Evolution Of Planetary Boundary Layer Research Articles

Surface Meteorological Conditions and Boundary Layer Height Variations During an Air Pollution Episode in Nanjing, China

AbstractThe evolution of planetary boundary layer (PBL) was investigated using observations from a laser ceilometer, an eddy covariance system, and an automatic meteorological station in the north of Nanjing city during an air pollution episode in 2016–2017 winter. Based on 7‐day observation under clean to polluted day, we recorded the temporal variations of backscatter signals observed by the ceilometer, and then intercompared the planetary boundary layer height (PBLH) retrieved from individual methods. The results show that backscatter signal gradient, standard deviation, and wavelet transform analysis methods generated similar PBLH values and PBL diurnal variation patterns. Moreover, the PBL structure varied diurnally, with distinct patterns corresponding to clean and polluted days. Based on these measurements, the relationships between PBLH, weather conditions, and contaminants were analyzed. Results show that on clean days, strong surface turbulence exchange makes the PBL fully developed and makes the PBLH increase sharply after sunrise, with a maximum of 1,483 m; on polluted days, stable synoptic conditions and the weaker wind speeds facilitated the accumulation of air pollutants, leading to smaller net surface radiation and weaker turbulence. Consequently, these conditions during polluted days led to lower PBLH values, which were typically less than 900 m.

Combined effects of boundary layer dynamics and atmospheric chemistry on aerosol composition during new particle formation periods

Abstract. Characterizing aerosol chemical composition in response to meteorological changes and atmospheric chemistry is important to gain insights into new particle formation mechanisms. A BAECC (Biogenic Aerosols – Effects on Clouds and Climate) campaign was conducted during the spring 2014 at the SMEAR II station (Station for Measuring Forest Ecosystem–Aerosol Relations) in Finland. The particles were characterized by a high-resolution time-of-flight aerosol mass spectrometer (HR-ToF-AMS). A PBL (planetary boundary layer) dilution model was developed to assist interpreting the measurement results. Right before nucleation events, the mass concentrations of organic and sulfate aerosol species were both decreased rapidly along with the growth of PBL heights. However, the mass fraction of sulfate aerosol of the total aerosol mass was increased, in contrast to a decrease for the organic mass fraction. Meanwhile, an increase in LVOOA (low-volatility oxygenated organic aerosol) mass fraction of the total organic mass was observed, in distinct comparison to a reduction of SVOOA (semi-volatile OOA) mass fraction. Our results demonstrate that, at the beginning of nucleation events, the observed sulfate aerosol mass was mainly driven by vertical turbulent mixing of sulfate-rich aerosols between the residual layer and the newly formed boundary layer, while the condensation of sulfuric acid (SA) played a minor role in interpreting the measured sulfate mass concentration. For the measured organic aerosols, their temporal profiles were mainly driven by dilution from PBL development, organic aerosol mixing in different boundary layers and/or partitioning of organic vapors, but accurate measurements of organic vapor concentrations and characterization on the spatial aerosol chemical composition are required. In general, the observed aerosol particles by AMS are subjected to joint effects of PBL dilution, atmospheric chemistry and aerosol mixing in different boundary layers. During aerosol growth periods in the nighttime, the mass concentrations of organic aerosols and organic nitrate aerosols were both increased. The increase in SVOOA mass correlated well with the calculated increase in condensed HOMs' (highly oxygenated organic molecules) mass. To our knowledge, our results are the first atmospheric observations showing a connection between increase in SVOOA and condensed HOMs during the nighttime.

Characterization of vertical distribution and radiative forcing of ambient aerosol over the Yangtze River Delta during 2013–2015

