Diammonium Phosphate Research Articles

Cyclodextrin grafted chitosan thermosensitive hydrogel using dual gelling agents: Drug delivery and antibacterial materials

In this paper, three kinds of cyclodextrin-grafted-chitosan (CD-g-CS) were synthesized from chitosan (CS) and β-cyclodextrin (β-CD) with different ratios. And a series of hydrogel with good temperature sensitivity and injectability were prepared by using sodium glycerophosphate (GP) and ammonium hydrogen phosphate (AHP) as dual gelling agents. The gelation formation time of hydrogel was short, and the shortest time was 0.75 min. The FTIR spectrum and 1H-NMR spectrum showed the structure of the compounds and intermolecular interactions. The molecular docking technique probed the encapsulation mechanism of the drug with β-CD. The SEM results showed that the hydrogel had a highly interconnected three-dimensional spatial structure. The swelling ratio of hydrogel was not less than 150 % within 1 h and the degradation rate of hydrogel was not less than 75 % within 14 days. The in vitro drug release results showed that the hydrogel had optimal sustained release effect, and the cumulative release ratio was 58.3 % in 34 h. The release kinetics analysis exhibited that the hydrogel conformed to the Riter-Peppas model. The hemocompatibility test and cytotoxicity test proved that the hydrogel had good biocompatibility and biosafety. The antibacterial experiments showed that the hydrogel could inhibit the biological activity of Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus). Therefore, the CD-g-CS/GP-AHP hydrogel has a broad application prospect in the biological fields of drug delivery and antibacterial materials.

Nanobiochar-Coating Regulates N and P Release from DAP Fertilizer in Soil and Improves Maize Crop Productivity

Nanobiochar-Coating Regulates N and P Release from DAP Fertilizer in Soil and Improves Maize Crop Productivity

Developing inorganic coatings with nano-TiO2 for heritage concrete and assessing their self-cleaning performance by a new laboratory test

Heritage concrete and cement mortars urgently need preventive treatments which slow down their deterioration, allow to avoid extensive demolition and reconstruction, and preserve the aesthetic significance of texturized surfaces. In this paper new inorganic treatments were developed, which combine the self-cleaning behaviour of nano-TiO2 and the beneficial effect of inorganic consolidants. In a preliminary phase, two consolidants were investigated for the incorporation of titania nanoparticles, namely diammonium phosphate and ethyl silicate (TEOS), and the latter one was selected as the most promising one. In the second phase, combined treatments with TEOS and titania nanoparticles were developed and applied by different techniques to cement mortars manufactured to mimic historic substrates, providing a novel and valuable solution for heritage concrete protection that is unprecedented in the literature. Besides evaluating the photoactivity of the treatments in terms of methylene blue discolouration, a novel test was developed in this study to assess in a more realistic way the actual ability of the treatments to boost the removal of soiling by rain. The combination of TEOS and nano-TiO2 into a single treatment has the potential to slow down carbonation and chloride diffusion, to help the removal of soiling and to provide the substrates with antimicrobial activity, hence it can be considered highly innovative. The results also showed that more realistic laboratory assessment procedures are necessary to predict the actual effectiveness of the treatments when applied to real substrates and exposed to real outdoor conditions. The novel test proposed and applied in this study may serve as a basis for the development of a new procedure of assessment of self-cleaning ability.

Analysis of Viscometric and Conductometric Properties of l-Ascorbic Acid in Aqueous Potassium Chloride and Diammonium Hydrogen Phosphate

Analysis of Viscometric and Conductometric Properties of <scp>l</scp>-Ascorbic Acid in Aqueous Potassium Chloride and Diammonium Hydrogen Phosphate

Phosphate ester-linked carbonized polymer nanosheets to limit microbiological contamination in aquaculture water

