green Analytical Chemistry tools to phthalate residue analysis in edible oils

Edible oils are essential in daily diet due to their high contribution of fatty acids, fat-soluble vitamins, and triglycerides. During the processes of growing, processing, storage, transport, or packaging, they can be contaminated by ubiquitous phthalate esters, considered endocrine disruptors. Thus, analytical methodologies to allow tight control of their presence are mandatory. Several sample treatments have been considered in this study: microwave-assisted extraction (MAE), liquid-liquid extraction (LLE), dispersive solid phase extraction (DSPE), magnetic SPE (MSPE), solid phase microextraction (SPME), Surface-enhanced Raman spectroscopy (SERS) or its combinations. However, the selection of an analytical procedure is usually performed from an Analytical Chemistry perspective, without considering factors such as the sustainability of the selected methodology and/or its impact on the environment. In this sense, the Green Analytical Chemistry strategy can play an important role. To demonstrate this fact, six different analytical procedures have been evaluated in terms of sustainability by using several greenness evaluation tools. Procedures from MAE-gel permeation chromatography (GPC)-SPE till SERS, showing adequate analytical characteristics, have been selected. The application of Analytical GREEnness calculator (AGREE), AGREE preparation (AGREE prep), and blue applicability grade index (BAGI) tools showed that MAE-GPC-SPE was the less green analytical procedure while SERS was the greener one. The BAGI evaluation showed that headspace (HS) and SERS were the most applicable procedures.

Adsorbed microdroplets are mobile at the nanoscale

The extraordinary chemistry of microdroplets has reshaped how we as a community think about reactivity near multiphase boundaries. Even though interesting physico-chemical properties of microdroplets have been reported, "sessile" droplets' inherent mobility, which has been implicated as a driving force for curious chemistry, has not been well established. This paper seeks to answer the question: Can adsorbed microdroplets be mobile at the nanoscale? This is a tantalizing question, as almost no measurement technique has the spatiotemporal resolution to answer it. Here, we demonstrate a highly sensitive technique to detect nanometric motions of insulating bodies adsorbed to electrified microinterfaces. We place an organic droplet atop a microelectrode and track its dissolution by driving a heterogeneous reaction in the aqueous continuous phase. As the droplet's contact radius approaches the size of the microelectrode, the current versus time curve remarkably displays abrupt changes in current. We used finite element modeling to demonstrate these abrupt steps are due to nanometric movements of the three-phase boundary, where the nonaqueous droplet meets the aqueous phase and the electrode. Furthermore, the velocity with which the liquid interface moves can be estimated to tens-to-hundreds of nanometers per second. Our results indicate that processes that are driven by contact electrification and the frictional movement of bodies on a surface may be at play even when a droplet seems quiescent.

Numerical Implementation of Electrostatic Solver Within OpenFOAM for Gas Turbine Intake Filtration

Abstract Gas turbines require filtered air to preserve operability, availability, and efficiency. Fouling, corrosion, and erosion severely affect the performance of the axial compressor and it can be in part prevented by filtering the air intake. For this reason, several stages of filters can be used in series to catch pollutant particles gradually smaller and with a high level of capturing efficiency. Traditionally, the separation is obtained using cartridges of porous material, which provide a high level of filtration but at the same time generate a pressure drop increasing over time. Another common type of filter is the inertial one, whose operating principle is based on the inertial force acting on the solid particles to separate them from the mainstream. The capturing efficiency of the inertial filter is not comparable with the porous one and for this reason, it is used upstream as a pre-filter. In recent years, another technique has been developed to filter air flows thanks to an electrostatic field, that is induced inside the flow. The electrostatic force generated is able to attract and separate metallic particles. In the present work, numerical investigations are carried out to simulate the effect of the electrostatic force for gas turbine filtering systems. The computational fluid dynamics tool used is openfoam, whose official release can simulate inertial and porous filtering media, while for electrostatic one is not possible due to the absence of a library able to simulate the electrostatic force that acts on the discrete phase. A new library was developed in order to calculate the electric field, the electric potential, and the charge density of the continuous phase. Simulation results show how the calculation of these quantities allows us to predict the electrostatic force acting on particle flows in the presence of electrostatic fields.

