dimethyl-N,N'-dioctylhexylethoxymalonamide Research Articles

Americium(III)/curium(III) separation by countercurrent chromatography using malonamide extractants

Abstract The separation of Am(III) and Cm(III) by countercurrent chromatography (CCC) was achieved using the liquid phase systems "diamide–hydrogenated tetrapropylene (TPH)–HNO3" following the optimisation of: (i) the compositions of the mobile (HNO3 concentration) and the stationary (nature of the diamide and its concentration in TPH) phases, (ii) column length and (iii) operating parameters of the CCC (flow rate of the mobile phase and rotation speed of the coil column). The following diamide extractants have been studied: (i) N,N´-dimethyl-N,N´-dibutyltetradecylmalonamide (DMDBTDMA), (ii) N,N´-dimethyl-N,N´-dioctylhexyl-ethoxymalonamide (DMDOHEMA) and (iii) N,N´-dimethyl-N,N´-dibutyldodecylethoxymalonamide (DMDBDDEMA). It is shown that these diamides can be used for the separation of Am(III) and Cm(III) by CCC. Increasing the column length leads to an increase of the stationary phase retention on the column while improving the Am/Cm separation. Increasing the speed of rotation of the centrifuge from 660 to 950 rpm also results in increasing the stationary phase retention but does not influence the resolution of the Am/Cm separation. Decreasing the flow rate of the mobile phase from 1.0 to 0.5 mL/min leads to a better resolution of Am and Cm separation. The best Am/Cm separation was achieved with systems based on DMDBDDEMA and DMDOHEMA in TPH using a two-layer coil column and an isocratic elution mode. The application of CCC makes it possible to separate the elements within 100 min: the Cm fraction contains 99.5% of Cm(III) and 0.6% of Am(III) inventories and the Am fraction contains 99.4% of Am(III) and 0.5% of Cm(III).

Multistage extraction separation of Am(III) and Cm(III) in planet centrifuges

Countercurrent chromatography (CCC), a support-free partition chromatography, allows realization of multistep extraction separations in specially designed planet centrifuges. Highly efficient Am(III)/Cm(III) separation in nitric acid solutions in the dynamic mode was obtained using two-phase systems based on diamide extractants such as N, N′-dimethyl-N,N′-dibutyltetradecylmalonamide (DMDBTDMA), N,N′-dimethyl-N,N′-dioctylhexylethoxymalonamide (DMDOHEMA), and N,N′-dimethyl-N,N′-dibutyldodecylethoxymalonamide (DMDBDDEMA). All these extractants could be recommended to use for CCC separation of 243Am and 244Cm. Increasing coil length and decreasing pumping rate of the mobile phase increase the stationary phase retention in the column and improves the resolution of the Am(III) and Cm(III) elution curves. The basic chromatographic parameters of the column (number of theoretical plates and peak resolution of the elements to be separated) are optimized. CCC could be used for separation of elements with similar properties and also for testing quality of radionuclidic products. Single-stage chromatographic separation, when realized under optimal conditions, gives the Cm fraction containing 99.5% Cm(III) and 0.6% Am(III), and the Am fraction containing 99.4% Am(III) and 0.5% Cm(III). Separation is carried out by the isocratic elution method.