Variation Of Dielectric Constant Research Articles

Unique features of plasmonic absorption in ultrafine metal nanoparticles: unity and rivalry of volumetric compression and spill-out effect

Abstract We present a solution to a longstanding challenge in nanoplasmonics and colloid chemistry: the anomalous optical absorption of noble metal nanoparticles in the ultrafine size range of 2.5–10 nm, characterized by a rapid long-wavelength shift in plasmon resonance as the particle size increases. Our investigation delves into the impact of alterations in electron density along the radial direction of nanoparticles and the resulting variations in dielectric constants on the spectral positioning of the plasmon resonance. We explore the interplay of the spill-out effect, volumetric compression, and their combined impact in different experimental conditions on electron density variation within the particle volume and its blurring at the particle boundary. The latter effectively forms a surface layer with altered dielectric constants and a size-independent extent. As particle size decreases, the influence of the surface layer becomes more pronounced, especially when its extent is comparable to the particle radius. These findings are specific to ultrafine plasmonic nanoparticles and highlight their unique properties.

Giant permittivity and humidity sensitivity of SrTiO3 based ceramics induced by K, Nb donor-acceptor co-doping

This research utilizes a solid-state sintering process to fabricate a series of Sr1-xKxTi1-xNbxO3 (x =0.01, 0.02, 0.025, 0.03) ceramics. The sample with a doping concentration of x=0.025 achieved a dielectric constant of 10409 and a dielectric loss of 0.026 at 1 kHz. With increased dopant concentrations of K and Nb, the thermal stability of the ceramics is significantly enhanced, as evidenced by a dielectric constant variation of less than 15 % for x=0.025 sample over a temperature range from room temperature to 240 °C. Employing activation energy analysis, impedance spectroscopy, humidity response assessments, and X-ray photoelectron spectroscopy, it is indicated that the excellent electrical performance is attributed to the combined effects of the Internal Barrier Layer Capacitance and the formation of complex defect dipoles. Moreover, the insights into the moisture characteristics of SrTiO3 presented in this paper imply that the giant dielectric Sr1-xKxTi1-xNbxO3 ceramics have potential in the application of humidity sensing devices.

ISM band CPW-fed antenna for detection of skin cancer

A CPW-fed antenna sensor with high quality factor is designed to identify the skin cancer. The proposed antenna operates in the ISM band at 2.47 GHz frequency. The proposed antenna aims to exploit the variations in dielectric constants of skin, fat, and muscle tissues to enable non-invasive and early detection of skin cancer. The antenna design process involves considerations for achieving a high frequency shift and quality factor to discern subtle variations in dielectric properties. Electromagnetic simulations, utilizing advanced numerical techniques are employed to analyze the antenna's performance in different tissue environments. The proposed antenna design is optimized for enhancing its sensitivity to changes in the dielectric constants associated with healthy and cancerous skin tissues. To validate the antenna's effectiveness, experimental setups using tissue-mimicking phantoms are utilized. This research not only emphasizes the technical aspects of antenna design but also underscores the potential clinical applications for non-invasive skin cancer detection.

Size dependent dielectric properties in BaTiO3 nanopowders for application of MLCC

With the development of technology, electronic devices are constantly improving in performance, leading to an increase in the number of components. Consequently, there is a need to downsize passive components such as multi-layer ceramic capacitors (MLCCs). As a result, the size of the dielectric material used in MLCCs, namely BaTiO3, must also be reduced. However, previous studies have primarily investigated the dielectric properties of BaTiO3 nanopowders using the slurry method, of which approach has limitations as it combines the dielectric properties of both nanopowders and solvent. In this study, we employed scanning dielectric microscopy (SDM) to individually measure the dielectric constants of single BaTiO3 nanopowders. We demonstrate dielectric constant dependent on the size of nanopowder. Furthermore, the variation in dielectric constant can be attributed to the surface cubic layer of BaTiO3 nanopowders. Our findings revealed a peak dielectric constant of 60 occurring at an approximate nanopowder size of 55 nm, a phenomenon explicable through a three-phase structural model. This exploration into the nanoscale characteristics of BaTiO3 holds promise for advancing the development of next-generation MLCCs.

