Dielectric Research Articles

Size dependent dielectric properties in BaTiO3 nanopowders for application of MLCC

With the development of technology, electronic devices are constantly improving in performance, leading to an increase in the number of components. Consequently, there is a need to downsize passive components such as multi-layer ceramic capacitors (MLCCs). As a result, the size of the dielectric material used in MLCCs, namely BaTiO3, must also be reduced. However, previous studies have primarily investigated the dielectric properties of BaTiO3 nanopowders using the slurry method, of which approach has limitations as it combines the dielectric properties of both nanopowders and solvent. In this study, we employed scanning dielectric microscopy (SDM) to individually measure the dielectric constants of single BaTiO3 nanopowders. We demonstrate dielectric constant dependent on the size of nanopowder. Furthermore, the variation in dielectric constant can be attributed to the surface cubic layer of BaTiO3 nanopowders. Our findings revealed a peak dielectric constant of 60 occurring at an approximate nanopowder size of 55 nm, a phenomenon explicable through a three-phase structural model. This exploration into the nanoscale characteristics of BaTiO3 holds promise for advancing the development of next-generation MLCCs.

The Effect of the Wall Thickness of the Material Loaded Cavity On the RCS Reduction

In this paper, the effect of a parallel plate waveguide's wall thickness on radar cross-section reduction (RCS) is rigorously analyzed for H-polarization by using the Wiener-Hopf Technique, when the waveguide region is loaded with dielectric material and terminated with a perfect electric conductor (PEC) plate. Transfer matrices are incorporated into the analysis to account for the effect of different material layers through continuity relations. The Fourier transforms of the diffracted field and the boundary conditions yield a modified scalar Wiener-Hopf equation of the second kind (MWHE-2). The classical procedure to solve the MWHE-2 is applied and the approximate expression of the diffracted far field is obtained. Numerical results are given by comparing with the results available in the literature for the case of the wall thickness of the cavity not being considered.

One-Port Coaxial Line Sample Holder Characterisation Method of Dielectric Spectra.

A technique for solving the one-port closed coaxial transmission line sample holder scattering equation for complex permittivity inversion for lossy materials is presented. A non-linear least-squares procedure is used for the determination of parameters for the specification of the spectral functional form of the complex permittivity. The method allows for accurate retrieval of many low- and high-permittivity dielectric materials in the frequency range of 1 GHz to 3 GHz inserted into the coaxial cell. Using this method, the complex permittivity of a number of liquids and a Maltese soil known as Bajjad soil have been extracted by measurements using a short terminated coaxial transmission line sample holder. The proposed novel inversion method is mainly based on the reflection coefficient of the test material. The measured results of the complex permittivity of liquid dielectrics such as ethanol, methanol, and TX100 are validated and compared with previously published data obtained from measurements made by the National Physical Laboratory (NPL) using a two-port measurement setup made with the same commercial coaxial transmission line sample holder used in the one-port setup. Since the technique allows broadband measurements, it has been used to characterise the soil dielectric spectrum in the frequency range of 1-3 GHz, which is also compared with results from a two-port setup of the same coaxial line. The experimental results are a validation of the proposed approach for different types of materials.

Analysis and Application of Poly(vinyl alcohol) (PVA) and Polyacrylonitrile (PAN) Nanofiber Membrane-Based Triboelectric Nanogenerators.

The triboelectric property of materials is used to harvest energy from intentional or nonintentional sources of vibration. Contact mode freestanding dielectric based nanogenerators (CFTENGs) have many advantages when compared with other modes of triboelectric nanogenerators. The property of dielectric materials plays an important role in the energy harvesting process. In this work, we aim to fabricate nanofiber membranes of poly(vinyl alcohol) (PVA) and polyacrylonitrile (PAN) and study their properties for CFTENGs. The morphology and porosity of both membranes were tested experimentally. The mechanical property is modeled with a representative volume element (RVE) technique to understand its deflection behavior. In addition, an electromechanical model is developed to predict and analyze the behavior of those membranes in the energy conversion process. Our research reveals that the PAN dielectric layer achieves a maximum open circuit voltage of 192 kV compared to the PVA dielectric layer (2.2 kV) in the CFTENG system. In comparison, the dielectric layer of the PAN nanofiber membrane reflects its flexibility to generate electrical energy in a CFTENG with the effect of contact electrification and electrostatic induction under various sources of unused energies for a wide range of applications. Moreover, the same methodology is applied to various sources of vibration, and their performance is reported. With an appropriate power management circuit, we can design a PAN membrane-based TENG for various applications.

