Depositional Age Research Articles

Tectono‐sedimentary history of the upper Cedar Mountain Formation, Central Utah, USA

ABSTRACTCurrent investigations into the Albian–Cenomanian sedimentary record within the Western Interior have identified multiple complex tectono‐sedimentary process–response systems during the ongoing evolution of North America. One key sedimentary succession, the upper Cedar Mountain Formation (Short Canyon Member and Mussentuchit Member), has historically been linked to various regionally and continentally significant tectonic events, including Sevier fold‐and‐thrust deformation. However, the linkage between the Short Canyon Member and active Sevier tectonism has been unclear due to a lack of high‐precision age constraints. To establish temporal context, this study compares maximum depositional ages from detrital zircons recovered from the Short Canyon Member with that of a modified Bayesian age stratigraphic model (top‐down) to infer that the Short Canyon Member was deposited at ca 100 Ma, penecontemporaneous with rejuvenated thrusting across Utah [Pavant (Pahvant), Iron Springs and Nebo thrusts]. These also indicate a short depositional hiatus with the lowermost portion of the overlying Mussentuchit Member. The Short Canyon Member and Mussentuchit Member preserve markedly different sedimentary successions, with the Short Canyon Member interpreted to be composed of para‐autochthonous orogen–transverse (across the Sevier highlands) clastics deposited within a series of stacked distributive fluvial fans. Meanwhile, the muddy paralic Mussentuchit Member was a mix of orogen–transverse (Sevier highlands and Cordilleran Arc) and orogen–parallel basinal sediments and suspension settling fines within the developing collisional foredeep. However, the informally named last chance sandstone (middle sandstone of the Mussentuchit Member) is identified as an orogen–transverse sandy debris flow originating from the Sevier highlands, similar to the underlying Short Canyon Member. During this phase of landscape evolution, the Short Canyon Member – Mussentuchit Member depocentre was a sedimentary conduit system that would fertilize the Western Interior Seaway with ash‐rich sediments. These volcaniclastic contributions, along with penecontemporaneous deposits across the western coastal margin of the Western Interior Seaway, eventually would have lowered oxygen content and resulted in a contributing antecedent trigger for the Cenomanian–Turonian transition Oceanic Anoxic Event 2.

Middle Triassic and middle Permian radiolarians from the Kamitaki Complex in the Sasayama area, Hyogo Prefecture, Southwest Japan: Evidence for Triassic plate subduction along the eastern margin of Paleo-Asia

The Kamitaki Complex, situated in the Sasayama area in Southwest Japan, has long been presumed to be a Permian subduction-related accretionary complex based on correlations from previous studies. However, because of the lack of fossil evidence, the exact age of the complex remained uncertain for a long time period. To address this gap in knowledge, a geological survey and microfossil mapping were conducted in the Kamitaki Complex to determine its age and geological context.A geological survey revealed that the Kamitaki Complex mainly consists of clastic rocks, and a mixture of sandstone, basalt, and chert blocks within the mudstones. The Kamitaki Complex is tectonically intercalated into the Lopingian (Late Permian) accretionary complex of the Ultra-Tamba Terrane and Late Triassic accretionary complex of the Tamba Terrane. The lithological and structural characteristics of the Kamitaki Complex confirm that it is an accretionary complex. Microfossil mapping yielded depositional ages, with radiolarian fauna such as Eptingium nakasekoi, Pseudostylosphaera japonica, Cryptostephanidium japonicum, and Oertlispongus cf. diacanthus identified in mudstones suggesting an Anisian (early Middle Triassic) age. In contrast, radiolarian fauna found in cherts, including Pseudoalbaillella? aff. longicornis, and Follicucullus cf. porrectus, indicate an early Capitanian (late Guadalupian, middle Permian) depositional age. These findings suggest that the Kamitaki Complex records a trenchward migration of the oceanic plate in a pelagic environment from the early Capitanian and an accretion at the trench during the Anisian period.Conventionally, the plate boundary between the Panthalassa and Paleo-Asia during the latest Permian to Middle Triassic was of the transform type, primarily because no subduction-related accretionary complexes from this period have been identified in the Japanese Islands. However, the discovery of Kamitaki Complex, an Anisian accretionary complex, provides evidence of Middle Triassic subduction activity along the eastern margin of Paleo-Asia. According to the internal structure and age polarity of the Ultra-Tamba and Tamba terranes, an accretionary complex developed over a prolonged period (approximately 120 million years) in a tectonic setting that persisted along the eastern margin of Paleo-Asia from the late Guadalupian to the earliest Cretaceous period.

