Dipole Force Research Articles

Control of Electromagnetic Formation Flight of Two Satellites in Low Earth Orbits

Electromagnetic formation flight uses the electromagnetic interaction between satellites to provide maneuver control for formation satellites, with the advantages of no propellant consumption, long life, and high flexibility. However, high-precision control for electromagnetic formation flight is challenging because of the nonlinear and coupling characteristics of the dynamics, optimal assignment of magnetic dipoles, model uncertainties, and the angular momentum management issues caused by the geomagnetic field. This paper studies the 6-DOF control problem of two-satellite electromagnetic formation flight in low-Earth orbit. A new electromagnetic frame is introduced to promote the decoupling of the translation dynamics model and the electromagnetic model. The electromagnetic model can be expressed as a simple two-dimensional model in this electromagnetic frame. The proposed electromagnetic force envelope diagram can intuitively show the relationship between electromagnetic force and magnetic dipoles, providing practical guidance for dipole assignment. The frequency division multiplexing method is designed for angular momentum management considering the effect of the earth’s magnetic field on the electromagnetic satellites, and the active disturbance rejection control method is used to solve the 6-DOF stability problem with external disturbance and model uncertainties. Numerical simulation verifies the effectiveness of the proposed control method and angular momentum management strategy.

Optimization and mass transfer simulation of remazol brilliant blue R dye adsorption onto meranti wood based activated carbon

Remazol brilliant blue R dye (RBBR) brings toxicity to living organisms once it enters the environment. This study utilized response surface methodology (RSM) and Polymath software for optimization and mass transfer simulation purposes, respectively. RSM revealed that the optimum preparation conditions of meranti wood-based activated carbon (MWAC) were 441 W, 5.76 min, and 1.35 g/g for radiation power, radiation time, and KOH:char impregnation ratio (IR), respectively, which translated into 86.39 mg/g of RBBR uptakes and 31.94 % of MWAC’s yield. The simulation study predicted the mass transfer rate, rm to be 112.20 to 1007.50 s−1 and the adsorption rate, k1 to be 3.96 to 4.34 h−1. The developed model predicted the adsorption surface area, am to be 790.04 m2/g and this value is highly accurate as compared to the actual mesopores surface area of 825.58 m2/g. Mechanism analysis divulged that the interaction that occurred between RBBR molecules and MWAC’s surface were hydrogen bond (methylene and alkyne), dipole–dipole force (alkyl carbonate, terminal alkyne, and methoxy), and ion–dipole force (primary amine). The isotherm and kinetic studies found that the adsorption data obeyed the Freundlich model and pseudo-first-order (PFO) model the best, respectively. The Langmuir maximum adsorption capacity, Qm was computed to be 327.33 mg/g. Thermodynamic parameters were calculated to be −4.06 kJ mol−1, 0.06 kJ mol−1 K−1, –22.69 kJ mol−1, and 16.03 kJ mol−1 for ΔH°, ΔS°, ΔG°, and Ea, respectively, which signified the adsorption process studied was exothermic, spontaneous and governed by physisorption.

Unveiling Spin State‐Dependent Micropollutant Removal using Single‐Atom Covalent Triazine Framework

AbstractSingle‐atom materials, with unique electronic structure and maximized atom utilization, have shown huge application potential in the remediation of emerging organic pollutants (EOPs), but revealing intrinsic reaction mechanisms at spin state level remains a formidable challenge. Herein, a single‐atom Ti‐loaded covalent organic framework (Ti1/CTF) is constructed for two‐stage process that involved adsorption and photocatalytic synergy, and the essential role of the electronic spin state in regulating the intrinsic activity of the material is evidenced. Spin‐polarized Ti1N3/CTF‐10 considerably enhances the adsorption capacity (453.285 µmol g−1) and degradation kinetics (2.263 h−1, 17.0‐fold faster than CTF‐0) for 2,2,4,4'‐tetrehydroxybenzophenone (BP‐2) and provides long‐term stability (93.3% BP‐2 removal in seven cycles) and favorable cost‐effectiveness (4.45 kWh∙m−3electrical energy per order) in natural water applications. Theoretical calculations and experimental results suggest that the Ti1N3moieties of single‐atom Ti bonded to pyridine and triazine N induce electron spin‐down polarization near the Fermi energy level of the active site, providing a strong dipole force and motive power for electron transfer. This study provides new insights into the adsorption, activation, and photodegradation of EOPs at the material interface from the electronic spin level and demonstrates promising solutions for water micropollution control.

