Diagenetic Processes Research Articles

Diagenetic development of rhizoliths in the Ironshore Formation (Pleistocene) of the Cayman Islands

Rhizoliths in the Ironshore Formation on the Cayman Islands, up to 12 cm in diameter and 1 m long, developed in skeletal grainstones that accumulated on sand flats above high tide level. Internally, these well-preserved rhizoliths are characterized by well-defined concentric zones, centered around the central root opening, that reflect radial variations in calcite–aragonite content, decreases in micrite content, increases in porosity, and radial variations in trace element (e.g., Ca, Ni, S, Si, and Sr) concentrations. The stable isotopes, δ13C and δ18O, which vary in accord with the internal zones are more variable than the δ13C and δ18O of the host sediments. For the rhizoliths there is a high correlation between the δ13C and δ18O values and the calcite content. The contrast between the rhizoliths and their host sediments is largely a reflection of the more intense diagenetic processes that were largely mediated by the microbial populations that were concentrated in the rhizosphere that developed around each plant root. Microbial activity, which mediated micritization of the skeletal sands and micrite precipitation in the intergranular pores, was largely responsible for development of the internal zonation in the rhizoliths. Use of the δ13C values to determine if the rhizoliths developed in association with C3 or C4 vegetation failed because the δ13C values correlate with the calcite content that developed largely as diagenetic products.

The Coprecipitation of Akaganeite and Jarosite and Its Implications for the Late‐Stage Diagenetic Fluids in the Vera Rubin Ridge, Gale Crater, Mars

AbstractAkaganeite and jarosite were detected in two mudstone drill samples from Vera Rubin ridge (VRR), Gale crater by Chemistry & Mineralogy X‐Ray Diffraction (CheMin). The co‐occurrence of these two minerals is quite rare in both terrestrial and Martian aqueous environments. In order to confine the chemical conditions of paragenetic akaganeite and jarosite, and provide insight into late‐stage diagenetic alterations at VRR, we synthesized akaganeite and jarosite with varying SO42− concentrations and initial pH levels. Synthetic samples were characterized using Field Emission Scanning Electron Microscopy, X‐ray powder diffraction and Raman spectroscopy. Our study reveals that akaganeite and jarosite exist in equilibrium in the solution with 0.011–0.028 M SO42− with respect to 0.6 M Cl− and an initial pH of 1.3–2.2. In combination with the CheMin detection results, the chemistry and pH values of the fluids at VRR can be further constrained. Considering the absence of goethite and the relative higher portion of akaganeite than jarosite in the drill samples, the pH values should be 1.4–2 and the S/Cl molar ratio should be within the range of 0.018–0.042. Based on our laboratory results, we hypothesize that the presence of akaganeite and jarosite at VRR represents an individual episode of acidic groundwater activity. During the late‐stage diagenetic process at VRR, upwelled acidic groundwater dissolved the local chlorides to form the Cl−‐dominated fluids. Subsequent evaporation further concentrated the acid saline fluids and therefore resulted in an extremely acidic environment (1.4 ≤ pH＜2 with S/Cl molar ratio of 0.018–0.042), which produced akaganeite and jarosite.

Types, composition and diagenetic evolution of authigenic clay minerals in argillaceous limestone of sepiolite-bearing strata: A case study of Mao-1 Member of Middle Permian Maokou Formation, eastern Sichuan Basin, SW China

