An array of metallic nanoparticles can diffract or concentrate the incident electromagnetic wave and behave as an antenna. In this paper, the effects of the inner sub-wavelength structure of nanoparticles are studied on the directivity of the plasmonic nanoantenna, which is coated on the output of a waveguide. Three 5*5 element configurations are analyzed: nanocubes, nanoshells, and nanoframes array. Numerical results are obtained using the 3D FDTD technique. The results show that structured nanoantennas can improve the antenna's directivity due to the plasmonic properties and hybridization mechanism. Between the three configurations investigated in the 250–800 nm wavelength range, the nanoshell array exhibits maximum and minimum amounts of its directivity at 321.5 nm and 591 nm, respectively. At 558 nm, nanoframes and nanoshells' arrays show the same amount of directivity, and from the wavelength greater than 558 nm, the nanoframe array has the best performance. The results may help design and fabricate directive optical fiber endcaps.