Direct Current Method Research Articles

Morphology and multifractal characteristics of Ag–Cu films with N doping prepared by direct current magnetron sputtering method

Morphology and multifractal characteristics of Ag–Cu films with N doping prepared by direct current magnetron sputtering method

Effect of local pressure difference caused by argon flow on properties of DLC films on rubber

The application of a diamondlike carbon (DLC) coating on rubber surfaces is a promising method to enhance the tribological properties of rubber and alleviate its poor wear resistance. However, in the preparation of DLC films, accurate pressure detection in the sputtering region is challenging due to the single detection position in common sputtering systems. In this paper, the direct current magnetic sputtering method was used to prepare DLC films on nitrile butadiene rubber (NBR). A set of Faraday beam detection device (FBDD) was employed to monitor the current density in the sputtering region. It was found that even if the pressure at the detection position of the vacuum gauge is consistent, the actual pressure in the sputtering region may be different under different rates of argon flow based on the detection results from the FBDD. The surface energy of DLC films was also calculated and researched. According to the results of FBDD, a series of analytical characterization methods were selected to explore the influence mechanism of changing the Ar flow rate on the properties of DLC films on NBR when the initial sputtering pressure remained consistent. The results of FBDD show that the density of the beam in the sputtering region increases with the increase in the Ar flow rate introduced into the vacuum chamber. The surface energy of DLC films was also calculated and evaluated by a contact angle tester. Raman and x-ray photoelectron spectroscopy results indicate that the increase in the Ar flow rate leads to an increase in pressure, which is conducive to the formation of sp3 in DLC films, and the increase in sp3 improves the surface energy of DLC films. The highest sp3 content and surface energy among as-prepared DLC films are observed when the argon flow rate was 40 SCCM. Ball-on disk friction experiment was used to characterize the tribological performance of DLC films on NBR rubber and the adhesion between DLC films and NBR rubber was evaluated by a nanoscratching test. Combining the results of tribology and nanoscratching testing, it can be inferred that the Ar flow rate plays an important role in improving the mechanical properties of DLC films on NBR rubber. Furthermore, the results of scanning electron microscopy confirmed that the sputtering atoms can effectively fill in the grooves of the rubber substrate. This finding is of significance for controlling the sputtering process of preparing DLC on rubber and improving the frictional properties of rubber.

A feasibility study on time-lapse transient electromagnetics for monitoring groundwater dynamics

Time-lapse geophysical studies have been used as noninvasive tools to study subsurface processes. However, compared to direct current resistivity methods, the transient electromagnetic (TEM) method has not been explored in much detail for time-lapse investigations. Here, we introduce the use of a monitoring TEM (mTEM) system and methodology for long-term groundwater monitoring purposes. The system can run measurements automatically and the modeling approach uses a time-constrained inversion (TCI) scheme based on an existing laterally constrained inversion scheme. Instead of lateral constraints that traditionally ensure lateral coherency between measurements, temporal constraints are used to control the temporal coherency between measurements. Synthetic analysis demonstrates that very tight time constraints on resistivities and a time constraint on the depth to the water table fixed at a fraction of the expected annual water table variation is needed to track water table changes at the decimeter level. Furthermore, the synthetic analysis indicates that the mTEM method can track annual variations in the water table with amplitudes as low as 0.6 m with a mean absolute error of 0.2 at depths between 16 m and 30 m. A field example consisting of 233 1D TEM measurements acquired over 10 months using the mTEM instrument supports the synthetic results. The estimated water table depth from the TCI scheme reproduces the variation in the water table accurately, as confirmed by measurements from a water level data logger in a nearby well. The differences between the results from the TEM monitoring system and the diver measurements are in the range of ±0.1 m with an average absolute difference of 0.05 m. This study demonstrates the potential to monitor changes in the groundwater level noninvasively.