The types, occurrence and composition of authigenic clay minerals in argillaceous limestone of sepiolite-bearing strata of the first member of the Middle Permian Maokou Formation (Mao-1 Member) in eastern Sichuan Basin were investigated through outcrop section measurement, core observation, thin section identification, argon ion polishing, X-ray diffraction, scanning electron microscope, energy spectrum analysis and laser ablation-inductively coupled plasma-mass spectrometry. The diagenetic evolution sequence of clay minerals was clarified, and the sedimentary-diagenetic evolution model of clay minerals was established. The results show that authigenic sepiolite minerals were precipitated in the Si4+ and Mg2+-rich cool aragonite sea and sepiolite-bearing strata were formed in the Mao-1 Member. During burial diagenesis, authigenic clay minerals undergo two possible evolution sequences. First, from the early diagenetic stage A to the middle diagenetic stage A1, the sepiolite kept stable in the shallow-buried environment lack of Al3+. It began to transform into stevensite in the middle diagenetic stage A2, and then evolved into disordered talc in the middle diagenetic stage B1 and finally into talc in the period from the middle diagenetic stage B2 to the late diagenetic stage. Thus, the primary diagenetic evolution sequence of authigenic clay minerals, i.e. sepiolite–stevensite–disordered talc–talc, was formed in the Mao-1 Member. Second, in the early diagenetic stage A, as Al3+ carried by the storm and upwelling currents was involved in the diagenetic process, trace of sepiolite started to evolve into smectite, and a part of smectite turned into chlorite. From the early diagenetic stage B to the middle diagenesis stage A1, a part of smectite evolved to illite/smectite mixed layer (I/S). The I/S evolved initially into illite from the middle diagenesis stage A2 to the middle diagenesis stage B2, and then totally into illite in the late diagenesis stage. Thus, the secondary diagenetic evolution sequence of authigenic clay minerals, i.e. sepiolite–smectite–chlorite/illite, was formed in the Mao-1 Member. The types and evolution of authigenic clay minerals in argillaceous limestone of sepiolite-bearing strata are significant for petroleum geology in two aspects. First, sepiolite can adsorb and accumulate a large amount of organic matters, thereby effectively improving the quality and hydrocarbon generation potential of the source rocks of the Mao-1 Member. Second, the evolution from sepiolite to talc is accompanied by the formation of numerous organic matter pores and clay shrinkage pores/fractures, as well as the releasing of the Mg2+-rich diagenetic fluid, which allows for the dolomitization of limestone within or around the sag. As a result, the new assemblages of self-generation and self-accumulation, and lower/side source and upper/lateral reservoir, are created in the Middle Permian, enhancing the hydrocarbon accumulation efficiency.

Rock physical characteristics of deep dolomite under complex geological conditions: A case study of 4th Member of Sinian Dengying Formation in the Sichuan Basin, China

The deep-ultra deep carbonate reservoir in China, commonly subjected to modification of multi-stage diagenesis, has extremely high heterogeneity. Conventional rock physics analysis cannot accurately identify the elastic responses of reservoir. Here, the rock physics properties of the dolomite from the 4th Member of the Sinian Dengying Formation are experimentally measured, and the change law of rock physics characteristics is investigated within the framework of the diagenetic processes by the analysis of the elastic and petrologic characteristics, pore structure, and sedimentary environments. The results show that the differentiated diagenesis results in different pore structure characteristics and micro-texture characteristics of the rock. The microbial dolomite of the algal mound-grain beach facies is subjected to the contemporaneous microbial dolomitization and seepage-reflux dolomitization, penecontemporaneous selective dissolution, burial dolomitization, and hydrothermal dolomitization. The resultant crystalline dolomite is found with one main type of the dolomite crystal contact boundaries, and the dissolution pore is extensive development. The siliceous, muddy, and limy dolomite of the inter-beach sea environment mainly experiences the weak capillary concentration dolomitization, intensive mechanical compaction-induced densification, and burial dolomitization. Such crystalline dolomite is observed with four types of contact boundaries, namely the dolomite contact, clay contact, quartz contact, and calcite contact boundaries, and porosity mostly attributed to residual primary inter-granular or crystalline pores. The samples with the same crystal boundary condition have consistent correlations between the compressional- and shear-wave velocities, and between the compressional-wave velocity and the velocity ratio. Additionally, the variation of the acoustic velocity with effective pressure and the intensity of pore-scale fluid-related dispersion are controlled by the differentiation of pore structure types of the samples. The varied effects of soft pores like micro-cracks on the compressional- and shear-wave velocity causes considerable changes in the relationships between the compressional- and shear-wave velocities, compressional-wave velocity and velocity ratio, and porosity and acoustic velocity. This research is an attempt to demonstrate a novel method for investigating the rock physics variation of rock during the geological process, and the obtained findings can provide the rock physics basis for seismic prediction of the characteristics of deep carbonate reservoirs.

Diagenesis, Provenance, Tectonic Setting and Palaeoclimate of the Eocene Kopili Sandstone, Assam, India: A Petrographic Study

Abstract The Eocene Kopili Sandstone outcropping in the North Cachar Hills (NCHs) of Assam, India, was petrographically studied to unravel its diagenetic features, provenance, tectonic setting and palaeoclimate conditions. The modal analysis of the Kopili Sandstone reveals that the detrital mineralogy is dominated by quartz (48.78 to 83.70 %), with variable amounts of rock fragments (0.37 to 7.35 %), feldspar (0.37 to 8.33 %), micas (0.36 to 7.84 %) and subordinate amount of heavy minerals. The matrix and cement content varies from 9.88 to 21.50 % and 1.12 to 19.41 % respectively. The Kopili Sandstone is classified as quartz arenite to sub lithic arenite. Compaction, cementation, dissolution and replacement are the observed diagenetic processes in the studied sandstones. Diagenetic transformations are manifested in the fractured detrital grains, overgrowth of quartz, corrosion of grain boundaries of quartz, modification of grain boundaries, and silica and iron oxide cement precipitation in the interstices of the framework grains. The provenance is of granite-gneissic rock terrain. The detritus in the depositional basin is derived predominantly from craton interior with minor input from recycled orogen. The study discerns humid palaeoclimate conditions for the Kopili Sandstone.