Polarization‐Dependent Optical Forces Arising from Fano Interference

AbstractA Fano resonance originates from the resonant coupling between interacting multipoles inside nanostructures. It breaks the symmetry of spectral line shape and enables Fano‐resonant media to present unusual scattering properties. However, understanding the mechanical effects of such multipolar coupling systems is highly complex compared with the traditional simple dipole. In this work, using single Si nanospheres as the Fano‐resonant media, optical forces arising from different types of Fano resonances including the electric, magnetic, and magnetoelectric Fano resonances are investigated. It is shown that the directions of these types of forces are tunable in three dimensions. The necessary condition to realize a direction change of the Fano‐resonance‐induced forces and elucidate the underlying physics are presented. Furthermore, it is found that the Fano‐resonance‐induced forces exhibit strong polarization‐dependent properties which traditional optical (dipolar) forces cannot possess.

Spin-crossover in [Fe(Quinazoline)2][Fe(CN)5NO]. Evidence of its framework flexibility

The titled material shows a thermally induced spin-crossover (SCO) in the 75–150 K temperature region, with a narrow hysteresis of about 3 K. The recorded DSC data show a similar small hysteresis. Such behavior suggests that its framework has high flexibility, making possible the reversible spin transition on the sample cooling and warming, with slight kinetic effects. The crystal structure of this material was solved and refined from powder XRD patterns, complemented with information from IR, Raman, TG, and Mössbauer data. It crystallizes with a monoclinic unit cell in the P21 space group. Its framework is formed by stacked [Fe(Quinazoline)2][Fe(CN)5NO] layers. The organic molecule occupies the axial coordination sites for the iron atom linked to the N ends of equatorial CN ligands. In the interlayer region, organic ligands from adjacent layers remain coupled through weak dipolar and dispersive forces and a π⋅⋅⋅π interaction. Such relatively weak forces between adjacent layers explain the high framework flexibility inferred from the magnetic and DSC data. The crystal structure for the low temperature (low spin) phase was obtained by periodic DFT calculations using the VASP package. The results herein discussed contribute to understanding the role of the solid framework flexibility on the spin-crossover behavior in Hofmann-like 2D coordination polymers.

Instability of a thin film of chemotactic active suspension

In this paper, we analyse the instability of a thin-film suspension of micro-swimmers subjected to an attractant gradient. The imposed attractant gradient introduces a preferential swimming direction for the swimmers, resulting in an anisotropic orientation field. By modelling the swimmers as force dipoles, the study by Kasyap & Koch (Phys. Rev. Lett., vol. 108, issue 3, 2012, 038101, J. Fluid Mech., vol. 741, 2014, pp. 619–657) found an instability arising from the coupling between the active stress associated with an anisotropic orientation field and perturbations to the swimmer density field. In this work we begin by presenting a stability analysis that calculates the modification of this instability in the presence of an interface. We then detail the presence of a new mode of instability that arises solely from the deformation of the interface mediated by the active stress in the suspension. The resulting hydrodynamic instabilities in the system are observed to be sensitive to the direction of the attractant gradient relative to the interface. Furthermore, we show that the coupling between the two modes involving a jump in interfacial viscous stresses and normal stress differences within the suspension allows for an instability to manifest in a suspension of chemotactic pullers, previously thought to be unconditionally stable. We then use a long-wave theory to write down a set of nonlinear equations governing the film evolution. The numerical solution of the system using the long-wave theory aids in explaining the mechanism associated with the instability in addition to validating the predictions from the linear stability theory.