As the central part of eastern China, the Yangtze River Delta (YRD) region, with its rapid economic growth and industrial expansion, has experienced severe air quality issues. In this study, the monthly variation and interaction between aerosol direct radiative forcing (ADRF) and aerosol vertical structure during 2013–2015 over the YRD were investigated using ground-based observations from a Micro Pulse Lidar (MPL) and a CE-318 sun-photometer. Combining satellite products from MODIS and CALIPSO, and reanalysis wind fields, an integrated discussion of a biomass burning episode in Hangzhou during August 2015 was conducted by applying analysis of optical properties, planetary boundary layer (PBL), spatial-temporal and vertical distributions, backward trajectories, Potential Source Contribution Function (PSCF), and Concentration Weighted Trajectory (CWT). The results reveal that a shallower PBL coincides with higher scattering extinction at low altitude, resulting in less heating to the atmosphere and radiative forcing to the surface, which in turn further depresses the PBL. In months with a deeper PBL, the extinction coefficient decreases rapidly with altitude, showing stronger atmospheric heating effects and ADRF to the surface, facilitating the turbulence and vertical diffusion of aerosol particles, which further reduces the extinction and raises the PBL. Because of the hygroscopic growth facilitated by high relative humidity, June stands out for its high scattering extinction coefficient and relatively low PBL, and the reduced ADRF at the surface and the enhanced cooling effect on near-surface layer in turn depresses the PBL. Absorptive aerosols transported from biomass burning events located in Zhejiang, Jiangxi, and Taiwan provinces at 1.5 km, result in high ADRF efficiency for atmospheric heating. And the enhanced heating effect on near-surface layer caused by absorptive particles facilitates PBL development in August over the YRD.

Impact of Aerosol‐PBL Interaction on Haze Pollution: Multiyear Observational Evidences in North China

AbstractAtmospheric aerosols have been found to influence the development of planetary boundary layer (PBL) and hence to enhance haze pollution in megacities. Previous works on aerosol‐PBL interaction were mainly based on model simulation for short‐term cases; so far, there is a lack of long‐term observational evidences. In this study, based on multiyear measurements and reanalysis meteorological data, we give observational evidences on aerosol‐PBL interaction and its impact on pollution aggravation. We found a significant heating in upper PBL with maximum temperature change about 0.7 °C on average and a substantial dimming near surface with a mean temperature drop of −2.2 °C under polluted condition. By integrating Eulerian forward simulation and Lagrangian backward trajectory calculation, we demonstrated that the atmospheric heating was mainly induced by light‐absorbing aerosols like black carbon. Then an index representing such effect was proposed, which could well characterize aerosol‐PBL interaction and its impact on air pollution.

Planetary boundary layer evolution over an equatorial Andean valley: A simplified model based on balloon‐borne and surface measurements

Planetary boundary layer (PBL) evolution over a populated Andean valley east of Quito, Ecuador is investigated through an empirical model. Balloon‐borne measurements of boundary layer height (PBLh) were found to correlate strongly (R2 = 0.871) as a function of virtual temperature at the surface calculated with 10 min ground station observations. This simplified model captures slow and fast regimes of PBL growth observed from the early morning to midday, which lead to the development of either shallow or deep PBLs. Surface conditions under which different scenarios of PBL develop are discussed in light of a test performed with 2015 station data. The proposed model can be used with the purpose of interpreting air quality measurements.

First simultaneous measurements of peroxyacetyl nitrate (PAN) and ozone at Nam Co in the central Tibetan Plateau: impacts from the PBL evolution and transport processes

Abstract. Both peroxyacetyl nitrate (PAN) and ozone (O3) are key photochemical products in the atmosphere. Most of the previous in situ observations of both gases have been made in polluted regions and at low-altitude sites. Here we present the first simultaneous measurements of PAN and O3 at Nam Co (NMC; 30°46′ N, 90°57′ E, 4745 m a.s.l.), a remote site in the central Tibetan Plateau (TP). The observations were made during summer periods in 2011 and 2012. The PAN levels averaged 0.36 ppb (range: 0.11–0.76 ppb) and 0.44 ppb (range: 0.21–0.99 ppb) during 17–24 August 2011 and 15 May to 13 July 2012, respectively. The O3 level varied from 27.9 to 96.4 ppb, with an average of 60.0 ppb. Profound diurnal cycles of PAN and O3 were observed with minimum values around 05:00 LT, steep rises in the early morning, and broader platforms of high values during 09:00–20:00 LT. The evolution of the planetary boundary layer (PBL) played a key role in shaping the diurnal patterns of both gases, particularly the rapid increases of PAN and O3 in the early morning. Air entrainment from the free troposphere into the PBL seemed to cause the early-morning increase and be a key factor for sustaining the daytime high concentrations of both gases. The days with higher daytime PBL (about 3 km) showed stronger diurnal variations in both gases and were mainly distributed in the drier pre-monsoon period, while those with shallower daytime PBL (about 2 km) showed minor diurnal variations and were mainly distributed in the humid monsoon period. Episodes of higher PAN levels were occasionally observed at NMC. These PAN episodes were caused either by rapid downward transport of air masses from the middle/upper troposphere or by long-range transport of PAN plumes from north India, north Pakistan, and Nepal. The maximum PAN level in the downward transport cases ranged from 0.5 to 0.7 ppb. In the long-range transport case, the PAN level varied in the range of 0.3–1.0 ppb, with an average of 0.6 ppb. This long-range transport process influenced most of the western and central TP region for about a week in early June 2012. Our results suggest that polluted air masses from South Asia can significantly enhance the PAN level over the TP. As PAN acts as a reservoir of NOx, the impacts of pollution transport from South Asia on tropospheric photochemistry over the TP region deserve further studies.