Constraining the age of the Pleistocene sedimentary infill of Cueva Mayor (Atapuerca, N Spain) through a multi-technique dating approach

Establishing chronologies of archaeological sites by using a single dating method may not always reliably constrain the age of a deposit or a fossil, as potential biases may naturally arise, particularly in complex sedimentary settings such as caves. In this study, we performed a multi-technique dating approach that targets different materials in two caves from the Cueva Mayor-Cueva del Silo karst system, Sierra de Atapuerca, Spain. Two new fossil teeth from lithostratigraphic unit LU4 (GE-I pit) at Galería de las Estatuas have been dated by combined U-series/ESR and Amino Acid Racemisation (AAR) methods. The former provides ages of 117 ± 13 and 87 ± 9 ka that agree with previous dating studies of this Neandertal site, confirming the assignment of level LU4 to Marine Isotope Stage (MIS) 5. In contrast, AAR analyses produce very scattered ages, pointing to significant post-burial chemical modifications in dentine. A first set of ages is presented for the Cata Litario pit at Sala de los Cíclopes, a palaeontological site formed exclusively of cave bear fossils belonging to the Middle Pleistocene species Ursus deningeri. We provide U-series/ESR and AAR ages for two bear teeth from lithostratigraphic unit LU5, and extended-range luminescence ages for the sediment deposits that host, and immediately underlie and overlie, the bear accumulation. Depositional ages of the sediment were obtained using single-grain thermally-transferred optically stimulated luminescence (TT-OSL) dating of individual quartz grains and post-infrared-infrared stimulated luminescence (pIR-IR) dating of K-feldspars. Several speleothems, both in situ and reworked fragments embedded in the different lithostratigraphic units, have additionally been dated by U-series to constrain the timing of the sequence formation. The results indicate that the sediment originally entered the cave between MIS-12 and MIS-10 (444 ± 28 ka to 367 ± 32 ka). Nevertheless, the AAR and U-series/ESR fossil ages, as well as some of the speleothem fragment ages from LUs 5 and 6 are significantly younger. Leaving aside methodologically questionable results for one of the bear tooth samples, the most reliable AAR and U-Series/ESR ages range from 287 ± 23 ka to 256 ± 24, while the speleothem fragments indicate several formation episodes between 444 ± 19 and 284 ± 8 ka. The apparent difference between the U-Series/ESR ages on the fossils and the luminescence ages on the host sediment are not likely to be wholly explained by uncertainties on uranium uptake modelling or gamma dose rate evaluation, and thus is most likely related to taphonomic processes or a complex site formation history.The presence of fossils and eroded speleothem clasts of younger age within these levels is consistent with either an event of prior erosion, transport and resedimentation of LUs 4, 5 and 6, and/or a complex post-depositional mixing history for the stratigraphic sequence at Cata Litario. This study highlights the importance of using different dating methods to reconstruct reliable chronological frameworks, and to understand the geological factors that can affect the dated materials. This includes the accumulation and taphonomic histories of fossils, post-depositional mixing or reworking processes affecting sediments during the residence time within the karst system.

Studies on the 2.2 Ga monzogranite and its wall rocks in western part of North Qinling Orogen: Constraints on early Precambrian tectonic attributes and evolution of the southwestern margin of Ordos Block

Precambrian continent remnants in Phanerozoic orogenic belts contain vital information about not only the Precambrian evolution history of continent remnants but also the relationship between orogenic belts and adjacent blocks. This paper presents an integrated study of petrology, geochemistry and accessory mineral chronology on a monzogranite, its wall rocks biotite-quartz schist and an amphibolite interlayer in the schist in the Kuanping Group, from the western part of the North Qinling Orogen (NQO), adjacent to the southwestern margin of the Ordos Block (OB). The results reveal that the crystallization age of the monzogranite is 2200 ± 12 Ma and the protolith of the biotite-quartz schist deposited during 526–447 Ma, and they experienced similar multistage metamorphism during 450–400 Ma. The 2.2 Ga formation age of the monzogranite is significantly older than the protolith deposition age of the biotite-quartz schist, and there is almost no ca. 2.2 Ga detrital zircon age in the schist, indicating that the monzogranite is neither an intrusive body in the Kuanping Group, nor its provenance. Considering the ca. 2.2 Ga magmatism is widely distributed in North China Craton but never found in the NQO, and the monzogranite and host schist recorded similar metamorphic ages, we proposed that the monzogranite initially formed at the southwestern margin of the North China Craton and involved into the NQO during the closure of the Kuanping sedimentary basin at early Paleozoic. Combined with existing studies, three Paleoproterozoic magmatic events of ca. 2.5 Ga, 2.2–2.0 Ga and 1.8–1.75 Ga, and one ca. 1.9–1.85 Ga metamorphic event occurred at the southwestern margin of OB. These tectono-thermal events as well as their geological setting are very similar to the basement rocks of the central-southern part of the OB. Therefore, the early Precambrian rocks at the southwestern margin of the OB should belong to the basement of the central-southern part of OB, and the late tectonic events placed them at their present position.