Oriented and Continuous Phase Epitaxy Enabled by A Highly Dendrite‐Resistant Plane Toward Super‐High Areal Capacity Zinc Metal Batteries

AbstractUnstable Zn metal anodes with dendrites/side reactions are becoming the main obstacle to the practical application of zinc‐based aqueous batteries. Epitaxial growth has been considered to be an effective strategy for solving these issues, especially for inducing the (002) plane growth. Nonetheless, the (002)‐textured Zn is difficult to achieve highly stable Zn anode under high capacity resulting from its large lattice distortion. Herein, the Cu single atom anchored polymeric carbon nitride (Cu@PCN) is synthesized by a facile thermal polymerization method. Serving as multifunctional protective layer on Zn surface, the Cu@PCN can provide massive nucleation sites at a nano‐level and uniformize the electron distribution through coordination engineering. Optimizing the coordination structures of single Cu and N atoms within the carbon matrix enables a redistribution for electric field and regulates ion flux. More importantly, this coordination strategy with single atoms is first reported to customize oriented and continuous phase epitaxy along highly dendrite‐resistant Zn(101) plane by reducing (101) surface energy. This pattern of oriented dense deposition leads to stable and reversible Zn plating/stripping is achieved, which delivers an extended cycling life of 550 h at 10 A cm−2, 20 mAh cm−2. The practical full cell also displays stable performance for 1200 cycles.

Porous PEG Scaffold Fabricated via Emulsion-Templating Technique Towards Immobilization of Saccharomyces cerevisiae Cells

The cell immobilization technique, which restricts living cells to a certain space, has received widespread attention as an emerging biotechnology. In this study, a yeast (Saccharomyces cerevisiae)-loaded highly open-cell emulsion-templated polyethylene glycol (PEG-polyHIPE) was synthesized to be a reusable enzymatic catalyst. An emulsion was prepared with polyethylene glycol diacrylate (PEGDA) aqueous solution, cyclohexane, and polyethylene-polypropylene glycol (F127) as the continuous phase, dispersed phase, and surfactant, respectively. Then PEG-polyHIPE was obtained by polymerization of the PEGDA in emulsion. The highly porous materials obtained by the emulsion-templating method are suitable for use as carrier materials for yeast immobilization, due to their favorable structural designability. During the activation process, the yeast S. cerevisiae can readily gain access to the interior of the material via the interconnected pores and immobilize itself inside the voids. The yeast-loaded polyHIPE was then used to ferment glucose for ethanol production. The yeast immobilized inside the polyHIPE has high fermentation efficiency, good recoverability, and storage stability. After seven cycles, the yeast maintained 70% initial fermentation efficiency. The S. cerevisiae kept more than 90% of the initial cellular activity after one week of storage both in the dry state and in yeast extract peptone dextrose medium (YPD) at 4 °C. This study strongly demonstrates the feasibility of using high-throughput porous materials as cell immobilization carriers to efficiently osmotically immobilize cells in polyHIPEs for high-performance fermentation.

Microencapsulation of Lactobacillus reuteri by Emulsion Technique and Evaluation of Microparticle Properties and Bacterial Viability Under Storage, Processing, and Digestive System Conditions

ABSTRACTIn this research, the emulsification method was used to encapsulate Lactobacillus reuteri in microparticles of whey protein concentrate (WPC) at different levels (1%, 2%, and 4%) and gum Arabic (GA) at three levels (0/5%, 1%, and 1/5%) and a constant level of sunflower oil (5%). The results showed that emulsions with higher quantities of wall materials exhibited better encapsulation efficiency (67%/57%) and preservation ability at different temperatures, different pH, and presence of 1% bile salt. During the storage time, the droplet size of the emulsion increased more than two times (from 2.2 to 4.6 μm) and the absolute zeta potential of the optimal emulsion decreased (from −19/63 to −16/76 mV). Encapsulating Lactobacillus reuteri in the stabilized emulsion with the highest concentration of wall material improved the cells' protection during storage. The study also observed a decline in the number of primary encapsulated live cells in the gastrointestinal tract (from 4/32 to 3/58 Log CFU/mL) after 90 days of storage. In the case of the nonencapsulated sample, the initial live population decreased from 2.8 to 1 Log CFU/mL after 90 days of storage. The electron microscope images showed that the emulsions became unstable after 30, 60, and 90 days of storage, but the microbial cells were still visible in the continuous phase. Overall, encapsulating Lactobacillus reuteri using emulsification technique can preserve the probiotics during storage and “in vitro” gastrointestinal digestion.

Numerical Study of the Influence of Boundary Conditions on Calculations of the Dynamics of Polydisperse Gas Suspension

The work numerically simulates the flow of a polydisperse gas suspension in a channel. The carrier medium was described as a viscous, compressible, heat-conducting gas. The mathematical model implemented a continuum technique for the dynamics of multiphase media, taking into account the interaction of the carrier medium and the dispersed phase. For each component of the mixture, a complete hydrodynamic system of equations of motion for the carrier phase and dispersed phase fractions was solved. The dispersed phase consisted of particles with different sizes of dispersed inclusions. For the carrier medium, homogeneous Dirichlet boundary conditions were specified on the side surfaces of the channel. For fractions of the dispersed phase, boundary conditions for slippage. The influence of the boundary conditions of the flow of the carrier medium on the dynamics of gas suspension fractions has been revealed.