Investigation on microstructure and tribological performances of electrodeposited Ni-W-Y2O3 composite coatings

Nickel-tungsten-yttrium oxide (Ni-W-Y2O3) composite coatings were co-electrodeposited onto low-carbon steel surfaces using the direct current electrodeposition method with a constant current density of 2 A/dm2. The influence of Y2O3 nanoparticles on the microstructure, morphology, microhardness and tribological performance of the composite coatings was investigated. The incorporation of Y2O3 nanoparticles was found to significantly refine the crystallite size of the coatings. The microhardness improvement and superior tribological properties of the Ni-W-Y2O3 composite coatings were attributed to the dispersion strengthening and refine crystalline strengthening effects induced by the addition of Y2O3 nanoparticles. It was also observed that the coating prepared from an electrolyte containing 10 g/L Y2O3 nanoparticles exhibits the highest wear resistance. These results highlight the potential of Y2O3 nanoparticles as a promising additive for enhancing the mechanical and tribological properties of coatings.

Multi-scale multivariate detection method for the effective impact range of hydraulic fracturing in coal seam

Hydraulic fracturing enhances coal seam permeability and reduces original gas content. Determining the effective range of hydraulic fracturing is essential in evaluating its effectiveness. This paper analyzes physical field changes during hydraulic fracturing and proposes a multi-scale multivariate detection method for determining the effective range of hydraulic fracturing in coal seams based on changes in wave velocity and resistivity due to fracture expansion.The method was validated through field experiments. The result shows that vibration wave computed tomography (VWCT) is a passive, large-scale area detection method. In contrast, the direct current (DC) method is a small-scale, local active detection method. In the hydraulic fracturing process, the microseismic (MS) events increase. After fracturing, the wave velocity of coal seam decreases significantly, indicating the formation of fractures around the fractured holes and a fracture zone. The fracturing expands the pre-existing fractures adjacent to fractured holes, forming a fracture network between them and natural fractures, leading to a decrease in wave velocity around the coal seam. The DC detection results indicate a noticeable development of pores around the fractured holes following hydraulic fracturing. The increased resistance value area is mainly concentrated on both sides of the 9–4 drilling, with an influence range of approximately 30 m, and an increased range of 100–400 Ω·m, indicating a hydraulic fracturing pore expansion range of 30 m in coal seams. Comprehensively, the maximum impact area of fracturing is the area surrounding the fractured holes, and the impact area is not uniform. The DC method test results reflect the extension of fracturing around fractured holes, while the VWCT test results represent the extension of fracturing around fractured holes and the connectivity of primary fractures, both of which include each other.

Enhanced Methanol Oxidation in Alkaline Media on Electrodeposited Ni Electrodes by Morphological and Crystallographic Evolution

This research aims at exploiting the electrocatalytic behaviour of nano-crystalline nickel electrodes electrodeposited by different techniques including direct current (DC), pulse current (PC), or pulse reversal current (PRC) for methanol electrooxidation in alkaline solutions. We understand that PC electrodeposition forms pyramidal shaped grains with a preferential Bragg diffraction peak of (111), whereas PRC produced refined spherical grain morphology with a strong (200) diffraction peak. However, DC electrodeposition exhibits an intermediate morphology and crystalline structure. Cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS) show that PRC electrodeposition develops Ni electrodes with better electrocatalytic activity for methanol electrooxidation than other two nickel electrodes. Based on the CV curve, the current density for Ni prepared by PRC electrodeposition methods is about 75.26 mA.cm−2, which is higher than those of DC and PC methods. This higher activity of PRC electrodeposited nickel is attributed to the low charge transfer resistance confirmed by Nyquist plots. We attributed this behavior to the (200)-oriented crystallographic texture, spherical grain morphology, and consequently the high electrochemical active surface area of this nickel electrode. This work reveals the importance of surface morphology and crystallography on the electrocatalytic behaviour of nickel electrodes for electrochemical energy devices.

Performance Evaluation of Brushless Direct Current Motor Control Methods through Low-Cost Microcontroller-Based Real-Time Experiments

Brushless direct current (BLDC) motors are high efficiency synchronous motors that are employed in a variety of applications due to prominent features such as long operational life, low maintenance requirements, and great dynamic response. BLDC motors are driven by energizing the motor stator windings with an inverter circuit. To commute the inverter switches, the trapezoidal (120°) method is generally used by considering the back electromagnetic force induced on unenergized phase of BLDC. Furthermore, depending on the application requirements, alternative commutation modes (CM) such as 180°, 150°, and sinusoidal-based approaches are utilized. In the literature, the performance comparison of some CMs was studied for two-phase on operation and three-phase on operation mode as a switching pattern. However, only a few research assessed the performance of two or three commutation modes simultaneously. In this study, the performance comparison of pulse width modulation (PWM) based commutation modes are examined by considering 120°, 180°, 150° modes, and sinusoidal PWM. In this scope, it is the first time that direct digital synthesis (DDS) is addressed as a BLDC control algorithm in a performance comparison study. In experimental studies, a simple and a low-cost drive circuit is designed to acquire the case results. According to the results, the proposed DDS-based sine commutation method is more efficient than other commutation methods and it has lower power consumption at both low and high speeds also a wider operable speed range.