In this study, we developed a simple, low-temperature method to synthesize carbonized polymer nanosheets (CPNSs) using sodium alginate, a biopolymer derived from algae, and diammonium hydrogen phosphate. These nanosheets are produced through a solid-state pyrolysis at 180 °C, involving dehydration, cross-linking through phosphate ester bonds, and subsequent carbonization, forming 2D structured CPNSs. These synthesized CPNSs exhibit excellent bacterial adsorption capabilities, particularly against V. parahaemolyticus and S. aureus. When applied to ordinary filter paper, the CPNS-modified paper efficiently filters bacteria from aquaculture water, removing over 98% of V. parahaemolyticus within two hours and maintaining effectiveness after 24 h. In contrast, control filter paper showed significantly reduced efficiency over the same period. Our filtration tests demonstrated enhanced survival rates for shrimp in aquaculture systems, highlighting the potential of CPNSs-modified filter paper as a suitable treatment to reduce the microbiological contamination levels in recirculating aquaculture systems in the event of a disease outbreak.

Effect of diammonium hydrogen phosphate coated with silica on flame retardancy of epoxy resin.

Epoxy resin has become one of the most widely used polymers owing to their excellent comprehensive properties. However, the inherent inflammability of epoxy resin (EP) has seriously limited its application in a range of fields with high fire safety requirements. Herein, a novel shell-core hierarchy architecture (DAP@SiO2) was prepared, composed of diammonium hydrogen phosphate (DAP) and in situ grown silica, and its structure and morphology were characterized by electron microscopy and infrared spectroscopy. The results indicated that silica particles were uniformly coated onto the surface of DAP. The modified DAP was used to reinforce the epoxy resin. The thermal stability of the EP blends was studied with the use of thermogravimetric analysis. The diammonium phosphate in DAP@SiO2 flame retardant produces pyrolysis gases such as NH3 and N2 during decomposition, diluting the concentration of oxygen and flammable volatile products around the flame. Secondly, silica migrates to the surface of epoxy resin to form a shielding layer, forming compounds containing Si-O-Si and O-Si-C structures, which can be cross-linked with other condensed phase products, greatly improving the thermal stability of the carbon layer. Fire behavior was evaluated using the limiting oxygen index (LOI), vertical burning test, and the cone calorimetry, and the flame retardancy mode of action was explained. With 12% of DAP@SiO2 involved, the EP blend passes UL-94 V-0 level, and its limiting oxygen index (LOI) reaches 33.2%. The incorporation of DAP@SiO2 in an EP matrix showed a slight reduction in the heat release and smoke production. The flame retardant mode of the EP polymer shows that its flame retardant and smoke suppression characteristics are related to the interaction of flame retardants in the gas phase and condensed phase. The mechanical properties test results illustrated that the tensile strength, elastic modulus and impact strength of EP/3%DAP@SiO2 are improved compared with pure EP. This is due to the crosslinking reaction between a large number of amino groups on the surface of DAP@SiO2 and the epoxy group on the epoxy resin, which significantly enhances the interfacial compatibility between DAP@SiO2 and epoxy resin, making the combination of DAP@SiO2 and epoxy resin closer.

Low temperature phase transitions in the visible and near-infrared (VNIR) reflectance spectra of (NH4)2HPO4 and (NH4)HSO4 salts

The detection of ammonium bearing crystalline solids in salt-water systems on icy bodies and solar system bodies could provide information about the ascent of these salts from a deep reservoir within the hydrosphere. Due to their chemical-physical properties, NH4+ compounds play a key role both in the internal dynamics of celestial bodies and in the potential habitability of ocean worlds. In this work we analysed the reflectance spectra of two synthetic NH4+ salts: ammonium hydrogen phosphate (NH4)2HPO4 and ammonium hydrogen sulphate (NH4)HSO4 in the 1–4.2 μm spectral range at low temperature, between 110 and 290 K. For (NH4)2HPO4 we also examined the effect of three different grain sizes (150–125 μm; 125–80 μm; 80–32 μm). The collected reflectance spectra show absorption features related to NH4+ group overtone and combination modes in the 1–2.5 μm range. In particular, the bands located at ∼1.09 μm (3ν3), ∼1.30 μm (2ν3 + ν4), ∼1.58 μm (2ν3), ∼2.02 μm (ν2 + v3) and ∼ 2.2 μm (v3 + v4) could be useful to discriminate these salts. The low temperature spectra, compared to those at ambient temperature, reveal finer structures, displaying sharper and narrower absorption bands. The selected NH4+-bearing salts are subjected to reversible low temperature phase transitions, which are revealed in the spectra by a progressive growth and shift of the bands toward shorter wavelengths with a drastic change of their depth. We performed laboratory measurements of ammonium (NH4+) compounds to address the limited data available expanding the existing database. The collected cryogenic spectra can be directly compared with remote sensing data from planetary missions of the upcoming decade such as NASA's Europa Clipper, and ESA's JUICE and the newly launched James Webb Space Telescope expanding the existing database of ammonium compounds at cryogenic temperature.