The Climatology of Low‐Level Jet in Beijing and Guangzhou, China

AbstractThe important roles of low‐level jet (LLJ) in transport of heat, moisture, and pollutants have long been recognized. However, partly due to the lack of long‐term observations, the characteristics of LLJs in Beijing and Guangzhou have not been well understood. Using long‐term wind profiler observations and numerical simulations, the basic climatological characteristics of LLJ in Beijing and Guangzhou were documented, and their relationships with large‐ and local‐scale forcings were investigated. The occurrence frequencies of LLJ in both megacities approximately exhibit a bimodal distribution during an annual cycle. In terms of the seasonality, the LLJs in Beijing occur more often in spring and winter, and those in Guangzhou appear more frequently from October to December and from February to April. Pronounced diurnal variations of LLJ are found in Beijing, where most LLJs occurred during the nighttime, and the diurnal variations of LLJ in Guangzhou are less prominent. Favorable synoptic conditions for LLJ formations in Beijing are those having a southwest‐northeast or southeast‐northwest pressure gradient across Beijing. Dominant synoptic patterns associated with LLJs in Guangzhou are those having a low‐pressure or high‐pressure system to the northwest. Overall, the LLJs are primarily induced by synoptic forcings and modulated by the diurnal evolution of planetary boundary layer. The key findings from this study provide us a better understanding of the LLJs in these highly populated regions.

Spatial Characterization of Black Carbon Mass Concentration in the Atmosphere of a Southeast Asian Megacity: An Air Quality Case Study for Metro Manila, Philippines

Black carbon (BC) particles have gathered worldwide attention due to their impacts on climate and adverse health effects on humans in heavily polluted environments. Such is the case in megacities of developing and emerging countries in Southeast Asia, in which rapid urbanization, vehicles of obsolete technology, outdated air quality legislations, and crumbling infrastructure lead to poor air quality. However, since measurements of BC are generally not mandatory, its spatial and temporal characteristics, especially in developing megacities, are poorly understood. To raise awareness on the urgency of monitoring and mitigating the air quality crises in megacities, we present the results of the first intensive characterization experiment in Metro Manila, Philippines, focusing on the spatial and diurnal variability of equivalent BC (eBC). The average mass concentration of eBC at the urban background station (UBS) was 7.0 ± 4.8 µg m–3 while at roadside (RS), hourly concentrations reached maximum values of 138 µg m–3, levels that are significantly higher than in European cities. At RS, the diurnal cycles of eBC mass concentration were connected most strongly with traffic dynamics and street configuration, while a notable influence of planetary boundary layer evolution was observed in the UBS. Results of mobile measurements conducted multiple times along two fixed routes showed high spatial variability ranging from 3-80 µg m–3 within a 500-m radius. Alarmingly, the highest concentrations were found in the most crowded areas where people spend more than eight hours a day.

Simulations of summertime fossil fuel CO2 in the Guanzhong basin, China

Recent studies on fossil fuel CO2 simulation associated with Δ14CO2 measurements is quite limited, particularly in China. In this study, the fossil fuel CO2 recently added to the atmosphere (δCO2ff) over the Guanzhong basin, central China, during summer 2012 is simulated using a modified WRF-CHEM model constrained by measured CO2 mixing ratio and Δ14CO2. The model well captures the temporal variation of observed CO2 mixing ratio and Δ14CO2, and reasonably reproduces the distribution of observed Δ14CO2. The simulation shows a significant variation of δCO2ff during summertime, ranging from <5ppmv to ~100ppmv and no remarkable trend of δCO2ff is found for June, July, and August. The δCO2ff level is closely associated with atmospheric diffusion conditions. The diurnal cycle of δCO2ff presents a double-peak pattern, a nocturnal one and a rush-hour one, related to the development of planetary boundary layer and CO2 emission from vehicles. The spatial distributions of summertime δCO2ff within the basin is clearly higher than the outside, reaching up to 40ppmv in urban Xi'an and 15ppmv in its surrounding areas, indicative of large local fossil fuel emissions. Furthermore, we find that neglecting the influence of summer heterotrophic respiration in terrestrial biosphere would slightly underestimate the calculated δCO2ff by about 0.38ppmv in the basin.

