Direct-reading Instruments Research Articles

Direct-reading instruments for aerosols: A review for occupational health and safety professionals part 1: Instruments and good practices

With advances in technology, there are an increasing number of direct-reading instruments available to occupational health and safety professionals to evaluate occupational aerosol exposures. Despite the wide array of direct-reading instruments available to professionals, the adoption of direct-reading technology to monitor workplace exposures has been limited, partly due to a lack of knowledge on how the instruments operate, how to select an appropriate instrument, and challenges in data analysis techniques. This paper presents a review of direct-reading aerosol instruments available to occupational health and safety professionals, describes the principles of operation, guides instrument selection based on the workplace and exposure, and discusses data analysis techniques to overcome these barriers to adoption. This paper does not cover all direct-reading instruments for aerosols but only those that an occupational health and safety professional could use in a workplace to evaluate exposures. Therefore, this paper focuses on instruments that have the most potential for workplace use due to their robustness, past workplace use, and price with regard to return on investment. The instruments covered in this paper include those that measure aerosol number concentration, mass concentration, and aerosol size distributions.

Evaluation of lung inflammation from daily exposures to fine and ultrafine particulate matter in a trade school

Background - Daily short-term exposure to ambient fine particles (PM₂.₅ ; < 2.5 μm) in the general environment has been related to acute respiratory effects such as respiratory symptoms and inflammation, emergency room visits for respiratory conditions and mortality. Although exposure is higher in trade/occupational settings, acute respiratory effects of daily exposures remain unexplored. Objective - To evaluate the association between daily exposures to fine particles (PM₂.₅) and Ultrafine Particles (UFP; < 0.1 μm), and fractional exhaled nitric oxide (FeNO), a relevant indicator of lung inflammation, in two trade settings from a construction school. Method - A repeated-measure panel study was carried out on students performing welding and bricklaying activities (n=30). PM₂.₅ and UFP concentrations were measured daily (area measurements with direct-reading instruments) and fractional exhaled FeNO were measured two times per day, pre-work and post-work, for 5 consecutive days. Mixed GLM models were used to assess associations. Results - Daily geometric mean exposure to PM₂.₅ from welding and bricklaying activities were respectively 183 μg/m³ (σg=3.5) and 90.8 μg/m³ (σg=1.6). Daily geometric mean UFP concentrations for these activities were 106,000 (σg=1.6) particles/cm³ and 4,400 (σg=1.7) particles/cm³. Combining bricklaying and welding activities, for a 10,000 particles/cm³ increase in UFP, there was a 0.2 ppb (95%CI: 0.05-0.3) increase in FeNO inter-day. There was also a tendency for a small increase in FeNO (0.2 ppb; 95%CI: -0.06 - 0.5) per 100 µg/m³ of PM₂.₅ . Further analyses will be performed with additional participants and stratified by occupational trade. Conclusion - Bricklaying and welding activities expose workers daily to PM₂.₅ and UFP that may contribute to recurrent pulmonary inflammation and impair respiratory health. Keywords: particulate matter, occupational exposures, short-term exposure, pulmonary inflammation.

Multi-route exposure sampling of quaternary ammonium compounds and ethanol surface disinfectants in a K-8 school.

The frequency of surface disinfectant use has increased over the last several years in public settings such as schools, especially during the COVID-19 pandemic. Although these products are important for infection control and prevention, their increased use may intensify the exposure to both persons applying the disinfection product as well as bystanders. Safety assessments have demonstrated that these products, when used as intended, are considered safe for use and effective; however, point-of-contact effects (such as respiratory or dermal irritation) may still occur. Additionally, relative exposures may vary significantly due to the wide variation in disinfectant formulation and application methods. Quantitative estimations of exposures to two commonly used active ingredients, quaternary ammonium compounds (QACs) and ethanol, are not well characterized during product use and application scenarios. To assess the potential for health risks attributable to increased use in classroom settings, as well as to quantitatively evaluate the potential exposure to both ethanol and QACs, student and adult bystander surface and air measurements were collected in a K-8 school setting in Ohio, United States, over a three-day period. Direct-reading instruments were utilized to collect real-time air samples that characterized mass fraction concentrations following the use of the QAC- and ethanol-based disinfectants. Furthermore, surface and air sampling of microbial species were conducted to establish the overall bioburden and effectiveness of each disinfectant to inform the comparative risk and health effect impacts from the tested products use scenario. Both tested products were approximately equally effective at reducing bioburdens on desk surfaces. In some classrooms, concentrations of QAC congeners were significantly increased on desk surfaces following the application of the disinfectant spray; however, the magnitude of the change in concentration was small. Ethanol was not measured on surfaces due to its volatility. Airborne concentrations increased immediately following spray of each disinfectant product but rapidly returned to baseline. Each of the QAC congeners listed in the product safety data sheets were detected and measurable on desk surfaces; however, air concentrations were generally below the limit of detection. The 15-min time-weighted averages (TWAs) of both QACs and ethanol in the air were below respective health effects benchmarks, and therefore, the negative impact on health outcomes is considered to be minimal from short-term, repeated use of ethanol- or QAC-based spray products in a school setting when the products are used as directed.