Response of Growth and Yield of two Broad Bean (Vicia faba L) varieties for antioxidants and diammonium phosphate DAP fertilizer.

Response of Growth and Yield of two Broad Bean (Vicia faba L) varieties for antioxidants and diammonium phosphate DAP fertilizer.

Effect of nano DAP fertilizer on growth and yield of rice (Oryza sativa L.)

Effect of nano DAP fertilizer on growth and yield of rice (Oryza sativa L.)

Effect of different nitrogen source and Saccharomyces cerevisiae strain on volatile sulfur compounds and their sensory effects in chardonnay wine

Three commercial Saccharomyces cerevisiae strains with low, medium, and high H2S-producing capacity were chosen to investigate the effect of yeast assimilable nitrogen (YAN) levels and composition on volatile compounds in a chemically defined medium, specifically high, medium, and low initial YAN levels with varying proportions of DAP or sulfur-containing amino acids (cysteine and methionine). The results revealed that the initial YAN containing a larger proportion of diammonium phosphate resulted in a higher YAN consumption rate during the early stages of fermentation. The yeast strain had a greater effect on the volatiles than the YAN level and composition. Keeping the total YAN constant, a higher proportion of sulfur-containing amino acids resulted in a considerably higher production of 3-methylthiopropanol. The sensory impact of three key volatile sulfur compounds was investigated in a Chardonnay wine matrix, indicating that 3-methylthiopropanol at subthreshold or greater concentrations was effective in enhancing the cantaloupe aroma.

The Effect of Di-Ammonium Phosphate (DAP) towards Flammability Properties of Polyester-Cotton Military Fabrics

Polyester-cotton fabric is one of the most common materials used in military fabrics. The study of the suitable fabric material is critical because military personnel must prepare themselves from inevitable events such as heat exposure. Therefore, the purpose of this study was to examine the flammability features of various cotton compositions in polyester-cotton military textiles with and without the presence of Di-ammonium Phosphate (DAP). We performed a full flammability test, including a cone calorimeter test and a limited oxygen index (LOI) test on three distinct types of polyester-cotton textiles treated with 10% di-ammonium phosphate (DAP). The result shows that, the higher the percentage of cotton, the lower the fire-retardant properties. Besides that, this study also found that the di-ammonium phosphate (DAP) improves the flammable properties of the military fabric.

Enhanced Efficiency Organo-Mineral Nitrogen Fertilizer improves Yield and Quality of Red Amaranth

Crop production with increased yield in a sustainable manner requires less environmental impact. Therefore, a pot experiment was accomplished to investigate the effect of newly developed enhanced efficiency nitrogen (N) fertilizer and conventional N fertilizers on the growth, yield, nutritional quality, and N use efficiency of red amaranth (Amaranthus tricolor cv. BARI lalshak 1). All the pots were placed at the experimental pot-house of the Department of Agricultural Chemistry, Bangladesh Agricultural University following a completely randomized design (CRD) with four replications. Brown coal-urea (BCU) was applied as enhanced efficiency N fertilizer following top dressing and basal application strategy where urea and diammonium phosphate were applied as conventional N fertilizer. All the N fertilizers were applied at five rates viz., 0, 50, 75, 100, 150 kg N ha ̶ 1. The growth parameters and biomass yield of red amaranth were significantly impacted by varying amounts and types of N fertilizers. The highest dry biomass yield was obtained at 150 kg N ha ̶ 1 whereas the highest number of branch plant ̶ 1 was found at 100 kg N ha ̶ 1. Again, the highest biomass N concentration was found at 100 kg N ha ̶ 1. Application of a higher dose of fertilizer showed the highest N concentration in the post-harvest soil. Overall, the growth parameters and biomass N concentration were the highest in BCU basal-treated soil. In contrast, BCU top-dressed soil showed a higher N concentration after harvest than all other treatments. Based on the overall findings, the use of higher-efficiency organo-mineral N fertilizer has the potential to serve as a viable substitute for traditional N fertilizers in the context of sustainable crop production with reduced environmental effects. J. of Sci. and Tech. Res. 5(1): 37-44, 2023