Damage of Nickel-coated glass/epoxy foam-core composites induced by artificial lightning strikes

In the field of composite materials, many reports have shown that catastrophic structural damage is caused by lightning strikes. In this study, new design concepts were proposed for the lightning-strike protection of nickel-coated glass/epoxy foam-core composites. Instead of using a neat metal mesh, glass fibers were modified with nickel particles via a plating technique to improve their thermal and electrical conductivities. In addition, a thin Invar plate was inserted at the middle of the structure and a foam core was introduced to reduce damage to the structure. Three models with different materials and stacking sequences were used in this study. Severe damage was experimentally observed following artificial lightning at a peak current of approximately 150 kA when considering a waveform A. Furthermore, numerical prediction was performed to identify the damage mechanisms of the structures. Besides the heat flux source, a mechanical source known as the shock wave overpressure was investigated separately as a new factor for dielectric materials. These two sources of lightning were determined as minor reasons for the structural damage. The failure modes were analyzed for further discussion about the failure mechanism in this study.

Superior energy storage performance of Sr0.7Bi0.2TiO3-modified Na0.5Bi0.5TiO3-K0.7La0.1NbO3 lead-free ferroelectric ceramics

Na0.5Bi0.5TiO3 (NBT)-based ceramics exhibit significant potential as energy storage dielectric materials due to their high maximum polarization (Pmax). However, their limited energy storage density significantly restricts their practical applications. To address this, this study optimizes the dielectric energy storage characteristics of lead-free relaxor ferroelectric ceramics based on 0.91Na0.5Bi0.5TiO3-0.09 K0.7La0.1NbO3 (NBT-KLN) by incorporating Sr0.7Bi0.2TiO3 (SBT) relaxor additives. The introduction of SBT helps maintain large polarization and induces local disorderly fields, promoting the formation of polar nanoregions. Subsequently, a viscous polymer processing (VPP) technique was employed to reduce defects and enhance density, markedly improving the breakdown strength (BDS). The findings indicate that the BDS of the optimized 0.30SBT (VPP) ceramics increased to 440 kV/cm, while achieving a high energy storage efficiency (η) of 78 % and an elevated energy storage density (Wrec) of 6.29 J/cm3. Additionally, the 0.30SBT (VPP) ceramics demonstrate excellent temperature stability across a broad temperature range from 30 to 120 °C, making them ideal for long-term operation in variable environments. This study demonstrates superior results compared to previous research, thereby opening up new avenues for developing novel lead-free relaxor ferroelectric ceramics with superior energy storage characteristics.

Customized Pore Creation Strategies for Hyperelastic, Robust, Insulating Multifunctional MXene Aerogels for Microwave Absorption.

The construction of heterogeneous microstructure and the selection of multicomponents have turned into a research hotspot in developing ultralight, multifunctional, high-efficiency electromagnetic wave absorbing (EMA) materials. Although aerogels are promising materials to fulfill the above requirements, the increase in functional fillers inevitably leads to the deterioration of intrinsic properties. Tuning the electromagnetic properties from the structural design point of view remains a difficult challenge. Herein, we design customized pore creation strategies via introducing sacrificial templates to optimize the conductive path and construct the discontinuous dielectric medium, increasing dielectric loss and achieving efficient microwave absorption properties. A 3D porous composite (MEM) was crafted, which encapsulated an EVA/FeCoNi (EVA/MNPs) framework with Ti3C2Tx MXene coating by employing a direct heated cross-linking and immersion method. Controllable adjustment of the conductive network inside the porous structure and regulation of the dielectric character are achieved by porosity variation. Eventually, the MEM-5 with a porosity of 66.67% realizes RLmin of -39.2 dB (2.2 mm) and can cover the entire X band. Moreover, through off-axis electronic holography and the calculation of conduction loss and polarization loss, the dielectric property is deeply investigated, and the inner mechanism of optimization is pointed out. Thanks to the inherent characteristic of EVA and the porous structure, MEM-5 showed excellent thermal insulating and superior compressibility, which can maintain 60 °C on a 90-100 °C continuous heating stage and reached a maximum compressive strength of 60.12 kPa at 50% strain. Conceivably, this work provides a facile method for the fabrication of highly efficient microwave absorbers applied under complex conditions.

