Diffusive Flux Research Articles

Unveiling the initial oxidation mechanism of a single crystal Ni-based superalloy with pre-deformation

The role of pre-deformation on the initial oxidation mechanism of a single crystal Ni- was revealed. With pre-deformation, the recrystallized grain boundaries and dislocations provided sites for the nucleation of Al2O3 and enhanced the diffusion flux of Al irrespective of γ/γ′ interface, γ′, and γ phase. Ultimately, a thin compact α-Al2O3 layer formed, improving the oxidation resistance. Without pre-deformation, Ni and Al atoms diffused along the γ'/γ interface, however, the Al-flux is insufficient to maintain the growth of Al2O3. As a result, a loose multilayer film formed on the surface, which decreased the oxidation resistance.

Stream CO2 emissions are overestimated without consideration of diel water and atmospheric CO2 variability

AbstractStreams are significant emitters of carbon dioxide (CO2) to the atmosphere that are influenced by diel CO2 dynamics. However, we know little about diel CO2 variability within streams, the diel dynamics of CO2 in the air above streams, and the consequences for emission calculations. We studied five pre‐alpine streams by equipping three sites per stream in close proximity (~ 1 km apart) with automatic logging stations that continuously recorded water and air CO2 partial pressures (pCO2) for 2–4 d. All streams and sites showed increased pCO2 at night and decreased pCO2 during the day, however, with fourfold higher diel amplitudes for atmospheric pCO2 compared to the water. Calculating diffusive CO2 fluxes with fixed compared to dynamic measured atmospheric CO2 resulted in negligible to 431% lower estimates. We might thus currently overestimate fluvial CO2 emissions and should include diel water and air CO2 variability to more accurately assess stream CO2 emissions.

Diffusion in multicomponent mixed solvent electrolyte systems

Thermodynamic ideality is often assumed in diffusion calculation, implying concentrations are assumed equal to the activities with activity coefficients of one. A general set of diffusion flux and molar flux equations are developed, incorporating equilibrium thermodynamic models for non-ideal conditions in well-known non-equilibrium diffusion theory. Derivations are based on the Maxwell-Stefan friction theory with the chemical potential as the driving force. Isothermal and isobaric conditions are assumed, and the theory does not include the Soret coefficient or the Onsager formalism.In this work, Fick's law is derived from the general diffusion theory, also as a function of activity gradients. The results illustrate that concentration cannot just be substituted by activity. Using a similar approach demonstrates that the Nernst-Planck (NP) equation may be derived from the general theory incorporating terms for migration and convection. An extended NP equation is derived including the thermodynamic correction factors (TCF) to account for the non-ideality of the liquid. The derived equation shows the improvement of the self-diffusion terms and friction coefficients in the NP equation and that the TCF enhances the observed effective diffusivities.Examples of TCF are presented using the extended UNIQUAC thermodynamic model. This is done for the CO2-NaOH-monoethyleneglycol-water system, which is typically found in wet natural gas pipeline CO2 corrosion systems. pH-stabilization is classically used in the prevention of corrosion, but the results show that glycol has a noticeable effect of the diffusion on key components in the corrosion mechanism. A TCF of 0.4 to 1.3 may be expected. This indicates that the flux calculation deviates up to 60 % from the real-life scenario if ideality is assumed. The thermodynamic model may therefore improve the diffusion calculations considerably.

Pre-oxidation of porous ferritic Fe22Cr alloys for lifespan extension at high-temperature

Pre-oxidation of porous ferritic Fe22Cr alloys was extensively studied in this paper. Weight gain measurements and SEM analysis revealed that pre-oxidation performed at 900°C for 40 min increased the lifespan of the alloy. A Cr evaporation study did not disclose any significant influence of the pre-oxidation process on the Cr content in the alloy. For a more detailed assessment, TEM imaging and X-ray tomography measurements of pre-oxidized samples were performed. These analyses showed that alteration in the grain and grain boundary diffusion fluxes might be the key for explaining the corrosion prevention role of pre-oxidation.

