Dielectric Parameters Research Articles

Electrical characterization of Al/SnO2/PbO/Si double layer MOS under the moderate radiation effect

The metal-oxide semiconductor-based structures are among the most prominent optoelectronic devices that can be used in several application fields. The performance of these structures is strongly dependent on the local radiation dose. In this study, we examined the sample structures with and without radiation. The electrical parameters of the studied samples such as ideality factor, series resistance, saturation current, barrier height, and zero-bias barrier height were obtained by performing the forward bias I–V data analyses. The values of n indicate that the irradiation emission mechanism is dominated. Also, this value depends on the evaluation method of the device. According to the Cheung method, while the ideality factor was found to be 5.72 before irradiation, it was found to be 7.04 after irradiation with 30 kGy. According to the TE method, on the other hand, the value of the ideality factor was found to be 6.337 before irradiation while it was found to be 5.016 after irradiation. The high figures of n were considered to be the result of the interface states of the metal/oxide/semiconductor, i.e. the device, and the barrier height's image force lowering. The obtained dielectric parameters do not have to be absolutely correct, especially when there is radiation on the device. It was found that the value of Rs extremely depended on the particular current transport mechanism's contributions to the total current. The non-ideality factor n increases with the 30 kGy irradiation according to the Cheung method while it does not according to the TE theory. At the same time, the forward bias I–V characteristics and their logarithmic plots reveal two distinct linear sections in the entire linearly increasing voltage.

Structural and dielectric relaxation studies of 1, 4, and 1, 3 -butanediol–1, 4-dioxane mixtures using TDR technique

Time domain reflectometry (TDR) was used to examine the complex dielectric permitivity spectra (CPS) of binary mixtures of 1,4, and 1,3 butanediol (BD) with 1,4 Dioxane (Dx) at high frequencies (10 MHz–50 GHz). Both systems show the Cole–Davidson type of relaxation process. The least squares fit (LSF) method is applied to compute dielectric relaxation parameters from the CPS. The interest of the ongoing research is to understand the molecular associations, orientation of electric dipoles, and change in electric dipole density in the liquid mixture with the help of excess dielectric parameters, Bruggeman factor (fB) and the Kirkwood correlation factor for both systems.

Fully carboxy-functionalized polyhedral silsesquioxanes as polar fillers to enhance the performance of dielectric silicone elastomers

Octakis(2-carboxyethyl-thioethyl)silsesquioxane (T8-COOH), a structurally well-defined organo-functionalized nano-silica, was used as an addition in different percentages (up to 15 wt.%) to a high molecular mass PDMS, obtaining composites that were processed as films by solution casting and stabilized by condensation crosslinking. SEM images showed a common aggregation phenomenon within polymeric matrix at high filler concentration. The presence of T8-COOH pushed the main stage of thermal decomposition to higher temperatures, generally around 500 °C, as compared to 400 °C for pure PDMS. The mechanical strength of the obtained composites was also enhanced by increased addition of filler that acts as a reinforcing agent. Tensile toughness, strains at break, and Young's modulus increased with increasing filler content. The viscoelastic behavior of the silicone composites was evaluated in five cyclic stress-strain tests. All materials showed relatively large hysteresis loops for the first cycle due to Mullin's effect, while the subsequent hysteresis became smaller from the second cycle. The composites showed dielectric behavior with low loss (<10−1), relative permittivity superior to pure siloxane (4–5 vs. 3.4), and slightly increased electrical breakdown strength (30–36 V/μm vs. 27 V/μm). The applicative potential of these composites in electromechanical devices was estimated by calculated figures of merit, based on mechanical and dielectric parameters, which indicate their suitability for energy harvesting/capacitive sensors rather than for actuators. In addition, the composite with the highest ε′ was tested as capacitive pressure sensor, showing a high sensitivity at low pressure, with potential application in wearable devices.