A campaign for investigating aerosol optical properties during winter hazes over Shijiazhuang, China

As the capital of the most air-polluted Hebei province in China, Shijiazhuang has been suffering serious haze pollutions especially during wintertime. An integrated campaign for investigating aerosol optical properties under haze conditions over Shijiazhuang were carried out using a sunphotometer, an aethalometer and a lidar in the winter from late 2013 to early 2014. The results indicated that the haze episodes during the measurement period were severer and more frequent over Shijiazhuang than Beijing. Under heavy pollution conditions (PM2.5>150μg/m3) over Shijiazhuang, fine-mode fractions of AOD500nm were larger than 0.80 with more dispersive angstrom exponent due to hygroscopic growth. The mean values of SSA over Shijiazhuang were smaller than those over Beijing both in this study and the severe haze episodes in January 2013, suggesting that there were more fine-mode absorbing particles over Shijiazhuang. More significant spectrally-dependence of imaginary part of refractive index over Shijiazhuang implies larger relative magnitude of brown carbon (BrC) as compared to Beijing. The black carbon (BC) measurement displayed extremely high records with a larger ratio of BC to PM2.5 (12.11% in average) comparing with other cities in China. The high carbonaceous aerosols (BC and BrC) should be attributed to large amounts of coal consumption. During the hazes with high BC concentrations, the daily maximal planetary boundary layer (PBL) heights were consistently lower than 500m, implying the impacts of BC aerosols on the PBL development and hence enhance the surface haze pollution.

The climatology of planetary boundary layer height in China derived from radiosonde and reanalysis data

Abstract. The important roles of the planetary boundary layer (PBL) in climate, weather and air quality have long been recognized, but little is known about the PBL climatology in China. Using the fine-resolution sounding observations made across China and reanalysis data, we conducted a comprehensive investigation of the PBL in China from January 2011 to July 2015. The boundary layer height (BLH) is found to be generally higher in spring and summer than that in fall and winter. The comparison of seasonally averaged BLHs derived from observations and reanalysis, on average, shows good agreement, despite the pronounced inconsistence in some regions. The BLH, derived from soundings conducted three or four times daily in summer, tends to peak in the early afternoon, and the diurnal amplitude of BLH is higher in the northern and western subregions of China than other subregions. The meteorological influence on the annual cycle of BLH is investigated as well, showing that BLH at most sounding sites is negatively associated with the surface pressure and lower tropospheric stability, but positively associated with the near-surface wind speed and temperature. In addition, cloud tends to suppress the development of PBL, particularly in the early afternoon. This indicates that meteorology plays a significant role in the PBL processes. Overall, the key findings obtained from this study lay a solid foundation for us to gain a deep insight into the fundamentals of PBL in China, which helps to understand the roles that the PBL plays in the air pollution, weather and climate of China.

Improvement of the Mellor–Yamada–Nakanishi–Niino Planetary Boundary-Layer Scheme Based on Observational Data in China

The Mellor–Yamada–Nakanishi–Niino (MYNN) planetary boundary-layer (PBL) scheme is a second-order turbulence closure model that is an improved version of the Mellor–Yamada scheme based on large-eddy simulation data. It simulates PBL structure and evolution well, particularly over the ocean surface. However, when used with various underlying surfaces in China, the scheme overestimates the turbulent momentum flux and the sensible heat flux. Based on observations of surface fluxes in China, we attempt to improve the MYNN model by modifying the parameters and representation of the turbulence scale. Closure constants and empirical expressions in the diagnostic equation are chosen first, and an additional component of the turbulent heat flux is considered in the potential temperature prognostic equation to improve the surface heat-flux modelling. The modified MYNN scheme is incorporated into a three-dimensional mesoscale model and is evaluated using various underlying surface observations. Amelioration of the surface turbulent fluxes is confirmed at five observational sites in China over different land-use types.