Alternating current polarization to enhance piezoelectric performance of single crystal composites

Pb-based relaxor piezoelectric single crystal composites (PSCCs) have attracted widespread attention for improving the bandwidth and sensitivity performance of acoustic transducers due to their excellent electromechanical and piezoelectric properties. Alternating current polarization (ACP) has been proven as an effective method for enhancing the dielectric and piezoelectric properties of relaxor-PbTiO3 single crystals. Herein, we investigated the effects of the amplitude, frequency, and cycle number of the poling electric field on the piezoelectric and dielectric performances of PSCCs and obtained the optimum poling condition of ACP. Compared with the traditional direct current poling method, both the dielectric permittivity (ε33T/ε0) and piezoelectric coefficient (d33) of the AC-poled PSCCs were both increased by up to 20%. Notably, the ACP PSCC with a volume fraction of 60% exhibited a high d33 of 1610 pC/N, which is superior to values previously reported for PSCCs. This work provides an alternative strategy for enhancing the properties of PSCCs and may contribute to the further development of piezoelectric applications.

Temporal and spatial distribution characteristics of hydraulic crack propagation under true triaxial loading using the direct current method

Hydraulic fracturing (HF) has been widely used in coal and rock dynamic disasters prevention and control and coalbed methane production in underground coal mines. However, how to effectively and accurately monitor and evaluate the hydraulic crack propagation process and impact range has not been resolved. We developed a novel experimental system for HF-direct current (DC) monitoring under true triaxial loading conditions. With the use of this system, we conducted HF-DC monitoring experiments under true triaxial loading conditions. The response characteristics of the emission current, apparent resistivity, and apparent resistivity difference contour map throughout the entire experimental process were studied. The results showed that the DC monitoring data contain a wealth of effective information on hydraulic cracks propagation. The emission current and apparent resistivity reflected the overall electrical conductivity of the rock. The contour map of the apparent resistivity difference between two measuring lines could accurately characterize the propagation process and spatial distribution of hydraulic cracks. The evolution process of the difference contour map showed that hydraulic cracks were more likely to spread into areas with low homogeneity. The change range and degree of the apparent resistivity were mainly affected by the spatial distribution, water-bearing state of the hydraulic cracks and wet area surrounding the hydraulic cracks. As the hydraulic crack network expanded, a highly conductive channels were formed inside the rock, which could affect the rock conductive properties and patterns. By comprehensively considering the temporal and spatial evolution characteristics of the apparent resistivity difference contour map and the regional apparent resistivity change curve, the dynamic expansion and spatial shape of hydraulic cracks in the rock could be accurately characterized via the DC monitoring method.

Oxygen Vacancy-Induced Ferromagnetism and Resistive-Magnetization Switching Characteristics in In2O3 Films

Ordered porous indium oxide thin films (In2O3) with higher ferromagnetism were prepared by the direct current magnetron sputtering method using porous anodic aluminum oxide thin films as the template. The experiment results show that the saturation magnetization reaches a maximum of about 42.03 emu/cm3 at a sputtering pressure of 3.2 Pa. The room-temperature ferromagnetism of In2O3 films mainly originates from the oxygen vacancies in the films. In addition, the spin can generally only be regulated by a magnetic field, which makes it challenging to realize miniaturization and integration of spin devices, while the regulation by an electric field can solve this contradiction. Based on this, the In2O3 composite thin-film resistive-magnetization switching device (Ag/In2O3/PAA/Al) was successfully prepared, showing bipolar resistive-magnetization switching characteristics and stable electrical and magnetic control characteristics. This research provides a way to develop a new multifunctional memory combining magnetic and resistive-magnetization storage and lays the foundation for the application of In2O3 in spintronic devices.