Improving the air bubble stability of air-entrained mortar in low air pressure environments via adopted rheology and surface tension methods

Air bubble stability in cementitious materials in low air pressure (AP) environments is influenced by the Ostwald ripening process, which causes coarsening behavior of air bubbles. This research reports the enhancement of air bubble stability in low AP via the adoption of rheology and surface tension methods. Besides, the evolution of air bubbles during the cement early hydration process is proposed. It was found that incorporating viscosity-modifying agents (VMAs) and shrinkage-reducing admixtures (SRAs) resulted in improving air bubble stability by 37.7 % and 23.4 %, upon undergoing AP change from 100 to 60 kPa. Calculation of air bubbles via ripening equations under low AP revealed that VMA induced a notable decrease in the effective diffusion flux within fresh cement mortar, leading to a reduction of 9.8 % in air bubble ripening within 120 min. Conversely, SRAs were primarily aimed at reducing the initial dimensions of air bubbles.

Ultrafast bimetallic interface reinforcement in additively manufactured multi-material via electropulsing

The bimetallic interface in additively manufactured multi-material was subjected to intense thermal cycling, and thus forming sizable heat affected zone and drastic mutation of chemical component, which led to weak metallurgical bonding. In this investigation, the pulsed current (1255 Hz; 64 μs; 35.4 V; 191 A; 1000 ℃; 20 min) was used to rapidly broaden the compositional mutation zone from 16 μm to 45 μm, and the heat affected zone was completely eliminated. However, the roles of equivalent heat treatment (1000 ℃; 20 min) were opposite with the pulsed one. The width of compositional mutation zone became narrower and the morphology heat affected zone did not change after equivalent heat treatment. Furthermore, the hot compression experiment proved the better bimetallic interface quality of pulsed sample. The rapid regulation of microstructure and composition gradient is caused by increasing interfacial diffusion flux and the promotion of electron wind force to the solute atom.

Organic Matter Accumulation and Hydrology as Drivers of Greenhouse Gas Dynamics in Newly Developed Artificial Channels.

Artificial channels, common features of inland waters, have been suggested as significant contributors to methane (CH4) and carbon dioxide (CO2) dynamics and emissions; however, the magnitude and drivers of their CH4 and CO2 emissions (diffusive and ebullitive) remain unclear. They are characterized by reduced flow compared to the donor river, which results in suspended organic matter (OM) accumulation. We propose that in such systems hydrological controls will be reduced and OM accumulation will control emissions by promoting methane production and outgassing. Here, we monitored summertime CH4 and CO2 concentrations and emissions on six newly constructed river-fed artificial channels, from bare riparian mineral soil to lotic channels, under two distinct flow regimes. Chamber-based fluxes were complemented with hydrology, total fluxes (diffusion + ebullition), and suspended OM accumulation assessments. During the first 6 weeks after the flooding, inflowing riverine water dominated the emissions over in-channel contributions. Afterwards, a substantial accumulation of riverine suspended OM (≥50% of the channel's volume) boosted in-channel methane production and led to widespread ebullition 10× higher than diffusive fluxes, regardless of the flow regime. Our finding suggests ebullition as a dominant pathway in these anthropogenic systems, and thus, their impact on regional methane emissions might have been largely underestimated.

All-sky Search for Transient Astrophysical Neutrino Emission with 10 Years of IceCube Cascade Events

Neutrino flares in the sky are searched for in data collected by IceCube between 2011 and 2021 May. This data set contains cascade-like events originating from charged-current electron neutrino and tau neutrino interactions and all-flavor neutral-current interactions. IceCube’s previous all-sky searches for neutrino flares used data sets consisting of track-like events originating from charged-current muon neutrino interactions. The cascade data set is statistically independent of the track data sets, and while inferior in angular resolution, the low-background nature makes it competitive and complementary to previous searches. No statistically significant flare of neutrino emission was observed in an all-sky scan. Upper limits are calculated on neutrino flares of varying duration from 1 hr to 100 days. Furthermore, constraints on the contribution of these flares to the diffuse astrophysical neutrino flux are presented, showing that multiple unresolved transient sources may contribute to the diffuse astrophysical neutrino flux.

