Direct Condensation Research Articles

Research Progress in the Synthesis of N-Acyl Amino Acid Surfactants: A Review

This paper reviews the research progress in the synthesis of N-acyl amino acid surfactants, including chemical synthesis methods, enzymatic synthesis methods, chemo-enzymatic methods, and fermentation methods. Chemical synthesis is currently the main route for laboratory and industrial synthesis, including methods such as direct dehydration condensation of fatty acids, amidation of fatty acid anhydrides, carbonyl addition of fatty amides, amidation of fatty acid activated esters, amidation of fatty acid methyl esters, amidation of oils and fats, hydrolysis of fatty nitriles, and Schotten–Baumann condensation. Enzymatic synthesis has the advantages of mild reaction conditions and being green and pollution-free, but the yield is relatively low. The chemo-enzymatic method combines the advantages of enzymatic and chemical methods, but it has not been widely promoted. Fermentation methods have low production costs and are environmentally friendly but the technology is not yet mature. This paper elaborates on the principles, advantages, and disadvantages of each synthesis method and provides an outlook on future research directions.

The apparatus for atmospheric water harvesting in an arid climate - Prototype design and testing in laboratory conditions

The paper describes the development of a prototype system for water extraction from the air. The aim was to develop a device that allows one to autonomously obtain, without the need for external energy, an annual average of 100 L of water per day during extreme desert conditions. In this paper, a mathematical model simulating the operation of the unit for extracting water from the air in any climatic conditions is presented. Psychrometric calculations for different climatic conditions were carried out for two basic principles: condensation and sorption. The analyses confirmed that devices based on the condensation of water vapour from the air can only be used to a limited extent in extreme desert conditions. The average water production of a condensation-based system is only 20 l/day in Riyadh, with an air flow rate of 2000 m3/h. A unit with a desiccant wheel and an integrated heat pump was designed for water harvesting from the air. The prototype of the unit was tested in a climate chamber with the possibility of adjusting the climatic conditions and the presented mathematical model was experimentally verified. The final prototype designed for a nominal outdoor air flow rate of 2000 m3/h will produce 168 l of water per day under dry desert conditions (Riyadh) with continuous operation. The verification of the computational model allows one to determine the real water production and the required unit performance. An analyses of energy requirements and evaluation of levelized cost of water (LCOW) have been performed. Sorption unit has lower LCOW in target arid desert climate and electricity prices under 0.1 EUR/kWh compared to direct condensation technology.

Formation, chemical evolution and solidification of the dense liquid phase of calcium (bi)carbonate.

Metal carbonates, which are ubiquitous in the near-surface mineral record, are a major product of biomineralizing organisms and serve as important targets for capturing anthropogenic CO2 emissions. However, pathways of carbonate mineralization typically diverge from classical predictions due to the involvement of disordered precursors, such as the dense liquid phase (DLP), yet little is known about DLP formation or solidification processes. Using in situ methods we report that a highly hydrated bicarbonate DLP forms via liquid-liquid phase separation and transforms into hollow hydrated amorphous CaCO3 particles. Acidic proteins and polymers extend DLP lifetimes while leaving the pathway and chemistry unchanged. Molecular simulations suggest that the DLP forms via direct condensation of solvated Ca²+⋅(HCO3-)2 complexes that react due to proximity effects in the confined DLP droplets. Our findings provide insight into CaCO3 nucleation that is mediated by liquid-liquid phase separation, advancing the ability to direct carbonate mineralization and elucidating an often-proposed complex pathway of biomineralization.

Synthesis of N-Sulfonyl Formamidines by Direct Condensation between Sulfonamide and Formamide Enabled by a Photogenerated Vilsmeier-Type Reagent.

Herein, we report the synthesis of N-sulfonyl formamidines from carbon tetrabromide and formamide under UVA irradiation without any additional catalysts. This approach represents a straightforward methodology for accessing this class of structural units and has been applied to a wide range of readily available sulfonamides and formamides, providing the corresponding products in moderate to excellent yields (30 examples, 16-99% yields). Mechanistic investigations associated with previous reports suggest the implication of an activated iminium intermediate (Vilsmeier-Haack reagent derivatives), obtained by the photoinduced reaction between carbon tetrabromide and formamides.