Design and sensitivity analysis of a vertical TFET with dielectric pocket for its use as label free biosensor

A comprehensive analysis of a dielectrically modulated vertical tunnel field effect transistor (VTFET) as a label free biosensor is presented in this article. The proposed structure considers an n+ pocket at the source /channel interface and a dielectric pocket at channel/drain interface. The sensitivity of the VTFET biosensor has been investigated, introducing neutral and charged biomolecules of different dielectric constants at the nanogap cavity. The n+ doped pocket introduced at the source/channel junction improves the output characteristics of the proposed VTFET due to its conduction mechanism in both lateral and vertical directions, thereby improving the sensitivity of VTFET biosensor as well. The proposed VTFET biosensor gains the sensitivity in the order of 105 for a fully filled cavity. Moreover, the HfO2 dielectric pocket at the channel/drain interface suppresses the deteriorating ambipolar behaviour and also enhances the ambipolar current sensitivity compared to a VTFET biosensor without dielectric pocket. Thus, it is perceived that the main drawback of TFET, ambipolar nature, has evolved as an advantage for sensing applications. The VTFET biosensor has been analyzed with regards to variations in dielectric constant of cavity, density of charge, length and height of cavity, mole fraction and also operating temperature at a particular bias condition to judge its sensing capability. A status map has been presented where the proposed VTFET biosensor has been compared with some of the significant works reported in literature in terms of sensitivity and selectivity.

Surface properties of the seas of Titan as revealed by Cassini mission bistatic radar experiments

Saturn’s moon Titan was explored by the Cassini spacecraft from 2004 to 2017. While Cassini revealed a lot about this Earth-like world, its radar observations could only provide limited information about Titan’s liquid hydrocarbons seas Kraken, Ligeia and Punga Mare. Here, we show the results of the analysis of the Cassini mission bistatic radar experiments data of Titan’s polar seas. The dual-polarized nature of bistatic radar observations allow independent estimates of effective relative dielectric constant and small-scale roughness of sea surface, which were not possible via monostatic radar data. We find statistically significant variations in effective dielectric constant (i.e., liquid composition), consistent with a latitudinal dependence in the methane-ethane mixing-ratio. The results on estuaries suggest lower values than the open seas, compatible with methane-rich rivers entering seas with higher ethane content. We estimate small-scale roughness of a few millimeters from the almost purely coherent scattering from the sea surface, hinting at the presence of capillary waves. This roughness is concentrated near estuaries and inter-basin straits, perhaps indicating active tidal currents.

Investigation of structural and electrical properties of RLaLiTeO6 (R = Ca, Sr, and Ba) double perovskites

In this study, we synthesized RLaLiTeO6 compounds (R = Ca, Sr, and Ba) via a high-temperature solid-state reaction route and thoroughly investigated their structural, dielectric, and impedance properties. X-ray diffraction (XRD) was used to determine the crystal structure of the samples. Symmetry confirmation was achieved through Raman spectroscopy and further solidified through Rietveld refinement employing FullProf Suite software. Our results showed that CaLaLiTeO6 and SrLaLiTeO6 exhibited a monoclinic (P21/n) phase, while BaLaLiTeO6 displayed a tetragonal (I4/m) phase. Structural optimization was further carried out using the VESTA and GFourier programs, with microstrains and crystallite sizes assessed via the Williamson-Hall (W-H) plot. Field Emission Scanning Electron Microscopy (FESEM) revealed a decrease in average grain size from 0.87 μm to 0.26 μm with increasing ionic radii from Ca to Ba. The dielectric properties, characterized by the variation of dielectric constant (ε′) and dielectric loss (tanδ) with frequency (0.1 Hz to 1 MHz) at specific temperatures, exhibited dispersive behavior at low frequencies and became independent at high frequencies. Furthermore, temperature-dependent dielectric constants and losses were investigated over 300 K to 625 K under fixed applied AC field values. The impedance study was assessed through Z′ vs. Z″ (Nyquist) plots at different temperatures, with the fitting performed at 583 K to provide insight into the grain and grain resistance values. The observed high dielectric constant suggests a promising potential for electronic applications such as capacitors or microwave resonators.