Using U-Pb detrital zircon systematics to constrain the architecture and provenance of the Ronda peridotites’ crustal hanging wall, S Spain

Detrital zircon geochronology is frequently used for sediment provenance analysis in orogenic belts, but it can also be applied to locate the boundary between basement and sedimentary cover in successions and tectonometamorphic units where the paleontological record is missing, and primary stratigraphic relationships have been erased by intense deformation and/or metamorphism. This is critical to differentiate metamorphic mineral associations, P-T conditions and deformational events associated with superposed orogenic cycles. In this work, detrital zircon geochronology has been applied to the Ronda peridotites’ crustal hanging wall (hinterland of the Alpine Betic Cordillera, southern Spain), apparently made up of two major tectonic units – the Jubrique unit and the Maláguide complex – separated by a major Alpine tectonic contact camouflaged in between low-grade metamorphic rocks.Our results show that pre-Paleozoic peaks (c. 650, 1000, 2000, and 2600 Ma) are common along the entire studied crustal sequence, and Paleozoic ages are only recorded in the upper part of the Jubrique unit (c. 290, 350, and 475 Ma) and in the Maláguide complex (c. 350 and 475 Ma). Thus, the Paleozoic rocks of the Maláguide complex, constituting the highest crustal unit overlying the Ronda peridotites, represent syn-to-late orogenic Variscan sediments deformed and slightly metamorphosed prior to the Alpine cycle. In contrast, the underlying Jubrique unit is made of a post-Variscan sedimentary cover deposited on a Variscan basement, with the contact between both (hidden unconformity?) located within low- to medium-grade schists. These data support the presence of a major tectonic contact between the Maláguide complex (Late Carboniferous maximum depositional ages) and the Jubrique unit (Early Permian maximum depositional ages), i.e. the Maláguide complex would have overthrust the Jubrique unit during the Alpine orogeny. These results indicate a Permian or younger exhumation/emplacement up to crustal levels of the Ronda peridotites subcontinental mantle slab.Altogether, these detrital zircon age spectra support a relatively, but not entirely local derivation of the studied crustal sequences (fragments of the Iberian Massif) and suggest some Mesozoic drifting with respect to its present position. Nonetheless, the different age distribution of the Paleozoic populations between the Jubrique (Alpujárride complex) and Maláguide samples suggests that the former deposited relatively close to other samples from the eastern-central Alpujárride complex and Nevado-Filábride complex, which, in turn, show strong similarities with the Cantabrian zone and NE Iberia (Iberian Massif). In contrast, the Maláguide samples were probably deposited close to the Ossa-Morena Zone (Iberian Massif) . Thus, Alpujárride/Nevado-Filábride and Maláguide complexes would have been juxtaposed during the Triassic-Cretaceous Neotethys rifting/drifting and/or the subsequent Alpine collisional events.

Combined geochronological U-Pb, Hf isotopes and trace element zircon studies from Piedra Alta Terrane, Rio de la Plata Craton (West Uruguay, South America): A geodynamic model

This work delves into the intricate Paleoproterozoic geological setting of Uruguay, focusing on the Rio de la Plata Craton (RPC) and its prominent constituent Piedra Alta Terrane (PAT). The PAT constitutes the core of the RPC, characterized as a complex geological entity that encompasses a granite-migmatite basement, metamorphic belts, granite intrusions, and Proterozoic magmatism. To the west, it interfaces with the Transbrasiliano-Kandi tectonic corridor, bounded by the Late-Neoproterozoic Pampia Terrane. The PAT s southeastern boundary extends to Sierra de Tandil and perhaps to Sierra de La Ventana, demarcating its limits with Phanerozoic rocks of the North Patagonian Massif. The Sarandí del Yí shear zone defines the eastern limit of the PAT. Despite varied interpretations of the Piedra Alta Terrane’s significance, it is important to note that consensus prevails regarding its four major associations: a granite-gneiss-migmatitic basement complex, three volcanosedimentary belts of low to medium metamorphic grade, diverse late igneous intrusions, and extensional Statherian magmatism (1.79 Ga), represented by tholeiitic gabbroic dikes. In this study, a novel tectonic model for the PAT evolution emerges, supported by an extensive zircon dataset comprising new U-Pb ages, Hf isotopes, and trace element geochemistry. The analytical core involves U-Pb analyses on zircon for dating igneous rocks and establishing the provenance and maximum age of deposition of metavolcanosedimentary sequences. Lu-Hf isotopic analyses on the same zircon crystals provide petrogenetic insights, revealing episodes of crustal growth and minor recycling. Trace element geochemistry and zircon εHf(t) data further accentuate these findings, hinting at mantle source enrichment due to subduction within an intraoceanic magmatic-arc arc setting.