Temperature-dependent hydration behavior of aqueous lysine: an approach towards protein binding through dielectric spectroscopy

Present work reports interaction between water and amino acid lysine for understanding the physicochemical properties that will be useful in the structure formation of protein. The dielectric relaxation of aqueous lysine was systematically investigated over a temperature range spanning from 298.15 K to 278.15 K, encompassing frequencies ranging from 10 MHz to 30 GHz, and across a concentration range of 0.152 M to 0.610 M. Within this study, aqueous lysine revealed the presence of two distinct relaxation modes. The low-frequency relaxation process (l-process) is primarily associated with the relaxation of lysine molecules, whereas the high-frequency relaxation process (h-process) is attributed to water molecules interacting with lysine. Several key dielectric parameters, including static dielectric constant (εj), relaxation time (τj), dipole moment (μj), correlation factor (gj), and the number of water molecules rotationally bonded by solute molecules (Zib), were meticulously determined. These parameters were interpreted in terms of molecular interactions, hydrogen bonding, hydrophobicity, and Lys-Lys binding. Additionally, various thermodynamic parameters such as molar enthalpy (ΔHj), molar entropy (ΔSj), and molar free energy (ΔFj) were calculated to provide further insights into the system’s characteristics and behavior. Communicated by Ramaswamy H. Sarma

Structural, optical, and dielectric properties of M/SnO2 (M= Al2O3, NiO, Mn3O4) nanocomposites

The structural parameters, optical properties, and dielectric constants at a frequency (f) range of 0.1–20 MHz, and temperature (T) range of 300–400 K of hydrothermally synthesized M/SnO2 nanocomposites (for simplicity M denotes oxides of Al, Ni, or Mn) were compared. Rietveld refined X-ray powder diffraction (XRD) analysis demonstrated the formation of hexagonal, cubic, or spinel crystal structures of Al2O3, NiO, or Mn3O4 phases, respectively, besides the tetragonal rutile crystal structure of SnO2. The impact of Al addition on the optical band gap of SnO2 is negligible while it decreased or increased by incorporation of Ni or Mn, respectively. The residual lattice dielectric constant of SnO2 was increased, while the real part of the dielectric constant and the ac conductivity of SnO2 were decreased by M incorporation. The dielectric parameters are remarkably affected by selected M, T, and f values and their changes agree with the Maxwell-Wagner model. The Q-factor of SnO2 was increased by M addition while decreased with increasing T. The Ni/SnO2 obeys the hole conduction at T ≤ 330 K, while Mn/SnO2 and Ni/SnO2 obey the electronic conduction at T > 330 K. The binding energy is independent of the chosen T for SnO2, whereas it sharply increases for Ni/SnO2 and slightly decreases for Al/SnO2 and Mn/SnO2. The F-factor of SnO2 was slightly decreased by M addition, but it was increased with T for SnO2, Al/SnO2, and Mn/SnO2 while was decreased for Ni/SnO2. The Cole-Cole plots for M/SnO2 composites were analyzed, and the components of the equivalent circuit were determined. The electrical impedance, resistance of grains, resistance of grain boundaries, and equivalent resistance of SnO2 were increased by M incorporation, whereas equivalent capacitance was decreased. The findings recommend the SnO2-based nanocomposites for applications in optoelectronics, lithium batteries, supercapacitors, and solar cell devices.

MoO3 nanoplates reinforced the structural, electrical, mechanical, and antibacterial characteristics of polyvinyl pyrrolidone/sodium alginate polymer blend for optoelectronics and biological applications

Organic/Inorganic nanostructures enable the development of new functional materials for optoelectronics and biological applications. In this work, nanocomposite films of polyvinyl pyrrolidone (PVP) and sodium alginate (NaAlg) blend matrix (30/70 wt%) filled with molybdenum trioxide (MoO3) nanoplates were prepared using solution casting procedure. The effect of MoO3 nanoplates on structural, optical, electrical and antibacterial characteristics of pure PVP/NaAlg blend was investigated. The sizes of MoO3 nanoplates had dimensions between 90 and 420 nm with orthorhombic phase as indicated by the TEM and XRD techniques. Also, the XRD patterns of filled films suggested that the presence of crystalline phases of MoO3 within PVP/NaAlg matrix. FTIR analysis revealed the primary vibrational peaks of PVP and NaAlg, whose strength altered randomly after filling. The UV absorption increased gradually and shifted to the higher wavelength side. The alternating current (AC) conductivity and dielectric parameters were improved with increasing MoO3 concentration. The antibacterial activity against Staphylococcus aureus and Escherichia coli increased with increase of MoO3 nanoplates concentration. The filled PVP/NaAlg-MoO3 samples displayed considerable enhancements in the values of Young's modulus (Y), tensile stress (σt) and elongation at break (εB). The obtained results imply that these nanocomposite films can be potentially used in optoelectronics and biological applications.