Reasons for the Extremely High-Ranging Planetary Boundary Layer over the Western Tibetan Plateau in Winter

Abstract The planetary boundary layer (PBL) over the Tibetan Plateau (with a mean elevation about 4 km above sea level) reaches an unmatched height of 9515 m above sea level. The proximity of this height to the tropopause facilitates an exchange between the stratosphere and the boundary layer. However, the underlying mechanisms responsible for this unique PBL have remained uncertain. Here, the authors explore these mechanisms and their relative importance using measurements of the PBL, the associated surface fluxes, and single-column and regional numerical simulations, as well as global reanalysis data. Results indicate that the dry conditions of both ground soil and atmosphere in late winter cannot explain the special PBL alone. Rather, the results from a single-column model demonstrate the key influence of the stability of the free atmosphere upon the growth of extremely deep PBLs over the Tibetan Plateau. Simulations with the numerical weather prediction model Consortium for Small-Scale Modelling (COSMO) exhibit good correspondence with the observed mean PBL structure and realistic turbulent kinetic energy distributions throughout the PBL. Using ERA-Interim, the authors furthermore find that weak atmospheric stability and the resultant deep PBLs are associated with higher upper-level potential vorticity (PV) values, which in turn correspond to a more southerly jet position and higher wind speeds. Upper-level PV structures and jet position thus influence the PBL development over the Tibetan Plateau.

Particle Climatology in Central East China Retrieved from Measurements in Planetary Boundary Layer and in Free Troposphere at a 1500-m-High Mountaintop Site

ABSTRACTParticle number size distribution (PNSD) is an important variable for evaluating the effect of aerosols on climate. In this study, the PNSD in the size range of 3 nm–2.5 µm was measured over a 20-month period at Mt. Tai station, located at ~1500 m asl. in central east China (CEC). The mean particle number concentrations in the nucleation (Nnuc, 3–25 nm), Aitken (NAit, 25–100 nm), accumulation modes (Nacc, 100–1000 nm) and in total measured particle size range were 3200 cm–3, 5200 cm–3, 3400 cm–3, and 11800 cm–3, respectively. New particle formation (NPF) events determined from the PNSD data occurred on 32% of measured days, with particle formation rate and growth rate of 4.0 ± 3.7 cm–3 s–1 and 6.1 ± 2.5 nm h–1, respectively. Time periods of 12:00–17:00 and 23:00–7:00 local time were selected to represent periods when the air mass at the station was dominated by planetary boundary layer (PBL) and free troposphere (FT) air, respectively. The diurnal variation of particle number concentration was influenced mostly by NPF events and evolution of the PBL. When NPF event days were excluded, the particle number concentration also experienced a seasonal variation with maximum in summer and minimum in winter. This seasonality was influenced by seasonal variations in PBL evolution and by air mass advection. The results of this study characterize the regional particle climatology in central east China in terms of particle number and size.

Sea-Breeze and Topographic Influences on the Planetary Boundary Layer in the Coastal Upwelling Area of Cabo Frio (Brazil)

We use a fully coupled oceanic-atmospheric model to investigate the sources and sinks of turbulent kinetic energy in the Cabo Frio coastal area and to determine the role of topography and the sea breeze in planetary boundary-layer (PBL) development. The study area presents similar boundary-layer characteristics than other coastal upwelling areas with complex topography, such as increased stability and low-level jets. The results show that the major effect of upwelling, over the investigated area, is to maintain low temperatures in the lower atmosphere over the coastal zone, sustaining a strong temperature inversion that precludes the vertical PBL development. Therefore, the cooling effect reduces the horizontal thermal contrast between land and water, generating a negative feedback between the intensity of the sea breeze and the intensity of the upwelling. The topography at Cabo Frio prevents this cooling effect from propagating inland, since it limits the penetration of the sea-breeze circulation.