Contributing to understand how Cordilleran batholiths build from detailed geochronology of the Carboniferous Tabaquito batholith, Frontal Cordillera (Argentina)

Cordilleran Granitic batholiths or Andean/Cordilleran batholiths serve as plutonic expressions of continental arcs, offering valuable insights into the processes that operate in large silicic magmatic systems at subduction environments. This work presents a comprehensive geochronological study of the Carboniferous Tabaquito batholith in the Frontal Cordillera of western Argentina, which is the best exponent of the Carboniferous arc-related magmatism in this region. Using new data obtained through LA-MC-ICP-MS and comparing it with previously published data (LA-MC-ICP-MS and SHRIMP techniques), we identify five distinct magmatic events in the Tabaquito batholith: 325 ± 2 Ma; 332 ± 2 Ma; 337 ± 2 Ma; 346 ± 1 Ma, and 362 ± 2 Ma. The 325 Ma event is considered as the best estimate of the crystallization age during the emplacement. The 332 Ma, 337 Ma, 346 Ma and 362 Ma events suggest the presence of zircon antecrysts, implying a complex magmatic system that worked for a protracted time lapse of ca. 40 Myr, or ca. 15 Myr if we consider the ages of 346 and 362 Ma as xenocrysts from a source like the Potrerillos pluton (346 ± 3 Ma to 356 ± 3 Ma), which was interpreted in previous studies as possible source of the parental magmas of the Tabaquito batholith. Furthermore, it has been also identified inherited zircons with ages older than ca. 370 Ma that are consistent with the detrital zircon pattern obtained for the country rock. Inherited zircon ages from the referred country rock yield a maximum deposition age estimated at 387 Ma that is consistent with the fossil ammonoids record, indicating that the granitic rocks were emplaced in Devonian rocks.

Age of the Zashikhinskoye Rare Metal Deposit (Eastern Sayan): Results of U–Pb (ID TIMS) Geochronological Studies of Metamictic Zircon

Age of the Zashikhinskoye Rare Metal Deposit (Eastern Sayan): Results of U–Pb (ID TIMS) Geochronological Studies of Metamictic Zircon

Reassessing early to mid-Neoproterozoic (∼885–720 Ma) tectonic evolution of the southwestern Jiangnan Orogen: A detrital zircon perspective

The Neoproterozoic Jiangnan Orogen (JNO) marks the consolidation of the South China Block, sparking ongoing debates on its early to mid-Neoproterozoic tectonic evolution. In this study, we have gathered detrital zircon data from the southwestern JNO, presenting new detrital zircon U-Pb ages alongside trace element data from the mid-Neoproterozoic Banxi Group and Sinian System within this region. Our objective is to illuminate the early to mid-Neoproterozoic tectonic evolution within the southwestern JNO through a comprehensive detrital zircon analysis. The obtained dating results derived from detrital zircons reveal maximum depositional ages of ∼733 Ma and ∼713 Ma for Mobin Formation (Banxi Group) and Jiangkou Formation (Sinian System) sedimentary rocks, suggesting a proximal source, possibly originating from magmatic rocks within the southwestern JNO. Within the paleo-geographic context, it is plausible that these samples were deposited within the deep-water expanse of the Nanhua Rift Basin. Trace element analysis of detrital zircons within the southwestern JNO highlights distinctive fluctuations, delineating three crucial time points (∼885 Ma, ∼835 Ma, and ∼810 Ma): the beginning of early Neoproterozoic subduction of the South China Ocean towards the Yangtze Block beneath the southwestern JNO, the subduction slab rollback, and the Nanhua rifting initiation. The discernible shifts in detrital zircon age distributions within these sedimentary rocks serve as robust validation for the proposed model and crustal reworking. We then propose that the southwestern JNO was in a lull of magmatism before ∼885 Ma, then transitioned to a convergent setting around 885–835 Ma, subsequently subduction slab rollback after ∼835 Ma. The time of final assembly of the Yangtze and Cathaysia blocks in the southwestern JNO is no later than ∼810 Ma. This transformative period (∼810–720 Ma) witnessed the development of a rift basin concurrently with the accumulation of deep-water deposits within the southwestern JNO.

Permian tectonic evolution of the proto-Japan and East Asia: Insights from detrital zircon geochronology and crystal morphology

Combination analyses of detrital zircon ages and morphology from Permian sandstones in Japan provide evidence of orogenic evolution caused by collision in East Asia and reveal their paleogeographic setting. This study compares published and newly measured data from Permian fore-arc accretionary complexes (Akiyoshi Belt) and back-arc basin deposits (Maizuru Belt) in the Inner Zone of Southwest Japan. The fore-arc deposits and lower part of the back-arc deposits consist mainly of approximately 300–250 Ma zircon grains that are close to the depositional ages and are generally angular to subangular. These sediments formed around the Late Paleozoic volcanic arc isolated from the older continental crust, and their source rocks were exposed immediately prior to their erosion and transport and were transported directly to the depositional site in a relatively short time. In contrast, upper part of the back-arc deposits generally contains approximately 2,700–1,800 and 500–250 Ma zircon grains, which are commonly older than their depositional ages and are rounded. These grains were supplied from multiple sources, such as the Paleozoic volcanic arc and Precambrian continental block, and were affected by long-distance transport and a strong abrasion effect during transport. Comprehensive detrital zircon data emphasize that the oceanic arc–back-arc basin–continental margin system formed along the eastern margin of East Asia, and that the volcanic arc collided with the eastern margin of the Sino-Korean Block during the Permian. The variation in detrital zircon ages and shapes of back-arc deposits provides a constraint for modeling the East Asian Permian collision. Detritus derived from continental crust was captured by a back-arc basin and blocked by the uplift zone of the volcanic arc. However, a small amount of detritus originating from the continental crust was supplied to the fore-arc.