Rapid microwave fabrication of highly luminescent nitrogen and phosphorous co-doped carbon quantum dots for the determination of glutathione in pharmaceutical supplements

A facile and sensitive nano-probe for spectrofluorometric glutathione (GSH) determination has been developed based on dual-doped nitrogen and phosphorus carbon quantum dots (NP@CQDs). The NP@CQDs were prepared, through a rapid, one-step microwave heating method in only 180 s with a high quantum yield (0.63) using ethylenediaminetetraacetic acid as carbon and nitrogen precursor and diammonium hydrogen phosphate as nitrogen and phosphorus dopant. The synthesised NP@CQDs had a maximum bluish fluorescence emission at 420 nm, after excitation at 360 nm. The luminescence of the prepared NP@CQDs was quenched via a static quenching mechanism by ferrous ions, while ferric ions did not affect the emission of NP@CQDs. GSH was mixed with ferric ions before adding NP@CQDs to exploit this observation. The attenuation in emission observed after adding NP@CQDs to GSH/ferric ions was directly related to the GSH concentration, as GSH worked to reduce the ferric ions present and produce ferrous ions. The proposed fluorometric method was validated in compliance with the International Council on Harmonization (ICH) guidelines. The proposed fluorescent nano-probe showed good linearity for GSH determination over a range of 0.5–10 µg/mL with % recoveries ranging between 99.50 and 101.86 %, and RSD less than 2 %. NP@CQDs were implemented for GSH determination in pharmaceutical supplementary capsules with respectable accuracy and precision. This approach is simple, reliable, accurate, specific, and it also does not require expensive chemicals or sophisticated equipment. This work opens up other uses of NP@CQDs in pharmaceutical and environmental analysis.

Synthesis of hydroxyapatite (HAp) from eggshells via thermal decomposition method for the application of dye adsorption

The study aims to synthesize hydroxyapatite (HAp) from eggshells and explore its potential for dye removal from wastewater streams. Calcium was derived from the disposed eggshells, through which CaO was acquired using the thermal decomposition technique. HAp synthesis was conducted via the direct precipitation method with the addition of diammonium hydrogen phosphate as the phosphorus source. The synthesized HAp was characterized using various techniques including XRD, SEM, FTIR, BET and UV–Vis Analysis. HAp appeared to be in a large form with tightly agglomerated rod-like nanometric particles with a surface area of 16.700 m2/g and pore volume of approximately 0.137 cm³/g, from which HAp was confirmed to have a porous structure. The synthesized hydroxyapatite showed a pure crystalline phase with a particle size in the nanometer range, according to the test results. The effectiveness of hydroxyapatite (HAp) in adsorbing methylene blue dye from wastewater was assessed using methylene blue as a representative dye. The results demonstrated that HAp exhibited a high adsorption capacity for methylene blue, indicating that the synthesized HAp was an effective adsorbent. Based on the studies conducted, it is evident that the hydroxyapatite synthesized from eggshells exhibits great potential as a cost-effective and efficient adsorbent for removing dyes from wastewater.

