Deterministic Transfer Research Articles

Material Transfer and Contact Optimization in MoS2 Nanotube Devices

While the promise of clean and defect‐free nanotubes as quantum electronic devices is obvious, ranging from strong spin–orbit interaction to intrinsic superconductivity, device fabrication still poses considerable challenges. Deterministic transfer of transition metal dichalcogenide nanomaterials and transparent contacts to the nanomaterials are nowadays highly active topics of research, both with fundamental research and applications in mind. Contamination from transport agents as well as surface adsorbates and surface charges play a critical role for device performance. Many techniques have been proposed to address these topics for transition metal dichalcogenides in general. Herein, their usage for the transfer‐based fabrication of nanotube devices is analyzed. Further, different contact materials are compared in order to avoid the formation of a Schottky barrier.

A System Built for Both Deterministic Transfer Processes and Contact Photolithography

A home‐built compact system that functions as both a transfer stage for deterministic transfer processes and a mask aligner for contact photolithography, is constructed. The precision translation sample stage and optical microscope are shared between the two modes. In the transfer mode, assisted by either an adhesive or a heating element, the setup has been used to deterministically transfer freestanding semiconductors, 2D materials, and van der Waals electrodes. When configured in photolithography mode, the proposed instrument has been employed to fabricate various microscale patterns and devices, with minimum feature sizes of 1–2 μm achieved. The prototype instrument provides a feasible solution for performing high‐quality deterministic transfer and photolithography processes on one single tool in‐house.

A Survey of Multimaterial Treatments for Thermal Radiative Transfer

Arbitrary Lagrangian-Eulerian methods are a popular choice for hydrodynamic modeling in radiation (rad-hydro) simulations. Because these methods involve a relaxation step that moves the mesh relative to material boundaries, multimaterial spatial zones are generally present. Accurate treatments of these zones are needed to resolve various physical phenomena of interest for inertial confinement fusion applications. However, these codes are often paired with single-material, deterministic thermal radiative transfer (TRT) codes that are oblivious to the material compositions of each zone. These single-material TRT codes can only accept homogenized material properties (opacities, specific heats, etc.) from the hydrodynamic code and output homogenized solutions. After each TRT time step, the multimaterial hydrodynamic code must dehomogenize the quantities computed by the TRT package in order to update subzonal material temperatures. The process by which hydrodynamic codes perform this dehomogenization has not been well documented in previous literature, and the methods can vary significantly from code to code. The purpose of this paper is to document, study, and compare existing techniques used for rad-hydro simulations as well as present a new method with potentially promising results. We summarize several methods and give comparisons on infinite-medium problems as well a finite-medium problem for two of the methods.

Ultracold field-linked tetratomic molecules.

Ultracold polyatomic molecules offer opportunities1 in cold chemistry2,3, precision measurements4 and quantum information processing5,6, because of their rich internal structure. However, their increased complexity compared with diatomic molecules presents a challenge in using conventional cooling techniques. Here we demonstrate an approach to create weakly bound ultracold polyatomic molecules by electroassociation7 (F.D. et al., manuscript in preparation) in a degenerate Fermi gas of microwave-dressed polar molecules through a field-linked resonance8-11. Starting from ground-state NaK molecules, we create around 1.1 × 103 weakly bound tetratomic (NaK)2 molecules, with a phase space density of 0.040(3) at a temperature of 134(3) nK, more than 3,000 times colder than previously realized tetratomic molecules12. We observe a maximum tetramer lifetime of 8(2) ms in free space without a notable change in the presence of an optical dipole trap, indicating that these tetramers are collisionally stable. Moreover, we directly image the dissociated tetramers through microwave-field modulation to probe the anisotropy of their wavefunction in momentum space. Our result demonstrates a universal tool for assembling weakly bound ultracold polyatomic molecules from smaller polar molecules, which is a crucial step towards Bose-Einstein condensation of polyatomic molecules and towards a new crossover from a dipolar Bardeen-Cooper-Schrieffer superfluid13-15 to a Bose-Einstein condensation of tetramers. Moreover, the long-lived field-linked state provides an ideal starting point for deterministic optical transfer to deeply bound tetramer states16-18.