Frequency Detection for String Instruments Using 1D-2D Non-Contact Mode Triboelectric Sensors.

The proliferation of small electronic devices has significantly increased the demand for self-powered sensors. This study introduces a triboelectric frequency sensor (TFS) that combines the frequency-responsive characteristics of triboelectric nanogenerators with a simple one-dimensional structure for sustainable vibration measurement. This sensor is specifically designed to aid in the tuning of string instruments, capable of detecting frequency responses up to 330 Hz generated by string vibrations. Structural optimization was achieved by setting a non-contact mode with a gap distance of 3 mm and utilizing perfluoroalkoxy alkane (PFA) as the contact dielectric material. The TFS exhibits dynamic response characteristics by varying the vibrating frequency and the tension of the string, facilitated by a custom-built testing setup. Frequency data captured by the sensor can be visualized on a monitor through the integration of a microcontroller unit (MCU) and dedicated coding. The practical applicability and effectiveness of this sensor in real-world scenarios are demonstrated experimentally. This innovation represents a significant step forward in the development of self-sustaining sensing technologies for precision instrument tuning.

Construction of polymer-derived double transition metal compound/carbon matrix nanocomposites for efficient electromagnetic wave absorber

As typical dielectric materials, transition metal compounds have a broad potential in the field of stealth, but their application is still hampered by poor conductivity. In this study, based on the mechanism of electrostatic self-assembly of heteropolyacids and organic ligands, the electrostatic structures obtained after the introduction of different heteropolyacids into the conductive phase pyrrole are carbonized. On the one hand, the as-prepared transition metal compounds/carbon matrix nanocomposites produce synergistic effects and optimize impedance matching, and on the other hand, the formation of the abundant heterogeneous interfaces as well as the doping of the N, P heteroatoms induce the generation of interfacial polarisation and dipole polarisation, all of which provide the opportunities to produce composites with enhanced electromagnetic wave absorption properties. Unsurprisingly, the best synthesised sample, Mo2C/W2C/NPC, exhibits a significantly improved electromagnetic wave absorption performance, with an effective bandwidth of 5.7 GHz at a matched thickness of 2.5 mm, where the minimum reflection loss value of −54.5 dB is also achieved. The total effective bandwidth of the Mo2C/W2C/NPC-35 wt% is up to 10.5 GHz (7.3–17.8 GHz) via adjusting the matching thickness in the range of 1.7–3.5 mm. Therefore, this study reflects that dual transition metal compound/carbon based composite wave-absorbing materials provide a new material basis for the construction of high-performance absorption materials.

Investigating the dielectric and ferromagnetic behaviour of Ni and Co dual doped ZnO for diluted magnetic semiconductor

Herein, Ni/Co co-doped ZnO nanoparticles (NPs) were successfully prepared via chemical co-precipitation process. The structural, purity and crystallite size of as-prepared particles were confirmed by using x-ray diffraction (XRD). The results revealed the hexagonal wurtzite structure of ZnO without any impurity phase of as-prepared samples. The crystallite size decreased from 34.9 to 9.6 nm, whereas lattice strain reduced to 0.00086. The change in crystallite size, lattice parameters, strains and dislocation density further indicates the successful incorporation of dopants in ZnO host lattice. The dielectric properties, ac conductivity, and magnetic behaviour were steadily examined. The dielectric constant has been found to be 1070 with 5wt% at low frequency and become constant at higher frequency. It was revealed that dopant additions lead to attain high dielectric constant and low loss possibly attributed to interface polarization, and dipole polarization due to oxygen vacancy defects. M-H measurement observed that ferromagnetism at room temperature pure and doped ZnO samples. The ferromagnetic behaviour of pure ZnO NPs with Ms = 0.17 emu g−1, Mr = 0.11 emu g−1 and Hc = 67 which was increased to Ms = 0.85 emu g−1 and Mr = 0.65 emu/g for 5wt% Co. This improvement with increasing Co concentration indicates that oxygen defects may stabilize the ferromagnetic order. These interesting features encouraging to use this material for ultrahigh dielectric materials and spintronics.