Effect of mechanochemically modified MoO3–ZnO on Mo supply to plants when co-granulated with macronutrient fertilizers

Molybdenum (Mo) is an essential micronutrient required for plant growth but is prone to leaching from neutral and alkaline soils. The use of slow-release Mo sources could potentially reduce leaching losses from soils and increase crop yields. In this study, we assessed mechanochemistry as a green method to produce slow-release Mo sources. Molybdenum compounds (MoO3 or (NH4)6Mo7O24·4H2O) were mechanochemically (MC) treated with ZnO to synthesize compounds with a Mo content of 1–36%. Reduced Mo solubility after MC treatment, compared to the initial Mo source, was obtained with the MoO3 source and these composites were used for co-compaction with macronutrient fertilizers. Macronutrient pellets with 0.2% Mo were compacted using the 4% Mo and 36% Mo (characterized as ZnMoO4) compounds. A column dissolution test showed that the 4% Mo compound in a macronutrient carrier (DAP and MAP) only released around 40% of the total Mo compared to 80% for a non-MC treated control over 72 h. Column leaching using two soils revealed that the release behavior of Mo was strongly related to the pH of the leachate, which was affected by both the soil pH and the macronutrient carrier. More Mo was released when the MC-treated compound was co-compacted with diammonium phosphate (DAP) compared to monoammonium phosphate (MAP). The MC-treated compound with 4% Mo showed significantly less leaching than the control without ball milling when co-compacted with both MAP and DAP. In a pot trial with simulated leaching, the uptake of Mo was greater for the MC-treated 4% Mo compound co-compacted into DAP than for the other Mo sources. Overall, our results indicate that MC-treated MoO3–ZnO could be used as a slow-release Mo source in high-rainfall areas.Graphical

Enhancing maize phosphorus uptake with optimal blends of high and low-concentration phosphorus fertilizers.

High-concentration phosphorus (P) fertilizers are crucial for crop growth. However, fertilizers with lower P concentrations, such as calcium magnesium phosphate (CMP) and single super phosphate (SSP), can also serve as efficient P sources, especially when blended with high-concentration P fertilizers like diammonium phosphate (DAP) or monoammonium phosphate (MAP). In this study, we conducted a 48-day pot experiment to explore how blending low-P fertilizers could optimize maize P utilization, using CMP to replace DAP in acidic soil, and SSP to replace MAP in alkaline soil, with five SSP+MAP and CMP+DAP mixtures tested. Key metrics such as shoot and root biomass, shoot P uptake, root length, and soil P bioavailability were measured. We found that maize biomass and P uptake with 100% DAP were comparable to those with 50% CMP and 50% DAP in acidic soil. Similar results were observed for 100% MAP compared to 50% SSP and 50% DAP in alkaline soil. Root biomass and length were largest with 100% MAP in acidic soil and at 100% DAP in alkaline soil, with no significant differences at 50% SSP or CMP substitutions for MAP and DAP, respectively. Furthermore, 50% SSP or CMP substitutions for MAP and DAP increased the content and proportion of the labile inorganic P (Pi) pool (H2O-Pi and NaHCO3-Pi), had a direct and positive effect on Olsen-P. Our findings reveal that 1:1 blends of SSP and MAP in acidic soil, and CMP and DAP in alkaline soil, effectively meet maize's P requirements without relying solely on high-concentration P fertilizers. This indicates that strategic blending of fertilizers can optimize P use, which is crucial for sustainable agriculture.

Biomimetic Calcium Phosphate Nanoparticles: Biomineralization Models and Precursors for Composite Materials.

The formation of calcium phosphate under the control of water-soluble polymers is important for understanding bone growth in living organisms. These experiments also have spin-offs in the creation of composite materials, including for regenerative medicine applications. The formation of calcium phosphate (hydroxyapatite) from calcium chloride and diammonium phosphate was studied in the presence of polymers containing carboxyl, amine, and imidazole groups. Depending on the polymer composition, solid products and stable dispersions of positively or negatively charged nanoparticles were obtained. Oppositely charged nanoparticles can interact with each other to form a macroporous composite material, which holds promise as a filler for bone defects. The formation of a calcium phosphate layer around a living cell (dinoflagellate Gymnodinium corollarium A. M. Sundström, Kremp et Daugbjerg) using positive composite nanoparticles is a one-step approach to cell mineralization.