Geochronology, geochemistry, and geological evolution of the Troiseck-Floning and Rosskogel nappes (Eastern Alps): unraveling parallels between the Eastern Alps and Western Carpathians

The Troiseck-Floning and Rosskogel nappes are part of the Austroalpine Unit in the eastern part of the Eastern Alps. The nappes are in tectonic contact and comprise Permian to Mesozoic lower greenschist facies metamorphic metasediments, but only the Troiseck-Floning Nappe consists of a pre-Permian crystalline basement (Troiseck Complex) as well. LA-ICP-MS U–Pb zircon ages, Rb–Sr biotite ages and geochemical data unravel the geological evolution of these tectonic units from Neoproterozoic to Mesozoic times. Detrital U–Pb zircon analyses from siliciclastic metasediments of the Troiseck Complex indicate a late Ediacaran to early Cambrian deposition age of the volcanoclastic sequence. The age distribution correlates with a position along the northeastern Gondwana margin. A late Cambrian crystallization age (502.4 ± 6.8 Ma) of granitic intrusions together with evidence for Late Cambrian/Ordovician magmatism and metamorphism indicate a position at an active plate margin. Polyphase overprinting during the Variscan orogeny is recorded by Late Devonian/early Carboniferous pegmatite dikes (~ 353 Ma) that formed after an early Variscan event, while Pennsylvanian ages of overgrowth rims and inherited grains (~ 320 Ma) are evidence for late Variscan metamorphism. Rhyolitic to andesitic volcanic rocks from the Troiseck-Floning and Rosskogel nappes (271–264 Ma) concomitant with intrusions of porphyric granitoids now transformed to augen gneiss (271 Ma) yield evidence for Permian rift-related magmatism that is widely reported from the Eastern Alps and Western Carpathians. Rb–Sr biotite ages (75–74 Ma) indicate Late Cretaceous cooling below c. 300 °C. This relates to Late Cretaceous exhumation of the Troiseck-Floning Nappe following an Eo-Alpine metamorphic overprint at lower greenschist-facies metamorphic conditions. Based on the similar lithostratigraphy, analogous geological evolution and structure, the Troiseck-Floning Nappe represents the lateral extension of the Seckau Nappe. The new dataset also allows for correlations with other basement complexes that occur in the Western Carpathians.

Late Pleistocene depositional processes of coastal aeolian deposits and their relationship with environment change on the Changxing Island of Liaodong Peninsula, northeastern China

Coastal aeolian deposits are product of the coupling between aerodynamics and coastal hydrodynamics, which is of great significance for reconstructing aeolian activities and the coastal environmental change. Here, we investigated the coastal aeolian deposits on Changxing Island, northeastern China, using geochemistry and microscopy of the minerals together with the published sedimentological data. The results showed that aeolian deposits are mainly derived from beach sands reworked by wind. Previously published Optically Stimulated Luminescence (OSL) dating results show that the deposition ages of the aeolian deposits are 41 ka, 49 ka, and 67 ka, respectively. The sedimentologic and geochemistry of aeolian deposits are sensitive to climate change. Notably, the micromorphology structure of the surface of quartz sand particles reveals the process of the coastal environment evolution. ∼41 ka, the surface of the grains is characterized by significant subaqueous environments, showing subangular with high relief, large conchoidal fracture, and V-shaped pits. These features correspond to the early sub-interstadial stage of MIS3, characterized by a warm and humid climate and sea level highstand. Under the relative sea level rise, the high rate of sand supply produced by coastal erosion contribute to aeolian deposit formation. In contrast, at 49 ka and 67 ka, the quartz grain exhibits typical aeolian environment features that exhibits subrounded with low relief, upturned plates, and dish-shaped pits, which respond to glacial periods of cold and windy conditions and sea level lowstand. The exposure of abundant sandy material, coupled with lower vegetation cover and strong East Asian winter monsoon (EAWM) contribute to higher sediment availability and sand accumulation. We therefore propose that sediment supply control by sea-level change is the primary reason for coastal aeolian sand deposition under different climatic backgrounds.

Middle Jurassic deposits of Ulakhan-Sis Ridge (Sakha Republic): biostratigraphy, lithological features and depositional environments

The age and sedimentation conditions of the Middle Jurassic terrigenous deposits crowning the Mesozoic section of the northeastern flank of the Nagondzha terrane within the Ulakhan-Sis Ridge are discussed. Based on our own finds of retrocerams and analysis of biostratigraphic data of predecessors, we accept the age of the deposits as Bajocian–Middle Bathonian. Three lithologically different strata are identified in the section. Sandstones from the lower unit belong to feldspathic litharenites, and from the upper strata – to litharenites with a predominance of extrabasinal carbonate clastics (calklithites). Analysis of textural and structural features, mineralogical, petrographic composition and distribution of trace elements in litharenites suggests that all these strata had been accumulated in the shelf part of the paleobasin associated with an active volcanic island arc, which presumably existed from the Early Jurassic on the Omulevka craton terrane until the completion of the formation of Kolyma-Omolon microcontinent.