Day/Night Differences in Molecular Oxygen in the Martian Upper Atmosphere

AbstractWe use the extensive stellar occultation data set of the Imaging Ultraviolet Spectrograph aboard the Mars Atmosphere and Volatile EvolutioN spacecraft to determine the first quantification of vertical variation in O2 mole fraction separately for day and night in the ∼90–130 km altitude range. The upper atmospheric O2 variation is expected to be due to the interplay between diffusion and advection because of its long photochemical lifetime. It is therefore a useful tracer of the state of atmospheric mixing and circulation. The altitude‐averaged mixing ratio is measured to be 2.69(±0.03) × 10−3 for the nightside and 2.05(±0.03) × 10−3 for the dayside. The average O2 mole fraction for day and night are nearly identical below 105 km, consistent with the value of 1.61 × 10−3 derived from the Mars Curiosity Rover/Sample Analysis at Mars near‐surface measurements. At higher altitudes, dominated by molecular diffusive separation, the measured O2 mole fraction demonstrates a vertical gradient with a local time dependence. The nightside mole fraction is a factor of 1.37 ± 0.04 larger than the dayside value at ∼125 km. This nightside enhancement is explained in terms of the relative role of solar‐driven rapid horizontal winds at high altitudes and slower vertical diffusion, resulting in a nightside (dayside) downward (upward) diffusive flux. Using the 1‐D diffusion model, the measured profiles correspond to a vertical eddy diffusion coefficient K = 3.5(±1.5) × 106 cm2/s. The Mars Climate Database predicts comparable but lower day‐night differences in oxygen mole fraction due to an overestimated K = 7.0(±1.0) × 106 cm2/s, which affects atmospheric mixing as well as the rate of atmospheric escape to space.

Magnitude of and Hydroclimatic Controls on CO2 and CH4 Emissions in the Subtropical Monsoon Pearl River Basin

AbstractRivers are important ecosystems for carbon emissions and play a crucial role in the global carbon cycle. However, CO2 and CH4 emissions from subtropical rivers are substantially under‐represented in global‐scale estimates. Here, we explored the regional patterns of riverine CO2 and CH4 dynamics in the Pearl River basin with a subtropical monsoon climate. We found that its CO2 and diffusive CH4 emissions showed a decreasing trend with increasing stream order. Seasonality in CO2 and diffusive CH4 emissions was primarily driven by variations in partial pressure of CO2 (pCO2) and CH4 (pCH4) and gas transfer velocities, which were strongly regulated by hydrology and climate. We further estimated the basin‐wide CO2 and diffusive CH4 fluxes at 17.8 ± 7.4 Tg C yr−1 and 191.5 ± 139.9 Gg C yr−1, respectively. When normalized to the water surface, the mean diffusive fluxes were 790.1 and 8.5 mmol m−2 d−1 for CO2 and CH4, respectively, which were 1.3 and 2.5 times higher than the global mean riverine CO2 and CH4 fluxes, respectively. This suggests that the global significance of subtropical rivers is probably underestimated because their substantially higher CH4 fluxes are unaccounted for. Furthermore, compared with measured pCO2, the alkalinity‐based pCO2 could introduce significant errors by 20% at ∼30% of the sampling sites, underscoring the necessity of direct measurements to reduce uncertainty. This study provides the first estimate of basin‐wide CO2 and diffusive CH4 emissions in the PRB through direct pCO2 and pCH4 measurements, and highlights the role of hydrologic and climatic factors in governing riverine carbon emissions.

Influence of Foehn Winds of Truong Son Mountains on the High Temperatures Observed in North-Central Vietnam during 31 May–5 June 2017

Abstract North-central Vietnam often experiences high temperatures. Foehn winds originating from the Truong Son Mountains (also known as Laos winds) are believed to contribute to abnormally high temperatures; however, no quantitative research has focused on foehn warming in Vietnam. In this study, we conducted numerical simulations using the Weather Research and Forecasting (WRF) Model to investigate the contribution of foehn warming to abnormally high temperatures in north-central Vietnam in early June 2017. Generally, May–June is the monsoon period in Vietnam. Consequently, foehn warming during this season is thought to be mainly caused by latent heating and precipitation mechanism. However, the primary factor in the cases covered in this study was foehn warming with an isentropic drawdown mechanism. Diabatic heating with turbulent diffusion and sensible heat flux from mountain slopes also plays significant roles. The warming effect of the foehn winds on the temperatures during the events was approximately 2°–3°C. It was concluded that the high temperature events from 31 May to 5 June 2017 were caused by synoptic-scale warm advection and foehn warming. Sensitivity experiments were conducted on the WRF Model, utilizing three atmospheric boundary layer turbulence schemes (YSU, ACM2, and MYNN), consistently yielding results for simulated temperature and relative humidity. The wind speed bias for the MYNN scheme was found to be lower than that of the other schemes. However, this study did not delve into the underlying reasons for these differences. The optimal performance of each scheme remains an open question. Significance Statement It was hypothesized that north-central Vietnam often experiences high temperatures owing to foehn winds (also known as Laos winds) descending from the Truong Son Mountains. This study conducted numerical experiments to validate this hypothesis and investigate the associated mechanisms of foehn winds in this region. Surprisingly, despite the monsoon season, the isentropic drawdown mechanism without precipitation effects provides the primary explanation for the high temperatures caused by foehn winds in north-central Vietnam, and not the latent heating and precipitation mechanism with precipitation effects that researchers expected. The results of this study contribute to better prediction of high temperatures in this region and improve our understanding of foehn winds in tropical monsoon climate zones.