The role of Carica papaya latex bio-catalyst and thermal shock in water on synthesizing rice husk

A bio-catalyst made of natural resources, such as Carica papaya latex, is very challenging for nanoparticle separation. In addition, differences in thermal conditions between nanoparticles affect the movement of substances in the separation process. The study experimentally investigated the role of Carica papaya latex bio-catalyst and thermal shock in water on synthesizing rice husk (RH). The synthesis retained the Mg and C elements attached to SiO2, which were generally neglected during the process. The study's objective was to evaluate the effectiveness of biocatalysts and thermal effects on the separation of Mg-SiO2-C from rice husk carbon nanoparticles (CNPs-RH). The research involved various treatment processes, such as RH pyrolysis in obtaining charcoal, High energy milling (HEM) to have carbon particles, and washing to get nano-sized carbon particles. The bonding of elemental compounds to rice husk carbon particles (CPs-RH) was released using NaOH and coagulation using a bio-catalyst. Coagulated CPs-RH was injected into water at a temperature of 60–70 °C to have a thermal shock effect for H2O clusters in Na+ and Mg2+ ions attached to the surface of the nanoparticles. Several tests were carried out, such as the SEM-EDX, TEM, XRD, and FTIR tests, to investigate the two nanoparticle clusters formed up to the nanometer scale. The results indicated that CNPs-RH nanoparticles consist of spherical particles with a diameter of 1.2 nm, while Mg-SiO2-C nanoparticles have a diameter of 0.6 nm. Both are classified as amorphous. Based on the FTIR test, CNPs-RH is hydrophilic, while Mg-SiO2-C is hydrophobic. Thermal shock in water strengthens the ion's mobility, increasing the interfacial dipole forces between nanoparticles and accelerating the separation process.

Range and strength of mechanical interactions of force dipoles in elastic fiber networks.

Mechanical forces generated by myosin II molecular motors drive diverse cellular processes, most notably shape change, division and locomotion. These forces may be transmitted over long range through the cytoskeletal medium - a disordered, viscoelastic network of biopolymers. The resulting cell size scale force chains can in principle mediate mechanical interactions between distant actomyosin units, leading to self-organized structural order in the cell cytoskeleton. Inspired by such force transmission through elastic structures in the cytoskeleton, we consider a percolated fiber lattice network, where fibers are represented as linear elastic elements that can both bend and stretch, and the contractile activity of myosin motors is represented by force dipoles. Then, by using a variety of metrics, we show how two such contractile force dipoles interact with each other through their mutual mechanical deformations of the elastic fiber network. As a prelude to two-dipole interactions, we quantify how forces propagate through the network from a single anisotropic force dipole by analyzing clusters of nodes connected by highly strained bonds, as well as through the decay rate of strain energy with distance from a force dipole. We show that predominant fiber bending screens out force propagation, resulting in reduced and strongly network configuration-dependent dipole interactions. On the other hand, stretching-dominated networks support longer-ranged inter-dipole interactions that recapitulate the predictions of linear elasticity theory. By characterizing the differences between tensile and compressive force propagation in the fiber network, we show how inter-dipole interaction depends on the dipoles' mutual separation and orientation. The resulting elastic interaction energy may mediate a force between multiple distant dipoles, leading to their self-organization into ordered configurations. This provides a potential pathway for active mechanical force-driven structural order in elastic biopolymer networks.

Spontaneous flows and dynamics of full-integer topological defects in polar active matter.

Polar active matter of self-propelled particles sustain spontaneous flows through the full-integer topological defects. We study theoretically the incompressible flow profiles around ±1 defects induced by polar and dipolar active forces. We show that dipolar forces induce vortical flows around the +1 defect, while the flow around the -1 defect has an 8-fold rotational symmetry. The vortical flow changes its chirality near the +1 defect core in the absence of the friction with a substrate. We show analytically that the flow induced by polar active forces is vortical near the +1 defect and is 4-fold symmetric near the -1 defect, while it becomes uniform in the far-field. For a pair of oppositely charged defects, this polar flow contributes to a mutual interaction force that depends only on the orientation of the defect pair relative to the background polarization, and that enhances defect pair annihilation. This is in contradiction with the effect of dipolar active forces which decay inversely proportional with the defect separation distance. As such, our analyses reveals a long-ranged mechanism for the pairwise interaction between topological defects in polar active matter.

Fluid interfaces laden by force dipoles: towards active matter-driven microfluidic flows.

