Dipole Field Research Articles

Dipole field as charge-transfer bridge between Cu atomic clusters/PtCu alloy nanocubes and nitrogen-rich C3N5 for superior photocatalytic hydrogen evolution

Utilizing spontaneous polarization field to harness charge transfer kinetics is a promising strategy to boost photocatalytic performance. Herein, a novel Cu atom clusters/PtCu alloy nanocubes coloaded on nitrogen-rich triazole-based C3N5 (PtCu-C3N5) with dipole field was constructed through facile photo-deposition and impregnation method. The dipole field-drive spontaneous polarization in C3N5 acts as a charge-transfer bridge to promote directional electron migration from C3N5 to Cu atom clusters/PtCu alloy. Through the synergistic effects between Cu atom clusters, PtCu alloy and dipole field in C3N5, the optimized Pt2Cu3-C3N5 achieved a record-high performance with H2 formation rate of 4090.4 μmol g−1 h−1 under visible light, about 154.4-fold increase compared with pristine C3N5 (26.5 μmol g−1 h−1). Moreover, the apparent quantum efficiency was up to 25.33 % at 320 nm, which is greatly superior than most previous related-works. The directional charge transfer mechanism was analyzed in detail through various characterizations and DFT calculations. This work offers a novel pathway to construct high-efficiency multi-metal photocatalysts for solar energy conversion.

Columnar Macrocyclic Molecule Tailored Grain Cage to Stabilize Inorganic Perovskite Solar Cells with Suppressed Halide Segregation

AbstractSolidifying the soft lattice of all‐inorganic mixed‐halide perovskites is of great importance to restrain the notorious halide segregation under persistent light illumination. Herein, a multifunctional columnar macrocyclic molecule additive, namely cucurbituril into perovskite precursor to enhance the crystallization and reduce the defect density in the final perovskite film is introduced. Based on the theoretical calculation and simulation, the cucurbituril molecule with a strong double‐ended negatively‐charged cavity surrounded by terminated oxygen atoms not only coordinates with dangling Pb2+ ions to form host‐guest complexation but also induces an electric dipole field at perovskite grain boundary to effectively repel the iodide ion migration from the inside grain to the defective boundary, significantly suppressing the halide segregation and improving the device performance. As a result, the carbon‐based, all‐inorganic CsPbI2Br solar cell achieves an enhanced efficiency of 15.59% with great tolerance to environmental stresses. These findings provide new insights into the development of a novel passivation strategy with macrocyclic molecules for making high‐efficiency and stable perovskite solar cells.

A quantitative explanation of the cyclotron-line variation in accreting magnetic neutron stars of super-critical luminosity

Context. Magnetic neutron stars (NSs) often exhibit a cyclotron resonant scattering feature (CRSF) in their X-ray spectra. Cyclotron lines are believed to be generated in the radiative shock in the accretion column. High-luminosity NSs show a smooth anti-correlation between the cyclotron-line centroid (ECRSF) and X-ray luminosity (LX). Aims. It has been pointed out that the observed ECRSF − LX smooth anti-correlation in high-luminosity NSs is in tension with the theoretically predicted one, if the radiative shock is the site of cyclotron-line formation. The shock height increases approximately linearly with luminosity, while the dipolar magnetic field drops as the cubic power of distance, thereby implying that the cyclotron-line energy ought to decrease significantly when the luminosity increases by, say, an order of magnitude, which is contrary to observations. Since there is no other candidate site for the cyclotron-line formation, we re-examine the predicted rate of change of the cyclotron-line energy with luminosity at the radiative shock, taking a closer look at the Physics involved. Methods. We developed a purely analytical model describing the overall dependence of the observed cyclotron energy centroid on the shock front’s height, including both the relativistic boosting and the gravitational redshift effects in our considerations. The relativistic boosting effect is due to the mildly relativistic motion of the accreting plasma upstream with respect to the shock’s reference frame. Reults. We find that the cyclotron-line energy varies with (a) the shock height due to the dipolar magnetic field, (b) the Doppler boosting between the shock and bulk-motion frames, and (c) the gravitational redshift. We show that the relativistic effects noticeably weaken the predicted ECRSF − LX anti-correlation. We use our model to fit the data of the X-ray source V0332+53 that exhibits a weak negative correlation and demonstrate that the model fits the data impressively well, thereby alleviating the tension between observations and theory. Conclusions. The reported weak anti-correlation between cyclotron-line centroid and X-ray luminosity in the supercritical accretion regime may be explained by the combination of the variation of the magnetic-field strength along the accretion column, the effect of Doppler boosting, and the gravitational redshift. As a result of these effects, the actual magnetic field on the surface of the neutron star may be a factor of ∼2 larger than the naively inferred value from the observed CRSF.