A Qualitative and Quantitative Occupational Exposure Risk Assessment to Hazardous Substances during Powder-Bed Fusion Processes in Metal-Additive Manufacturing

Metal-additive manufacturing (AM), particularly the powder-bed fusion (PBF) technique, is undergoing a transition from the short-run production of components to higher-volume manufacturing. The industry’s increased production efficiency is paired with a growing awareness of the risks related to the inhalation of very fine metal powders during PBF and AM processes, and there is a pressing need for a ready-to-use approach to assess the risks and the occupational exposure to these very final metal powders. This article presents a study conducted in an AM facility, which was conducted with the aim to propose a solution to monitor incidental airborne particle emissions during metal AM by setting up an analytical network for a tailored approach to risk assessment. Quantitative data about the respirable and inhalable particle and metal content were obtained by gravimetric and ICP-MS analyses. In addition, the concentrations of airborne particles (10–300 nm) were investigated using a direct reading instrument. A qualitative approach for risk assessment was fulfilled using control banding Nanotool v2.0. The results show that the operations in the AM facility are in line with exposure limit levels for both micron-sized and nano-sized particles. The particulate observed in the working area contains metals, such as chromium, cobalt, and nickel; thus, biological monitoring is recommended. To manage the risk level observed for all of the tasks during the AM process, containment and the supervision of an occupational safety expert are recommended to manage the risk. This study represents a useful tool that can be used to carry out a static evaluation of the risk and exposure to potentially harmful very fine metal powders in AM; however, due to the continuous innovations in this field, a dynamic approach could represent an interesting future perspective for occupational safety.

Particle Size, Mass Concentration, and Microbiota in Dental Aerosols

Many dental procedures are considered aerosol-generating procedures that may put the dental operator and patients at risk for cross-infection due to contamination from nasal secretions and saliva. This aerosol, depending on the size of the particles, may stay suspended in the air for hours. The primary objective of the study was to characterize the size and concentrations of particles emitted from 7 different dental procedures, as well as estimate the contribution of the nasal and salivary fluids of the patient to the microbiota in the emitted bioaerosol. This cross-sectional study was conducted in an open-concept dental clinic with multiple operators at the same time. Particle size characterization and mass and particle concentrations were done by using 2 direct reading instruments: Dust-Trak DRX (Model 8534) and optical particle sizer (Model 3330). Active bioaerosol sampling was done before and during procedures. Bayesian modeling (SourceTracker2) of long-reads of the 16S ribosomal DNA was used to estimate the contribution of the patients’ nasal and salivary fluids to the bioaerosol. Aerosols in most dental procedures were sub-PM1 dominant. Orthodontic debonding and denture adjustment consistently demonstrated more particles in the PM1, PM2.5, PM4, and PM10 ranges. The microbiota in bioaerosol samples were significantly different from saliva and nasal samples in both membership and abundance (P < 0.05) but not different from preoperative ambient air samples. A median of 80.15% of operator exposure was attributable to sources other than the patients’ salivary or nasal fluids. Median operator’s exposure from patients’ fluids ranged from 1.45% to 2.75%. Corridor microbiota showed more patients’ nasal bioaerosols than oral bioaerosols. High-volume saliva ejector and saliva ejector were effective in reducing bioaerosol escape. Patient nasal and salivary fluids are minor contributors to the operator’s bioaerosol exposure, which has important implications for COVID-19. Control of bioaerosolization of nasal fluids warrants further investigation.