Electrical and Ferroelectric Properties of Strontium Doped Lead-Free BCZT Ceramics

Herein, we synthesized Ba0.9-xCa0.1SrxTi0.8Zr0.2O3 (x = 0.05, 0.1, 0.15, 0.2) ceramic samples by employing a solid-state reaction technique. The variation of dielectric constant is studied concerning temperature in the range 1 kHz to 1 MHz frequency. Variation of dielectric constant ( εr ) with temperature reveals that charge carrier dispersion pushes the transition temperature towards higher frequency. Impedance analysis reveals that the maximum value of the imaginary part of impedance i.e., Z″ maxima, increases in all samples except for x = 0.05, which shows the opposite behaviour. This behaviour is due to the calcium (Ca2+) substitution at the titanium (Ti4+)-site at low doping concentration of Sr2+ ions. Nyquist plots show the presence of a single semi-circular arc, indicating the contribution of resistance and capacitance through grain boundary. PE hysteresis loops reveal that the values of saturation polarization ( Ps ) decrease with increasing Sr-doping, from 10.989 μC cm−2 to 6.586 μC cm−2, whereas the remnant polarization ( Pr ) shows variable values with increasing Sr-doping.

Enhanced energy-storage performance with optimized thermally stable dielectric property in BNT–BST ceramics modified by KNN doping

Developing environmental-friendly materials with high-density energy storage is of paramount importance to meet the burgeoning demands for energy storage. In this study, we harness the modulation of a multicomponent solid solution by introducing KNN as a third element into the BNT–BST system, thereby achieving a marked enhancement in both energy storage performance and the temperature stability of the dielectric constant. BNBST–4KNN stands out for its exceptional dielectric stability, with a dielectric constant variation rate within 10% across a broad temperature range of [Formula: see text]C to [Formula: see text]C, a feat attributed to the flattening and broadening of the [Formula: see text] peak. BNBT–2KNN exhibits superior energy storage capabilities, with an energy storage density of 1.324 J/cm3 and an energy storage efficiency of 72.3%, a result of the P–E loop becoming more slender. These advancements are pivotal for the sustainable progression of energy storage technologies.

Photocatalytic dye degradation, H2 evolution, electrical and mechanical performances of mechano-synthesized multifunctional Bi2Te3 nanoparticles: Effect of milling time and thermal treatment

Bi2Te3 nanoparticles are synthesized by mechanical alloying the Bi and Te powders under the Ar and pressed powdered samples are sintered at 573 K. Rietveld refined XRD patterns, FESEM images and EDX spectra reveal the microstructure, morphology and phase purity of the samples. Bandgaps are obtained from the FTIR spectra and a blue shift with size reduction indicates the size confinement effect. The non Debye type ac conductivity and dielectric constant variations with milling time and sintering are measured. The improved photocatalytic degradation efficiency of the sintered sample (83.59 %) using Rhodamine B dye under visible light elucidates reduced porosity effect. The photocatalytic hydrogen evolution efficiencies of these nanoparticles are measured and a probable mechanism is depicted. The highest H2 generation efficiency (1462.5 μmol g−1h−1) is observed with the sintered sample. Microhardness measurement reveals normal indentation size effect. Empirical correlations among electrical conductivity, microhardness and photodegradation are established for the first time.

A Theoretical Approach to Study the Frequency Dependent Dielectric behavior of Breast Cancer Cells using AlN buffer-based AlGaN/GaN HEMT

Abstract This article investigates the applicability of open gated high electron mobility transistor (HEMT) as a biosensing platform for Breast cancer detection. The present study reports the detection of healthy (MDA-10) and malignant cells (MDA-MB-231) associated with breast cancer using high-quality AlN buffer AlGaN/GaN HEMT with dual cavity structure formed by etching out the gate metal from source and drain sides under the gate region. The AlN buffer AlGaN/GaN HEMT provides better 2DEG confinement and large conduction band offset than GaN buffer. The proposed design is analyzed at frequencies of 900 MHz and 10 GHz, as breast cells have distinct dielectric properties at different microwave frequencies. The variation in dielectric constant of the cavity region corresponding to biomolecular species will change the device’s electrical characteristics and hence can be used to detect breast cancer cells. In this work, the device sensing parameters considered for analysis are shift in threshold voltage and drain current sensitivity. The device performance has also been analyzed by optimizing cavity thickness and length to select the best design for the sensing. The effect of non-ideal conditions such as steric hindrance and probing is also studied by emulating these real time effects in simulation. The device shows a maximum drain current sensitivity of 29.94% for 20 nm of cavity thickness and 1µm of the cavity length. The results depict that the proposed device design exhibits a highly sensitive response and can be promising alternate for future biosensing applications.