Microelectronics-compatible reduced graphene oxide based nanomechanical resonators capable of all-electrical actuation and read-out

Photolithographic patterning and deterministic transfer of reduced graphene oxide (rGO) are key innovations that can give way to cost-effective batch processing of nanoelectromechanical system (NEMS)-based resonators with high throughput. Here, by implementing the same, we report a facile fabrication process for NEMS-based resonators consisting of rGO as the active material for the structural layer. The structural properties of rGO thin film are confirmed using Raman spectroscopy and X-ray diffraction analysis. Temperature-dependent current–voltage characteristics of rGO film ensure the typical 2D Mott variable range hopping (VRH) transport with ambipolar charge conduction, further supporting the effectiveness of the fabrication process. All-electrical actuation and readout of the fabricated resonators are performed using both frequency modulation (FM) downconversion and piezoresistive mixing methods adeptly to achieve a resonance frequency of around 28–32 MHz. The fabrication process is compatible with the current microelectronic technology and can foster the prospect of on-chip implementation of rGO NEMS toward possible applications such as molecular sensors, mass detectors, etc.

Improving quantum state transfer: correcting non-Markovian and distortion effects

Quantum state transfer is a key operation for quantum information processing. The original pitch-and-catch protocols rely on flying qubits or single photons with engineered wavepacket shapes to achieve a deterministic, fast and high-fidelity transfer. Yet, these protocols overlook two important factors, namely, the distortion of the wavepacket during the propagation and non-Markovian effects during the emission and reabsorption processes due to time-dependent controls. Here we address both difficulties in a general quantum-optical model and propose a correction strategy to improve quantum state transfer protocols. Including non-Markovian effects in our theoretical description, we show how to derive control pulses that imprint phases on the wavepacket that compensate the distortion caused by propagation. Our theoretical results are supported by detailed numerical simulations showing that a suitable correction strategy can improve state transfer fidelities up to three orders of magnitude.

Low T direct plasma assisted growth of graphene on sapphire and its integration in graphene/MoS2 heterostructure-based photodetectors

We report on outstanding photo-responsivity, R > 103 A/W, fast response (~0.1 s), and broadband sensitivity ranging from the UV to the NIR in two terminal graphene/MoS2 photodetectors. Our devices are based on the deterministic transfer of MoS2 on top of directly grown graphene on sapphire, and their performance outperforms previous similar photodetectors using large-scale grown graphene. Here we devise a protocol for the direct growth of transparent (transmittance, Tr > 90%), highly conductive (sheet resistance, R□ < 1 kΩ) uniform and continuous graphene films on sapphire at 700 °C by using plasma-assisted chemical vapor deposition (CVD) with C2H2/H2 gas mixtures. Our study demonstrates the successful use of plasma-assisted low-temperature CVD techniques to directly grow graphene on insulators for optoelectronic applications.

Asymmetries in triboelectric charging: Generalizing mosaic models to different-material samples and sliding contacts

Nominally identical materials exchange net electric charge during contact through a mechanism that is still debated. `Mosaic models', in which surfaces are presumed to consist of a random patchwork of microscopic donor/acceptor sites, offer an appealing explanation for this phenomenon. However, recent experiments have shown that global differences persist even between same-material samples, which the standard mosaic framework does not account for. Here, we expand the mosaic framework by incorporating global differences in the densities of donor/acceptor sites. We develop an analytical model, backed by numerical simulations, that smoothly connects the global and deterministic charge transfer of different materials to the local and stochastic mosaic picture normally associated with identical materials. Going further, we extend our model to explain the effect of contact asymmetries during sliding, providing a plausible explanation for reversal of charging sign that has been observed experimentally.

Three-Dimensional Distributions of the Direct Effect of anExtended and Intense Dust Aerosol Episode (16–18 June 2016) over the Mediterranean Basin on Regional Shortwave Radiation, Atmospheric Thermal Structure, and Dynamics