Implications of the depositional and diagenetic attributes on the reservoir properties of the siliciclastic mangahewa formation, Taranaki Basin, New Zealand: Integrated petrographical and petrophysical studies

The siliciclastic Mangahewa reservoir in the Pohokura Gas Field presents a formidable challenge for gas exploration due to its diverse petrophysical properties. To address this challenge, our study employs a comprehensive approach integrating petrography and petrophysical analyses for core and well logging data. In the present study, we uncover an association of sandstone microfacies, in the key wells like Pohokura South-1, Pohokura-1, and Pohokura-2 wells, which change from fine to medium-grained subfeldsarenites to lithic feldsarenites microfacies. The petrographic investigation pinpoints the critical factors influencing the reservoir quality, including facies types, grain size, pore types, sedimentary structure, detrital clay content, and mineral composition. Both the primary intergranular and secondary dissolution pore spaces are responsible for the influential large intergranular pore volumes causing a superior reservoir quality. Mineral composition, influenced by the source and lithofacies, significantly impacts the reservoir properties. Diagenetic processes further control the reservoir quality, where the abundant silica cement, the illitic clays, and the rare pervasive carbonate cementation render the low reservoir quality. Compaction significantly reduces porosity during diagenesis. High-quality reservoir sandstones are characterized by coarse grain size, minimal detrital clay presence, predominantly quartz composition, limited carbonate and moderate silica cementation, low authigenic illite levels, and minor compaction impact. Based on the petrophysical data, the Mangahewa reservoir is composed of five RRTs (reservoir rock types) with the RRT1 samples having the best reservoir characteristics due to their fair porosity, very good permeability, and macro pore sizes. On the other side, the RRT5 samples are characterized by the lowest reservoir quality (poor porosity and permeability and micropore sizes) due to cementation and compaction. Our study provides valuable insights into the intricate petrophysical properties of the Mangahewa reservoir, enhancing the predictability of the reservoir behavior and optimizing hydrocarbon production in this challenging geological setting.

Quantitative Analysis of Diagenesis Control on the Spatial Heterogeneity of Sarvak Carbonate Formation, the Dezful Embayment of Zagros Basin, Western Iran

Summary The heterogeneity indices in conventional carbonate reservoirs are usually influenced by various diagenetic processes. The main aim of this study is to build 3D geological models of the diagenetic and heterogeneity indices addressing the role of diagenesis on spatial heterogeneity variations in the Sarvak carbonate reservoir of an Iranian oil field situated in the Dezful Embayment in the Zagros Basin. Vertical heterogeneity has been discussed in many studies, but the literature is limited on the 3D geological modeling of heterogeneity and providing spatial heterogeneity maps. In this study, we determined the main diagenetic parameters influencing the reservoir heterogeneity and constructed 3D geological models for evaluating the spatial heterogeneity. A couple of heterogeneity indices including the coefficients of variation (CVs) of porosity and permeability, Lorenz coefficient, and Dykstra-Parsons coefficient in cored intervals along with some diagenetic parameters were calculated and modeled. This study shows that lateral heterogeneity is mappable and correlatable with different diagenetic overprints along with shale volume, which controls the reservoir quality and spatial heterogeneity. It also indicates that lateral trends of the heterogeneity indices in different zones of the studied reservoir are influenced by other diagenetic parameters such as secondary porosity (SPI), dolomitization, cementation, and velocity deviation log (VDL, as a diagenetic index). Different diagenetic parameters control reservoir heterogeneity in each zone by decreasing or increasing the degree of the heterogeneity, some of which have dual constructive or destructive effects on heterogeneity indices. Moreover, the results show that the effect of shale volume on reservoir heterogeneity is significant, especially when the amount of the shale volume is notable.