Inverse correlation between age of onset and myocardial amyloid deposition quantified by 99mTc-PYP scintigraphy in patients with wild-type transthyretin amyloid cardiomyopathy.

Wild-type transthyretin amyloidosis cardiomyopathy (ATTRwt-CM) is increasingly recognized as a contributing factor to cardiac insufficiency in the elderly population. We aimed to identify the factors affecting age of onset of ATTRwt-CM, encompassing the assessment of amyloid deposition in myocardial tissue through the use of 99mTc-pyrophosphate (PYP) and clinical parameters. A retrospective investigation involving a consecutive cohort of 107 cases, each having been diagnosed with ATTRwt-CM confirmed through histopathological and genetic analysis, was performed. All patients underwent PYP scintigraphy, and the heart-to-contralateral (H/CL) ratio was calculated to measure amyloid deposition in the myocardium. Univariate and multivariate analyses were performed to identify independent predictors of the age of onset of ATTRwt-CM, considering the H/CL ratio and various clinical risk factors for heart failure. Gender (p = 0.03), Creatinine (Cr) (r = 0.32, p < 0.01), hemoglobin (Hb) (r = - 0.44, p < 0.01), albumin (Alb) (r = - 0.32, p < 0.01), brain natriuretic peptide (BNP) (r = 0.21, p = 0.03), low-density lipoprotein-cholesterol (LDL-C) (r = - 0.27, p < 0.01), and H/CL ratio (r = - 0.44, p < 0.01) were all significantly associated with the onset age. In multiple regression analysis, the independent predictive factors for the onset age of ATTRwt-CM were identified as the H/CL ratio (p < 0.01), Hb (p < 0.01), and Cr (p < 0.01). The H/CL ratio, Hb, and Cr independently affect age of onset in patients with ATTRwt-CM. The H/CL ratio is inversely correlated with age of onset, and may be the sole factor in the development of heart failure in early onset patients, while it may have a synergistic effect on heart failure with anemia and renal dysfunction in late-onset patients.

New paleofloristic and geochronological U–Pb zircon data in late Paleozoic deposits of the Matzitzi formation in southern Mexico

The fossil flora of the Matzitzi Formation, is a fluvial unit of late Paleozoic age exposed in southern Mexico, has been studied since the last century; however, the discovery of new plant elements during the last decade imposes a reevaluation of two aspects that have always been the subject of debate: the depositional age of the unit and the taxonomy of its paleoflora. The objective of the present work is to report new paleofloral records from two areas of the Matzitzi Formation as well as their chronological implications. The study sites are named Carretera and Coatepec. Nineteen genera and 11 species have been identified in beds from the Carretera site, whereas 23 genera and 16 species in beds from the Coatepec site. The analysis of floral assemblages of both sites shows that they share 49% of taxa. Ovopteris, Lesleya, Lobatopteris, and Trigonocarpus are unique to the Carretera site, while Coatepec is characterized by the presence of cf. Bjuvia, Schizoneura, and Velascophyllum. When analyzing the greatest ranges of the paleoflora awareness for the Carretera site indicates that deposition of these beds took place in a time interval that may span between Pennsylvanian and lower Permian. On the other side, the floral assemblage recovered from the Coatepec site indicates that the hosting beds were deposited in upper Permian time. U–Pb detrital zircon geochronology indicates that the maximum depositional age of the fossiliferous beds at the Carretera and Coatepec sites are of 276 ± 15 Ma and 254 ± 11 Ma, respectively. The integration of the paleontological and geochronological data obtained in this work suggests that the analyzed floral assemblage recovered from the Carretera site is of Kungurian age, whereas the one from the Coatepec site is of Lopingian age. Alternatively, we explore the possibility that deposits that are presently grouped within the Matzitzi Formation could be the vestiges of different fluvial cycles associated with different tectonic settings. Finally, the work on this unit has not finished, since there are still localities where its flora and age are still unknown.