In the present study, we used the FORTH deterministic spectral Radiation Transfer Model (RTM) to estimate detailed three-dimensional distributions of the Direct Radiative Effects (DREs) and their consequent modification of the thermal structure of the regional atmosphere during an intense dust episode that took place from 16 to 18 June 2016 over the Mediterranean Basin (MB). The RTM operated on a 3-hourly temporal and 0.5 × 0.625° spatial resolution, using 3-D aerosol optical properties (i.e., aerosol optical depth, single scattering albedo, and asymmetry parameter) and other surface and atmospheric properties from the MERRA-2 reanalysis and cloud properties (i.e., cloud amount, cloud optical depth, and cloud top height) from the ISCCP-H dataset. The model ran with and without dust aerosols, yielding the upwelling and downwelling solar fluxes at the top of the atmosphere, in the atmosphere, and at the Earth’s surface as well as at 50 levels in the atmosphere. The dust direct radiative effect (DDRE) was estimated as the difference between the two (one taking into account all aerosol types and one taking into account all except for dust aerosols) flux outputs. The atmospheric heating rates and subsequent convection induced by dust radiative absorption were calculated at 50 levels to determine how the DDRE affects the thermal structure and dynamics of the atmosphere. The results showed that such a great and intense dust transport event significantly reduces the net surface solar radiation over the MB (by up to 62 W/m2 on a daily mean basis, and up to 200 W/m2 on an hourly basis, at 12:00 UTC) while increasing the atmospheric solar absorption (by up to 72 W/m2 daily and 187 W/m2 hourly, at 12:00 UTC). At the top of the atmosphere, both heating (over desert areas) and cooling (over oceanic and other continental areas) are observed due to the significantly different surface albedos. Transported dust causes considerable heating of the region’s atmosphere, which becomes maximum at altitudes where the dust loadings are highest (0.14 K/3 h on 17 June 2016, 12:00 UTC, at 3–5 km above sea level). The dust solar absorption and heating induce a buoyancy as strong as 0.014 m/s2, resulting in considerable changes in vertical air motions and possibly contributing to the formation of middle- and high-level clouds over the Mediterranean Basin.

Transferable nano-patterned ALD membrane

We demonstrate fabrication of nano-patterned thin ALD (Atomic layer deposition) membrane (suspended/transferable) by using a bi-layer resist process where the bottom layer resist acts as a sacrificial layer. This method enables an all dry deterministic transfer of nano-patterned ALD membrane on desired substrate, allowing assembly of multitude of hetero-structures and functionalities that are not yet accessible. Unlike conventional ways of achieving patterned alumina membrane reported in literature our technique requires significantly less fabrication steps and paves the way for novel ALD membrane-based technology.

All‐Dry Deterministic Transfer of Thin Gold Nanowires for Electrical Connectivity

AbstractMetallic nanowires (NWs) exhibit a number of interesting properties, such as high conductivity, flexibility, and cold‐weldability, making them ideal for nanocircuits. They are usually adsorbed on substrates by depositing a colloidal solution of NWs on the surface. However, they remain randomly scattered and solvent residues may contaminate/ degrade the sample. This study presents a method for forming electrical contacts with gold nanowires based on all‐dry deterministic transfer. The process begins with the adsorption of gold nanowires by drop casting the colloidal solution onto a viscoelastic substrate. These wires are transferred to selected locations on the substrate, minimizing manipulation with fabrication times a factor of 2 shorter than direct drop casting deposition, preserving surface and sample conditions, and improving the fabrication of nanocircuits. Atomic force microscopy is used to manipulate the NWs for the final connections, which have contact resistances of a few ohms. To illustrate the technique, three different examples of applicability are presented. This work is expected to be a starting point for expanding the potential of deterministic transfer that is successfully used in 2D materials. For example, to study local electrical transport in heterogeneous samples such as van der Waals heterostructures and twisted layers of 2D materials.

Multi-fidelity optimization of a quiet propeller based on deep deterministic policy gradient and transfer learning

In a propeller blade optimization, both aerodynamic and aeroacoustic performance were considered simultaneously. A multi-fidelity sampling scheme was adopted by Transfer Learning (TL) to improve the overall optimization efficiency. A Deep Neural Network (DNN) was selected to map the non-linear relationship between the blade parameters and the aerodynamic/aeroacoustic performance, with the optimization being achieved by implementing a deep reinforcement learning algorithm, namely, Deep Deterministic Policy Gradient (DDPG), upon which a Multi-fidelity DNN based surrogate model (TL-MFDNN) was introduced with Transfer Learning between pre-trained and retrained processes. It was found that, by comparing the TL-MFDNN surrogate model based optimization with DDPG optimization using direct CFD simulation, the overall computing cost can be saved up to 77.3% and the optimized propeller has maximum noise reduction of up to 1.69 dB, with a negligible penalty on propulsive performance.

