<abstract> <p>The aim of the reported results in this manuscript is to handle the existence, uniqueness, extremal solutions, and Ulam-Hyers stability of solutions for a class of $ \Psi $-Caputo fractional relaxation differential equations and a coupled system of $ \Psi $-Caputo fractional relaxation differential equations in Banach spaces. The obtained results are derived by different methods of nonlinear analysis like the method of upper and lower solutions along with monotone iterative technique, Banach contraction principle, and Mönch's fixed point theorem concerted with the measures of noncompactness. Furthermore, the Ulam-Hyers stability of the proposed system is studied. Finally, two examples are presented to illustrate our theoretical findings. Our acquired results are recent in the frame of a $ \Psi $-Caputo derivative with initial conditions in Banach spaces via the monotone iterative technique. As a results, we aim to fill this gap in the literature and contribute to enriching this academic area.</p> </abstract>