Urban green spaces (UGS) have emerged as a main nature-based solution proven to effectively cool urban areas, and cooling efficiency (CE) serves as a prominent indicator for assessing the performance of UGS. Yet few studies have explored the diurnal dynamics of CE and the comprehensive effects of both 2D and 3D urban morphology on CE over a 24-h period. In this study, we employed diurnal land surface temperature (LST) data from Ecosystem Spaceborne Thermal Radiometer Experiment on Space Station (ECOSTRESS) to delve into the diurnal CE of UGS within the urban core area of megacity Paris, France. Meanwhile, using high-resolution land cover data, digital height model, and explainable machine learning models, we elucidated the intricate relationship between various 2D and 3D urban morphology metrics and CE during a 24-h cycle. In summary, city-scale continuous monitoring revealed diurnal CE variations, with values ranging from 0.008 °C to 0.13 °C and a standard deviation of 0.04 °C. On an average of a day, the relative importance of the 2D and 3D urban form indicators was 77.25 % and 22.75 %, respectively. Enhancing the dispersion of trees or improving the integrity of non-tree vegetation patches proves to be an effective strategy for augmenting CE. The results can be further used in urban planning to improve urban thermal resilience and adaptability.
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