Silica surface modification using cellulose as a renewable organosilane derived from coconut coir fiber for carbon capture

The properties of silica surface modification for carbon capture were studied, utilizing cellulose-amine as a modification agent derived from dissolved coconut coir fiber. To form bonds with NH2 functional groups through amination processes, cellulosic biomass waste is utilized, which is analogous to replacing alkoxy ligands. The dual-function mixture reagents dimethyl sulfoxide (DMSO) and ammonium hydroxide (NH4OH) were employed in the same system as the amine sources and solvents. Waterglass is used as a source of silica, and the modified particles are formed using a one-step consecutive sol-gel spray drying process used in a direct condensation route. Changes in the concentration of sodium lauryl sulfate (SLS) were examined to determine how they affected the essential parameters of the particles. The template is removed during particle formation without further physical or chemical processing. The particle morphology changed from donut-shaped to spherical after SLS application, as evidenced by the increase in SLS concentration. This also shows that the increase in the particle surface area is directly influenced by the increase in the formation of new pore structures with increasing SLS concentration. Through this mechanism, it is possible to extend the pore size distribution to the meso-macropore regime and initiate the formation of new mesopores. This has a direct impact on the capacity to absorb CO2 gas by increasing the cellulose-amine mass fraction that can be grafted to as high as 32.35 %wt. At an operating pressure of 6 bar, a maximum CO2 gas adsorption capacity of 5.32 mmol/g silica was attained by adding SLS 3 CMC to the silica particles. This value is 2.3 times higher than that obtained when using an aminosilane-based modification agent.

Polyphosphoric Acid-Promoted Efficient Synthesis of Cinnamides via Aldol Condensation of Amide

Cinnamides are common core structures that exist in a great number of pharmaceuticals and natural products. The development of efficient methods for preparing cinnamides is in great need. We report herein an efficient polyphosphoric acid (PPA)-promoted direct aldol condensation of an amide for the convenient and straightforward preparation of cinnamides. A variety of cinnamides were obtained in moderate-to-excellent yields (65–89%). This strategy features the use of equivalent amides and a short reaction time.

Performances of the ITER Pressure Suppression System during unstable steam condensation regimes

Abstract The paper deals with the qualification of the main safety system of the nuclear fusion reactor ITER: the Vacuum Vessel Pressure Suppression System (VVPSS). This safety system manages the Loss of Coolant Accident (LOCA), that could occur in the Vacuum Vessel (VV), avoiding a significant increase of the internal pressure that could breach the primary confinement barrier. Steam condensation occurs at sub-atmospheric pressure. This condition is original respect the usual applications of steam direct condensation in nuclear fission reactors. An extensive experimental research program, funded by ITER Organization, on reduced scale experimental rigs (scale 1/22 and 1/10) have been carried out at the University of Pisa. Unstable condensation regimes occurred during some tests at about 500 g/s of steam mass flow rate (10 % of the maximum steam mass flow rate foreseen for the relevant accidental scenarios). In these conditions, high intensity vibrations of the whole experimental rig occurred. These events can be classified as ‘Chugging’ or Condensation Induced Water Hammer (CIWH). 
The performed tests have been analysed elaborating the images of the video-cameras located in the pool and comparing the steam jet shape with the acceleration values recorded by an accelerometer mounted on the sparger structure.
These elaborations permitted to evaluate the dynamic of bubble collapse, the volume of the developed external bubbles, the collapse frequency as function of thermal-hydraulic parameters. 
Moreover, the paper emphasizes the beneficial effects of non-condensable gases on the unstable condensation regimes. In fact, the non-condensable gas inhibits the occurrences of Water Hammer inside the sparger and eliminates the thermal stratification inside the water pool increasing the turbulence.