In recent years, nonlinear microfluidics in combination with lab-on-a-chip devices has opened a new avenue for chemical and biomedical applications such as droplet formation and cell sorting. In this article, we integrate ideas from active matter into a microfluidic setting, where two fluid layers with identical densities but different viscosities flow through a microfluidic channel. Most importantly, the fluid interface is laden with active particles that act with dipolar forces on the adjacent fluids and thereby generate flows. We perform lattice-Boltzmann simulations and combine them with phase field dynamics of the interface and an advection-diffusion equation for the density of active particles. We show that only contractile force dipoles can destabilize the flat fluid interface. It develops a viscous finger from which droplets break up. For interfaces with non-zero surface tension, a critical value of activity equal to the surface tension is necessary to trigger the instability. Since activity depends on the density of force dipoles, the interface can develop steady deformation. Lastly, we demonstrate how to control droplet formation using switchable activity.

A polymer chain with dipolar active forces in connection to spatial organization of chromatin.

A living cell is an active environment where the organization and dynamics of chromatin are affected by different forms of activity. Optical experiments report that loci show subdiffusive dynamics and the chromatin fiber is seen to be coherent over micrometer-scale regions. Using a bead-spring polymer chain with dipolar active forces, we study how the subdiffusive motion of the loci generate large-scale coherent motion of the chromatin. We show that in the presence of extensile (contractile) activity, the dynamics of the loci grows faster (slower) and the spatial correlation length increases (decreases) compared to the case with no dipolar forces. Hence, both the dipolar active forces modify the elasticity of the chain. Interestingly in our model, the dynamics and organization of such dipolar active chains largely differ from the passive chain with renormalized elasticity.

Active compound particles in a quadratic flow: hydrodynamics and morphology.

Generating core-shell particles with a well-controlled morphology is of great interest due to the interdependence between the morphology and different properties of these structures. These particles are often generated in microfluidic devices in a background quadratic flow. Therefore, in this study, we investigate the hydrodynamics and morphology of a concentric active compound particle, an active particle encapsulated in a fluid droplet, in an imposed quadratic flow. Governing equations for fluid flow are analytically solved in the inertia-less limit assuming that the surface tension force dominates the viscous forces (capillary number, Ca ≪ 1). Poiseuille flow deforms the compound particle into a three-lobe structure governed by the hexapolar component of the Poiseuille flow. Activity deforms the compound particle into a prolate shape owing to the velocity field of a force dipole. For an active compound particle in a Poiseuille flow, morphology is sensitive to the orientations and relative strengths of the activity and Poiseuille flow. Primarily, the presence of activity breaks the three-lobe symmetry of the drop shape and makes it more asymmetric and elongated. Moreover, the active compound particle becomes more susceptible to breakup in a quadratic flow when (i) the strength of activity is much stronger than the imposed flow strength, (ii) the active particle is oriented along the symmetry axes of the quadratic flow, (iii) the size ratio of the confining droplet to the encapsulated active particle is small and (iv) the viscosity ratio of the outer fluid to the inner fluid is small. Finally, we demonstrate that imposing the pulsatile quadratic flow prevents the breakup of an active compound particle during its generation and transport, and further assists in tuning the morphology.

Adsorption of naphthalene and its derivatives onto high-density polyethylene microplastic: Computational, isotherm, thermodynamic, and kinetic study

Microplastics (MP) have received great attention due to the mass-produced residues discharged into the environment. MP are ideal for adhering to organic pollutants that can be easily dispersed, thus posing risks to human health. Furthermore, little has been reported on how different functional groups in polycyclic aromatic hydrocarbons (PAH) derivatives influence the adsorption behavior on MP. To better understand this process, groups methyl (–CH3) and hydroxyl (–OH) were selected and commercial and waste high-density polyethylene (HDPE, ≤ 1 mm) were used as adsorbents, and Naphthalene (Nap), 1-Methyl-Naphthalene (Me-Nap) and α-Naphthol as adsorbates. The results showed different behaviors for nonpolar and polar adsorbates. Dispersion forces were the main type of interaction between HDPE and Nap/Me-Nap, while dipole-induced dipole forces and H-bonding were the chief interactions involving MP and polar compounds. Regardless the HDPE source, Nap and Me-Nap have a Type III isotherm, and α-Naphthol presents a Type II isotherm. Nap and Me-Nap fitted to Freundlich isotherm of an unfavorable process (n = 2.12 and 1.11; 1.87 and 1.31, respectively), with positive values of ΔH° (50 and 77.17; 66 and 64.63 kJ mol−1) and ΔS° (0.070 and 0.0145; 0.122 and 0.103 kJ mol−1) for commercial and waste MP, respectively. Besides, the adsorption isotherm of α-Naphthol on commercial and waste HDPE fitted to the Langmuir model (Qmax = 42.5 and 27.2 μmol g−1, respectively), presenting negative values of ΔH° (−43.71 and −44.10 kJ mol−1) and ΔS° (−0.037 and −0.025 kJ mol−1). The adsorption kinetic study presents a nonlinear pseudo-second-order model for all cases. The K2 values follow the order Me-Nap > Nap >α-Naphthol in both MP. Therefore, this experimental study provides new insights into the affinity of PAH derivatives for a specific class of MP, helping to understand the environmental fate of residual MP and organic pollutants.