Exploring the structural and electrical trends in Mo2+ substituted Ba0.7Gd0.3MoxF12-xO19 Hexaferrite

The investigation of structural and electrical properties of Ba0.7Gd0.3MoxF12-xO19 for x = 0.02, 0.04, 0.06, and 0.08 were synthesized using a solid-state reaction method. Dielectric study and different impedance parameters were measured at temperature ranging from room temperature (RT) to 500 °C and frequencies ranging from 20Hz to 20 MHz. XRD study confirms the presence of hexagonal P63/mmc phases. Average crystallite size of Ba0.7Gd0.3MoxF12-xO19 for x = 0.02, 0.04, 0.06, and 0.08 were found as 42.177 nm, 42.550 nm, 48.026 nm, and 55.057 nm respectively. Dielectric constant of the sample decreases (at a specific frequency) when the Mo2+ concentration increases. Two transition peaks were observed in the dielectric plot with the temperature variation, indicating multiple electrical transitions in Mo2+ substituted barium hexaferrite. The existence of one semicircle in the Nyquist plot indicates the presence of grain effect in all ceramic samples.

Structural and Dielectric Parameters of PVA/CMC Blend Reinforced with SiO2/SnO2 Nanoparticles for Nanoelectronics Applications

Structural and Dielectric Parameters of PVA/CMC Blend Reinforced with SiO2/SnO2 Nanoparticles for Nanoelectronics Applications

Mechanical, dielectric properties and gamma-ray buildup factors of CaO–Li2O–B2O3–As2O3 glasses: Significant role of As2O3

Newly boro-arsenic (BCL-As) glasses with chemical compositions 15CaO -15Li2O - (70-x)B2O3- xAs2O3: x = 0 (BCL-As0), 5 (BCL-As5), 10 (BCL-As10), 15 (BCL-As15), and 20 (BCL-As20) in mol% were synthesized via the quenching melt technique. The role of As2O3 on the mechanical, dielectric characteristics and γ-ray and neutron-shielding features of BCL-As specimens have been investigated. The maximum values of exposure- (EBF) and absorption- (EABF) buildup factors shift towards higher values as the molar fraction of arsenic (As) element increased in the samples. This reflects its effect the shielding properties of each glassy mixture. The BCL-As0 glass sample possesses the maximum value of neutron-removal-cross-section value of ΣR = 0.1074 in the absence of arsenic in the sample and possesses the highest Poisson ratio (σ = 0.40675) among all studied samples. The elastic moduli of the prepared BCL-As specimens were enhanced with increasing As2O3 concentration in the sample network. Young-modulus was varied from 43.26695 GPa to 67.54429 GPa, bulk (B) modulus changed from 34.86087 GPa to 72.29779 GPa, shear (S) modulus varied from 16.72935 GPa to 25.12264 and longitudinal (L) modulus was changed from 47.40789 GPa to 91.13977 GPa. The dielectric parameter and dielectric-loss (i.e., tan δ) was enhanced with As2O3 concentration.

Structural characteristics and dielectric properties of irradiated polyvinyl alcohol/sodium iodide composite films

This study, sodium iodide (NaI) is doped with polyvinyl alcohol (PVA) to prepare the PVA/NaI films. The films were irradiated by argon with beam fluence (50x1016, 100x1016, and 150x1016ions.cm−2). The composite structural were studied by XRD, FTIR and photoluminescence methods. Moreover, the SRIM/TRIM simulations is used to record the changes in the samples. The FTIR data showed that the PVA/NaI peak intensity is shifted by ion irradiations due to the interaction of PVA and NaI. In addition, the changes in surface morphology, which recorded by SEM, indicated relative modifications of the irradiated films. The electrical characteristics were measured with applied frequency of 50 Hz and 5 MHz. The dielectric constant value at frequency 100 Hz is 40 for PVA/NaI and reached to 70 and 85 respectively for irradiated with fluence 50x1016 and 100x1016ions.cm−2. Moreover, the dielectric loss, at frequency 100 Hz, was decreased from 70 for blank sample to 25 for the irradiated film with 150x1016ions.cm−2. This change in dielectric parameters is due argon irradiation. The results investigate the dielectric behavior of treated PVA/NaI films were modified to be more applicable in various devices.