PEG-assisted synthesis of highly dispersed Cs/Zr-SiO2 catalyst for aldol condensation of methyl acetate with formaldehyde

The dispersion of active sites plays an imperative role in the promotion of catalytic performance on methyl acrylate synthesis via direct vaporous aldol condensation. Herein, a novel PEG-assisted impregnation method was proposed to synthesize Cs/Zr-SiO2 catalyst with high dispersion of acid and base sites. A series of characterization techniques including NMR, TEM, physical N2 adsorption isotherms, XRD, XPS, NH3-/CO2-TPD, and Py-IR were used to investigate the physico-chemical properties of these prepared catalyst series. The introduction of PEG improved the specific surface area, dispersion of active sites, and density of acid and base sites, resulting in superior catalytic performance of Cs/PEG@Zr-SiO2 by comparison with that of Cs/SiO2 and Cs/Zr-SiO2. The kinetic experiments revealed that the activation energy of aldol condensation was 80.8 kJ/mol over the Cs/PEG@Zr-SiO2 catalyst. The deactivation behavior derived from carbon deposition was discovered, and the spent catalyst could be regenerated by simple thermal treatment.

Numerical heat transfer analysis of steam injection into subcooled water

Steam direct contact condensation (DCC) into subcooled water may be encountered in different important industrial process applications, such as steam jet pumps, steam ejectors, pressurizers, and emergency cooling systems of nuclear reactor core. In this work, a numerical simulation study has been done for injection of steam into a tank full of subcooled water. In the simulations, the Eulerian multiphase flow in addition to a realizable k-epsilon turbulence model has been utilized. Moreover, a DCC model has been used for condensation capturing. Fluent software with a user-defined function (UDF) for the DCC model was employed for simulations. The results obtained from simulations were validated with experimental results, and a fair agreement was observed. This study considered the local Nusselt number (LNN) the most suitable parameter for investigating the heat transfer rate (HTR) at the computational cell level. Therefore, the contours of the LNN, its axial distribution, and radial distribution were studied with respect to the inlet pressure of injected steam, temperature of tank water, and location along the axis of the nozzle. The results reveal the fact that the value of the LNN reaches a maximum at the nozzle exit along the axis of the nozzle at 323 K tank water temperature. LNN decreases by increasing or decreasing the tank water temperature beyond 323 K. It is claimed that the heat transfer (HT) study at such a local scale has been conducted for the first time to the best of our knowledge, and it unfolds various crucial facts regarding steam-water interaction.

Synthesis of Oxaazaisowurtzitane Derivatives Via Condensation of p‐Toluenesulfonamide With Glyoxal

ABSTRACTThis work presents the study results on the acid‐catalyzed cascade condensation of p‐toluenesulfonamide with glyoxal in H2SO4 in order to synthesize aza‐ and oxaazaisowurtzitanes—a platform for promising high‐energy‐density compounds—and explore their formation processes. The effects of the ratio of starting reactants, acidity, reaction medium concentration, and temperature on this process were studied in detail. Five novel compounds were derived, including four oxaazaisowurtzitanes comprising one to three aza groups, and one condensation intermediate. The most favorable conditions for the formation of the resultant caged compounds were established and some new regularities of the process were revealed. For instance, the reaction medium concentration was discovered for the first time to influence the generation process of oxaazaisowurtzitanes via direct condensation. The limiting stage of the cage formation process of oxaazaisowurtzitanes was identified. The formation rate of the oxaazaisowurtzitanes was shown to be dependent on their structure. The factor dramatically reducing the yield of the oxaazaisowurtzitanes at elevated synthesis temperature was also revealed.