Gauging Nanoswimmer Dynamics via the Motion of Large Bodies.

Nanoswimmers are ubiquitous in biotechnology and nanotechnology but are extremely challenging to measure due to their minute size and driving forces. A simple method is proposed for detecting the elusive physical features of nanoswimmers by observing how they affect the motion of much larger, easily traceable particles. Modeling the swimmers as hydrodynamic force dipoles, we find direct, easy-to-calibrate relations between the observable power spectrum and diffusivity of the tracers and the dynamic characteristics of the swimmers-their force dipole moment and correlation times.

Polarizable Molecular Block Model: Toward the Development of an Induced Dipole Force Field for DNA.

For flexible and highly ionized macromolecules such as DNA, it is important to correctly evaluate the intramolecular polarization in an induced dipole force field. In a proposed polarizable molecular block (PMB) model, a large molecule is divided into several molecular blocks. The atomic charges of the blocks are optimized by using the respective electrostatic potentials (ESPs) on the molecular surface. By using the capped hydrogen removal operation, the total charge of the blocks is controlled exactly to have an integer charge. The atomic polarizabilities of the blocks are optimized by using the respective polarized one-electron potentials that are the differences between ESPs with and without an external test charge. Induced dipole-charge interactions between the blocks are all included, but those interactions within the blocks are strictly excluded. All dipole-dipole interactions are included, but the damping functions are applied to the close dipole-dipole pairs. Several types of damping (simple scaling, exponential, linear, and Gaussian) are evaluated. The validity of the PMB model was verified by using trinucleotide duplexes which have A-, B-, and Z-DNA forms. The reference energies of trinucleotide duplexes including counterions (GGT3Na-ACC3Na, GAC3Na-GTC3Na, and GCG3Na-CGC3Na) are calculated using ωB97XD/aug-cc-pVDZ. All damping types reproduced well the reference interaction energies, dipole moments, and ESPs. Among them, the simple scaling with strong attenuation to 1-2 atomic pairs showed the highest stability against the polarization catastrophe. This study shows that it is possible to develop a high-quality polarizable force field by treating the intramolecular polarization on a block-by-block basis.

Many-Body Radiative Decay in Strongly Interacting Rydberg Ensembles.

When atoms are excited to high-lying Rydberg states they interact strongly with dipolar forces. The resulting state-dependent level shifts allow us to study many-body systems displaying intriguing nonequilibrium phenomena, such as constrained spin systems, and are at the heart of numerous technological applications, e.g., in quantum simulation and computation platforms. Here, we show that these interactions also have a significant impact on dissipative effects caused by the inevitable coupling of Rydberg atoms to the surrounding electromagnetic field. We demonstrate that their presence modifies the frequency of the photons emitted from the Rydberg atoms, making it dependent on the local neighborhood of the emitting atom. Interactions among Rydberg atoms thus turn spontaneous emission into a many-body process which manifests, in a thermodynamically consistent Markovian setting, in the emergence of collective jump operators in the quantum master equation governing the dynamics. We discuss how this collective dissipation-stemming from a mechanism different from the much studied superradiance and subradiance-accelerates decoherence and affects dissipative phase transitions in Rydberg ensembles.