Effect of rare–earth (Ce, La) compounds on the microstructure, mechanical and electrochemical corrosion characteristics of electroplated Ni films

For optimizing the microstructure and performance of Ni–electroplating film, the soluble rare–Earth (RE) compounds CeCl3 or LaCl3 were introduced, which were electrodeposited on Cu substrate by direct current (DC) and pulse current (PC) methods, respectively. The surface characteristics of morphology, composition, and phase of obtained different deposits were investigated, and the relationship between the structure and the performance of internal stress, hardness, and electrochemical responses was discussed. The results show that both RE compounds were conducive to eliminating the surface pits by inhibiting the hydrogen evolution reaction, while did not co–deposit into the Ni film. Moreover, the preferred orientation of Ni (111) crystalline plane was altered into Ni (200) by LaCl3, and its combination with PC–electrodeposition further had a better grain refinement effect than CeCl3. Due to the formation of a relatively dense and fine deposit, the PC–electrodeposited Ni/LaCl3 film exhibited the highest hardness of 320 HV, lowest tensile stress of 55 MPa, and best electrochemical passivation protection, which effectively improved the comprehensive performance of Ni film and demonstrated a good prospect for industrial applications.

Magnetic integrals minimization methods for superconducting insertion devices

Stretched wire with direct current magnetic measurements method is used for producing synchrotron radiation generation insertion devices. The method allows to measure and to minimize the first and the second magnetic field integrals. The paper focuses on the wire sag problem.

Thermoluminescence properties of TiO2/Cu/TiO2 multilayer thin films fabricated by (RF/DC) sputtering for radiation dosimetry

The most popular TLDs are composed of phosphors, ceramics, and crystals. Despite having a high light output per unit of absorbed dose, they suffer from rapid signal fading, light scattering, saturation at higher doses, and difficulties annealing for re-use. Here, we report the characteristics of a novel TiO2/Cu/TiO2 multilayer thin film dosimeter fabricated using radio-frequency (RF) and direct current (DC) sputtering methods with a faster deposition rate, high purity, and uniformity. The multilayer sequence was set to TiO2 (150 nm)/Cu (x)/TiO2 (50 nm), at varying Cu thicknesses (x = 5, 10, 25, 40, and 50 nm). The structure, morphology, elemental composition, and optical properties of the films were characterized by the XRD, FESEM, EDX, and UV–Vis, respectively. Next, the best TiO2 multilayer films with 5 nm Cu were tested for morphological, structural, and optical properties at 600 and 1200 mGy of x-ray radiation. The dosimetric properties of samples irradiated with X-ray doses ranging from 100 to 1500 mGy were then investigated. The best annealing time, reproducibility, fading, low minimum detectable dose as well as the effect of different heating rates on the TL glow curve have all been studied. Our results indicate that the films are amorphous, porous with spherically shaped nanoparticles, have a uniform distribution of elements, and are transparent in the visible region. The optimum TL intensity was found at TiO2 (445 nm)/14.2 nm Cu/TiO2 (130 nm) sequence. The dose-response has a good linear correlation to x-ray radiation with a sensitivity that is 0.444 times less than that of TLD-100 sensitivity within the dose range 100–1500 mGy. Upon irradiation, the band gap decreases, crystallinity increases, pores increase, films become rougher, and the absorption band edge extends to higher wavelengths. The single and multilayer TiO2 films have high-intensity peaks at 270 and 274 ∘C, respectively, which is typical of TL glow curve peaks used in TLD applications. There were no significant changes in the TL reading after six times of reuse, and the fading was observed at 49.57% after 15 days of irradiation. The findings indicate that TiO2/Cu/TiO2 multilayer films are appropriate for thermoluminescence dosimetric applications.