Direct-Read Fluorescence-Based Measurements of Bioaerosol Exposure in Home Healthcare

Home healthcare workers (HHCWs) are subjected to variable working environments which increase their risk of being exposed to numerous occupational hazards. One of the potential occupational hazards within the industry includes exposure to bioaerosols. This study aimed to characterize concentrations of three types of bioaerosols utilizing a novel fluorescence-based direct-reading instrument during seven activities that HHCWs typically encounter in patients’ homes. Bioaerosols were measured in an indoor residence throughout all seasons in Cincinnati, OH, USA. A fluorescence-based direct-reading instrument (InstaScope, DetectionTek, Boulder, CO, USA) was utilized for all data collection. Total particle counts and concentrations for each particle type, including fluorescent and non-fluorescent particles, were utilized to form the response variable, a normalized concentration calculated as a ratio of concentration during activity to the background concentration. Walking experiments produced a median concentration ratio of 52.45 and 2.77 for pollen and fungi, respectively. Fungi and bacteria produced the highest and lowest median concentration ratios of 17.81 and 1.90 for showering, respectively. Lastly, our current study showed that sleeping activity did not increase bioaerosol concentrations. We further conclude that utilizing direct-reading methods may save time and effort in bioaerosol-exposure assessment.

Real-Time Emission and Exposure Measurements of Multi-walled Carbon Nanotubes during Production, Power Sawing, and Testing of Epoxy-Based Nanocomposites.

ObjectivesThe use of manufactured nanomaterials is increasing globally. Although multi-walled carbon nanotubes (CNTs) are used in a wide range of applications, only limited data are available on emissions and exposures during CNT composite production. No exposure data using portable aethalometers in the personal breathing zone (PBZ) to monitor occupational exposure to CNTs have yet been published. The aim of this study was to characterize emissions of and exposures to CNTs during CNT composite production, sawing, and shear testing. We also investigated whether real-time aethalometer measurements of equivalent black carbon (eBC) could be used as a proxy filter sampling of elemental carbon (EC). The presence of CNTs as surface contamination in the production facility was monitored since this could contribute to airborne exposure.MethodsDuring CNT composite production in an industrial setting including both chemical and manufacturing laboratories, different work tasks (WTs) were studied with a combination of direct-reading instruments (aethalometer, aerodynamic particle sizer, condensation particle counter) and filter-based methods. Measurements were performed to monitor concentrations in the emission zone (EZ), PBZ, and background zone. The filter samples were analysed for EC and fibre concentration of CNTs using scanning electron microscopy (SEM). Additionally, surfaces in the facility were tape sampled for monitoring of CNT contamination, and analysed with SEM.ResultsClear eBC peaks were observed in the PBZ during several WTs, most clearly during open handling of CNT powder. Power sawing emitted the highest particle number concentration in the EZ of both nanoparticles and coarse particles, but no individual airborne CNTs, agglomerates, or aggregates were detected. Airborne CNTs were identified, for example, in a filter sample collected in the PBZ of a worker during mixing of CNT epoxy. The airborne CNT particles were large agglomerates which looked like porous balls in the SEM images. Significant EC exposures were found in the inhalable fraction while all respirable fractions of EC were below detection. The highest inhalable EC concentrations were detected during the composite production. No significant correlation was found between inhalable EC and eBC, most likely due to losses of large EC containing particles in the sampling lines and inside the eBC monitor. In total, 39 tape samples were collected. Surface contamination of CNTs was detected on eight surfaces in the chemical and manufacturing laboratories, mainly in the near-field zone. Elongated CNT-like features were detected in the sawdust after sawing of CNT composite.ConclusionsCharacterization of a workplace producing CNT composite showed that open handling of the CNT powder during weighing and mixing of CNT powder material generated the highest particle emissions and exposures. The portable direct-reading aethalometer provided time-resolved eBC exposure data with complementary information to time-integrated EC filter samples by linking peak exposures to specific WTs. Based on the results it was not possible to conclude that eBC is a good proxy of EC. Surface contamination of CNTs was detected on several surfaces in the near-field zone in the facility. This contamination could potentially be resuspended into the workplace air, and may cause secondary inhalation exposure.