Cryogenic Deep Drawing Tool Design for Reduced Heat Transfer

Subject of this study is the usage of macro-structured tools for deep drawing of aluminum alloys at cryogenic temperatures in order to increase the drawing depth. The advantage of the macro-structure is the reduced contact area, which primarily leads to a reduction in frictional forces in the flange area and also minimizes the heat transfer from the tool to the cooled sheet metal. In addition to the geometry of the tools, the heat transfer is also influenced by the thermal properties of the tool materials. Therefore, the tool must be designed to reduce heat flux and thermal diffusivity. In this regard, substitute materials for the tools, specifically polymer, and steel-shielded polymer, were investigated. In this context, the heat transfer coefficients between the tool material and the aluminum blank are determined experimentally. The influence of thermal conditions on the cryogenic deep drawing process are investigated numerically and experimentally. The result of the study is an improved process understanding to ensure the blank temperature in a cryogenic range and increase the resistance against bottom cracks.

Implications on star formation rate indicators from H ii regions and diffuse ionized gas in the M101 Group

ABSTRACT We examine the connection between diffuse ionized gas (DIG), H ii regions, and field O and B stars in the nearby spiral M101 and its dwarf companion NGC 5474 using ultra-deep H α narrow-band imaging and archival GALEX UV imaging. We find a strong correlation between DIG H α surface brightness and the incident ionizing flux leaked from the nearby H ii regions, which we reproduce well using simple cloudy simulations. While we also find a strong correlation between H α and co-spatial far-ultraviolet (FUV) surface brightness in DIG, the extinction-corrected integrated UV colours in these regions imply stellar populations too old to produce the necessary ionizing photon flux. Combined, this suggests that H ii region leakage, not field OB stars, is the primary source of DIG in the M101 Group. Corroborating this interpretation, we find systematic disagreement between the H α- and FUV-derived star formation rates (SFRs) in the DIG, with SFRH α <SFRFUV everywhere. Within H ii regions, we find a constant SFR ratio of 0.44 to a limit of ∼10−5 M⊙ yr−1. This result is in tension with other studies of star formation in spiral galaxies, which typically show a declining SFRH α/SFRFUV ratio at low SFR. We reproduce such trends only when considering spatially averaged photometry that mixes H ii regions, DIG, and regions lacking H α entirely, suggesting that the declining trends found in other galaxies may result purely from the relative fraction of diffuse flux, leaky compact H ii regions, and non-ionizing FUV-emitting stellar populations in different regions within the galaxy.

Sorption of Soil Carbon Dioxide by Biochar and Engineered Porous Carbons.

CO2 is 45 to 50 times more concentrated in soil than in air, resulting in global diffusive fluxes that outpace fossil fuel combustion by an order of magnitude. Despite the scale of soil CO2 emissions, soil-based climate change mitigation strategies are underdeveloped. Existing approaches, such as enhanced weathering and sustainable land management, show promise but continue to face deployment barriers. We introduce an alternative approach: the use of solid adsorbents to directly capture CO2 in soils. Biomass-derived adsorbents could exploit favorable soil CO2 adsorption thermodynamics while also sequestering solid carbon. Despite this potential, previous study of porous carbon CO2 adsorption is mostly limited to single-component measurements and conditions irrelevant to soil. Here, we probe sorption under simplified soil conditions (0.2 to 3% CO2 in balance air at ambient temperature and pressure) and provide physical and chemical characterization data to correlate material properties to sorption performance. We show that minimally engineered pyrogenic carbons exhibit CO2 sorption capacities comparable to or greater than those of advanced sorbent materials. Compared to textural features, sorbent carbon bond morphology substantially influences low-pressure CO2 adsorption. Our findings enhance understanding of gas adsorption on porous carbons and inform the development of effective soil-based climate change mitigation approaches.