The Phase Structure of Wave Disturbances Excited by a Pulsating Source at the Interface of a Liquid Flow of Finite Depth and an Ice Sheet

The floating ice sheet determines the dynamic interaction between the ocean and the atmosphere, affects the dynamics of the sea surface and subsurface waters, since the ice sheet and the entire mass of liquid under it participate in the general vertical movement. The paper investigates the phase structure of wave fields arising at the interface between ice and a flow of homogeneous liquid of finite thickness when flowing around a localized pulsating source of disturbances. The ice sheet is modeled by a thin elastic plate, the deformations of which are small, and the plate is physically linear. An integral representation of the solution is obtained, and the results of calculations of dispersion dependencies and phase patterns for various parameters of wave generation are presented. It is shown that the main parameters determining the characteristics of the amplitude-phase structure of wave disturbances of the ice sheet surface are ice thickness, flow velocity, and pulsation frequency. Numerical calculations demonstrate that when the flow velocities, ice thickness, and frequency change, there is a noticeable qualitative restructuring of the phase patterns of the excited long-range wave fields at the ice-liquid interface.

Ultrafast Tailoring Amorphous Zn0.25V2O5 with Precision‐Engineered Artificial Atomic‐Layer 1T′‐MoS2 Cathode Electrolyte Interphase for Advanced Aqueous Zinc‐Ion Batteries

AbstractVanadium (V)‐based oxides as cathode materials for aqueous zinc‐ion batteries (AZIBs) still encounter challenges such as sluggish Zn2+ diffusion kinetics and V‐dissolution, thus leading to severe capacity fading and limited life span. Here, we designed an ultrafast and facile colloidal chemical synthesis strategy based on crystalline Zn0.25V2O5 (c‐ZVO) to successfully prepare a‐ZVO@MoS2 core@shell heterostructures, where atomic‐layer MoS2 uniformly coats on the surface of amorphous a‐ZVO. The tailored amorphous structure of a‐ZVO provides more isotropic pathways and active sites for Zn2+, thus significantly enhancing the Zn2+ diffusion kinetics during charge–discharge processes. Meanwhile, as an efficient artificial cathode electrolyte interphase, the precision‐engineered atomic‐layer MoS2 with semi‐metallic 1T′ phase not only contributes to improved electron transport but also effectively inhibits the V‐dissolution of a‐ZVO. Therefore, the prepared a‐ZVO@MoS2 and conceptually validated a‐V2O5@MoS2 derived from commercial c‐V2O5 exhibit excellent cycling stability at an ultralow current density (0.05 A g−1) while maintaining good rate capability and capacity retention. This research achievement provides a new effective strategy for various amorphous cathode designs for AZIBs with superior performance.

Turbulent convection in emulsions: the Rayleigh–Bénard configuration

This study explores heat and turbulent modulation in three-dimensional multiphase Rayleigh–Bénard convection using direct numerical simulations. Two immiscible fluids with identical reference density undergo systematic variations in dispersed-phase volume fractions, $0.0 \leq \varPhi \leq 0.5$ , and ratios of dynamic viscosity, $\lambda _{\mu }$ , and thermal diffusivity, $\lambda _{\alpha }$ , within the range $[0.1\unicode{x2013}10]$ . The Rayleigh, Prandtl, Weber and Froude numbers are held constant at $10^8$ , $4$ , $6000$ and $1$ , respectively. Initially, when both fluids share the same properties, a 10 % Nusselt number increase is observed at the highest volume fractions. In this case, despite a reduction in turbulent kinetic energy, droplets enhance energy transfer to smaller scales, smaller than those of single-phase flow, promoting local mixing. By varying viscosity ratios, while maintaining a constant Rayleigh number based on the average mixture properties, the global heat transfer rises by approximately 25 % at $\varPhi =0.2$ and $\lambda _{\mu }=10$ . This is attributed to increased small-scale mixing and turbulence in the less viscous carrier phase. In addition, a dispersed phase with higher thermal diffusivity results in a 50 % reduction in the Nusselt number compared with the single-phase counterpart, owing to faster heat conduction and reduced droplet presence near walls. The study also addresses droplet-size distributions, confirming two distinct ranges dominated by coalescence and breakup with different scaling laws.