Comprehensive characterization of firing byproducts generated from small arms firing of lead-free frangible ammunition

Following the introduction of lead-free frangible ammunition in United States Air Force small arms firing ranges, Combat Arms instructors have routinely reported experiencing adverse health symptoms during live fire training exercises, including sore throat, cough, and headache. Previous studies have found that these symptoms occur despite occupational exposure limits not being exceeded. To better characterize the potential source and mechanisms for health symptoms, a comprehensive characterization of the physicochemical properties of gases and aerosols emitted during the firing of the M9 pistol and M4 rifle using lead-free frangible ammunition was completed. Weapons were fired within a sealed chamber using a remote firing mechanism. A suite of direct-reading instruments and collection-based analytical methods were used to determine the composition of the emissions. Emissions were dominated by carbon monoxide and ultrafine particles. Other prevalent gases included carbon dioxide, ammonia, formaldehyde, hydrogen cyanide, and nitric oxide when measured using Fourier-transform infrared spectroscopy. An electrical, low-pressure impactor showed that, on average, the count median diameter immediately after firing was 36 ± 4 nm (n = 10 rounds) and 32 ± 3 nm (n = 14 rounds) for the M9 pistol and M4 rifle, respectively. Analytical methods were used to determine that emitted particles were primarily composed of soot, copper, and potassium, with trace amounts of calcium, silicon, sodium, sulfur, and zinc. Results from this research confirm prior work and expand upon the characterization of emissions generated from firing lead-free frangible ammunition. By employing multiple methods to measure and analyze data we were able to quantify both total and respirable particle fractions and determine particle morphology and composition. Characterization of the emissions provides insight into potential exposure risks that may lead to the development of adverse health symptoms allowing for the development of strategies for risk mitigation.

Comparison of Direct-reading and Gravimetric Methods of Particle Measurement in a Science Building, Silpakorn University

This study aimed to develop relationships between particulate matter (PM) concentrations obtained from a direct-reading instrument to those from a gravimetric method. TSI DustTrak II Aerosol Monitors (Model 8530), a direct-reading instrument for PM10 and PM2.5 measurement, together with personal air pumps connected to a Sensidyne cyclone and a SKC Personal Environmental Monitor (PEM) for gravimetric PM10 and PM2.5 measurements respectively were deployed in the Faculty of Science building, Silpakorn University, Nakhon Pathom, Thailand. Comparison of the results from each instrument indicated that PM10 and PM2.5 concentrations obtained from the TSI DustTrak were higher. The linear relationship from ordinary least squares (OLS) regression between PM10 data determined by TSI DustTrak (x) and Sensidyne cyclone (y ̂) was significant (R2=0.92) and could be represented as y ̂ = 0.272x. For PM2.5, the relationship between concentrations determined by TSI DustTrak (x) and SKC PEM (y ̂) was also significant (R2=0.92) and represented by y ̂ = 4.848√x. Validation of both equations was undertaken by comparing predicted values from these relationships against the actual concentrations found by gravimetric analysis, with R2=1.0 and 0.92 for PM10 and PM2.5, respectively. It is suggested that these site-specific OLS regression equations can provide fast and convenient estimation of concentrations derived by gravimetric analysis from direct-reading TSI DustTrak monitor data.

Characterization of Airborne Particulates and Worker Exposures in Electro-static Powder Coating Operations.