Quantifying the Land–Atmosphere Coupling Behavior in Modern Reanalysis Products over the U.S. Southern Great Plains

Abstract The coupling of the land with the planetary boundary layer (PBL) on diurnal time scales is critical to regulating the strength of the connection between soil moisture and precipitation. To improve understanding of land–atmosphere (L–A) interactions, recent studies have focused on the development of diagnostics to quantify the strength and accuracy of the land–PBL coupling at the process level. In this paper, the authors apply a suite of local land–atmosphere coupling (LoCo) metrics to modern reanalysis (RA) products and observations during a 17-yr period over the U.S. southern Great Plains. Specifically, a range of diagnostics exploring the links between soil moisture, evaporation, PBL height, temperature, humidity, and precipitation is applied to the summertime monthly mean diurnal cycles of the North American Regional Reanalysis (NARR), Modern-Era Retrospective Analysis for Research and Applications (MERRA), and Climate Forecast System Reanalysis (CFSR). Results show that CFSR is the driest and MERRA the wettest of the three RAs in terms of overall surface–PBL coupling. When compared against observations, CFSR has a significant dry bias that impacts all components of the land–PBL system. CFSR and NARR are more similar in terms of PBL dynamics and response to dry and wet extremes, while MERRA is more constrained in terms of evaporation and PBL variability. Each RA has a unique land–PBL coupling that has implications for downstream impacts on the diurnal cycle of PBL evolution, clouds, convection, and precipitation as well as representation of extremes and drought. As a result, caution should be used when treating RAs as truth in terms of their water and energy cycle processes.

Vertical Distribution and Columnar Optical Properties of Springtime Biomass-Burning Aerosols over Northern Indochina during 2014 7-SEAS Campaign

ABSTRACTIn this study, the aerosol optical properties and vertical distributions in major biomass-burning emission area of northern Indochina were investigated using ground-based remote sensing (i.e., four Sun-sky radiometers and one lidar) during the Seven South East Asian Studies/Biomass-burning Aerosols & Stratocumulus Environment: Lifecycles & Interactions Experiment conducted during spring 2014. Despite the high spatial variability of the aerosol optical depth (AOD; which at 500 nm ranged from 0.75 to 1.37 depending on the site), the temporal variation of the daily AOD demonstrated a consistent pattern among the observed sites, suggesting the presence of widespread smoke haze over the region. Smoke particles were characterized as small (Angstrom exponent at 440–870 nm of 1.72 and fine mode fraction of 0.96), strongly absorbing (single-scattering albedo at 440 nm of 0.88), mixture of black and brown carbon particles (absorption Angstrom exponent at 440–870 nm of 1.5) suspended within the planetary boundary layer (PBL). Smoke plumes driven by the PBL dynamics in the mountainous region reached as high as 5 km above sea level; these plumes subsequently spread out by westerly winds over northern Vietnam, southern China, and the neighboring South China Sea. Moreover, the analysis of diurnal variability of aerosol loading and optical properties as well as vertical profile in relation to PBL development, fire intensity, and aerosol mixing showed that various sites exhibited different variability based on meteorological conditions, fuel type, site elevation, and proximity to biomass-burning sources. These local factors influence the aerosol characteristics in the region and distinguish northern Indochina smoke from other biomass-burning regions in the world.

Numerical simulation of air convection in the atmosphere during the invasion of cold air over the Black Sea

The structure of a convective-mechanical planetary boundary layer (PBL) in the atmosphere over the Black Sea in the event of the invasion of cold air has been investigated using a WRF-ARW numerical model of regional atmospheric circulation. The features of the development of the convective PBL, typical of the quasi-stationary (but significantly heterogeneous in space) development of convection have been distinguished. Based on a series of test calculations, a numerical model assuming convective motions in the PBL has been chosen to study the small-scale structure of the PBL. Calculated horizontal scales of convective motions with cloud images from satellites have been compared. The vertical structure of convective motions has been investigated and the essential asymmetry in convective motions has been revealed. Vertical profiles of the velocity field components, as well as components of vertical heat fluxes, have been estimated. In addition, values of the separate components of the kinetic-energy balance equation for convective motions (KE) show that the KE is generated due to buoyancy forces and, to a lesser degree, by the mean velocity shift.