The role of lipid particle-laden interfaces in regulating the co-delivery of two hydrophobic actives from o/w emulsions

Co-delivery strategies have become an integral active delivery approach, although understanding of how the microstructural characteristics could be deployed to achieve independently regulated active co-delivery profiles, is still an area at its infancy. Herein, the capacity to provide such control was explored by utilizing Pickering emulsions stabilized by lipid particles, namely solid lipid nanoparticles (SLNs) and nanostructured lipid carriers (NLCs). These dual functional species, regarding their concurrent Pickering stabilization and active carrying/delivery capabilities, were formulated with different solid lipid and surfactant types, and the effect on the release and co-release modulation of two hydrophobic actives separately encapsulated within the lipid particles themselves and within the emulsion droplets was investigated. Disparities between the release profiles from the particles in aqueous dispersions or at an emulsion interface, were related to the specific lipid matrix composition. Particles composed of lipids with higher oil phase compatibility of the emulsion droplets were shown to exert less control over their release regulation ability, as were particles in the presence of surfactant micelles in the continuous phase. Irrespective of their formulation characteristics, all particles provided a level of active release control from within the emulsion droplets, which was dependant on the permeability of the formed interfacial layer. Specifically, use of a bulkier particle surfactant or particle sintering at the droplet interface resulted in more sustained droplet release rates. Compared to sole release, the co-release performance remained unaffected by the co-existence of the two hydrophobic actives with the co-release behavior persisting over a storage period of 1 month.

In-depth mechanistic insights into Au nanoparticles based polyurethane foams as a selective and efficient dispersive solid phase microextractor for textile dyes from water: performance and reusability study

ABSTRACT Herein, a simple, superhydrophobic, superoleeophilic and low cost microextractor Au nanparticles (Au NPs) based polyurethane (PUFs) solid platform (Au NPs/PUFs) has been developed as a promising sorbent for removal and recovery of Congo red (CR) textile dye from water bodies. The sorbent was characterised using UV-visible and SEM techniques. The procedure relied complete dye retention from the aqueous solution at pH 5.0–5.5 onto an Au NP/PUF extractor. Analytical assessments revealed that the Au NPs/PUFs combination significantly improves mass transfer of dye and enhances creation of active sites for CR retention. CR sorption by the sorbent fitted well with intra-particle diffusion and pseudo first-order kinetic models (R2 = 0.990). The enthalpy change, ΔH (37.8 kJ mol−1) indicates that dye extraction is endothermic whereas the entropy change, ΔS0 (116.6 J mol−1K−1), reveals a significant change in the entropy during dye uptake. The free energy change ΔG (3.12 kJ mol−1 at 298 K) of CR sorption indicated that the dye retention was not spontaneous at all temperatures. A twofold sorption mechanism involving absorption accompanying ‘solvent extraction’ and/or ‘weak ion exchange’, combined with surface adsorption of dye is proposed. Sorbent packed mini column demonstrated effective percent removal and recovery (101.8%) of CR from water samples using acetone or NaOH as an eluting agent. The study expands the utility of Au NPs/PUFs for reusability and spectrophotometric sensing of trace levels of CR in water. The key attention also includes integrating PUFs utility by improving the selectivity and sensing properties towards textile dyes.

Lights on the Synthesis of Surfactant-Free Colloidal Gold Nanoparticles in Alkaline Mixtures of Alcohols and Water.

Surfactant-free colloidal syntheses in aqueous media are attractive to develop nanomaterials relevant for various applications, e. g. catalysis or medicine. However, controlled green syntheses without surfactants of metal nanoparticles in aqueous media remain scarce. Here, room temperature syntheses of gold (Au) nanoparticles (NPs) that require only HAuCl4, alkaline water and an alcohol, i. e. relatively benign chemicals and mild reaction conditions, are developed. The findings of a comprehensive multi-parameters screening performed in small volumes (<3 mL) over 1000+ experiments pave the way to greener high throughput screenings of large parametric spaces and lead to scalable (100 mL) synthetic strategies. A rational selection of the alcohol is proposed. The influence of lights with defined wavelengths (222-690 nm) is investigated. It is found that lights with lower wavelengths favor the formation of smaller 5 nm NPs. Different kinetics and formation pathways are observed for different alcohols and for lights with different wavelengths. The sensitivity to various experimental parameters increases with the alcohol used in the order glycerol<ethylene glycol<ethanol<methanol. New strategies for a rational fine size control, and to some extend shape control, are identified. The results lead to more sustainable and reproducible surfactant-free colloidal syntheses of NPs.