Contribution of Neutrino-dominated Accretion Flows to the Cosmic MeV Neutrino Background

Neutrino-dominated accretion flows (NDAFs) are one of the important MeV neutrino sources and significantly contribute to the cosmic diffuse neutrino background. In this paper, we investigate the spectrum of the diffuse NDAF neutrino background (DNNB) by fully considering the effects of the progenitor properties and initial explosion energies based on core-collapse supernova (CCSN) simulations, and estimate the detectable event rate by the Super-Kamiokande detector. We find that the predicted background neutrino flux is mainly determined by the typical CCSN initial explosion energy and progenitor metallicity. For the optimistic cases, in which the typical initial explosion energy is low, the diffuse flux of the DNNB is comparable to the diffuse supernova neutrino background, which might be detected by upcoming larger neutrino detectors, such as Hyper-Kamiokande, the Jiangmen Underground Neutrino Observatory, and the Deep Underground Neutrino Experiment. Moreover, the strong outflows from NDAFs could dramatically decrease their contribution to the neutrino background.

Dynamics of methane emissions from northwestern Gulf of Mexico subtropical seagrass meadows

While seagrass meadows are perceived to be pertinent blue carbon reservoirs, they also potentially release methane (CH4) into the atmosphere. Seasonal and diurnal variations in CH4 emissions from a subtropical hypersaline lagoon dominated by Halodule wrightii in southern Texas, USA, on the northwest coast of the Gulf of Mexico were investigated. Dissolved CH4 concentrations decreased in the daytime and increased overnight during the diel observation period, which could be explained by photosynthesis and respiration of seagrasses. Photosynthetic oxygen was found to significantly reduce CH4 emissions from seagrass sediment. Diffusive transport contributed slightly to the release of CH4 from the sediment to the water column, while plant mediation might be the primary mechanism. The diffusive CH4 flux at the sea-air interface was 12.3–816.2 µmol/m2 d, over the range of the sea-air fluxes previously reported from other seagrass meadows. This was related to relatively higher dissolved CH4 concentrations (11.6–258.2 nmol/L) in a mostly closed lagoon with restricted water exchange. This study emphasizes seagrass meadows in the subtropical hypersaline lagoon as a source of atmospheric CH4, providing insights into the interactions between seagrass ecosystems and methane dynamics, with potential implications for seagrass meadow management and conservation efforts.

Propagation and fluxes of ultra-high energy cosmic rays in f(R)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\varvec{f(R)}$$\\end{document} gravity theory

In this work, we study the effect of diffusion of ultra-high energy cosmic ray (UHECR) protons in the presence of turbulent magnetic fields (TMFs) in the light of the f(R) theory of gravity. The f(R) theory of gravity is a successful modified theory of gravity in explaining the various aspects of the observable Universe including its current state of expansion. For this work, we consider two most studied f(R) gravity models, viz., the power-law model and the Starobinsky model. With these two models, we study the diffusive character of the propagation of UHECR protons in terms of their density enhancement. The density enhancement is a measure of how the density of CRs changes due to their diffusion in the intergalactic medium and interaction with the cosmic microwave background (CMB) radiation. Ankle, instep and Greisen–Zatsepin–Kuzmin (GZK) cutoff are all spectrum characteristics that extragalactic UHECRs acquire when they propagate through the CMB. We analyse all these characteristics through the diffusive flux as well as its modification factor. Model dependence of the modification factor is minimal compared to the diffusive flux. We compare the UHECR proton spectra calculated for the considered f(R) gravity models with the available data of the Telescope Array (TA) and Pierre Auger Observatory (PAO). We see that both models of f(R) gravity predict energy spectra of UHECRs with all experimentally observed features, which lay well within the range of combined data of both experiments throughout the energy range of concern. It is to be noted that our present work is only to investigate the possible effects of f(R) gravity theory on the UHECRs propagation, using pure proton composition as a simplified case study since protons are least affected by magnetic fields. Hence, at this stage, our results cannot be used to favor or disfavor f(R) cosmology over Λ\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\Lambda $$\\end{document}CDM cosmology as more work is needed in this regard.