Analysis of electrical performance and assessment of aging state for retired high-voltage cable accessory insulation

The cable accessories constitute a vulnerable element and are prone to failures in the operation of power transmission lines. To investigate the changes in the electrical performance and aging state of high-voltage cable accessories with different operating time, the volume resistivity, breakdown electric field, dielectric constant, and trap parameters of insulation samples taken from retired cable accessories were characterized. The results indicate that there is a certain correlation between the macroscopic dielectric characteristics of cable accessory insulation and its aging state. With the increase of operating time, the volume resistivity and breakdown electric field decrease, while the dielectric constant initially increases and then decreases. The trap distribution of cable accessory insulation can effectively reflect its aging state. With the increase of operating time, the trap energy levels of the accessory insulation become shallower, and the trap density increases. The trap results of the accessory insulation show good consistency with the resistivity and breakdown field strength. Clustering analysis is also used to classify the test data, and the results validate that the trap energy levels and trap density of the insulation samples have better correlation with the insulation aging state of cable accessories than macroscopic dielectric parameters.

Effect of Mn Doped on Structural, Optical, and Dielectric Properties of BiFe1-xMnxO3 for Efficient Antioxidant Activity.

Manganese-doped bismuth ferrites were synthesized using the coprecipitation method with the green extract Azadirachta indica. Our incorporation of the transition element, manganese, into bismuth ferrites tackles the challenge of increased leakage current often observed in intrinsic bismuth ferrites. We gained key insights through a comprehensive examination of the structural, dielectric, and optical properties of these materials, utilizing Fourier transform infrared spectroscopy (FTIR), impedance spectroscopy, and UV-visible spectroscopy, respectively. The formation of an octahedral geometry was confirmed using the FTIR technique. UV-visible spectroscopy indicated that 2% Mn doping is optimal, while we obtained a low band gap energy (2.21 eV) and high refractive index (3.010) at this amount of doping. The manufactured materials exhibited the typical ferrite-like dielectric response, that is, the dielectric parameter gradually decreased as the frequency increased and then stayed constant in the high-frequency range. Using the diphenylpicrylhydrazyl (DPPH) free radical assay, we also examined the antioxidant activity of bismuth ferrites. We concluded that among different Mn-doped BiFeMnO3-based nanomaterials, the 2 wt % Mn-doped BiFeMnO3 shows the highest antioxidant activity. This finding substantiates the efficacy of the optimized material with regard to its potent antioxidant activity, positioning it as a promising candidate for potential biomedical applications.

Structural, dielectric, thermoelectric, and magmatic properties of Er3+ ion substituted Mg-Zn spinal nanoferrites: High charge-storage capacitors and high-frequency microwave device applications

The Er-substituted magnesium and zink ferrite nanomaterials with the chemistry formula Mg0.8Zn0.2ErxFe2-xO4 (x = 0.00, 0.005, 0.01, 0.015, 0.02, 0.025) were generated in the study utilizing the citrate-gel auto combustion method. XRD is being used to investigate the cubic spinal structural structure. A transmission electron microscope (TEM) and a field emission scanning electron microscope (FESEM) were used to examine surface morphology. From the structural studies, the crystal sizes range from 14.46 to 96.40, with lattice parameters ranging from 8.434 to 8.449 and X-ray density (gm/cc) ranging from 4.585 to 4.671 and porosity (%) ranging from 7.67 to 7.91. The resulting macrostrain produces internal tension and can impair material grain growth. UV–visible absorption spectroscopy gives grain size pictures as well as quantifications at 300 K and 100 K, respectively. The wavelength range cut-off from 537.6 nm to 270.9 nm. The dielectric characteristics of the samples were tested at room temperature using an LCR meter at various frequencies. The dielectric parameters include the real component of the dielectric constant, the dielectric constant's imaginary portion, and the loss tangent. For each sample, the loss tangent of nanoferrites fell as the frequency increased. This type of material is used in capacitors and microwave devices. Thermoelectric power studies measured all samples. From the studies observed, the seeback coefficient decreases with increasing temperature and Er doping. The room temperature and low temperature magnetic properties were studied at 300 k and 100 k at low temperature ZFC and FC. The blocking temperature Tb was around 300 K.

Electromagnetic Performance Analysis of Inhomogeneous Radome Walls Considering Temperature and Ablation

The radome is an important component of the aircraft seeker. The radome of high-speed aircraft usually has ablation, which affects the electromagnetic performance of the radome. Therefore, it is important to study the electromagnetic performance of the radome wall during high-temperature ablation. However, most existing studies mainly consider the influence of temperature and ignore structural changes caused by ablation. To solve the above problems, this paper studies the influence of ablation on the electromagnetic performance of inhomogeneous radome walls (IRW) by considering the structure parameters, thermal expansion characteristics, and dielectric parameters during the ablation. The two typical types of IRW design methods are analyzed, the parameters calculation method in the ablation process is proposed, and the influence of ablation on the two types of IRW is studied. The results give the electromagnetic changing characteristics of the IRW under different ablation conditions. The contribution of this work is to lay a solid theoretical foundation for improving the performance of the radome in the ablation process, which is of great significance.