Numerical Simulation of Steam Jet Condensation Through a Triple Nozzle Submerged into a Subcooled Water Pool

Submerged steam jet condensation is widely applied in many industrial fields due to its high heat and mass transfer efficiency during the process of direct contact condensation (DCC). The injection of steam into a water pool usually passes through an array of nozzles. It is important to understand the interaction between neighboring jets from different nozzles. In this paper, two thermal resistance models for DCC are implemented into the computational fluid dynamics code ANSYS Fluent through a user-defined function. The triple steam nozzle cases, in which the inlet pressure ranges from 0.1 to 0.6 MPa, were investigated to understand the interaction of nozzles and their configuration as well as their mechanisms. The distributions of temperature, velocity, volumetric fraction, and pressure fields were analyzed for different cases. Furthermore, the plumes of steam jets always attract each other toward the center of the plumes, and when the inlet pressure is over 0.3 MPa, the mixing of neighboring steam plumes will occur. In addition, the location where the peak value occurs for the parameters of steam velocity, pressure, and temperature, etc. is getting closer and closer to the center of the flow domain. In addition, the curve of the pressure along the centerline of the nozzle verified the existence of compression and expansion of steam inside the plume.

Monothiolactide, a New Monomer for the Synthesis of Recyclable, Alternating Ester-Thioester Polymers.

Aliphatic polyesters and polythioesters are very interesting alternatives for current fossil-based and degradation-resistant plastics, due to their high (bio)degradability and (chemical) recyclability potential. Two important examples include polylactide (PLD), currently leading the synthetic bioplastics market, and its sulfur analog polythiolactide (PTLD). Both polymers can be made by ring-opening polymerization (ROP) of their corresponding (thio)dilactones, lactide (LD) and thiolactide (TLD) respectively. In this work, the benefits of esters and thioesters were combined in one material by the successful catalytic synthesis and ROP of monothiolactide (MTL), an unprecedented monomer containing half a LD and half a TLD structural unit. MTL can be obtained by a simple direct condensation of biobased lactic acid and thiolactic acid aided by Brønsted acid catalysis. The novel, but simple monomer showed to be easily polymerized with triethylamine to materials containing alternating lactic and thiolactic ester units with a very high molar mass. The lower stability of MTL (vs. TLD) resulted in improved ROP thermodynamics, while also fast and controllable polymerization kinetics were observed. The new polymers feature a good chemical recycling and hydrolytic degradation potential with important improvements compared to PTLD and PLD. Finally, a successful co-polymerization with commercial LD was shown, paving the way towards industrialization.

Momentum induced by steam injection into a subcooled pool

Boiling Water Reactors (BWR) and Advanced Pressurized Water Reactors (APWR) often use spargers to release steam from the primary coolant system into a pool with subcooled water to prevent containment overpressure. Direct contact Condensation (DCC) creates sources of mass, heat, and momentum determined by the condensation regimes in a subcooled pool. Thermal stratification can develop in the pool if buoyancy forces created by the heat source dominate the momentum source. Only part of the stratified pool volume can be used as the heat sink which is a safety concern. Modeling of steam injection and its effect on a large pool is computationally expensive due to the considerable spatial and temporal scale differences between the steam-water interface dynamics and global pool circulation. To enable the prediction of realistic plant transients, Effective Heat Source (EHS) and Effective Momentum Source (EMS) models were proposed. These models aim to calculate the time-averaged integral effects of the steam injection on the pool without resolving the dynamics of the interface and DCC phenomena.This work aims to develop the empirical correlations that predict the time-averaged effective momentum induced by steam injection into a subcooled pool. The experimental data were collected in a Separate Effect Facility (SEF-POOL) at LUT, Finland. The force acting on the injection pipe was measured in SEF-POOL to estimate the effective momentum rate created by steam injection. The condensation regime coefficient C, defined as the ratio of effective momentum rate to the theoretical momentum rate of injected steam, is presented as a function of Jakob and Mach numbers. We found that the pitch-to-diameter ratios (P/D) had a significant effect on both the effective (time averaged) momentum rate and instantaneous forces measured in the low Jakob number region, which might be attributed to the interactions between neighboring nozzles.