Generation of Field‐Aligned Currents in Response to Sudden Enhancement of Solar Wind Dynamic Pressure

AbstractWe investigated the generation of field‐aligned currents (FACs) in response to the sudden enhancement of the solar wind dynamic pressure by tracing backward in time a packet of the Alfvén wave in the global magnetohydrodynamic (MHD) simulation. The generation region is identified from three perspectives, including the continuity of the current, the energy conservation and the time rate of change in the FACs. The generation mechanism is found to be related with the tailward motion of the compressional wave, which is excited when the magnetopause is compressed due to the solar wind dynamic pressure pulse. The compressional wave with a high magnetic pressure center interacts with the Earth's dipole field and forms a protruding part of the wavefront near the equatorial plane. The leading edge of the merged magnetic pressure that pertains to the compressional wave and the Earth starts to generate preliminary impulse (PI) FACs off the equator, as the magnetic pressure force accelerates the plasma and magnetic field lines are bent (FAC dynamo 1). Main impulse (MI) FACs are generated behind the leading edge in the equatorial plane due to the enhanced magnetic tension force (FAC dynamo 2). Magnetic field lines would be extremely curved during the passage due to the increasing magnetic tension force. The polarity of PI FACs is decided by the parallel vorticity of plasma flow, and MI FACs are the result of enhanced perpendicular currents together with the plasma flow in the equatorial plane.

Dipole acoustic remote detection (ARD) logging and its application in fracture-cave reservoir

Abstract Oil and gas from deep reservoirs are mostly enriched in the fracture-cave reservoirs. For this reason, fine evaluation of large-scale fracture-cave and effective detection of small scale fracture-cave are the key issues to be solved in the exploration of fracture-cave type carbonate reservoirs. The acoustic remote detection logging technology is based on acoustic reflection method to continuously image the formation around the well. The cross dipole array sonic data can be processed to image geological anomalies within a range of about 20 meters outside the well. Dipole S wave remote detection has the remarkable advantages of low emission frequency and larger investigation depth, but it has 180 degrees’ azimuthal ambiguity. This study is based on previously developed far field dipole S wave remote detection tool, finite difference is performed on formation models with and without are obtained for representative fracture-cave formations and remote detection processing and interpretation software is updated. These are applied on a well in the northwestern area. Through the comprehensive analysis of remote logging, conventional logging, electrical imaging logging and seismic data of the fracture-cave geological anomalies, a fine picture of the morphology and development of the geological anomalies from the near wellbore to the far end is formed

Dual-Vacancy-Engineered ZnIn2S4 Nanosheets for Harnessing Low-Frequency Vibration Induced Piezoelectric Polarization Coupled with Static Dipole Field to Enhance Photocatalytic H2 Evolution.

This study investigates the impact of In- and S-vacancy concentrations on the photocatalytic activity of non-centrosymmetric zinc indium sulfide (ZIS) nanosheets for the hydrogen evolution reaction (HER). A positive correlation between the concentrations of dual In and S vacancies and the photocatalytic HER rate over ZIS nanosheets is observed. The piezoelectric polarization, stimulated by low-frequency vortex vibration to ensure the well-dispersion of ZIS nanosheets in solution, plays a crucial role in enhancing photocatalytic HER over the dual-vacancy engineered ZIS nanosheets. The piezoelectric characteristic of the defective ZIS nanosheets is confirmed through the piezopotential response measured using piezoelectric force microscopy. Piezophotocatalytic H2 evolution over the ZIS nanosheets is boosted under accelerated vortex vibrations. The research explores how vacancies alter ZIS's dipole moment and piezoelectric properties, thereby increasing electric potential gradient and improving charge-separation efficiency, through multi-scale simulations, including Density Functional Theory and Finite Element Analysis, and a machine-learning interatomic potential for defect identification. Increased In and S vacancies lead to higher electric potential gradients in ZIS along [100] and [010] directions, attributing to dipole moment and the piezoelectric effect. This research provides a comprehensive exploration of vacancy engineering in ZIS nanosheets, leveraging the piezopotential and dipole field to enhance photocatalytic performances.