An algorithm-guided Ediacaran global composite δ13Ccarb–Bayesian age model

While it remains uncertain whether excursions in the stable carbon isotopic composition of Ediacaran marine carbonate (δ13Ccarb) represent globally synchronous events (or a direct measure of ocean carbon cycling), the absence of widely distributed and readily preservable fauna, and the presence of several iconic carbon isotope excursions (CIEs), has sustained δ13Ccarb correlation as the primary means to establish relative time relationships for Ediacaran successions. Here we present an Ediacaran global δ13Ccarb composite built with a dynamic time warping (DTW) time-normalization algorithm that generates libraries of least-squares alignments between chemostratigraphic records of unequal length and distinct sediment accumulation rates. When developing a δ13Ccarb composite for each of 16 globally distributed Ediacaran paleo-depositional regions, we selected high Pearson r alignments that conformed with published geological guidance about the correlation of constituent sections. When applying DTW to align these regional algorithmic composites into one global δ13Ccarb stack, we selected alignments that allied the excursions that field workers have established (or speculated) are the Marinoan cap carbonate excursion, the Shuram excursion, and/or the basal Cambrian excursion. There are strengths and weaknesses to making explicit the temporal relationships (point-to-point correspondences) often left implicit in visual correlation. One strength is to extrapolate depositional ages by means of isotopic correlation, and here we explored this with a Bayesian Markov chain Monte Carlo age model that predicts a median age, and uncertainty, for every carbonate stratum in the global Ediacaran δ13Ccarb composite. Yet, one must caution against a false accuracy that can arise from selecting one alignment among many possibilities––the likelihood that time-uncertain time series can be stretched and squeezed into one unequivocal alignment is low. Thus, while these alignments are grounded in the expert assessment of the field worker, this global Ediacaran δ13Ccarb–Bayesian age model should be viewed as a working hypothesis to enrich, but not arbitrate, discussions of the correlation, synchrony, and completeness of Ediacaran successions.

Detrital zircon U-Pb + Hf data supports 2.1 Ga extensional and 2.0 Ga syn-orogenic basin in southwest Rae Province during early Nuna assembly

This study examines the Paleoproterozoic history of supracrustal rocks in the western Canadian Shield to better inform the tectonic history of northern Laurentia. Samples for detrital zircon U-Pb geochronology and Hf isotopes were collected from the western Rae Province, Taltson magmatic zone, and the Great Slave Lake shear zone in order to assess depositional ages, provenance and geodynamic significance of the detrital systems. Samples from the western Rae Province were sourced locally and deposited after 2.1 Ga in a broadly extensional regime, based on widespread source terrane ages and few data near the maximum depositional age as well as coeval regional mafic magmatism and absence of coeval metamorphism. By contrast, the Taltson samples were deposited after 2.0 Ga, have a significant 2.2 to 2.0 Ga detrital source of relatively juvenile material, have young zircon that overlap in age with the Taltson and Thelon orogens, and yield a significant fraction of the dates that are close to the maximum depositional age. These Taltson samples were also derived from western Rae Province sources or Buffalo Head and Chinchaga domain sources and are interpreted to have formed in a contractional or collisional regime coeval with Taltson-Thelon orogeny. The 2.2 to 2.0 Ga detritus was likely derived from reworked ca. 2.3 Ga juvenile source. A sample from the Great Slave Lake shear zone was deposited after 2.0 Ga in a contractional/collisional regime and was sourced from Slave Province crust and Taltson-Thelon plutons. Our data support extension along the western Rae Province margin at ca. 2.1 Ga and distinct histories of the Rae and Slave Provinces prior to their collision at ca. 1.95 Ga. Before 2.1 Ga, the Rae Province may have been attached to the Slave, North China, Bastar, Dharwar, or Sinhghbum cratons.

Tonian rift successions in Newfoundland, Canada: a window to late tectonic events in the Mesoproterozoic Laurentian margin

Basement rocks in the Humber terrane of the Appalachian Orogen record the last stages in the history of the Mesoproterozoic Laurentian margin in Canada. These stages were revealed by recent work in the East Pond Metamorphic Suite on the western Baie Verte Peninsula, Newfoundland, where two Tonian bimodal volcaniclastic-sedimentary successions were recognized (Pine Pond successions). The older, ca. 980 Ma succession, contains detrital igneous zircon and titanite (ca. 1160–1057 Ma) presumably derived from the Mesoproterozoic Laurentian margin, while the younger, ca. 950 Ma succession, contains 980 Ma detrital igneous zircon and titanite. Although metamorphosed to eclogite facies during the assembly of the Appalachian Orogen, the successions preserve protolith features and geochemical data that indicate melt likely originated in an extensional setting. The new ages integrated with geochemical and Sm–Nd isotopic data suggest that the felsic volcaniclastic units of the Pine Pond successions are related to 975–950 Ma granitic plutons in the Pinware terrane of the eastern Grenville Province in southeastern Labrador. These new data solidify a previous interpretation that the Pine Pond successions were deposited at the continental apex of the Asgard Sea and that the Pinware terrane intrusions are a part of this event. Furthermore, these new Tonian ages for rift-related strata call into question the interpretation of Ediacaran depositional ages for clastic sequences in the northern Appalachian Orogen, with youngest detrital zircons that are Tonian, and show that the tectonic evolution of the Mesoproterozoic Laurentian margin in Canada is more complex than previously known.