Fast Fabrication of WS2/Bi2Se3 Heterostructures for High-Performance Photodetection.

Two-dimensional (2D) material heterostructures have attracted considerable attention owing to their interesting and novel physical properties, which expand the possibilities for future optoelectronic, photovoltaic, and nanoelectronic applications. A portable, fast, and deterministic transfer technique is highly needed for the fabrication of heterostructures. Herein, we report a fast half-wet poly(dimethylsiloxane) (PDMS) transfer process utilizing the change of adhesion energy with the help of micron-sized water droplets. Using this method, a vertical stacking of the WS2/Bi2Se3 heterostructure with a straddling band configuration is successfully assembled on a fluorophlogopite substrate. Thanks to the complementary band gaps and high efficiency of interfacial charge transfer, the photodetector based on the heterostructure exhibits a superior responsivity of 109.9 A W-1 for a visible incident light at 473 nm and 26.7 A W-1 for a 1064 nm near-infrared illumination. Such high photoresponsivity of the heterostructure demonstrates that our transfer method not only owns time efficiency but also ensures high quality of the heterointerface. Our study may open new pathways to the fast and massive fabrication of various vertical 2D heterostructures for applications in twistronics/valleytronics and other band engineering devices.

Multifunctional indium selenide devices based on van der Waals contacts: High-quality Schottky diodes and optoelectronic memories

Van der Waals semiconductors, with ultrathin body thickness and dangling-bond-free surfaces, have been employed to fabricate a vast range of electronic and optoelectronic devices such as transistors, photodiodes and memories. The integration of these different functional elements into one single device, usually referred to as multifunctional device, has received great research attention in the recent years. In this work, we realized a multifunctional device, based on the van der Waals semiconductor Indium Selenide (InSe), which can work both as a high-quality Schottky diode with current rectification and photovoltaic characteristics and as a memory. By exploiting the all-dry deterministic transfer fabrication method, we deposited the 2D InSe channel onto pre-deposited graphite and platinum electrodes, whose theoretical work functions differ of ∼1.0–1.4 eV. Thanks to a controllable InSe air passivation treatment, these devices, which start in a non-rectifying state with negligible electrodes-InSe barriers, gradually evolve into Schottky diodes, presenting a final sizeable Schottky barrier height of 556 ± 50 meV at the Pt-InSe interface, thus resulting in a gradual tuning of the device photoresponsivity and photovoltaic parameters (such as the open circuit voltage Voc). The multifunctional capabilities of these devices were demonstrated by using them as optoelectronic memories, which can achieve on-off ratios between the logical ‘1’ and ‘0’ up to 100 and retention times of thousands of seconds. This multifunctional behavior can be ascribed to the traps present in the system, which on one side influences the metal-semiconductor barriers and on the other introduces charge storage capabilities at the base of the memory operation. Our results demonstrate that trap state modulation can be an important tuning knob for thin InSe in the field of electronics and optoelectronics.

Deterministic and replaceable transfer of silver flakes for microcavities

Deterministic and replaceable transfer of silver flakes for microcavities

Trion confinement in monolayer MoSe2 by carbon nanotube local gating

We have successfully confined trions into a one-dimensional restricted space of a MoSe2 device with carbon nanotube (CNT) gate electrodes. The dry transfer process, including deterministic dry transfer of aligned CNTs, has led to an hBN-encapsulated MoSe2 device with CNT back gate electrodes. In contrast to a location without CNT gate electrodes, applying voltage via CNT gate electrodes significantly alters PL spectra at a location with CNT gate electrodes. PL imaging has revealed that image contrast from trions is linear along the CNT electrode underneath, consistent with 1D confinement of trions in response to the CNT local gating. The confinement width obtained from the PL image is 5.5 × 102 nm, consistent with nanoscale 1D confined trions with the diffraction limit broadening. This work has demonstrated electrical control of excitonic states at the nanoscale, leading to novel optoelectronic properties and exciton devices in the future.

Enhanced Field-Effect Control of Single-Layer WS2 Optical Features by hBN Full Encapsulation.