Circular Polarization of Simulated Images of Black Holes

Models of the resolved Event Horizon Telescope (EHT) sources Sgr A* and M87* are constrained by observations at multiple wavelengths, resolutions, polarizations, and time cadences. In this paper, we compare unresolved circular polarization (CP) measurements to a library of models, where each model is characterized by a distribution of CP over time. In the library, we vary the spin of the black hole, the magnetic field strength at the horizon (i.e., both SANE and magnetically arrested disk or MAD models), the observer inclination, a parameter for the maximum ion–electron temperature ratio assuming a thermal plasma, and the direction of the magnetic field dipole moment. We find that Atacama Large Millimeter/submillimeter Array (ALMA) observations of Sgr A* are inconsistent with all edge-on (i = 90°) models. Restricting attention to the MAD models favored by earlier EHT studies of Sgr A*, we find that only models with magnetic dipole moment pointing away from the observer are consistent with ALMA data. We also note that in 26 of the 27 passing MAD models, the accretion flow rotates clockwise on the sky. We provide a table of the means and standard deviations of the CP distributions for all model parameters, along with their trends.

Toward a Live Homogeneous Database of Solar Active Regions Based on SOHO/MDI and SDO/HMI Synoptic Magnetograms. II. Parameters for Solar Cycle Variability

Solar active regions (ARs) determine solar polar fields and cause solar cycle variability within the framework of the Babcock–Leighton dynamo. The contribution of an AR to the polar field is measured by its dipole field, which results from flux emergence and subsequent flux transport over the solar surface. The dipole fields contributed by an AR before and after the flux transport are referred to as the initial and final dipole fields, respectively. For a better understanding and prediction of solar cycles, in this paper, we provide a database including AR's initial and final dipole fields and the corresponding results of their bipolar magnetic region (BMR) approximation from 1996 onward. We also identify the repeated ARs and provide the optimized transport parameters. Based on our database, we find that although the commonly used BMR approximation performs well for the initial dipole field, it exhibits a significant deviation for the final dipole field. To accurately assess an AR’s contribution to the polar field, the final dipole field with its real configuration should be applied. Despite the notable contributions of a few rogue ARs, approximately the top 500 ARs ordered by their final dipole fields are necessary to derive the polar field at the cycle minimum. While flux transport may increase or decrease the dipole field for an individual AR, its collective impact over all ARs in a cycle is a reduction in their total dipole field.

Conceptual Design Study of a Superconducting Flywheel System With Enhanced Speed Using Dipole Field

Conceptual Design Study of a Superconducting Flywheel System With Enhanced Speed Using Dipole Field

Magnetic skin effect in Pb(Fe _{1/2}$ Nb _{1/2}$ )O3

Relaxor-ferroelectrics display exceptional dielectric properties resulting from the underlying random dipolar fields induced by strong chemical inhomogeneity. An unusual structural aspect of relaxors is a skin-effect where the near-surface region in single crystals exhibit structures and critical phenomena that differ from the bulk. Relaxors are unique in that this skin effect extends over a macroscopic lengthscale of ∼100 μm whereas usual surface layers only extend over a few unit cells (or ∼nm). We present a muon spectroscopy study of Pb(Fe _{1/2} Nb _{1/2} )O3 (PFN) which displays ferroelectric order, including many relaxor-like dielectric properties such as a frequency broadened dielectric response, and antiferromagnetism with spatially short-range polar correlations and hence can be termed a multiferroic. In terms of the magnetic behavior determined by the Fe3+ ( S=5/2 , L ≈ 0) ions, PFN has been characterized as a unique example of a ‘cluster spin-glass’. We use variable momentum muon spectroscopy to study the depth dependence of the slow magnetic relaxations in a large 1 cm3 crystal of PFN. Zero-field positive muon spin relaxation is parameterized using a stretched exponential, indicative of a distribution of relaxation rates of the Fe3+ spins. This bandwidth of frequencies changes as a function of muon momentum, indicative of a change in the Fe3+ relaxation rates as a function of muon implantation depth in our single crystal. Using negative muon elemental analysis, we find small-to-no measurable change in the Fe3+/Nb5+ concentration with depth implying that chemical concentration alone cannot account for the change in the relaxational dynamics. PFN displays an analogous magnetic skin effect reported to exist in the structural properties of relaxor-ferroelectrics.

Robust parahydrogen-induced polarization at high concentrations.