Synthesis of acetonitrile from NH3/syngas mixtures on molybdenum nitride: Insights into the reaction mechanism

Owing to their metallic-like surface electronic properties and their capacity to act as reservoirs and solid transfer agents for active nitrogen, transition metal nitrides are interesting as solid catalysts for C-C and C-N coupling reactions for the bottom-up production of higher (C2+) nitrogenated chemicals from unconventional carbon resources. The catalytically active state and reaction mechanism for the direct synthesis of acetonitrile from syngas/ammonia mixtures are studied on an unsupported Mo catalyst from complementary experimental and computational approaches. Temperature resolved X-ray diffraction and X-ray photoemission spectroscopy verify that an oxidic MoO3 catalyst precursor undergoes in situ (near-surface) nitridation, upon exposure to reaction conditions at 723 K, rendering Mo2N the actual working catalyst. Density Functional Theory mechanistic investigations on a γ-Mo2N(100) model surface point to a hydrogen-assisted CO dissociation on the nitride surface. Moreover, surface oxygen, evolved from CO dissociation, is predicted to play a central role as hydrogen acceptor, to enable the dehydrogenative NH3 dissociation. Direct condensation of CH and N adspecies proceeds with a low energy barrier of 33 kJ mol−1, which makes C-N coupling preferred over full hydrogenation of CHx species, in agreement with the experimental modest selectivity to methane (ca. 10 %). Both experimental and computational results indicate that HCN is a major intermediate product along the reaction pathway to acetonitrile. No energetically feasible associative reaction pathways could be identified for C-C coupling from HCN. The dissociation of the latter intermediate product is predicted to precede the reaction of CN adspecies to CHx. Similarly to NH3 dissociation, dehydrogenative HCN activation on the Mo2N surface is predicted to be facilitated through hydrogen abstraction by surface oxygen species, yet subjected to a comparatively higher energy barrier (>120 kJ mol−1), therefore likely to control the overall kinetics. These findings suggest that the enhancement of HCN dissociation is a central design objective towards Mo2N-based catalysts with advanced performance.

Experimental study on effect of submergence depth on steam jet shape characteristics in direct contact condensation

The phenomenon of direct contact condensation is frequently utilized in the industrial sector due to low driving potential requirements and proficient heat and mass transfer characteristics. This experimental study investigates the influence of nozzle submergence depth by condensing steam through a straight pipe (SP) and converging-diverging (CD) nozzle. The effect of operating conditions i.e. steam pressure and water temperature in addition to nozzle geometry were also studied on steam cavity shape characteristics. Six different shapes were manifested including unstable, conical, ellipsoidal, cylindrical, divergent, and double expansion-contraction. The dimensionless penetration length of plumes was observed in a range of 1.46–3.91 and 2.14–4.41 for the CD and SP nozzle, respectively while the maximum expansion ratio was determined to be 1–1.25 for the CD nozzle and 1.16–1.58 for the SP nozzle. It has been observed that jet length increases with an increase in submergence depth, steam pressure, and water temperature. The maximum expansion ratio was observed to decrease with the increase in submergence depth and increase with an increase in steam pressure and water temperature. The empirical correlations for dimensionless penetration length were developed and predicted results were found to be lying between ±10 % and ±7 % for CD and SP nozzle respectively.

Quantum chemical pathways for the formation of 2,3,7,8-tetrachloro dibenzo-p-dioxin (TCDD) from 2,4,5-trichlorophenol: a mechanistic and thermo-kinetic study.

