Abstract The radiometric measurement of the marine air temperature using a Fourier transform infrared spectroradiometer is described. The measurements are taken by the Marine-Atmospheric Emitted Radiance Interferometer (M-AERI) that has been deployed on many research ships in a wide range of conditions. This approach is inherently more accurate than conventional techniques and can be used to determine some of the error characteristics of the standard measurements. Examples are given from several cruises ranging from the Arctic to the equatorial Pacific Oceans. It is shown that the diurnal heating signal in radiometric air temperatures in the tropical Pacific can typically reach an amplitude of ∼15% of that measured by conventional sensors. Conventional data have long been recognized as being contaminated by direct solar heating and heat island effects of the ships or buoys on which they are mounted, but here this effect is quantified by comparisons with radiometric measurements.