Parahydrogen-induced polarization (PHIP) is a potent technique for generating target molecules with high nuclear spin polarization. The PHIP process involves a chemical reaction between parahydrogen and a target molecule, followed by the transformation of nuclear singlet spin order into magnetization of a designated target nucleus through magnetic field manipulations. Although the singlet-to-magnetization polarization transfer process works effectively at moderate concentrations, it is observed to become much less efficient at high molar polarization, defined as the product of polarization and concentration. This strong dependence on the molar polarization is attributed to interference due to the field produced by the sample magnetization during polarization transfer, which leads to complex dynamics and can severely affect the scalability of the technique. We address this challenge with a pulse sequence that suppresses the influence of the distant dipolar field, while simultaneously achieving singlet-to-magnetization polarization transfer to the desired target spins, free from restrictions on the molar polarization.

A quantum sensor for atomic-scale electric and magnetic fields

The detection of faint magnetic fields from single-electron and nuclear spins at the atomic scale is a long-standing challenge in physics. While current mobile quantum sensors achieve single-electron spin sensitivity, atomic spatial resolution remains elusive for existing techniques. Here we fabricate a single-molecule quantum sensor at the apex of the metallic tip of a scanning tunnelling microscope by attaching Fe atoms and a PTCDA (3,4,9,10-perylenetetracarboxylic-dianhydride) molecule to the tip apex. We address the molecular spin by electron spin resonance and achieve ~100 neV resolution in energy. In a proof-of-principle experiment, we measure the magnetic and electric dipole fields emanating from a single Fe atom and an Ag dimer on an Ag(111) surface with sub-angstrom spatial resolution. Our method enables atomic-scale quantum sensing experiments of electric and magnetic fields on conducting surfaces and may find applications in the sensing of spin-labelled biomolecules and of spin textures in quantum materials.

Observational clues to the magnetic evolution of magnetars

ABSTRACT Utilizing four archival X-ray data sets taken with the Hard X-ray Detector onboard Suzaku, timing studies were performed on three magnetars, 1E 1841−045 (observed in 2006), SGR 0501+4516 (2008), and 1RXS J170849.0−400910 (2009 and 2010). Their pulsations were reconfirmed, typically in an energy range of 12–50 keV. The 11.783 s pulses of 1E 1841−045 and those of SGR 0501+4516 at 5.762 s were periodically phase modulated, with a long period of $\approx 23.4$ and $\approx 16.4$ ks, respectively. The pulse-phase modulation was also observed, at $\approx 46.5$ ks, from two data sets of 1RXS J170849.0−400910. In all these cases, the modulation amplitude was 6 per cent to 16 per cent of the pulse cycle. Including previously confirmed four objects, this characteristic timing behaviour is now detected from seven magnetars in total, and interpreted as a result of free precession of neutron stars that are deformed to an asphericity of $\sim 10^{-4}$. Assuming that the deformation is due to magnetic stress, these magnetars are inferred to harbour toroidal magnetic fields of $B_{\rm t}\sim 10^{16}$ G. By comparing the estimated $B_{\rm t}$ of these objects with their poloidal dipole field $B_{\rm d}$, the $B_{\rm t}/B_{\rm d}$ ratio is found to increase with their characteristic age. Therefore, the toroidal fields of magnetars are likely to last longer than their poloidal fields. This explains the presence of some classes of neutron stars that have relatively weak $B_{\rm d}$ but are suspected to hide strong $B_{\rm t}$ inside them.

Voltage-Driven Fluorine Motion for Novel Organic Spintronic Memristor.

Integrating tunneling magnetoresistance (TMR) effect in memristors is a long-term aspiration because it allows to realize multifunctional devices, such as multi-state memory and tunable plasticity for synaptic function. However, the reported TMR in different multiferroic tunnel junctions is limited to 100%. This work demonstrates a giant TMR of -266% in La0.6Sr0.4MnO3(LSMO)/poly(vinylidene fluoride)(PVDF)/Co memristor with thin organic barrier. Different from the ferroelectricity-based memristors, this work discovers that the voltage-driven florine (F) motion in the junction generates a huge reversible resistivity change up to 106% with nanosecond (ns) timescale. Removing F from PVDF layer suppresses the dipole field in the tunneling barrier, thereby significantly enhances the TMR. Furthermore, the TMR can be tuned by different polarizing voltage due to the strong modification of spin-polarization at the LSMO/PVDF interface upon F doping. Combining of high TMR in the organic memristor paves the way to develop high-performance multifunctional devices for storage and neuromorphic applications.