Applications of Energy Dispersive X‐Ray Fluorescence Spectrometry and Direct Current Arc Atomic Emission Spectroscopy Methods for Grouping Study of Automobile Windshield Glasses for Glass Forensics

AbstractA comprehensive evaluation was carried out for elemental characterization of automobile glasses having potential forensic application by Energy Dispersive X‐ray Fluorescence (ED‐XRF) spectrometry and Direct Current Atomic Emission Spectroscopy (DC Arc AES). The methods were optimized and validated using geological certified reference materials and glass standard reference material. Total seventeen elements including five major elements (Si, Na, Ca, Mg and Fe) and twelve minor and trace elements (Al, Ti, V, Cr, Mn, Ni, Cu, Zn, Rb, Mo, Zr and Sr) were found to be present. Though DC Arc AES performed better for minor and trace level determination, however, the precision was evaluated as 15–20 % RSD. On the contrary, ED‐XRF performed better for major elements with 5–10 % RSD. The detection limits for the analytes prone to form refractory oxides on heating were found to be poorer in DC Arc AES compared to ED‐XRF. Statistical analyses were also performed to evaluate the reliability of the data obtained by the optimized methods. As a part of forensic applications, the elemental concentrations of minor and trace elements were utilized for the grouping study of the glass samples by cluster analysis using average linkage method.

Deep Learning Joint Inversion of Electrical Data for Ahead-Prospecting in Tunneling

Water inrush has become one of the bottlenecks restricting tunnel construction. Among various advanced forecasting techniques, the direct current method is more cost-effective and sensitive to water-bearing structures. It has been widely used in exploring water inrush disasters in practical engineering. Although traditional resistivity linear inversion methods are reasonably practical, they usually suffer from volume effects and cannot accurately locate the location and morphology of water-bearing bodies. Therefore, nonlinear techniques such as deep learning have recently become popular to directly approximate the inversion function by learning the mapping of apparent resistivity data to the geoelectric model. This work presents a novel deep learning-based electrical approach that combines resistivity and polarizability to estimate water-bearing location and morphology. Specifically, we design an encoder-decoder network. A shared encoder extracts features from the input data, two encoders output resistivity, and polarizability models, respectively, and fine-tuned collinear regularization for both outputs reduces solutions’ multiplicity. Compared with traditional linear inversion methods and independent parameter inversion, our proposed joint inversion method shows superiority in locating and delineating anomalous bodies.

Multiparameter Estimation of IPMSMs Using Core Loss Current Calculations in dq-Axis Equivalent Circuit Model

Accurate parameter estimation is critical for high-performance modeling and control of interior permanent magnet synchronous machines (IPMSMs). Core loss effects affect the accuracy of the parameter estimation, especially in high loading conditions with saturated cores. Existing research on parameter estimation considering core loss effects generally focuses on the core loss equivalent resistance estimation; however, they require either accurate core loss experimental data or finite element analysis (FEA) model. The core loss equivalent resistance is dependent on the loading conditions, harmonics, frequency, and temperature, which increases the difficulty of accurately estimating the resistance. This article firstly proposes a direct core loss equivalent current estimation method for multiparameter estimation purposes without estimating the core loss equivalent resistance. Based on the estimated core loss equivalent currents, the <italic xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink">dq</i> -axis inductances equivalent currents are calculated to perform the multiparameter estimation. The proposed approach can improve the precision of the parameter estimation and the computation efficiency by calculating the core loss equivalent resistance currents without having the core loss data. The effectiveness of the proposed multiparameter estimation method is evaluated by comparing the calculated and measured torques of a laboratory 4.5 kW IPMSM in various operating conditions. The improved accuracy of the proposed method is verified by comparing it with two existing online parameter estimation methods and FEA-based offline parameter estimation results.

A novel ultrasonic non-destructive testing methodology to monitor fatigue crack growth in compact tension specimens.

Detection and evaluation of fatigue cracks in structural materials are extremely important for life prediction analysis as part of the structural integrity procedure. In this article, we present a novel ultrasonic measurement methodology, based on the diffraction of elastic waves at the crack tips, to monitor the fatigue crack growth near the threshold regime in compact tension specimens at different load ratios. The diffraction phenomenon of ultrasonic waves from the crack tip is demonstrated using a finite element 2D wave propagation simulation. The applicability of this methodology has also been contrasted with that of the conventional direct current potential drop method. In addition, the crack morphology obtained in the ultrasonic c-scan imaging showed a variation in the crack propagation plane as a function of the cyclic loading parameters. The results suggest that this novel methodology is sensitive to fatigue cracks and can form the basis of in situ ultrasonic-based crack measurements in metallic and non-metallic materials.