Boundary mixing. Part 2. The impact of ventilation

Through a combination of laboratory experiments and theoretical models, we investigate the interaction of a mean upwelling through a closed basin with a vertical buoyancy flux. The fluid is mixed by a horizontally oscillating rake, which either traverses the whole basin or which oscillates just near one vertical boundary. We first review the steady state and demonstrate that, in both mixing regimes, the vertical density profile across the basin is controlled by the steady-state balance between the upward advective and diffusive fluxes of salinity as described by the classical model introduced by Munk (Deep-Sea Res., vol. 13, issue 4, 1966, pp. 707–730). However, with boundary mixing, we show that both the upwelling and the buoyancy transport are localised to the mixing zone near the boundary, and the interior fluid is stagnant. We then develop a model to describe the transient evolution of the system if there is either a discrete increase or gradual decrease to the buoyancy flux. In the boundary mixing case, the change in the buoyancy flux at the lower boundary leads to a change in the buoyancy of the fluid in the boundary mixing region, and this induces a transient, buoyancy-driven flow in the boundary region in addition to the steady upwelling. In turn, an equal and opposite vertical flow develops in the interior, and this leads to a change in the density stratification of the interior fluid as the system adjusts to a new equilibrium. However, in our experiments, there is no vertical mixing in the interior and interior fluid may upwell or downwell dependent on the change to the buoyancy forcing. We discuss the implications of our results for the transport and mixing in the deep ocean, and the associated interpretation of field experiments.

Enhancing Sustainability in Construction: Investigating the Thermal Advantages of Fly Ash-Coated Expanded Polystyrene Lightweight Concrete

This study investigates a sustainable coating method for modified expanded polystyrene (MEPS) beads to improve the thermal insulation of lightweight concrete intended for wall application. The method employed in this study is based on a novel coating technique that represents a significant advancement in modifying Expanded Polystyrene (EPS) beads for enhanced lightweight concrete. This study experimentally assessed the energy-saving capabilities of MEPS concrete in comparison to control groups of uncoated EPS beads and normal concrete by analysing early-stage temperature, thermal conductivity, specific heat capacity, heat flux, and thermal diffusivity. The thermal conductivity of MEPS concrete is approximately 40% lower than that of normal concrete, demonstrating its usefulness in enhancing insulation. The heat flux calculated for MEPS concrete is significantly reduced (approximately 35%), and it has a 20% lower specific heat capacity than ordinary concrete, indicating a reduction in energy transfer through the material and, thus, potential energy-efficiency benefits. Furthermore, the study discovered that all test objects have very low thermal diffusivity values (less than 0.5 × 10−6 m2/s), indicating a slower heat transport through the material. The sustainable coating method utilized fly ash-enhanced thermal efficiency and employed recycled materials, hence decreasing the environmental impact. MEPS concrete provides a practical option for creating sustainable and comfortable buildings through the promotion of energy-efficient wall construction. Concrete incorporating coated EPS can be a viable option for constructing walls where there is a need to balance structural integrity and adequate insulation.

Photo-methanification of aquatic dissolved organic matters with different origins under aerobic conditions: Non-negligible role of hydroxyl radicals

Lingering inconsistencies in the global methane (CH4) budget and ambiguity in CH4 sources and sinks triggered efforts to identify new CH4 formation pathways in natural ecosystems. Herein, we reported a novel mechanism of light-induced generation of hydroxyl radicals (•OH) that drove the production of CH4 from aquatic dissolved organic matters (DOMs) under ambient conditions. A total of five DOM samples with different origins were applied to examine their potential in photo-methanification production under aerobic conditions, presenting a wide range of CH4 production rates from 3.57 × 10−3 to 5.90 × 10−2 nmol CH4 mg-C−1 h−1. Experiments of •OH generator and scavenger indicated that the contribution of •OH to photo-methanificaiton among different DOM samples reached about 4∼42 %. In addition, Fourier transform infrared spectroscopy and Fourier transform ion cyclotron resonance mass spectrometry showed that the carbohydrate- and lipid-like substances containing nitrogen-bonded methyl groups, methyl ester, acetyl groups, and ketones, were the potential precursors for light-induced CH4 production. Based on the experimental results and simulated calculations, the contribution of photo-methanification of aquatic DOMs to the diffusive CH4 flux across the water-air interface in a typical eutrophic shallow lake (e.g., Lake Chaohu) ranged from 0.1 % to 18.3 %. This study provides a new perspective on the pathways of CH4 formation in aquatic ecosystems and a deeper understanding on the sources and sinks of global CH4.