This study was to examine the airborne particulates/dusts and worker exposures in electro-static powder coating operations. Temporal variation and size distribution of dusts were assessed using direct-reading instrument, while the worker task-specific dust exposures (n = 41) were measured in three factories using conventional filter method. Additionally, toxic metal levels in the coating powder (n = 27) were analyzed to assess hazard potentials. Continuous monitoring of airborne respirable dust levels indicated large temporal variation across a normal working day. The particulate levels outside spraying booths were generally low (below 0.10 mg m-3) during normal spraying operation, but short-term level may reach as high as 21.8 mg m-3 (averaged at 4-5 mg m-3) when specific task such as cleaning the pipelines and spraying booth, was performed. Exploratory assessment on particle size distribution at four major working zones, administration, uploading, spraying, and baking, indicated no major difference among the zones, and between factories. The particle count median aerodynamic diameter was 0.88-1.69 µm, while the mean number concentrations were 10.97, 15.17, 18.49, and 27.03 (# cm-3) for zones administration, uploading, spraying, and baking, respectively. The worker task-specific dust exposures were found low during normal spraying, with the mean short-term total and respirable dust concentrations being 0.88 and 0.41 mg m-3, respectively. Both levels increased to 3.48 and 5.19 mg m-3, respectively (P < 0.05), if powder changing and system cleaning were done. Short-term total and respirable dust concentrations were 94.2 and 56.1 mg m-3, respectively, when complete cleaning process was performed inside spraying booth. Both levels exceeded the short-term exposure limits. The mean concentration of metals in the powder samples were 6.78, 9.52, 10 717, 2805, 1020, and 1361 µg g-1 for Pb, Cr (total), Al, Fe, Cu, and Sr, respectively. This study demonstrated that cleaning of spraying booth resulted in high dust exposures well exceeding the exposure limit. Toxic metals, particularly Pb, Cd, and Cr (total), levels measured in the powder samples were found low, and the resulting exposures were below the exposure limits, indicating relative low risks associated with the exposure at current dust levels.

Methods for the Analysis of 26 Million VOC Area Measurements during the Deepwater Horizon Oil Spill Clean-up.

The NIEHS GuLF STUDY is an epidemiologic study of the health of workers who participated in the 2010 Deepwater Horizon oil spill response and clean-up effort. Even with a large database of approximately 28 000 personal samples that were analyzed for total hydrocarbons (THCs) and other oil-related chemicals, resulting in nearly 160 000 full-shift personal measurements, there were still exposure scenarios where the number of measurements was too limited to rigorously assess exposures. Also available were over 26 million volatile organic compounds (VOCs) area air measurements of approximately 1-min duration, collected from direct-reading instruments on 38 large vessels generally located near the leaking well. This paper presents a strategy for converting the VOC database into hourly average air concentrations by vessel as the first step of a larger process designed to use these data to supplement full-shift THC personal exposure measurements. We applied a Bayesian method to account for measurements with values below the analytic instrument's limit of detection while processing the large database into average instrument-hour concentrations and then hourly concentrations across instruments on each day of measurement on each of the vessels. To illustrate this process, we present results on the drilling rig ship, the Discoverer Enterprise. The methods reduced the 26 million measurements to 21 900 hourly averages, which later contributed to the development of additional full-shift THC observations. The approach used here can be applied by occupational health professionals with large datasets of direct-reading instruments to better understand workplace exposures.

Colorimetric pad for low-concentration formaldehyde monitoring in indoor air

PurposeThe purpose of this study was to develop an accurate, selective, low-cost and user-friendly colorimetric pad to detect formaldehyde at low concentration.Design/methodology/approach1-phenyl-1,3-butanedione, a reactive chemical, was selected to develop the colorimetric pad for indoor air formaldehyde measurement. Silica nanoparticle impregnated with the reactive chemical was coated on the cellulose filter surface to increase the reactive site. A certified formaldehyde permeation tube was used to generate six varied concentrations between 0.01 and 0.10 ppm in a test chamber. The color intensity on the pads was measured using an image processing program to produce a formaldehyde concentration reading chart. The colorimetric pad was tested for optimum reaction time, accuracy, precision, stability, selectivity and shelf life.FindingsThe color of the pads changed from white to yellow and the color intensity varied with the concentrations and appeared to be stable after exposure to formaldehyde for 8 hours. At room temperature, the stability of the pad was 7 days, and shelf life was 120 days. The accuracy, precision and bias of the pad were 12.38%, 0.032 and 6.0%, respectively. Carbonyl compounds, benzene and toluene did not interfere with the reading of this developed colorimetric pad.Originality/valueThe developed colorimetric pad meets NIOSH's criteria for an overall accuracy of ±25%, bias = 10%. They were accurate at low concentrations, user-friendly and had low cost compared to an electronic direct reading instrument (cost of chemicals and materials was 21.50 Bath or 0.69 USD per piece) so that favorable for the use of general people for health protection.