Thermodynamic hydration behaviour of glycine below room conditions using time domain reflectometry

The present work reports the concentration-dependent hydrophobicity of glycine below room temperature. The dynamics of aqueous glycine have been studied by means of dielectric relaxation spectroscopy using Time Domain Reflectometry (TDR) technique in the frequency region of 10 MHz–30 GHz. Complex permittivity spectra are obtained using TDR that allowed evaluation of the static dielectric constant (ε0) and average relaxation time (τ). As dielectric relaxation spectroscopy provides information on the average relaxation time (τ) related to the mechanism of hydrogen bond (HB) formation and breaking, therefore the concentration-temperature dependence of τ was used to evaluate and study hydration behaviour through dielectric parameters such as dipole moment (μ), correlation factor (g), and the dynamics of irrationally bound water molecules (Zib). Aqueous glycine relaxes in two different relaxation modes in the broad microwave frequency region from MHz to GHz. The low-frequency relaxation process (l-process) observed is associated with glycine relaxation, while the detected peak in the high-frequency relaxation process (h-process) is attributed to water associated with glycine. We have attempted a concentration-temperature-dependent hydrogen bonding mechanism in both relaxation processes, and the results were corroborated with thermodynamical parameters such as molar entropy of activation (∆Sj), molar enthalpy of activation (∆Hj), and molar free energy of activation (∆Fj).

Nondestructive evaluation of aircraft stealth coating by Terahertz-time domain spectroscopy: experimental and numerical investigation

ABSTRACT Particle-reinforced polymer matrix composites (PMCs) are often used as radar-absorbing materials (RAM) in aircraft stealth applications. The thickness evaluation of such multilayered coatings with micrometre-level thickness is highly challenging from single-side access. In this study, we used Terahertz Time-domain Spectroscopy (THz-TDS) in the transmission mode to extract the refractive index of the dielectric coatings for measuring the thickness using the time-of-flight method. A numerical study based on the Finite Element method (FEM) has also been developed to validate the transmission experiments. A frequency-dependent complex dielectric parameters must be considered for coatings with high absorption in the THz regime. This was addressed by performing the finite element simulations in a frequency domain. The thickness of each layer of a multi-layered coating is estimated by carrying out the experiments in reflection mode. Since the interface echoes were overlapping, a deconvolution algorithm and frequency thresholding were employed to reconstruct the signals reflected from the different interfaces. Using this technique, the thickness of each layer of coating is estimated accurately in a single measurement, which was challenging to measure using other conventional non-destructive testing (NDT) methods.

Optimized crystal structure and microwave dielectric properties of BaZnSi3O8‐based ceramics

AbstractIn this study, we synthesized BaZnSi3O8‐based compounds with monoclinic structures (P21/a) using a solid‐state method. The crystal structure, phase composition, and microwave dielectric properties of BaZnSi3O8‐based ceramics were systematically investigated systematically. X‐ray diffraction (XRD) patterns and scanning electron microscopy (SEM) images proved that the maximum solubility of BaZn1‐xMgxSi3O8 ranged between 0.3 and 0.4. Rietveld refinement and Phillips–Van Vechten–Levine complex chemical bond theory were used to illustrate the relationship between the microwave dielectric performance and lattice parameters. To further improve the properties, we substituted Ba2+ with Sr2+ in BaZn0.8Mg0.2Si3O8. Ba1‐ySryZn0.8Mg0.2Si3O8 remained in a single‐phase as y increased from 0 to 1.0. We achieved thermal stability of the resonance frequency of the BaZnSi3O8‐based ceramics by adjusting TiO2 to form composite ceramics. After sintering at 1020°C for 5 h, excellent microwave dielectric properties with εr = 7.44, Q×f = 57,400 GHz, and τf = − 0.2 ppm/°C were realized in the SrZn0.8Mg0.2Si3O8+8 wt %TiO2 system.

