Up to 90% hydrogen energy fraction was achieved in a hydrogen diesel dual-fuel direct injection (H2DDI) light-duty single-cylinder compression ignition engine. An automotive-size inline single-cylinder diesel engine was modified to install an additional hydrogen direct injector. The engine was operated at a constant speed of 2000 revolutions per minute and fixed combustion phasing of −10 crank angle degrees before top dead centre (°CA bTDC) while evaluating the power output, efficiency, combustion and engine-out emissions. A parametric study was conducted at an intermediate load with 20–90% hydrogen energy fraction and 180-0 °CA bTDC injection timing. High indicated mean effective pressure (IMEP) of up to 943 kPa and 57.2% indicated efficiency was achieved at 90% hydrogen energy fraction, at the expense of NOx emissions. The hydrogen injection timing directly controls the mixture condition and combustion mode. Early hydrogen injection timings exhibited premixed combustion behaviour while late injection timings produced mixing-controlled combustion, with an intermediate point reached at 40 °CA bTDC hydrogen injection timing. At 90% hydrogen energy fraction, the earlier injection timing leads to higher IMEP/efficiency but the NOx increase is inevitable due to enhanced premixed combustion. To keep the NOx increase minimal and achieve the same combustion phasing of a diesel baseline, the 40 °CA bTDC hydrogen injection timing shows the best performance at which 85.9% CO2 reduction and 13.3% IMEP/efficiency increase are achieved.