Band gap and gate dielectric engineered novel Si0.9Ge0.1/InAs junctionless TFET for RFIC applications

In this study, we present a dual dielectric material gated novel Si0.9Ge0.1/InAs hetero-structure Junctionless TFET (DMG-HJLTFET), in which first time, a novel amalgamation of Si0.9Ge0.1/InAs along with HfO2 and SiO2 is used on the basis of band gap and gate dielectric engineering respectively. Our main goal is to examine the performance of the reported device in terms of radio frequency (RF), linearity, and intermodulation distortion parameters. The reported device’s (DMG-HJLTFET) result is compared with latest published articles and conventional Si-JLTFET to show the improvement. Our simulation results reveal that DMG-HJLTFET outperforms Si-JLTFET in several key metrics, such as parasitic capacitance (Cgg, 49% ↓), maximum oscillation frequency (fmax, 589 times ↑), gain bandwidth product (GBP, 238.5 times ↑), intrinsic gain (Av, 2.24 × 102 times ↑), peak transconductance (gm, 110 times ↑), and second-order voltage intercept point (VIP2, 330.2% ↑). Our findings lead us to the conclusion that DMG-HJLTFET might be a promising substitute for low-power and high-frequency applications.

Scalable In-situ Microfibrillar dielectric films: Achieving exceptional energy density and efficiency

It is a formidable challenge to develop a feasible strategy for the scalable fabrication of all-organic dielectrics with simultaneous improvements in both discharged energy density (Ud) and efficiency (η). Herein, an innovative technology of “melting extrusion-hot stretching-quenching” was put forward for the large-scale preparation of all-organic polymer dielectric films, where polymethyl methacrylate (PMMA) was miscible with polyvinylidene fluoride (PVDF) to form single dispersed phase in the polypropylene (PP) matrix and in-situ transformed into microfibrils with the aid of elongational flow field. Thereby, a simultaneous enhancement in the dielectric constant and breakdown strength was achieved and the as-prepared PP-based all-polymer dielectric film exhibited an unprecedented ultrahigh Ud of 9.6 J cm−3 and an exceptional η of 90.9 %. Experimental verification and computational simulation confirmed that the formation of highly oriented PMMA/PVDF microfibrils and well-aligned interfaces are constructive to enhancing breakdown strength by suppressing electric field distortion. The highly oriented dipoles in PVDF and PMMA, coupled with the eliminated ferroelectric behavior of PVDF, synergistically contributed to the heightened Ud and η. The approach presented in this work opens up a promising avenue for the large-scale production of all-organic capacitor films with enhanced Ud and η, heralding a new era of advanced dielectric materials.

Sputter deposited silver niobate thin films: Pathway towards phase purity

The quest for environmentally sustainable alternatives to lead-based dielectric materials in dielectric capacitors has led research to the exploration of options such as silver niobate (AgNbO3), which has been found to display excellent energy storage properties. Homogeneity and phase-purity of the used thin films are vital for optimal performance of these devices. In this study, a systematic variation of oxygen partial pressure and bias voltage during reactive d.c. magnetron co-sputtering from metallic targets is employed to synthesise AgNbO3 thin films. Structural and chemical composition of the films are investigated using X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, energy dispersive X-ray spectroscopy, elastic recoil detection analysis, and Rutherford backscattering spectrometry. The findings emphasise the necessity of precise parameter control during deposition to avoid the presence of undesirable secondary phases like Ag and Ag2Nb4O11 and to ensure the formation of homogeneous and phase-pure AgNbO3 thin films. The gained insights demonstrate the potential of reactive d.c. magnetron sputtering for the deposition of lead-free AgNbO3 thin films, offering pathways for enhanced environmental compatibility of future dielectric capacitors.

