This study explores the synergistic development between technological innovation and enterprises in green logistics supply chains from the sustainable development perspective. The study first introduces the latest progress of China's environmental policies and technological innovation and analyses the importance and necessity of green logistics supply chain management. Subsequently, through case studies and theoretical research, this paper discusses the policies and regulations of green supply chain management, collaborative management among enterprises, and the development path of technological innovation. It further analyses the contents of policies and regulations, enterprise collaboration management, and technological innovation in green logistics supply chain management. It proposes strategies and suggestions to solve problems by combining cases and theories. Finally, this study summarises the development status of green logistics supply chain management. It looks forward to future development trends, emphasizing that more enterprises should strengthen cooperation to jointly promote green logistics supply chains, environmental protection, and sustainable economic and social development.