Assessment of home care aides’ respiratory exposure to total volatile organic compounds and chlorine during simulated bathroom cleaning: An experimental design with conventional and “green” products

Home care (HC) aide visits to clients’ homes often involve cleaning and disinfecting (C&D) bathrooms. Some ingredients in C&D household products are associated with respiratory illness, including sodium hypochlorite (bleach) and quaternary ammonium compounds (quats). “Green” products may be safer for the environment, however there are limited quantitative evaluations of their respiratory risks. This study assessed airborne concentrations and time profiles of total volatile organic compounds (TVOC) and chlorine generated during typical bathroom cleaning performed by aides using conventional and green products. Aides performed cleaning tasks in a simulated residential bathroom constructed in an environmental air sampling laboratory. A balanced experimental design involved each aide coming to the lab for four visits during which she performed two 20-min cleaning sessions using one of three C&D products (bleach-based, 1–5% sodium hypochlorite by weight; quats-based, 0.1–1% by weight quaternary ammonium compounds; and “green,” 0.05% by weight thymol, a component of botanical thyme oil) or distilled water as a control. TVOC and chlorine direct reading instruments were attached to aides with sample inlets located in the breathing zone. Ten-second averages of TVOC and chlorine gas concentrations and instantaneous peak concentrations were recorded for the sessions’ duration. TVOC concentrations by methods of C&D application (spraying, streaming, wiping) also were evaluated. The study completed 169 air sampling sessions with 22 aides. The quats-based product generated more than twice the average TVOC concentrations (mean = 1,210 ppb) than the bleach-based (mean = 593 ppb) or green (mean = 498 ppb) products. Each product generated TVOC concentrations that rose rapidly within the first few minutes of application. Spraying produced the highest TVOC exposures, wiping the lowest. Thirteen aides (65%) experienced peak chlorine exposures above the OSHA PEL ceiling limit (1 ppm) when using the bleach-based product. HC aides may experience respiratory hazards from use of conventional or green C&D products formulated with bleach or other respiratory irritants and sprayed in small, poorly ventilated spaces typical of bathrooms. Spraying should be avoided.

Assessment of the mutagenicity of two common indoor air pollutants, formaldehyde and toluene.

Traditionally, direct-reading instruments have been used to directly determine the concentrations of indoor air pollutants that may exceed the regulation limits. However, these instruments cannot directly assess the potential health hazards of these pollutants to humans. In this study, we developed and improved a bacterial reverse mutation assay (Ames test) by using a direct gas exposure module to directly determine the mutagenicity of indoor air quality using five tester bacterial strains (TA98, TA100, TA102, TA1535, and TA1537). Thereafter, the module was used to evaluate the effects of exposure time, different concentrations of HCHO or toluene, and mutagenic activities. We found that TA100 was the most sensitive strain and was reverted by relatively lower concentrations of 0.035ppm HCHO. Furthermore, 50ppm of toluene exposures caused a significant increase in the number of revertant colonies of TA100 without S9 activation at the 1.5-8-h exposure time intervals. Our findings provide new evidence that gaseous HCHO exposure could display weak but direct, time-dependent, and dose-dependent mutagenic activities. The weak, direct-acting, indirect-acting, and time-dependent mutagen of 50ppm toluene was also confirmed. Moreover, our improved Ames module and the exposure conditions provided in this study can be further applied to evaluate the mutagenicity of indoor air quality.

The Composition of Emissions from Sanding Corian® with Different Sandpapers.

Laboratory tests were conducted to characterize the composition of emissions from sanding Corian®, a solid-surface composite material mainly composed of alumina trihydrate (ATH) and acrylic polymer. Three sandpaper materials (ceramic, silicon carbide, and aluminum oxide) were tested to distinguish the contribution of aluminum-containing dust in the emission from Corian® and sandpaper itself. The result can help identify the main cause of the pulmonary fibrosis from exposure to aluminum-containing dust while sanding Corian®. Airborne dust samples were measured using direct-reading instruments and collected using a Micro-Orifice Uniform Deposit Impactor (MOUDI) for estimating the normalized dust generation rate. The size-classified dust samples from MOUDI were analyzed for elemental aluminum content. Additionally, air samples were analyzed for characterizing methyl methacrylate (MMA). The results from the direct-reading instruments reveal that the size distribution of particulate from sanding Corian® differs from that of sawing Corian®, showing that the size distribution of dust is affected by the fabrication process. The normalized respirable dust generation rate indicates that more respirable dust was generated during sanding Corian® board. However, the use of aluminum oxide sandpaper does not result in a higher aluminum content in the respirable dust from sanding Corian®, suggesting that the aluminum content of the respirable dust is primarily originated from Corian® itself. The generation rates of MMA from sanding did not vary much among all types of sandpapers, and they were much lower than that of sawing, likely due to the higher temperature in the sawing process.