Atmospheric boundary layer top height in South Africa: measurements with lidar and radiosonde compared to three atmospheric models

Abstract. Atmospheric lidar measurements were carried out at Elandsfontein measurement station, on the eastern Highveld approximately 150 km east of Johannesburg in South Africa throughout 2010. The height of the planetary boundary layer (PBL) top was continuously measured using a Raman lidar, PollyXT (POrtabLe Lidar sYstem eXTended). High atmospheric variability together with a large surface temperature range and significant seasonal changes in precipitation were observed, which had an impact on the vertical mixing of particulate matter, and hence, on the PBL evolution. The results were compared to radiosondes, CALIOP (Cloud-Aerosol Lidar with Orthogonal Polarization) space-borne lidar measurements and three atmospheric models that followed different approaches to determine the PBL top height. These models included two weather forecast models operated by ECMWF (European Centre for Medium-range Weather Forecasts) and SAWS (South African Weather Service), and one mesoscale prognostic meteorological and air pollution regulatory model TAPM (The Air Pollution Model). The ground-based lidar used in this study was operational for 4935 h during 2010 (49% of the time). The PBL top height was detected 86% of the total measurement time (42% of the total time). Large seasonal and diurnal variations were observed between the different methods utilised. High variation was found when lidar measurements were compared to radiosonde measurements. This could be partially due to the distance between the lidar measurements and the radiosondes, which were 120 km apart. Comparison of lidar measurements to the models indicated that the ECMWF model agreed the best with mean relative difference of 15.4%, while the second best correlation was with the SAWS model with corresponding difference of 20.1%. TAPM was found to have a tendency to underestimate the PBL top height. The wind speeds in the SAWS and TAPM models were strongly underestimated which probably led to underestimation of the vertical wind and turbulence and thus underestimation of the PBL top height. Comparison between ground-based and satellite lidar shows good agreement with a correlation coefficient of 0.88. On average, the daily maximum PBL top height in October (spring) and June (winter) was 2260 m and 1480 m, respectively. To our knowledge, this study is the first long-term study of PBL top heights and PBL growth rates in South Africa.

Aerosol hygroscopicity derived from size-segregated chemical composition and its parameterization in the North China Plain

Abstract. Hygroscopic growth of aerosol particles is of significant importance in quantifying the aerosol radiative effect in the atmosphere. In this study, hygroscopic properties of ambient particles are investigated based on particle chemical composition at a suburban site in the North China Plain during the HaChi campaign (Haze in China) in summer 2009. The size-segregated aerosol particulate mass concentration as well as the particle components such as inorganic ions, organic carbon and water-soluble organic carbon (WSOC) are identified from aerosol particle samples collected with a ten-stage impactor. An iterative algorithm is developed to evaluate the hygroscopicity parameter κ from the measured chemical composition of particles. During the HaChi summer campaign, almost half of the mass concentration of particles between 150 nm and 1 μm is contributed by inorganic species. Organic matter (OM) is abundant in ultrafine particles, and 77% of the particulate mass with diameter (Dp) of around 30 nm is composed of OM. A large fraction of coarse particle mass is undetermined and is assumed to be insoluble mineral dust and liquid water. The campaign's average size distribution of κ values shows three distinct modes: a less hygroscopic mode (Dp &lt; 150 nm) with κ slightly above 0.2, a highly hygroscopic mode (150 nm &lt; Dp &lt; 1 μm) with κ greater than 0.3 and a nearly hydrophobic mode (Dp &gt; 1 μm) with κ of about 0.1. The peak of the κ curve appears around 450 nm with a maximum value of 0.35. The derived κ values are consistent with results measured with a high humidity tandem differential mobility analyzer within the size range of 50–250 nm. Inorganics are the predominant species contributing to particle hygroscopicity, especially for particles between 150 nm and 1 μm. For example, NH4NO3, H2SO4, NH4HSO4 and (NH4)2SO4 account for nearly 90% of κ for particles of around 900 nm. For ultrafine particles, WSOC plays a critical role in particle hygroscopicity due to the predominant mass fraction of OM in ultrafine particles. WSOC for particles of around 30 nm contribute 52% of κ. Aerosol hygroscopicity is related to synoptic transport patterns. When southerly wind dominates, particles are more hygroscopic; when northerly wind dominates, particles are less hygroscopic. Aerosol hygroscopicity also has a diurnal variation, which can be explained by the diurnal evolution of planetary boundary layer, photochemical aging processes during daytime and enhanced black carbon emission at night. κ is highly correlated with mass fractions of SO42−, NO3− and NH4+ for all sampled particles as well as with the mass fraction of WSOC for particles of less than 100 nm. A parameterization scheme for κ is developed using mass fractions of SO42−, NO3−, NH4+ and WSOC due to their high correlations with κ, and κ calculated from the parameterization agrees well with κ derived from the particle's chemical composition. Further analysis shows that the parameterization scheme is applicable to other aerosol studies in China.