Paleoclimate changes across the Cenomanian–Santonian transition at the southern Neo-Tethys margin (SW Iran): An integrated approach

The Cenomanian–Santonian (C–S) carbonate successions include valuable petroleum reservoirs in the Zagros Basin. They also provide important information on the paleogeographic setting, paleoclimatic conditions, and tectonic evolution of the southern Neo-Tethys margin. This study focuses on the paleoclimatic changes across the C–S transition using the petrographical, petrophysical, paleontological, major and trace element and isotope geochemical data from three subsurface sections selected from the southern Dezful Embayment and northwestern part of the Persian Gulf. Remarkable differences in allochemical (skeletal and non-skeletal) elements indicate dissimilar paleoclimatic conditions during the Cenomanian–Turonian and Santonian. Paleoexposure events are related to diagenetic processes such as extensive meteoric dissolution (karstification) and the development of bauxitic–lateritic paleosols with high Fe, Al, and kaolinite concentrations indicating warm and humid (tropical) conditions. Increased values of Fe, Al, Rb, and 87Sr/86Sr isotopic ratios and depletion of Ca, Sr, δ18O, and δ13C considered together indicate meteoric diagenetic effects under this paleoclimatic condition. Spectral gamma measurements are used to investigate paleoclimatic conditions. Low content of Uranium (U) throughout the transgressive systems tract (TST) and high concentration in the regressive systems tract (RST) along with low contents of kaolinite within the Santonian sequence denote the predominance of arid conditions. The major fall in U concentrations at the Cenomanian–Turonian interface (CT-Exposure Surface) could be regarded as an outcome of the fall in the relative sea-level and a proxy of oxidizing conditions (Th/U > 7) that could be the consequence of a change in paleoclimate from humid/semi-humid to humid. Evidence for a 3–4 °C decrease in paleo-temperature and increase in aridity are recorded during the Cenomanian–Santonian transition in the Zagros Basin, which is in close agreement with global trends. This cooling pattern is attributed to a decline in atmospheric CO2 levels and alterations in oceanic circulation, specifically an increase in meridional circulation.

Extracting paleo-weathering signals from authigenic phases in lake sediments: A case-study of Lake Baikal

Authigenic phases in lake sediments hold the potential to record changes in the isotope compositions of past lake water, potentially yielding valuable information on secular changes in continental weathering patterns and rates, including over past glacial cycles.Here, different leaching approaches are investigated with the aim of extracting Sr, Nd, Pb, and Be hosted in authigenic Fe-Mn (oxy)hydroxide sediment phases for precise isotope measurements. Elemental Al/Mn, Ca/Mn, and P/Mn ratios obtained via a mild reductive leach agree well with the composition of marine authigenic Fe-Mn phases. For core top sediments, leached Sr isotope compositions obtained with this leach agree well with the composition of lake water. The Be and Nd isotope compositions of core top leachates are consistent with the spatial variability observed in the water column. Due to high concentrations in Fe-Mn phases, leachate compositions are dominated by authigenic Be, Sr, Nd, and Pb, even in cases when as much as 40% of leached phases (by mass) are non-authigenic. These lines of evidence suggest that the mild reductive leach successfully extracts the modern lake isotope composition from modern sediments in terms of the isotope systems investigated. We further show that the leaching method is also reliable for older sediments (<340 ka): leached paleo-Sr isotope compositions are consistent between the current and previous interglacial periods, as well as for glacial periods. This suggests that reconstructed water isotope compositions are not affected by early diagenetic processes, instead reflecting environmental factors around the lake that determine the composition of weathering fluxes. Although more difficult to assess for Be, Nd, and Pb due to the heterogeneity of modern lake water, the data we present indicate the overall robustness of the leaching approach.These promising results open up lakes as archives for paleo-weathering reconstructions. Given that marine reconstructions face some important limitations (e.g., integration of basin-wide changes in weathering processes, long residence times for Sr, etc.Fe), lake records provide an avenue to improve our understanding of changes in regional weathering processes over glacial-interglacial timescales. The mild reductive leach used here may also be useful for meteoric Be studies in marine shelf settings, to prevent leaching of terrestrial sedimentary Fe-Mn oxy(hydroxide) phases.