Chemical pollutants in the respiratory zone of welders: Determination of concentrations and hazard analysis.

Welding pollutants have potentially dangerous effects on the health of welders. Analysis of exposure risks is an appropriate method for industrial hygiene occupational exposure. The present study aimed to determine the concentrations of exposure and risk evaluation of welders to fumes and gases in three common types of welding including Shielded Metal Arc Welding (SMAW), Gas Metal Arc Welding (GMAW) and Gas Tungsten Arc Welding (GTAW). This cross-sectional study was carried out at a steel company. Samples were taken from manganese, chromium and nickel fumes with NIOSH 7300 method and for NO, NO2, CO and O3 gases using direct reading instruments. SQRCA method was used to assess the level of exposure risk. Our study showed that the highest and lowest concentrations of exposure to gases were observed in MIG and GTAW welding, respectively. Also, the highest and lowest concentrations of exposure to metals were observed in SMAW and GTAW processes, respectively. Mean exposure to M, Cr and Ni metals was 2.302, 3.195, and 1.241 mg/m3, respectively. Also, mean exposure to CO, NO, NO2 and O3 was 43.05, 27.88, 4.30, and 0.41 ppm, respectively. Results of risk analysis showed that O3, NO2 and Cr had high and very high risk levels in all welding processes. MIG and SMAW welders have a high occupational exposure to metal and toxic gases in welding. Preventive measures such as assessment of workplace air, installation of the ventilation systems, and providing appropriate respiratory protection devices for welders should be taken.

Laboratory evaluation of a personal aethalometer for assessing airborne carbon nanotube exposures

Aethalometers are direct-reading instruments primarily used for measuring black carbon (BC) concentrations in workplace and ambient atmospheres. Aethalometer BC measurements of carbon nanotubes (CNTs) were compared to measurements made by other methods when subjected to high (>30 µg/m3) and low (1–30 µg/m3) CNT aerosol concentrations representing worst-case and typical workplace concentrations, respectively. A laboratory-based system was developed to generate carbon black, as an example of a nearly pure carbon, micron-sized aerosol, and two forms of multi-walled carbon nanotubes (CNTs): small-diameter (<8 nm) and large-diameter (50–80 nm). High-concentration trials were conducted during which a scanning mobility particle sizer (SMPS) was used to track particle count concentrations over time. Relative to the behavior of the SMPS counts over time, aethalometer readings exhibited a downward drift, which is indicative of aethalometer response subjected to high BC loading on the receiving filter of the instrument. A post-sample mathematical method was applied that adequately corrected for the drift. Low-concentration trials, during which concentration drift did not occur, were conducted to test aethalometer accuracy. The average BC concentration during a trial was compared to elemental carbon (EC) concentration sampled with a quartz-fiber filter and quantified by NIOSH Method 5040. The CB and large-diameter CNT concentrations measured with the aethalometer produced slopes when regressed on EC that were not significantly different from unity, whereas the small-diameter CNTs were under-sampled by the aethalometer relative to EC. These results indicate that aethalometer response may drift when evaluating CNT exposure scenarios, such as cleaning and powder handling, that produce concentrations >30 µg/m3. However, aethalometer accuracy remains consistent over time when sampling general work zones in which CNT concentrations are expected to be <30 µg/m3. A calibration check of aethalometer response relative to EC measured with Method 5040 is recommended to ensure that the aethalometer readings are not under sampling CNT concentrations as occurred with one of the CNTs evaluated in this study.