Genesis of Hongqiling Sn-W polymetallic deposit in Dongpo ore concentration field, southern Hunan: Evidences from U-Pb chronology and trace element geochemistry of cassiterite

Hongqiling deposit is one of the most typical hydrothermal vein type Sn-W polymetallic deposits in the Dongpo ore field, southern Hunan. It is an ideal object to study the Sn-W mineralization in the Nanling metallogenic belt and even in the whole South China Block, and to reveal the regional metallogenetic regularity. Based on the detailed investigation of the deposit geology, this paper discusses the mineralization age and processes of the Hongqiling hydrothermal vein type Sn-W polymetallic deposit by LA-MC-ICP-MS in-situ U-Pb dating and trace element geochemistry of cassiterite from the quartz vein type Sn-W ore body. Cathodoluminescence (CL) imaging shows that cassiterite in Hongqiling deposit can be divided into two generations.primary cassiterite (Cst-I) and altered cassiterite (Cst-II). The LA-MC-ICP-MS in-situ U-Pb age of the two groups of Cst-I samples are 158.9 ± 0.7 Ma and 158.4 ± 0.8 Ma, respectively, which are well consistent with the mineralization ages of most Sn-W deposits in the Nanling metallogenic belt, and are also consistent with the ages of middle to late Jurassic magmatic activity represented by the Qianlishan intrusion. This indicates that the Hongqiling deposit, like many Sn-W deposits in the Nanling metallogenic belt, is genetically related to the regional Middle to Late Jurassic granitic magmatic activities. LA-ICP-MS trace element analysis shows that trace elements such as Na and Cs are mainly distributed in fluid inclusions in cassiterite, while the major elements such as Mg, Al, and Si are mainly distributed in the mineral inclusions, and other elements such as W, U, Zr, Hf and Ti are mainly distributed in the cassiterite by isomorphic substitution. The high Fe and W contents in both primary and altered cassiterite indicate that the ore-forming fluid of Hongqiling deposit is mainly derived from granitic magma. The fluctuating variation of Fe, V, Sc, Ti, Zr, Hf, Nb and Ta in the primary cassiterite with the crystalline bands indicates that there are two large-scale pulses of magmatic hydrothermal fluid during the mineralization process, while the altered cassiterite is relatively depleted of Ti, Sc, Zr and U elements, and enriched in Pb which may represent the compositional characteristics of the late-stage fluid. In summary, the Hongqiling hydrothermal vein type Sn-W polymetallic deposit was formed by the pulsating exsolution of magmatic hydrothermal fluid of late Jurassic granitic magmatism. The trace elemental compositions of primary cassiterite are generally controlled by the compositions of ore-forming fluid and the rate of crystallization.

Characterization and Timing of Mineralization in the Garrison Gold District, Southern Abitibi Greenstone Belt, Canada

Abstract The decrease in gold discoveries is affecting the deployment of new technology and the general society demand, demonstrating the need for new gold exploration approaches. To date, gold exploration remains primarily focused in areas near well-known large gold districts. We demonstrate the potential for new discoveries and significant resource expansion in the Abitibi greenstone belt distal from the giant gold districts across the belt. Unlocking of additional resources in the Garrison district was accomplished by identification of zones of compentency contrast, which resulted in a variety of locally complex and unrecognized structural traps receptive to gold. Our approach is applicable to other little-explored areas in the Abitibi greenstone belt and other orogenic belts worldwide. The Garrison district, situated in the southern part of the Abitibi greenstone belt in the Superior province, lies along an ~3-km NE-trending segment of the gold-rich, Archean Porcupine-Destor deformation zone. The district contains several discoveries, which include the Buffonta deposit hosted in mafic volcanic rocks, the syenite-hosted 903 deposit, and the albitite dike-hosted Jonpol deposit. These deposits occur along high-strain zones developed in embayments and elongate, NE-trending domains of talc-chlorite-serpentine–altered ultramafic rocks, which localized strands and splays of the Porcupine-Destor deformation zone. In addition, the Garrcon deposit comprises northerly-trending gold-bearing quartz veins and lamprophyre dike swarms hosted in sedimentary host rocks that are bounded by high-strain zones. The intrusive rocks in all of these deposits were emplaced prior to gold deposition. They provided a competent substrate in areas of heterogeneous strain that localized gold mineralization. Initial alteration made the surrounding volcanic and sedimentary rocks also rheologically competent. This resulted in enhanced hydrofracturing and the formation of paragenetically late gold-bearing quartz veins. Widespread albite-pyrite-carbonate alteration in all of the gold deposits temporally overlapped with gold mineralization. New U-Pb zircon geochronology data reveal that ~2719 to 2712 Ma volcanism was followed by granitic magmatism and emplacement of a series of ~2683 to 2672 Ma dikes. One Re-Os analysis of a synmineralization molybdenite sample indicates that orogenic gold was deposited at 2671 ± 12 Ma. This is comparable to published ages of major orogenic gold deposits throughout the southern part of the Abitibi greenstone belt, indicating a broadly synchronous principal gold event across the belt.