Archie's cementation factors for natural rocks: Measurements and insights from diagenetic perspectives

Archie's cementation factor, m, is a critical parameter for petrophysical studies, and the value is influenced by several factors such as the shape, type, and size of grains, degrees of diagenesis, and associated pore structure. Using integrated experimental and theoretical approaches, the goal of this study is to obtain the cementation factor of rocks (both reservoir rock and caprock) and assess the impact of diagenetic processes on the values of the cementation factor. Thirteen samples of geologically diverse rocks (six mudstones, four fossiliferous limestones, two marbles, and one sandstone) were selected to achieve these research objectives. Two approaches, the diffusion of gas tracers and the Bosanquet formula calculation using pore-throat sizes from mercury intrusion porosimetry analyses, were used to derive the cementation factors of these rock samples. These rocks were categorized into two groups based on the correlation between average pore-throat diameter and diffusivity, and an exponential-law relationship between the cementation factor and porosity was determined for these sample groups. In addition, thin-section petrography and field emission-scanning electron microscopy observations were utilized to investigate diagenetic processes, with four diagenetic patterns being established: (1) strong compaction, strong cementation, and weak dissolution-diagenesis pattern; (2) weak compaction, medium cementation, and weak dissolution-diagenesis pattern; (3) weak compaction, medium cementation, and strong dissolution-diagenesis pattern; and (4) fracture-matrix pattern. The results indicated that diagenetic processes and microfractures contribute to the variability in the cementation factors of these rock samples.

Depositional Setting, Diagenetic Processes, and Pressure Solution-Assisted Compaction of Mesozoic Platform Carbonates, Southern Apennines, Italy

Pressure solution processes taking place during diagenesis deeply modify the hydraulic properties of carbonates, affecting their mechanical layering and hence the dimension, distribution, and connectivity of high-angle fractures. The formation of stylolites is controlled by the texture of the host rock and therefore by the depositional environment and the diagenetic processes that involve it. This study reports the results of a multidisciplinary study carried out on a Jurassic–Cretaceous carbonate platform in southern Italy. The goal is to unravel the control exerted by single carbonate textures and specific diagenetic processes on the formation of bed-parallel stylolites. Microfacies analyses of thin sections are aimed at obtaining information regarding the composition and texture of the carbonates. Petrographic observations coupled with CL analyses are key to deciphering their diagenetic history. Results are consistent with carbonates originally deposited in a shallow-water realm in which carbonate mud is occasionally abundant. In this environment, early cementation inhibits their chemical compaction. In grain-supported facies, pressure solution is only localized at the grain contacts. During shallow burial diagenesis, precipitation of blocky calcite predates the formation of bed-parallel stylolites in the grain-supported facies. Contrarily, mud-supported facies favor chemical compaction, which results in stylolites showing a good lateral extension and thick sediment infill. A classification of different types of stylolite morphology is attempted in relation to facies texture. In detail, rougher morphology (sharp-peak) characterizes the stylolites nucleated in grain-supported facies, while smoother morphology (rectangular to wave-like) is observed in stylolites on mud-supported facies. Application of this knowledge can be helpful in constraining the diagenetic history of carbonate rocks cored from depth, and therefore predict the fracture stratigraphy properties of carbonates buried at depth.

Resistance of eogenetic dolomites to geochemical resetting during diagenetic alteration: A case study of the lower Qiulitage Formation of the Late Cambrian, Tarim Basin

Rare earth elements (REEs), carbon, oxygen and Mg isotopes have been widely used to explain the origin of dolomite, but dolomite may undergo complex diagenetic alteration during long geological processes, and whether the geochemical signals of precursor dolomite can be preserved is still unknown. In order to further explore the formation mechanism of dolomite and the influence of diagenetic alteration processes on geochemical parameters, this paper takes the thick-layer dolomite of the Lower Qiulitage Formation of the Late Cambrian in the Tazhong uplift area as an example and divides the dolomite into two categories through petrologic observation. One category is fabric-retentive dolomite (FRD), including algal clotted dolomite, algal psammitic or psammitic grain dolomite, and aphanocrystalline dolomite; the other category is fabric-destructive dolomite (FDD), including crystalline dolomite (CD) and siliceous dolomite (SD). Cation ordering, unit cell parameters, major/trace elements, REEs as well as C–O–Mg isotopes of the pure matrix powders of different types of dolomites are further analyzed. The results show that the dolomites are near-source/far-source seepage reflux type and sabkha type eogenetic origin, and the magnesium ions mainly come from Late Cambrian seawater; dolomite crystals of different sizes are the result of the precursor dolomite suffering varying degrees of recrystallization during the early diagenesis period, inheriting the original geochemical characteristics; hydrothermal alteration occurs in the late stage of diagenesis, with limited magnesium ions in the hydrothermal fluid. Its impact on the dolomite is mainly reflected in local dolomite distortion and a large amount of aphanocrystalline silica and coarse-grained quartz cement filling, which fails to obviously reset the geochemical information of the matrix dolomite. The above results demonstrate that, under favorable conditions, early genetic marine dolomites may resist geochemical resetting over time intervals of more than 400 million years.