Physicochemical characteristics of colloidal nanomaterial suspensions and aerosolized particulates from nano‐enabled consumer spray products

Physicochemical properties between colloidal engineered nanomaterials (ENMs) and aerosols released from consumer spray products were characterized. A dynamic light scattering (DLS), transmission electron microscopy (TEM), and inductively coupled plasma mass spectrometer (ICP-MS) were used to evaluate the suspended ENMs in the products. Direct-reading instruments, TEM, and ICP-MS were used to characterize the properties of aerosolized ENMs. The aerosolized organic compounds with ENMs were assumed to be vaporized for a short time after spraying. The median diameter of ENMs in product solutions measured by DLS was about 200-350nm, while individual particle was confirmed from 3 to 50nm by TEM. The size of aerosolized ENMs was ranged from 7 to 44nm, and their aggregates were about 100-1000nm in near distance. Some inorganic substances including raw nanomaterials were also found in the aerosol. The particles released from the propellant sprays were identified in far distance, while they were not found in far distance when pump sprays were used. The number concentration from the propellant sprays increased up to 6000 particles/cm3 /g at near distance and dispersed to far distance, while the most of droplets emitted from pump sprays were settled down near sprayer's location. We found other metals besides labeled ENMs are included in each product and the characteristics of the particles are different when they are sprayed.

Exposure Assessment During the Industrial Formulation and Application of Photocatalytic Mortars Based on Safer n-TiO2 Additives

Titanium dioxide nanoparticles (n-TiO2) are added to photocatalytic mortars to improve urban air quality. Their activity can be increased by dispersing and binding them on natural sepiolite surface. Workers handling photocatalytic additives can be exposed to n-TiO2. However, the release of nanoparticles to the workplace can be different if the material used is raw n-TiO2 powders or if the nanoparticles are supported on sepiolite. In this work, we compare occupational exposure to n-TiO2 for raw n-TiO2 and a hybrid additive n-TiO2/sepiolite obtained by a proprietary process. Measurements were performed in two industrial sites that process 1 ton batches of mortars, formulated with the same quantity of n-TiO2, followed by their application outdoors. Direct reading instruments were used to monitor particle number concentration and size distribution. Simultaneously, filter-based samples were collected for mass concentration and microscopy analysis. Two tasks produced a significant release of particles, the addition of fillers during the mortar formulation, in site 1, and the mixing of mortar with water for its application in the second site. For the first task, particle concentration was significantly lower when the n-TiO2/sepiolite was added compared to the raw n-TiO2. For the second task, once the mortar is fully formulated, this metric does not identify differences among the batches. Titanium mass concentration was 3–10 times lower when handling the mortar formulated with the hybrid additive. These results suggest that supporting the n-TiO2 on the sepiolite network not only increases the photocatalytic activity, but is also a safer design that reduces exposure to nanoparticles.

Nitrogen dioxide exposures from biomass cookstoves in the Peruvian Andes.

Household air pollution from biomass cookstoves is a major contributor to global morbidity and mortality, yet little is known about exposures to nitrogen dioxide (NO2 ). To characterize NO2 kitchen area concentrations and personal exposures among women with biomass cookstoves in the Peruvian Andes. We measured kitchen area NO2 concentrations at high-temporal resolution in 100 homes in the Peruvian Andes. We assessed personal exposure to NO2 in a subsample of 22 women using passive samplers. Among 97 participants, the geometric mean (GM) highest hourly average NO2 concentration was 723ppb (geometric standard deviation (GSD) 2.6) and the GM 24-hour average concentration was 96ppb (GSD 2.6), 4.4 and 2.9 times greater than WHO indoor hourly (163ppb) and annual (33ppb) guidelines, respectively. Compared to the direct-reading instruments, we found similar kitchen area concentrations with 48-hour passive sampler measurements (GM 108ppb, GSD 3.8). Twenty-seven percent of women had 48-hour mean personal exposures above WHO annual guidelines (GM 18ppb, GSD 2.3). In univariate analyses, we found that roof, wall, and floor type, as well as higher SES, was associated with lower 24-hour kitchen area NO2 concentrations. Kitchen area concentrations and personal exposures to NO2 from biomass cookstoves in the Peruvian Andes far exceed WHO guidelines. More research is warranted to understand the role of this understudied household air pollutant on morbidity and mortality and to inform cleaner-cooking interventions for public health.