Dioxins, specifically 2,3,7,8-tetrachlorinated dibenzo-p-dioxin (TCDD), are highly toxic dioxins known for their severe health impacts and persistent environmental pollutants. This study focuses on understanding the formation pathways of TCDD from its precursor molecule 2,4,5-trichlorophenol (2,4,5-TCP). In our exploration of reaction pathways from 2,4,5-trichlorophenol (TCP), we delve into three reaction mechanisms: free-radical, direct condensation, and anionic. Our findings highlight the significance of the radical mechanism, particularly propagated by H radicals, with a notable increase in dioxin formation around 900K. These results are consistent with experimental observations indicating an increase in the conversion of trichlorophenol from 600 to 900K in the non-catalytic gas phase reaction. Thermodynamic parameters (∆H, ∆S, and ∆G), reaction barriers, and rate constants (k) were calculated across a temperature range of 300-1200K to support the findings and provide insights into the optimal temperature range for controlling dioxins during the incineration process. In this study, quantum chemical calculations were conducted using density functional theory (DFT) with the B3LYP functional and the 6-311 + + G(d,p) basis set in Gaussian 16 software. Stationary points, including transition states (TS), were confirmed with frequency calculations. Intrinsic reaction coordinate (IRC) calculations ensured minimum energy paths between TS and products, visualized in GaussView 6.0 Program. Single-point energy calculations utilized a more precise basis set, 6-311 + + G(3df,2p), for enhanced energy accuracy, incorporating zero-point vibrational energy (ZPE) and other energy corrections. These calculations were repeated over a temperature range of 298.15-1200K at 1atm pressure. Finally, rate constant (k) expressions associated with TCDD formation were determined using transition state theory (TST).

Study of Condensation during Direct Contact between Steam and Water in Pressure-Relief Tank

Direct contact condensation (DCC) is a phenomenon observed when steam interacts with subcooled water, exhibiting higher heat and mass transfer rates compared to wall condensation. It has garnered significant interest across industries such as nuclear, chemical, and power due to its advantageous characteristics. In the context of pressure-relief tanks, understanding and optimizing the DCC process are critical for safety and efficiency. The efficiency of pressure-relief tanks depends on the amount of steam condensed per unit of time, which directly affects their operational parameters and design. This study focuses on investigating the direct gas–liquid contact condensation process in pressure-relief tanks using computational fluid dynamics (CFD). Through experimental validation and a sensitivity analysis, the study provides insights into the influence of inlet steam parameters and basin temperature on the steam plume characteristics. Furthermore, steady-state and transient calculation models are developed to simulate the behaviour of the pressure-relief tank, providing valuable data for safety analysis and design optimization. There is a relatively high-pressure area in the upper part of the bubble hole of the pressure-relief tube, and the value increases as it is closer to the holes. The steam velocity in the bubbling hole near the 90° elbow position is higher. This study contributes to the understanding of steam condensation dynamics in pressure-relief tanks. When the steam emission and pressure are fixed, the equilibrium temperature increases linearly as the initial temperature increases (where a = 1, b = 20 in y = a x+ b correlation), the equilibrium pressure increases nearly exponentially, and the equilibrium gas volume decreases. When the steam emission and initial temperature are fixed, the equilibrium temperature does not change as the steam discharge pressure increases. The correlations between the predicted equilibrium parameters and the inlet steam parameters and tank temperature provide valuable insights for optimizing a pressure-relief tank design and improving the operational safety in diverse industrial contexts.

Ruthenium/η5-Phenoxo-Catalyzed Amination of Phenols with Amines.

Ruthenium(II) complexes are known to form η6-arene complexes with benzene-containing compounds through π-coordination, a property extensively utilized to initiate reactions not typically observed with free arenes. A prime example is nucleophilic aromatic substitution, where ruthenium-complexed aryl halides undergo nucleophilic attack, allowing the direct synthesis of diverse aromatic compounds by displacing halides with nucleophiles. However, this activation relies on the electron-withdrawing effect of the Ru(II) species, as well as is hindered by the resistance of η6-arenes to arene exchange. In the previous pursuit of catalysis, the emphasis of ligand design has centered on promoting arene exchange. In this study, we extended the ruthenium activation strategy to umpolung substitution reactions of phenols. The amination proceeds through a direct condensation between phenols and amines, with a key intermediate identified as [bis(η5-phenoxo)Ru], which is in situ generated from a commercially available ruthenium catalyst. In comparison with the well-studied cyclopentadienyl (Cp) type ligands, we demonstrated that an η5-phenoxo motif, as a superior alternative to Cp, contributes to the amination of phenols in two crucial ways: its less electron-donating nature enhances the withdrawing effect of the ruthenium unit, facilitating substitution on the phenol complex; its distinctive behavior in arene exchange allows for conducting the amination with a catalytic amount of metal. Additionally, hydrogen bonding, wherein the phenoxo serves as the acceptor, was found to be important for the substitution. The versatility of this ruthenium-catalyzed amination was validated by performing reactions with a diverse array of phenols exhibiting various electronic properties, in combination with a wide range of primary amines. This work exemplifies the expansion of the scope of π-coordination activation in catalysis through innovative ligand development.