Numerical simulation of non-central collisions of spherical magnets

We present a computational model of non-central collisions of two spherical neodymium-iron-boron magnets, suggested as a demonstration of angular momentum conservation. Our program uses an attractive dipole–dipole force and a repulsive contact force to solve the Newtonian equations of motion for the magnets. We confirm the conservation of angular momentum and study the changes in energy throughout the interaction. Using the exact expression for the dipole–dipole force, including non-central terms, we correctly model the final rotational frequencies, which is not possible with a simple power-law approximation.

Magnetically derived fabrication of aligned porous poly(sulfonated polystyrene-co.-chitosan) monolith as a high efficient adsorbent for metal ions separation

Designing and tuning towards the porous structure of adsorbents is of great importance for promoting the adsorptive performance. Herein, a magnetic-induced copolymerization method is applied to generate an aligned porous structure in the aligned porous poly(SPS-co.-CTS) monolith. Typically, the aligned macropores primarily derives from the equilibrium of the magnetic dipolar force to the thermodynamic Brown force by tuning the applied magnetostatic field intensity to 25 mT. Due to the aligned macroporous structure, the monolith features with low back pressure, low mass transfer resistance and high adsorptive capacity. The hydrophilicity of the monolith surface is further improved by capping chitosan activated by amino onto its porous surface via the Hinsber reaction. Detail analyses are performed by a series of physical characterizations, by which exhibit the aligned macropores centering at 5.18 μm, specific surface reaching 54 m2 g−1 and large porosity. Finally, batch adsorption experiments confirm that the adorptive behaviors to Cu2+ ions and Co2+ ions submit to the Langmuir model and Pseudo-second order adsorption kinetics. Most intriguing, the film mass transfer ([kLa]f) has been stabilized due to the aligned macropores, thus facilitating the porous diffusion ([kLa]d) and improving the chromatographic performance of the monolith. All results demonstrate that the aligned porous poly(SPS-co.-CTS) monolith promises broad applications in the field of wastewater remediation.

Direct detection of photoinduced magnetic force at the nanoscale reveals magnetic nearfield of structured light.

We demonstrate experimentally the detection of magnetic force at optical frequencies, defined as the dipolar Lorentz force exerted on a photoinduced magnetic dipole excited by the magnetic component of light. Historically, this magnetic force has been considered elusive since, at optical frequencies, magnetic effects are usually overshadowed by the interaction of the electric component of light, making it difficult to recognize the direct magnetic force from the dominant electric forces. To overcome this challenge, we develop a photoinduced magnetic force characterization method that exploits a magnetic nanoprobe under structured light illumination. This approach enables the direct detection of the magnetic force, revealing the magnetic nearfield distribution at the nanoscale, while maximally suppressing its electric counterpart. The proposed method opens up new avenues for nanoscopy based on optical magnetic contrast, offering a research tool for all-optical spin control and optomagnetic manipulation of matter at the nanoscale.

Decadal variability of the interannual climate predictability associated with the Indo-Pacific oceanic channel dynamics in CCSM4

The lag correlations between the observed sea surface temperature anomalies (SSTA) in the southeastern tropical Indian Ocean in fall and those in the Pacific cold tongue at the one-year time lag are calculated in running windows of 7–11 years and are shown to have decadal variability. Similar decadal variability has also been identified in the historical simulations of the Community Climate System Model version 4 (CCSM4) that participates in the Coupled Model Intercomparison Project phase-5 (CMIP5). During the positive phases of the decadal variability, the significant lag correlations are diagnosed to be dominated by the oceanic channel dynamics, i.e., upwelling Kelvin waves associated with the Indian Ocean Dipole (IOD) force enhanced Indonesian Throughflow transport anomalies and western Pacific thermocline anomalies to propagate eastward, resulting in SSTA in the central-eastern equatorial Pacific Ocean. During the negative phases of the decadal variability, the subsurface lag correlations suggest that the western Pacific Ocean are still dominated by the oceanic channel dynamics, but do not correlate well with the SSTA in the cold tongue due to a deeper thermocline in the eastern equatorial Pacific. The IOD-ENSO teleconnection is not affected significantly by the anthropogenic forcing during either the positive or the negative decadal phases. The CCSM4 model is found to underestimate Indonesian Throughflow transport variability but overestimate the westerly wind anomalies in the western-central equatorial Pacific, which forces unrealistic anomalies in the equatorial Pacific Ocean associated with the IOD.