Combined Application of Hydrogeological and Geoelectrical Study in Groundwater Exploration in Karst-Granite Areas, Jiangxi Province

Drinking water shortage is a major concern in villages across southern Jiangxi, and this has impacted economic and social development. In order to address this challenge, groundwater prospecting was carried out in the villages under the support of Drinking Water Safety Project of China Geological Survey. In this study, we present two example sites in Ningdu County selected to demonstrate the combined hydrogeological survey, and the direct current electrical resistivity method was utilized for the present study for groundwater exploration in karst-granite distribution areas. First, a hydrogeological study was effectively used to delineate shallow severely weathered structural fissures as prospective target water-bearing beds. Then, a direct current electrical resistivity survey was used to confirm the distribution, thickness scale, and water-bearing features. The structural fractured zone whose distribution and trend were first established through hydrogeological surveys and whose development characteristics and water-richness were investigated by the direct current electrical resistivity method is the target layer for water exploration in the karst-granite rock areas. The water-bearing fracture zone shows a groove or strip-shape low resistivity anomaly and can be identified in its aquifer position according to its IP half decay time (Th), apparent polarizability (ηs), and apparent resistivity (ρs). The findings demonstrate that the above methods were successful in locating water potential areas, providing information for comparison and accurate borehole positioning. The results of the subsequent drilling and pumping tests supported the interpretation of the geophysical exploration data, and the water output from both boreholes met the objectives of this study. This groundwater search might serve as a guide for future exploration projects in similar areas.

Effect of temperature and medium environment on corrosion fatigue behavior of Inconel 625

AbstractInconel 625 is a nickel‐based alloy with exceptional creep and corrosion resistance properties. It has emerged as a candidate material for operational and structural use in critical and supercritical power generation plants. Supercritical power plants work at high temperatures, pressure and in an erosive environment that makes metallic materials more vulnerable to corrosion fatigue. This study aimed to evaluate the fatigue crack growth rate (FCGR) at elevated temperatures (550–650°C) in a steam and supercritical water environment. All the experiments were performed at a water oxygen level of 8000 ppb. A cyclic stress of 1 Hz frequency and sine waveform was applied for the test. A 0.6 stress ratio was applied with a maximum stress intensity factor of 32 MPa√m. A direct current potential drop method was applied to detect the crack growth rate (CGR). For the given parameters, fractographic analysis validated the role of corrosion‐fatigue interaction as the primary source of variation in the FCGR. Results revealed that the CGR was enhanced with a rise in temperature under all test environments. The influencing mechanism of temperature on CGR was also discussed.

Self-powered visible transparent mathrm{Cu}/{mathrm{Zn}}_{left(1-xright)}{mathrm{Sn}}_{left(xright)}mathrm{O} Schottky-based ultraviolet photosensors fabricated via DC magnetron sputtering

Visible transparent mathrm{Cu}/mathrm{n}-mathrm{ZnO} and mathrm{Cu}/{mathrm{Zn}}_{left(1-xright)}{mathrm{Sn}}_{left(xright)}Oleft(x=0.14right) mathrm{TZO}, Schottky junctions were successfully fabricated on ITO-coated glass substrates via direct current magnetron reactive sputtering method. The structural, morphological, optical, and electrical properties were thoroughly investigated. The polycrystalline nature of the samples was confirmed by XRD studies. FESEM images validate the changes in surface morphology after doping and annealing, and AFM analysis confirmed the variation in surface roughness. The electrical analysis reveals the presence of a Schottky barrier in the fabricated devices. In dark condition, three-order rectification ratio was observed. A two-order increase in leakage current was also observed after illuminating 365 nm UV light of power 60 µW/cm2. The figures of merits of sensors, such as responsivity, detectivity, response speed, and linear dynamic range, were thoroughly investigated. The fabricated sensor had a responsivity of about 07.80 mA/W and a detectivity of 1.39 × 1011 Jones. At zero bias, the sensor also demonstrated a transient photocurrent response of approximately 783 ms for rise and 876 ms for fall. Similarly, 33.70 dB of linear dynamic range was observed. These findings suggests that Cu/TZO Schottky diodes could be useful for self-powered, visible transparent UV photosensors in next-generation optoelectronic devices.