Study on the efficacy and mechanism of treatment of manganese-containing wastewater by pulse-alternating current coagulation

ABSTRACT To assess the effectiveness and underlying mechanism of pulse-alternating current coagulation (PACC) for treating manganese-laden wastewater, we examined the influence of various parameters. Specifically, we investigated the impact of current density, initial pH, initial Mn2+ concentration, electrolyte concentration, and alternating current frequency on the removal efficacy. The removal mechanism was meticulously examined using an adsorption kinetics analysis, Scanning Electron Microscope (SEM), Energy Dispersive Spectroscopy (EDS), Fourier Transform Infrared Spectrum (FTIR), and X-ray Photoelectron Spectroscopy (XPS). The findings indicated that the concentration of Re (Mn2+) was 99.09% under the specified conditions: j = 2.5 A·m−2, pH0 = 7, c 0(Mn2+) = 50 mg·dm−3, f = 500 Hz, c 0(NaCl) = 500 mg·dm−3 and t = 40 min. When Re (Mn2+) = 98%, the energy consumption (EEC) was significantly lower for PACC at 1.23 kWh·m−3, compared to 1.52 kWh·m−3 for direct current condensation (DCC). This indicated a reduction in EEC by 19.1% when using PACC over DCC. The adsorption process of Mn2+ by the iron sol adheres to the principles of pseudo-second order kinetics. The primary component of flocs generated in the PACC process is α-FeOOH. The mechanism of Mn2+ removal in the PACC process involved the synthesis of Mn oxides, the formation of metal hydroxide precipitates and adsorption by nano-iron sol. This study provides a theoretical basis and technical support for the application of PACC technology in the field of manganese-containing wastewater treatment.

Bottom-up synthesis of a sulfhydryl-modified heteroporous covalent organic framework for ultrafast removal of trace Hg(Ⅱ) from water

The development of functionalized covalent organic frameworks (COFs) is crucial in expanding their potential for removing toxic heavy metals from drinking water. Here, a new sulfhydryl-modified heteroporous COF (COFDBD-BTA) was prepared using a “bottom-up” approach in which a direct amine-aldehyde dehydration condensation between 2,5-diamino-1,4-benzenedithiol dihydrochloride (DBD) and [1,1′-biphenyl]-3,3′,5,5′-tetracarbaldehyde (BTA) was occurred. The COFDBD-BTA featured a hexagonal kagome (kgm) structure and a sheet-like morphology. Notably, COFDBD-BTA contained densely S atoms that provided high-density Hg(II) adsorption sites for efficient and selective trace Hg(II) removal. COFDBD-BTA exhibited excellent performance in rapidly removing trace Hg(II) from 30 μg L−1 to 0.71 μg L−1 within 10 s, below the World Health Organization's allowable limit of 1 μg L−1. Additionally, COFDBD-BTA exhibited a high Hg (Ⅱ) removal level from water, achieving adsorption capacity of 687.38 mg g−1. Furthermore, the adsorbent exhibited a wide range of applicability for low concentration (6–500 μg L−1) Hg (Ⅱ), a simple and feasible regeneration method, and strong Hg(II) removal ability in real tap water systems. The excellent adsorption efficiency, outstanding recyclability, and one-step room temperature synthesis make S-rich COFDBD-BTA a promising candidate for eliminating Hg (Ⅱ) from drinking water.