Optimizing co-application of starter ammoniacal-N and K-containing fertilizers for barley in the seed-furrow

It is unclear how seed-placed starter ammoniacal-N-and-K fertilizers influence barley (Hordeum vulgare L.) seed-crop emergence, and its early establishment, due to salt injury and potential ammonia production and toxicity within the soil profile under different placement rates. Keeping in this view, the study was undertaken to experiment the effects of different fertilizer types, and rates using three different soil types characterized by fine (G1), medium (G2), and coarse (G3) textures when simultaneously placed with barley seed and establish safe-starter fertilizer recommendation models. The fertilizers were applied at varying rates from 0 to 60 kg N ha−1 and 0 to 74 kg K ha−1 alongside barley seeding. Maximum predicted safe starter ammoniacal-N-fertilizer rates were as follows: urea = 15, 35 and 26 kg N ha−1 is safe for G1, G2 and G3 soils, respectively. DAP (Diammonium phosphate), 52 kg N ha−1 is safe for fine textures whilst 12 and 37 kg N ha−1 for medium and coarse textures. MAP (Monoammonium phosphate) is safely placed at 55, 11 and ≥60 kg N ha−1 for G1 – G3 soils. For MOP (Muriate of Potash) and SOP (Sulfate of Potash), 67 and ≥74 kg K ha−1 were ideal for improved barley emergence across all the soil types. Visual appearances including delayed seed emergence, leaf chlorosis, and stubby coleoptiles were observed at varying seed-placed N and K rates. Intricate relationships among various emergence parameters, root architecture, aboveground and root biomass, chlorophyll content, all showing significant interrelationships. Data indicate that cubic model could be used for predicting seed-safe rates for multiple fertilizer types.

Nitrogen Availability and Utilisation of Oligopeptides by Yeast in Industrial Scotch Grain Whisky Fermentation

Scotch grain whisky is produced with a substantial proportion of unmalted grains, which can result in nitrogen deficiency for yeast in the fermentable grain mash. This study examined nitrogen source availability and utilisation by three commercial whisky strains (Saccharomyces cerevisiae) during Scotch grain whisky fermentation, focusing on oligopeptides. Peptide uptake kinetics in synthetic whisky mash with defined peptides showed that oligopeptides of up to nine amino acids were taken up by the strains, albeit with some variability between the strains. The study found that peptides with appropriate molecular weights could replace free amino acids without negatively affecting fermentation kinetics. Moreover, fermentation performance improved when additional nitrogen was provided via peptides rather than diammonium phosphate. Analysis of industrial grain mash indicated that despite low initial yeast assimilable nitrogen, residual proteolytic activity from malt increased nitrogen availability during fermentation. Approximately 30% of the nitrogen consumed by yeast during grain mash fermentation was derived from peptides. LC-HRMS peptide analysis revealed complex dynamics of peptide formation, degradation, and utilisation. This study highlights the importance of oligopeptides in ensuring optimal fermentation efficiency in Scotch grain mash and similar substrates.

Preparation and research of high electromagnetic wave transmission type concrete in 5G frequency band

In urban areas with many buildings, the transmission of 5 G signals can be greatly absorbed or reflected, leading to decreased effectiveness of transmission. To address the issues mentioned above, the functional admixture formed by the mixture of nanocrystalline cellulose (NCC) and diammonium hydrogen phosphate (DAP) is added into concrete in this study, the electromagnetic transmission performance (ETP) and mechanical properties of concrete are enhanced simultaneously for the first time, and the electromagnetic transmission coefficient of concrete is doubled. When NCC and DAP are mixed, the electromagnetic transmission coefficient of concrete improved by 117.65 %-124.35 %, among which, when 0.5 wt% DAP and 4 wt% NCC are mixed, the electromagnetic transmission coefficient of concrete is the highest, and some frequency bands are as high as 70 %, meeting the requirements of electromagnetic wave transmitting materials. In addition, the compressive strength of concrete containing 4 wt% NCC and 0.5 wt% DAP increases by 24.3 % compared to concrete containing only 4 wt% NCC.