Fracture analysis in borehole images from BM-C-33 area, outer Campos Basin, Brazil

In the BM-C-33 area, divided into the Raia Manta and Raia Pintada development areas, reservoirs are arranged into three structural highs: Gávea, Seat, and Pão de Açúcar. These reservoirs consist of pre-salt limestones deposited on volcanic sequences and underwent complex diagenetic evolution. Successive post-depositional processes, including silicification, affected original mineral assemblage, modified pore textures, and caused intense fracturing. Based on borehole image logs (BHI), wireline data from four wells, and 2D and 3D seismic data, this study details natural fracture acoustic and resistivity properties. It also discusses the relationship of faults, fractures, and vugs with diagenetic and tectonic processes. The authors used the data to divide the pre-salt section (Cabiúnas and Macabu formations) into three informal stratigraphic units. The analysis of interpreted fractures within these units suggests that major fracturing occurred due to regional tectonic stress, with local aspects like structural positioning interfering. The results of the fracture analysis imply a direct relationship between fracturing and silicification. Additionally, fracture density, vug volume distribution, and the presence of dissolution features like enlarged fractures limited to specific units imply stratigraphic control on fluid percolation. Finally, the study examines structural particularities in BM-C-33 area that potentially impacted intensity and extension of diagenetic alterations.

Novel insights about petroleum systems from source and reservoir rock characterization, Cretaceous Deposits, Babouri-Figuil Basin, Northern Cameroon

The Babouri-Figuil Basin (BFB) is a frontier basin for petroleum in Cameroon. It belongs to the series of Cretaceous rift basins of the West and Central Rift System (WCARS), the origin of which is related to the opening of the South Atlantic. Within the same rift system, commercial hydrocarbon accumulations have been discovered in Chad, Sudan, Niger and, more recently, in Nigeria (Gongola Basin). The study of the geology of the BFB just recently received considerable attention, mainly because of its presumed hydrocarbon potential. In the pursuit of researching possible petroleum systems in the BFB, the current study provides a first look into the characterization of source and reservoir rock and its integration into a 2D lithostratigraphic model. The study was solely based on outcrop samples. Black shale and massive claystone are good to excellent hydrocarbon source rocks [e.g., up to 38 wt% total organic carbon (TOC), up to 943 mg/g hydrogen index, up to 85 m thickness, up to 20–30 km lateral extension], with moderate to high values of extractable organic matter (e.g., >10,000 ppm). Calcareous claystone, on the other hand, are poor source rocks [e.g., <0.20 wt% TOC]. The samples are thermally immature, except for those located close to volcanic intrusion at Golombe that have reached the threshold for oil generation (Tmax >435 °C, production index >0.1). The petrographic analysis of sandstone revealed that they are fine-grained to coarse-grained, poorly to moderately sorted, texturally and compositionally immature to submature, subarkosic to arkosic arenites. The main diagenetic processes that affected sandstones are as follows: moderate to intense compaction characterized by the development of long, concavo-convex, and sutured contacts between grains; cementation through calcite, iron oxide, and quartz cements; alteration of mica and feldspar grains; partial to complete dissolution of feldspar, mica, amphibole grains, and calcite cement; and the replacement of feldspar and mica grains by clay minerals. Alteration and dissolution increase the porosity of sandstone through the creation of secondary pores. However, mechanical compaction through the development of a pseudomatrix and cementation as pore-filling materials have significantly reduced the quality of sandstone beds as conventional petroleum reservoirs. Hence, the best reservoir-quality sandstones in the basin are generally located in the upper portion of the basin in terms of its lithostratigraphic model. They are the cleanest sandstones with the smallest amount of cement and the lowest ductile grain content (pseudomatrix), with a thickness that varies from 3 m to 120 m and a lateral extension of 20 km. The lithostratigraphic model of the basin is characterized by an extensive lacustrine environment that provided a thick sequence of organic-rich formations; sand deposited as extensive reservoirs sandwiched between shale/claystone beds; the development of stratigraphic traps through lateral facies change; and the widespread deposition of lacustrine and floodplain claystone that provide regional seals. The similarities between the Babouri-Figuil Basin and proven petroleum systems in other WCARS rift basins suggest that the basin may host at least one petroleum system where actively generating source rocks are present.