The field-effect control of the electrical and optical properties of two-dimensional (2D) van der Waals semiconductors (vdW) is one important aspect of this novel class of materials. Thanks to their reduced thickness and decreased screening, electric fields can easily penetrate in a 2D semiconductor and thus modulate their charge density and their properties. In literature, the field effect is routinely used to fabricate atomically thin field-effect transistors based on 2D semiconductors. Apart from the tuning of the electrical transport, it has been demonstrated that the field effect can also be used to modulate the excitonic optical emission of 2D transition metal dichalcogenides such as MoS2 or WSe2. In this paper, we present some recent experiments on the field-effect control of the optical and excitonic properties of the monolayer WS2. Using the deterministic transfer of van der Waals materials, we fabricate planar single-layer WS2 devices contacted by a gold electrode and partially sandwiched between two insulating hexagonal boron nitride (hBN) flakes. Thanks to the planar nature of the device, we can optically access both the hBN encapsulated and the unencapsulated WS2 regions and compare the field-effect control of the exciton population in the two cases. We find that the encapsulation strongly increases the range of tunability of the optical emission of WS2, allowing us to tune the photoluminescence emission from excitons-dominated to trions-dominated. We also discuss how the full encapsulation of WS2 with hBN helps reduce spurious hysteretic effects in the field-effect control of the optical properties, similar to what has been reported for 2D vdW field-effect transistors.

Biometric Authentication-Based Intrusion Detection Using Artificial Intelligence Internet of Things in Smart City

Nowadays, there is a growing demand for information security and security rules all across the world. Intrusion detection (ID) is a critical technique for detecting dangers in a network during data transmission. Artificial Intelligence (AI) methods support the Internet of Things (IoT) and smart cities by creating gadgets replicating intelligent behavior and enabling decision making with little or no human intervention. This research proposes novel technique for secure data transmission and detecting an intruder in a biometric authentication system by feature extraction with classification. Here, an intruder is detected by collecting the biometric database of the smart building based on the IoT. These biometric data are processed for noise removal, smoothening, and normalization. The processed data features are extracted using the kernel-based principal component analysis (KPCA). Then, the processed features are classified using the convolutional VGG−16 Net architecture. Then, the entire network is secured using a deterministic trust transfer protocol (DTTP). The suggested technique’s performance was calculated utilizing several measures, such as the accuracy, f-score, precision, recall, and RMSE. The simulation results revealed that the proposed method provides better intrusion detection outcomes.

11.1: Invited Paper: Production‐Worthy Massive Parallel Transfer Technology for the Assembly of Micro‐LED Based Displays Makarem A. Hussein

In this work, the basis for high production, deterministic massive transfer process flow and equipment technology utilizing an electromagnetic force transfer head, are introduced and discussed. A fundamental requirement for using electromagnetic force is to include a paramagnetic material in the metallurgy of the micro-LED contacts.

Multimode Strong Coupling in Cavity Optomechanics

Optomechanical systems show great potential as quantum transducers and information storage devices for use in future hybrid quantum networks. In this context, optomechanical strong coupling can enable efficient, high-bandwidth, and deterministic transfer of quantum states. While optomechanical strong coupling has been realized at optical frequencies, it has proven difficult to identify a robust optomechanical system that features the low loss and high coupling rates required for more sophisticated control of mechanical motion. In this paper, we demonstrate strong coupling in a Brillouin-based bulk cavity optomechanical system in both the single-mode and the multimode strong-coupling regime, which leads to a useful device both for applications in quantum information and for investigating decoherence phenomena in bulk acoustic wave resonators. Using nontrivial mode hybridizations in the strong-coupling regime, we create hybridized photonic-phononic modes with lifetimes that are significantly longer than those of the uncoupled system. This surprising lifetime enhancement, which results from the interference of decay channels, showcases the use of multimode strong coupling as a general strategy to control extrinsic decoherence mechanisms. Moreover, phonons supported by such bulk-acoustic-wave resonators have a collection of properties, including high frequencies, long coherence times, and robustness against thermal decoherence, that make this optomechanical system particularly enticing for applications such as quantum transduction and memories. Hence, this system provides access to phenomena in a previously unexplored regime of optomechanical interactions and could serve as an important building block for future quantum devices.