Local defect structure design enhanced energy storage performance in lead-free antiferroelectric ceramics

Antiferroelectrics (AFEs) are ideal candidates in dielectric, electromechanical, and electrothermal applications. NaNbO3 (NN), as a lead-free antiferroelectric (AFE) material under extensive investigation, exhibits ferroelectric (FE)-like polarization–electric field (P-E) hysteresis loops, characterized by high remnant polarization and large hysteresis. Herein, the local defect structure design is proposed to achieve high energy storage (ES) density in NN-based AFE ceramics. The pinning effect of defect dipoles and the enhancement of local structural disorder stabilize the AFE phase and reduce hysteresis losses. Consequently, an excellent ES performance of large recoverable energy density (Wrec) of 9.70 J/cm3 and high efficiency (η) of 88.75 % is concurrently obtained in NN-based relaxor AFE ceramics, with outstanding charge–discharge performance (PD∼413.2 MW/cm3, WD∼4.47 J/cm3), which are significantly improved compared to other reported values in lead-free ES ceramics. This indicates that NN-based ceramics are candidates for advanced ES capacitors and provides a feasible modulation approach for the development of new lead-free high-performance dielectric materials.

Impact of volatility, non‐stoichiometry, and atmospheres in perovskite piezoelectric and dielectric materials

Impact of volatility, non‐stoichiometry, and atmospheres in perovskite piezoelectric and dielectric materials

Dramatic Influence of Temperature on Charging

Charging of cables outside of a spacecraft has been cited as the cause of multiple spacecraft anomalies based upon correlations with peaks in the energetic electron environment and because the electron flux exposure of external cables is much higher than internal cables. However, external cables are subject to much wider temperature changes than hardware located inside a thermally regulated spacecraft. Temperature affects bulk resistivity and radiation-induced conductivity, but temperature is often ignored in charging analyses and tests. In this paper, temperature effects are combined with a diurnal temperature variation and an external electron environment to simulate the charging of an external coax. The simulation shows that the coax dielectrics behave as perfect insulators during the cold portion of the 24 h cycle, but the accumulated charge leaks out during the hot portion of the cycle. There is no memory or hysteresis of charge density from one day to the next. This behavior is compared to the behavior of materials inside the spacecraft, where low flux and stable temperatures lead to charging time constants ranging from weeks to months that produce a slow, stair-step increase of trapped charge in response to multiple electron storms. These variations in charging response explain why some anomalies correlate best with peak 24 h average flux, whereas others correlate well with 14- or 21-day averaged flux. Analyses and tests used to qualify designs or investigate anomalies must account for the dramatic effects that temperature variation can have on the charging of insulators and isolated conductors.

Statistical evaluation of electric field distributions in 3D composites with a random spatial distribution of dielectric inclusions

Electromagnetic applications of composites often impose constraints on the internal electric fields, such as an upper limit on the field strength to prevent local heating or dielectric breakthrough. However, owing to heterogeneity, the local fields in a composite differ from those in a homogeneous material. Moreover, they are accessible neither by experiment nor by effective medium theories, at least for arbitrary microstructures. In this work, we use numerical simulations to evaluate the electric field distribution and the effective permittivity for 3D systems of monodisperse impenetrable spheres dispersed in a continuous matrix phase. We restrict ourselves to loss-free dielectric materials and to a random spatial distribution of particles. Samples are placed in a parallel plate waveguide and exposed to a transverse electromagnetic wave. The local field amplitudes are calculated via the finite element method and are normalized to those of a homogeneous sample exhibiting the same effective permittivity and geometry. We analyze the distribution of the local electric field strength in both constituents, namely, particles and matrix. Thus, we evaluate mean values and standard deviations as well as the field strengths characterizing the highest and lowest percentiles. Increasing particle concentration or permittivity enhances heterogeneity, and so the local electric field strength in some domains can become much higher than its average value. The methods we apply here can also be used in further investigations of more complex systems, including lossy materials and agglomerating particles.

Boosting Reactive Oxygen Species Generation via Contact-Electro-Catalysis with FeIII-Initiated Self-cycled Fenton System.