Influence of species and stand position on isotopic and molecular composition of leaf litter during degradation in an urban mangrove forest

Understanding the diagenetic processes of organic matter (OM) within mangrove forests is essential to grasp ecosystem dynamics and exchanges with adjacent ecosystems. This study investigated the influence of urban runoff on leaf litter degradation in a New Caledonian mangrove forest, subjected to urban rainwater for over 50 years. Focusing on Avicennia marina and Rhizophora stylosa, our objectives were to determine factors affecting leaf litter degradation, assess urban runoff effects on decay rates and element concentrations, and understand OM changes at the molecular level. Litterbags containing senescent leaves placed on the mangrove floor were collected after 7, 14, 28, 56, and 72 days. C and N along with their stable isotopes were evaluated during degradation as well as lignin and neutral carbohydrates contents. Despite lower initial N content, R. stylosa exhibited faster degradation (t1/2 of 36 ± 3 and 28 ± 2 days) than A. marina (t1/2 of 43 ± 9 and 33 ± 4 days), emphasizing the critical role of species position within the mangrove forest regarding tidal immersion. Urban runoff, submerging the urban site, intensified leaf litter degradation, influencing both mass loss and molecular changes in OM. After 72 days of leaf litter degradation, the loss of rhamnose and glucose was more pronounced at the control site (13 % and 75 % for rhamnose and 46 % and 53 % for glucose for A. marina and R. stylosa, respectively) compared to the urban site. The study also exposed molecular tendencies during mangrove leaf litter degradation. The content of ferulic acid in the leaf litter decreased at all stands after 72 days of degradation (between −25 % and −58 %), while total syringyl phenols increased (between + 64 % and + 232 %). This research exposed the global implications of urban runoff, indicating accelerated leaf litter degradation in mangrove forests, potentially disrupting C sequestration dynamics and threatening ecosystem services.

Diagenetic dolomite in planktonic foraminifera on the Australian Northwest Shelf

ABSTRACTPlanktonic foraminiferal shells are widely used to investigate past oceanographic and climatic variations via their trace elements and stable isotopes. However, these geochemical methods may be compromised by the presence of diagenetic high‐Mg calcite. In this study, dolomite crystals are observed in planktonic foraminifera from International Ocean Discovery Program Site U1464 sediments on the Australian Northwest shelf, a shallow marine environment (&lt;300 m). This study investigates the formation of the dolomite using new scanning electron microscopy, X‐ray diffraction, stable isotope (carbon and oxygen), Mg/Ca and rare earth element data, combined with shipboard geochemistry and available literature. This study finds that foraminiferal dolomite formation was probably associated with early diagenesis, microbial and ageing processes. Two potential diagenetic processes (seafloor diagenesis and post‐depositional diagenesis) are proposed, and both indicate that the favourable redox condition of dolomite formation is low oxygen, which may activate methanogenic catalysis to facilitate dolomite formation. It is postulated that high‐Mg calcite may be the precursor of foraminiferal dolomite in this case, and that dissolution–precipitation may be the ageing process of dolomite formation. In contrast to deeper, more normal pelagic environments, this study shows that the marine environment can facilitate dolomite precipitation by higher fluxes of organic matter to the seafloor.

Classificação textural de rochas carbonáticas do pré-sal da Bacia de Santos e análise do sistema permoporoso: uma abordagem baseada na interpretação de imagens de tomografia computadorizada de raios X

Pre-salt lacustrine carbonates remain in evidence for being rocks of high complexity and responsible for the great economic potential of the Santos Basin. Aiming to contribute to studies in this field, the objective of this research was to define the key textures of the carbonate rocks in X-ray computed tomography (CT) images. For the execution of this study, core samples from two wells were used, and the adopted methodology comprises detailed geological description, characterization of the permoporous system, definition of the main textures in CT images, and analysis of the relationship between textures and their permoporous systems. The description of the main properties enabled the definition of six lithofacies and, through the analysis of CT images, a recurring pattern of certain textural attributes in specific lithofacies was identified. Thus, a representative proposal with four textural classes was established: laminated, shrubby, clastiform fragmented, and recrystallized. A direct relationship was observed between certain textures and the progression of diagenetic processes, as well as their corresponding permoporous systems. Finally, the proposed textural classification of CT images applied to Brazilian pre-salt lacustrine carbonate rocks demonstrates effectiveness in standard segmentation performed by expert technicians, enabling rapid identification of reservoir intervals of interest. For future work, it is recommended to employ this classification as an input base for training algorithms using machine learning techniques.