The growth aspects and experimental techniques for the characterization of amino acid L-histidine hybrid crystals for nonlinear optical device applications

The development of crystal growth and measurement methods opens new possibilities for studying materials with remarkable nonlinear optical features. The development of bulk crystals is a constant concern to be beneficial for device applications. This study focuses on the development of nonlinear optical crystals of l-histidine complexes, characterization approaches, and prospective applications. The solution growth approach, a straightforward, inexpensive, and low-temperature growth technique, was adopted broadly. Recent studies show that l-histidine derivatives have potential optical, SHG, thermal, dielectric, and mechanical properties, making them an excellent choice for nonlinear optical devices. In this work, structural, spectroscopic, chemical composition, linear and nonlinear optical analyses, thermal, and dielectric characterizations of l-histidine derivatives were conducted. Most of the l-histidine complexes were found to be crystallized in orthorhombic and monoclinic crystal systems with P212121 and P21 space groups. The crystalline perfections of the samples were analyzed by the HR-XRD method. The energy-dispersive X-ray (EDX) spectroscopic technique was applied to evaluate the chemical content of the compounds. FT-IR and FT-Raman techniques were used to recognize the molecular vibrations and functional groups of the l-histidine derivatives. The UV-visible and photoconductivity studies were done to examine the optical behaviors of the developed crystals. Most of the crystals were found to have excellent optical transparency and wide bandgaps. It has been observed that l-histidine hydro-fluoride dehydrate and l-histidine tetrafluoroborate are found to have the highest second harmonic generation (SHG) efficiencies. The dielectric analyses were utilized to study the dielectric constant and dielectric loss variations with the applied frequency. According to the thermal analyses, most of the crystals were found to have substantial thermal stabilities suitable for device applications.

Optimizing dielectric constants for enhanced performance in nanoscale DG-FinFETs: A comprehensive study on short channel effects

This study explores how variations in fin and gate dielectric constants impact nanoscale, DG-FinFETs’ sensitivity to Short Channel Effects (SCEs). Various fin (channel) materials; Gallium Arsenide (GaAs), Gallium Antimonide (GaSb), Gallium Nitride (GaN), and Silicon (Si), are considered. PADRE simulation environment is used to investigate the threshold Voltage (Vth) Roll-off, a crucial performance parameter. GaAs-FinFET, with a gate dielectric and fin dielectric constant values of 15 and 45 shows the lowest threshold voltage of 0.412 V. The study concludes that FinFETs with a higher fin dielectric constant than gate dielectric constant exhibit reduced SCEs, leading to lower power consumption, faster switching, and improved efficiency. This underscores the importance of optimizing dielectric constants, especially the fin dielectric constant, for enhanced DG-FinFET performance.

Linear Capacitive Pressure Sensor with Gradient Architecture through Laser Ablation on MWCNT/Ecoflex Film.

The practical application of flexible pressure sensors, including electronic skins, wearable devices, human-machine interaction, etc., has attracted widespread attention. However, the linear response range of pressure sensors remains an issue. Ecoflex, as a silicone rubber, is a common material for flexible pressure sensors. Herein, we have innovatively designed and fabricated a pressure sensor with a gradient micro-cone architecture generated by CO2 laser ablation of MWCNT/Ecoflex dielectric layer film. In cooperation with the gradient micro-cone architecture and a dielectric layer of MWCNT/Ecoflex with a variable high dielectric constant under pressure, the pressure sensor exhibits linearity (R2 = 0.990) within the pressure range of 0-60 kPa, boasting a sensitivity of 0.75 kPa-1. Secondly, the sensor exhibits a rapid response time of 95 ms, a recovery time of 129 ms, hysteresis of 6.6%, and stability over 500 cycles. Moreover, the sensor effectively exhibited comprehensive detection of physiological signals, airflow detection, and Morse code communication, thereby demonstrating the potential for various applications.

Change of Dielectric Constant of Highly Doped-Silica Glass Used in Optical Fibers with Frequency and Temperature Under the Effect of Polarization

In this study, the variation of the dielectric constant, i.e. relative permittivity of highly doped-silica glass used in optical fibers with frequency and temperature under the effect of polarization has been investigated. In this context, simulations of the relationship between the dielectric constant and both frequency and temperature have been carried out in the Matlab environment. According to simulation and theoretical analysis, it has been concluded that the dielectric constant of highly doped-silica glass tends to increase with the increase of ambient temperature. On the other hand, as the frequency of the source increases linearly, the dielectric constant decreases. Hence, the variations of highly doped-silica glass with temperature and frequency have been found to be 2.884 × 10-5 (°K)-1 and – 7.50 × 10-15 (Hz)-1, respectively. Moreover, in response to the change in frequency between 1011 Hz and 1012 Hz, the dielectric constant has taken values between 2.085 and 2.070. Additionally, for dielectric constant variations in 2.070 – 2.085 range, values of the relative change in polarization have been obtained in the range of 9.4695 × 10-12 F/m – 9.6023 × 10-12 F/m.