Design and Implementation of an Energy Selector for Laser-Accelerated Protons

Highly intense bunches of protons and ions with energies of several MeV/u can be generated with ultra-short laser pulses focused on solid targets. In the most common interaction regime, target normal sheath acceleration, the spectra of these particles are spread over a wide range following a Maxwellian distribution. We report on the design and testing of a magnetic chicane for the selection of protons within a limited energy window. This consisted of two successive, anti-parallel dipole fields generated by cost-effective permanent C-magnets with customized configuration and longitudinal positions. The chicane was implemented into the target vessel of a petawatt laser facility with constraints on the direction of the incoming laser beam and guidance of the outgoing particles through a vacuum port. The separation of protons and carbon ions within distinct energy intervals was demonstrated and compared to a ray tracing code. Measurements with radiochromic film stacks indicated the selection of protons within [2.4, 6.9] MeV, [5.0, 8.4] MeV, or ≥6.9 MeV depending on the lateral dispersion. A narrow peak at 4.8 MeV was observed with a time-of-flight detector.

Influence of Solar Dipole Field on Earthquake Occurrence

Influence of Solar Dipole Field on Earthquake Occurrence

Novel Spectrometer Designs for Laser-Driven Ion Acceleration

We propose novel spectrometer designs that aim to enhance the measured spectral range of ions on a finite-sized detector. In contrast to the traditional devices that use a uniform magnetic field, in which the deflection of particles increases inversely proportional to their momentum, in a gradient magnetic field, the deflection of particles will decrease due to the reduction of the magnetic field along their propagation. In this way, low-energy ions can reach the detector because they are deflected less, compared to the uniform field case. By utilizing a gradient magnetic field, the non-linear dispersion of ions in a homogeneous magnetic field approaches nearly linear dispersion behavior. Nonetheless, the dispersion of low-energy ions, using a dipole field, remains unnecessarily high. In this article, we discuss the employed methodology and present simulation results of the spectrometer with an extended ion spectral range, focusing on the minimum detectable energy (energy dynamic range) and energy resolution.

Modeling the Propagation of Extremely Low Frequency Electromagnetic Emissions From the Power Lines to the Inner Magnetosphere in a Dipole Field

Modeling the Propagation of Extremely Low Frequency Electromagnetic Emissions From the Power Lines to the Inner Magnetosphere in a Dipole Field

Helmholtz–Galerkin Technique in Dipole Field Scattering from Buried Zero-Thickness Perfectly Electrically Conducting Disk

Non-invasive concealed object detection, identification, and discrimination have been of interest to the research community for decades due to the needs to preserve infrastructures and artifacts, guarantee safe conditions for the detection and location of landmines, etc. A modern approach is based on the use of an unmanned aerial vehicle equipped with ground-penetrating radar, which has the advantage of not requiring direct contact with the ground. Moreover, high-resolution underground images are obtained by coherently combining measurements by using a synthetic aperture radar algorithm. Due to the complexity of the real scenario, numerical analyses have always been welcomed to provide almost real-time information to make the best use of the potential of such kinds of techniques. This paper proposes an analysis of the scattering from a zero-thickness perfectly electrically conducting disk buried in a lossy half-space surrounded by air and illuminated by a field generated by a Hertzian dipole located in the air. It is carried out by means of a generalized form of the analytically regularizing Helmholtz–Galerkin technique, introduced and successfully applied by the authors to analyze the plane-wave scattering from a disk and a holed plane in a homogeneous medium. As clearly shown in the numerical results, the proposed method is very effective and drastically outperforms the commercial software CST Microwave Studio 2023.

Perfect transmission through lossy layers via ideal acoustic sources

Complementary acoustic metamaterials (CAMMs) have been proposed as a means of enhancing the transmission of acoustic imaging signals through aberrating layers. Aberrating layers with high impedance contrast compared to the surrounding material disrupt the acoustic field and hence distort acoustic images. However, conventional CAMMs are passive and thus unable to compensate for signal distortions associated with loss. This work presents an approach inspired by CAMMs that is not bound by the limits of passivity to compensate for both acoustic scattering and energy attenuation by augmenting a plane wave incident on a lossy material with monopolar and dipolar source fields to allow for perfect transmission, thus rendering the lossy medium acoustically transparent. We present a general approach to derive expressions for source magnitudes that are dimensionless with respect to frequency, system geometry, and the background medium. We validate these results with three-dimensional finite element simulations, where the appropriate monopolar and dipolar source fields are generated by prescribing velocities on finite-dimensional boundaries. We show the limitations of this approach with regard to frequency, system geometry, and lossy material characteristics via a parametric study.