Enhancement of the optical and electrical properties of poly ethyl methacrylate/polyvinyl chloride-zinc sulphide (PEMA/PVC@ZnS) ternary nanocomposite films

Our research introduces a novel ternary nanocomposite consisting of polyethyl methacrylate/polyvinyl chloride-Zinc sulphide nanoparticles (PEMA/PVC@ZnS). Zinc sulphide (ZnS) nanoparticles were produced via a chemical method and then dispersed at different concentrations (0.02, 0.05, 0.08, and 0.1 wt%) in a single step within the PEMA/PVC blend. The resulting PEMA/PVC@ZnS nanocomposite films were analyzed to investigate their spectroscopic and electrical properties. The dielectric parameters of the samples were also studied in detail. X-ray diffraction (XRD) data indicated an increase in the amorphous region and demonstrated the interaction between ZnS and PEMA/PVC. Fourier transform infrared (FT-IR) results confirmed the specific interactions in PEMA/PVC@ZnS nanocomposites. The synthesized films showed a distinct absorption band at 432 nm, which was attributed to the ZnS surface plasmon resonance. As the concentration of ZnS in PEMA/PVC increased, the band gap energies decreased for both direct and forbidden transitions. Optical parameters such as the extinction coefficient (k), refractive index (n), dielectric constants (ε′ and ε''), optical conductivity (σ(opt.), and photoluminescence (PL) were also studied. The values of dielectric permittivity and dielectric modulus from AC measurement of PEMA/PVC@ZnS nanocomposite films increased with increasing ZnS content. The data suggest that PEMA/PVC@ZnS nanocomposite films exhibit excellent optical and electronic properties, making them suitable for use in various electric and optoelectric applications.

Investigation of Material Loading on an Evolved Antecedent Hexagonal CSRR-Loaded Electrically Small Antenna.

Recent advances in embedded antenna and sensor technologies for 5G communications have galvanized a response toward the investigation of their electromagnetic performance for urban contexts and civil engineering applications. This article quantitatively investigates the effects of material loading on an evolved antecedent hexagonal complementary split-ring resonator (CSRR)-loaded antenna design through simulation and experimentation. Optimization of the narrowband antenna system was first performed in a simulation environment to achieve resonance at 3.50 GHz, featuring an impedance bandwidth of 1.57% with maximum return loss and theoretical gain values of 20.0 dB and 1.80 dBi, respectively. As a proof-of-concept, a physical prototype is fabricated on a printed circuit board followed by a simulation-based parametric study involving antenna prototypes embedded into Ordinary Portland Cement pastes with varying weight percentages of iron(III) oxide inclusions. Simulation-derived and experimental results are mutually verified, achieving a systemic downward shift in resonant frequency and corresponding variations in impedance matching induced by changes in loading reactance. Finally, an inversion modeling procedure is employed using perturbation theory to extrapolate the relative permittivity of the dielectric loaded materials. Our proposed analysis contributes to optimizing concrete-embedded 5G antenna sensor designs and establishes a foundational framework for estimating unknown dielectric parameters of cementitious composites.

Enhanced dielectric properties of α-MoO3 nanobelts dispersed polyethylene oxide-carboxymethyl cellulose matrix-based nanocomposites

Highly crystalline molybdenum trioxide nanobelts (MoO3 NBs) are synthesized via one-step hydrothermal method and the resulting NBs are incorporated with poly(ethylene oxide) (PEO)/carboxymethyl cellulose (CMC) blend matrix via a solution-casting method to be applicable in various nanoelectronics. The structural, optical, and dielectric characteristics of the polymer nanocomposite PEO/CMC-(x)MoO3 (x = 2, 4, 6, and 8 %wt) films are comprehensively examined by different techniques, including X-ray diffraction (XRD), Fourier-transform infrared (FTIR), ultraviolet–visible (UV–Vis) spectroscopy, and broadband dielectric spectroscopy. XRD results confirm the presence of nanofiller in the (PEO/CMC) blend at a higher fraction (8 wt%). Furthermore, FTIR investigations show an electrostatic interaction between the PEO/CMC polymer composite and MoO3 nanobelts, leading to the generation of metal oxides/polymer complexes. Optical properties of the synthesized PEO/CMC-(x) MoO3 matrix, including direct and indirect bandgap energies are decreased by increasing the content of MoO3 NBs in the PEO/CMC blend matrix, showing the promise of photocatalytic activity. The AC conductivity and dielectric parameters (ε′ and ε′′) are markedly increased at a higher fraction of MoO3 (8 wt%). The optical and electrical conductivity properties of the synthesized PEO/CMC-(x) MoO3 design confirms its ability to be used in optoelectronic devices.