Dynamic cerebral blood flow assessment based on electromagnetic coupling sensing and image feature analysis.

Dynamic assessment of cerebral blood flow (CBF) is crucial for guiding personalized management and treatment strategies, and improving the prognosis of stroke. However, a safe, reliable, and effective method for dynamic CBF evaluation is currently lacking in clinical practice. In this study, we developed a CBF monitoring system utilizing electromagnetic coupling sensing (ECS). This system detects variations in brain conductivity and dielectric constant by identifying the resonant frequency (RF) in an equivalent circuit containing both magnetic induction and electrical coupling. We evaluated the performance of the system using a self-made physical model of blood vessel pulsation to test pulsatile CBF. Additionally, we recruited 29 healthy volunteers to monitor cerebral oxygen (CO), cerebral blood flow velocity (CBFV) data and RF data before and after caffeine consumption. We analyzed RF and CBFV trends during immediate responses to abnormal intracranial blood supply, induced by changes in vascular stiffness, and compared them with CO data. Furthermore, we explored a method of dynamically assessing the overall level of CBF by leveraging image feature analysis. Experimental testing substantiates that this system provides a detection range and depth enhanced by three to four times compared to conventional electromagnetic detection techniques, thereby comprehensively covering the principal intracranial blood supply areas. And the system effectively captures CBF responses under different intravascular pressure stimulations. In healthy volunteers, as cerebral vascular stiffness increases and CO decreases due to caffeine intake, the RF pulsation amplitude diminishes progressively. Upon extraction and selection of image features, widely used machine learning algorithms exhibit commendable performance in classifying overall CBF levels. These results highlight that our proposed methodology, predicated on ECS and image feature analysis, enables the capture of immediate responses of abnormal intracranial blood supply triggered by alterations in vascular stiffness. Moreover, it provides an accurate diagnosis of the overall CBF level under varying physiological conditions.

Tunable Dielectric Spectroscopy of PVDF Thin Films Crossbred with TiO2 Nanoparticles for the Storage Devices

AbstractPolyvinylidenefluoride (PVDF) is a semi‐crystalline ferroelectric polymer with a wide range of interesting properties and shows potentiality in a variety of technological applications. Flexible thin films of PVDF nanocomposites (NCs) have attracted many researchers due to their tunable electronic properties. This paper reports the synthesis, characterization, and dielectric studies of PVDF‐TiO2 NC thin films. The synthesized films are self‐supporting thin and the average thickness of the thin films is 60 µm measured using a Digital thickness gauge of resolution 0.01 mm. TiO2 nanoparticles are prepared using the combustion method. Commercially available PVDF granules are used to develop PVDF‐TiO2 NC thin films using the film casting technique. The structural study of the prepared thin films is carried out using XRD that confirms the retention of the β‐phase of PVDF. The functional group and bonding nature have been studied using FTIR Spectroscopy. The thermal stability of the NC thin films is studied using TGA. The variation of dielectric constant (DC), dielectric loss (DL), AC conductivity, and dissipation factor of the medium of pristine PVDF and PVDF‐TiO2 NC thin films are studied in the frequency range of 10 Hz to 8 MHz at ambient temperature. The dielectric constant of PVDF‐TiO2 NC thin films increases up to 8 wt% and anomaly for 10 wt% of TiO2 fillers in the PVDF matrix at a lower frequency and found to decrease with increasing frequency. The dielectric loss of NC thin films is high at a lower frequency and decreases with an increase in the frequency that is in good agreement with the Maxwell–Wagner type of interfacial polarization. At lower frequencies, the dielectric constant of PVDF‐TiO2 NC increases with the increase in filler content. AC conductivity shows a sharp increase at higher frequencies whereas the dissipation factor of the polymer NCs remains unaltered with respect to frequency by maintaining the trend. This suggests that PVDF‐TiO2 NC is potential material for energy storage devices.