Contact Electro-Catalysis (CEC) using commercial dielectric materials in contact-separation cycles with water can trigger interfacial electron transfer and induce the generation of reactive oxygen species (ROS). However, the inherent hydrophobicity of commercial dielectric materials limits the effective reaction sites, and the generated ROS inevitably undergo self-combination to form hydrogen peroxide (H2O2). In typical CEC systems, H2O2 does not further decompose into ROS, leading to suboptimal reaction rates. Addressing the generation and activation of H2O2 is therefore crucial for advancing CEC. Here, we synthesized a catalyst by loading the dielectric material polytetrafluoroethylene (PTFE) onto ZSM-5 (PTFE/ZSM-5, PZ for short), achieving uniform dispersion of the catalyst in water for the first time. The introduction of an FeIII-initiated self-cycling Fenton system (SF-CEC), with the synergistic effects of O2 activation and FeIII-activated H2O2, further enhanced ROS generation. In the FeIII-initiated SF-CEC system, the synergistic effects of ROS and protonated azo dyes enabled nearly 99 % degradation of azo dyes within 10 minutes, a sixfold improvement compared to the CEC system. This represents the fastest degradation rate of methyl orange dye induced by ultrasound to date. Without extra oxidants, this system enabled stable dissolution of precious metals in weakly acidic solutions at room temperature, achieving 80 % gold dissolution within 2 hours, 2.5 times faster than similar CEC systems. This study also corrects the unfavorable perception of CEC applications under acidic conditions, providing new insights for the fields of dye degradation and precious metal recovery.

Investigation of process parameters for modeling of ceramic composite SiSiC IN dry EDM (DEDM) cutting

The manufacturing industry is currently grappling with issues related to energy dissipation and product quality, both of which significantly impact productivity. In addressing this pertinent concern, this study endeavours to identify the key indicators that contribute a crucial role in machining process. The Dry EDM (DEDM) emerges as a novel technology, wherein environmentally friendly gases serve as an alternative dielectric medium instead of liquid EDM approaches. In conventional EDM process, hydrocarbon oils release toxic emissions while the gases used in Dry EDM process don’t produce harmful emissions and hence make the DEDM process sustainable.An investigation has been carried out to observe the influence of different gases like O2, N2 and Air on Siliconized Silicon-Carbide plate (SiSiC) of ø50mm*2 mm under Dry Electrical Discharge Machining. Effect of different tools is also observed using varying shapes of electrodes like plane Cu electrode of ø6 mm diameter with 60 mm length and tubular shape with outer diameter ø6mm and inner diameter ø5.1 mm with a length of 60 mm. The three gases are one by one supplied through a nozzle in the presence of plane Cu electrode to make the holes in SiSiC plate. The same process is executed with tubular Cu electrode. Modified Taguchi Orthogonal Array is applied to analyze the effect of control factors such as gap voltage, discharge current and pulse on-time through a series of experiments. Effect of different shape of tools and different gases is observed for the material removal rate (MRR) and surface roughness (SR) of specimen.In this paper, a latest DEDM process of swirl assisted flushing is proposed which provides a new technique to solve the problems of low MRR and poor surface integrity. Swirl assisted flushing works on Decay Law and also microscopic investigation justifies its validity. It is concluded by this research that current and Pulse on time are more contributing factors about 53.3 % and 27 % respectively. Furthermore, it is noted that DEDM increases MRR 19.5 % and lowers Ra approximately 2/3 than traditional machining. The MRR of O2 is about 3.1 times more than Air and N2 comes at least position while N2 creates better quality of surface due to formation of an inert nitride layer. Empirical relations are established for SR and MRR using Minitab 18 Software to develop a robust model. Confirmation test is performed to check the validity of developed mathematical model. The Novelty of this research is also extended by introducing a new method SAF. The results are finally evaluated by ANOVA.

Research Status of Lignin-Based Polyurethane and Its Application in Flexible Electronics.

Polyurethanes (PU) have drawn great attention due to their excellent mechanical properties and self-healing and recyclable abilities. Lignin is a natural and renewable raw material in nature, composed of a large number of hydroxyl groups, and has a great potential to replace petroleum polyols in PU synthesis. This review summarizes the recent advances in modification methods such as the liquefaction, alkylation, and demethylation of lignin, and a systematic analysis of how to improve the reactivity and monomer substitution of lignin during polyurethane synthesis for the green manufacturing of high-performance polyurethanes was conducted. Polyurethane can be used in the form of films, foams, and elastomers instead of conventional materials as a dielectric or substrate material to improve the reliability and durability of flexible sensors; this review summarizes the green synthesis of polyurethanes and their applications in flexible electronics, which are expected to provide inspiration for the wearable electronics sector.