Electron backscatter diffraction analysis unveils foraminiferal calcite microstructure and processes of diagenetic alteration

Abstract. Electron backscatter diffraction (EBSD) analysis enables a unique perspective of the internal microstructure of foraminiferal calcite. Specifically, EBSD provides crystallographic data from within the test, highlighting the highly organised “mesocrystal” structure of crystallographically aligned domains throughout the test, formed by sequential deposits of microgranular calcite. We compared EBSD maps across the test walls of both poorly preserved and well-preserved specimens of the planktonic foraminifera species Globigerinoides ruber and Morozovella crater. The EBSD maps, paired with information about intra-test distributions of Mg/Ca ratios, allowed us to examine the effects of different diagenetic processes on the foraminifera test. In poorly preserved specimens EBSD data show extensive reorganisation of the biogenic crystal microstructure, indicating differing phases of dissolution, re-precipitation and overgrowth. The specimens with the greatest degree of microstructural reorganisation also show an absence of higher concentration magnesium bands, which are typical features of well-preserved specimens. These findings provide important insights into the extent of post-depositional changes, in both microstructure and geochemical signals that must be considered when utilising foraminifera to generate proxy archive data.

Diagenesis and lateral sealing types of fault zones in the Lishu Depression, Songliao Basin, NE China

The Lishu Depression in the Songliao Basin is characterized by well-developed faults, and the accumulation of oil and gas is closely related to fault sealing. However, there remains a dearth of comprehensive investigation into the diagenesis of fault zones and their influence on lateral sealing. This study employed electron probe analysis, cathodoluminescence, and carbon and oxygen isotope techniques to investigate the diagenetic processes in fault zones. This research also reconstructed the evolution of porosity and displacement pressure of fault rocks, and identified the lateral sealing characteristics of fault zones and their impact on oil and gas accumulation. The majority of faults in the study region formed earlier, and the fault zones experienced intricate diagenesis, characterized by compaction, cementation, replacement, and dissolution. The displacement pressure of fault rocks is higher during fault intermittent and static periods compared to active periods, and it is influenced by diagenesis. Late-stage calcite and pore-filling chlorite were deposited subsequent to the period of fault activity, filling dissolution pores. This led to relatively higher displacement pressure and improved lateral sealing of fault zone. The kaolinite cement exhibits a relatively elevated potassium concentration, due to its connection with the dissolution of feldspar, resulting in lower displacement pressure and poor sealing of fault zone. Based on the evolutionary characteristics of displacement pressure in fault rock and reservoir during various transportation stages, this study identified six types of lateral sealing of fault zones. Notably, the sealing types characterized by "fault core and damage zone sealing during static periods" and "fault core and damage zone sealing during intermittent and static periods" exhibit superior lateral sealing properties, effectively controlling the accumulation of oil and gas in the sand bodies on either side of the fault zone.

Tracking of uranium and thorium natural distribution in the chemical fractions of the Nile Valley and the Red Sea phosphorites, Egypt

The present study aims to elucidate the possible sources of uranium and thorium content in the Campanian–Maastrichtian phosphorites from the Duwi Formation in the Nile Valley and Red Sea by conducting facies analysis and sequential leaching method. Nile Valley samples were collected from the El-Sibaiya East area, while those of the Red Sea were collected from two locations: Hamadat and Zug El Bahar. The petrographic investigation revealed that the Sibaiya East phosphorites exhibit peloidal bioclastic phospharenite–phospharudite microfacies, while Hamadat and Zug El Bahar phosphorites display peloidal bioclastic phosphalutite and silicified peloidal bioclastic phospharenite microfacies, respectively. Besides, U–Th bearing accessory minerals, such as zircon and monazite occur in Sibaiya East phosphorites. Thorium is present in Zug El Bahar phosphorites as minute accumulations associating apatite and quartz. Moreover, uranium is found with vanadium and iron as fine patches in the Sibaiya East phosphorite, and as small disseminations associated with Ca and Si in the Hamadat phosphorite. The X-ray diffraction shows that the investigated phosphorites are essentially built up of hydroxyl apatite Ca5(PO4)3(OH) and quartz SiO2. To accurately evaluate the bioavailability and mobility of uranium and thorium in the investigated phosphorites, it was necessary to identify the overall concentration and the various chemical forms of these elements by a five-step sequential leaching technique. The results indicate that Th and U are more abundant in the Red Sea phosphorites than in the Nile Valley phosphorites. Furthermore, Th is not bio-available and it is mostly found in the residue as Th-bearing minerals. Uranium, unlike Th is bio-available and fractionates among all fractions, indicating that U accumulation is the result of various diagenetic processes.