A novel methodology for designing Mono/Bi-slab X-band microwave absorbers of Carbon-Powder composites

This work introduces a methodology for the design of X-band microwave absorbers using carbon-graphite powder composites. The reflection loss (RL) is adjusted through variations in sample thickness, mono/bi-slab geometries, and effective dielectric constant. The impact of the particle size of the powders and the volume fraction (v.f.) of the composites on the effective dielectric permittivity has been systematically investigated. The Nicolson-Ross-Weir (NRW) conversion and the Birchak dielectric mixing model were employed. Optimal absorption conditions predicted by RL simulations were validated through experimental waveguide measurements for mono/bi-slab systems of paraffin-carbon composite samples. The mono-slabs with a particle size of 3.5 μm showed the best versatility for tailoring the RL in the X-band through v.f. variations while maintaining a fixed thickness of 2 mm. In addition, a bi-slab system (powder-paraffin/paraffin) for such powder size, at 18.0 % of v.f., showed an enhanced RL with a bandwidth of 2.6 GHz and a minimum of − 40 dB (at 11 GHz). Other dielectrics based on resin:paint mixtures were tested to replace the paraffin-matrix, revealing a strong powder-matrix interaction capable of modulating the effective dielectric permittivity. Finally, experimental antenna RL measurements conducted in free space were corroborated by theoretical simulations based on the waveguide characterizations.

High quality factor double negative metamaterial for textile fabric and fabric moisture sensing applications

This study introduces an innovative high-Quality factor (Q-factor) double negative (DNG) metamaterial sensor designed for textile fabric and fabric moisture sensing applications in the dynamic realm of textile innovation. The sensor is specifically designed to detect the dielectric properties and moisture content of different textile fabrics. The high Q-factor of this metamaterial structure ensures heightened sensitivity and accuracy in fabric sensing, facilitating precise detection of even subtle changes in fabric properties. By measuring frequency shifting and analyzing S21 values, the sensor provides crucial information about the fabric’s dielectric characteristics. Sensing experiments conducted on various fabrics, including cotton, denim, corduroy, organza, and polyester unveil distinctive patterns of frequency shifting and Q-factors, establishing a nuanced link between fabric structure and sensor performance. The proposed sensor is capable of detecting fabrics with a very low dielectric constant variation of 0.05. In the experiment, the high-dielectric fabric denim (1.7) exhibited frequency shifting and Q-factor of 6970 and 834.87, respectively. Moreover, it is worth noting that the low-dielectric fabric organza (1.03) exhibits frequency shifting and Q factors of 2190 and 1367.03, respectively. Experimental results affirm the prominent efficacy of the proposed sensor in fabric and fabric moisture sensing. Its high Q-factor empowers the sensor to accurately detect and monitor fabric properties, rendering it highly suitable for critical tasks such as quality control, energy efficiency optimization, and process enhancement within the textile industry. The proposed metamaterial sensor (MMS) can significantly contribute to the development of a smart textile sensing technology and pave the way for innovative applications in the textile industry.

Boosting Photovoltaic Output by Dual External Manipulations on 1D Ferroelectric Nanorods Solar Cell: Electric Field and Giant Dielectric Constant Variation

Unlike common photovoltaic (PV) cells whose performance has been anchored, the merits for the cells made of ferroelectric crystals, due to the non‐centrosymmetric structure, provide possibility to further enhance the efficiency by dual external manipulations through increasing the internal electric field strength and the dielectric screening effect, based on anomalous photovoltaic (APV) arisen by the external poling and giant dielectric constant variation through temperature‐controlled ferro‐paraelectric phase transition. In this study, a synergistic effect achieving a 67% improvement in power conversion efficiency (PCE) of the n‐i‐p configuration solar cell by ferroelectric polarization and high dielectricity is observed, taking c‐axis‐aligned single‐crystalline ferroelectric SbSI nanorods as the active layer. The opposite poling effects are revealed leading to asymmetric characteristics in the n‐i‐p configuration. The enhancements of Jsc induced by inherent giant variation imply strong dielectric screening facilities to lower carrier cross section captured by charged defects, uniformly suppressing various recombination mechanisms, understood by the Langevin model. Therefore, solar cells employing n‐i‐p structured ferroelectric thin films as absorbing layers hold promising potential for achieving defect‐tolerance high performance through rational design, external polarization, and dielectric property control.