Sediment Flux Research Articles

Comprehensive evaluation of the distribution, transport and ecological risk of heavy metals in intra-urban river sediments using high-resolution techniques

Determining the distribution trends, transport mechanisms, and ecological risks of heavy metals (HMs) in urban river sediments is essential for the government to conduct appropriate remediation work. In this study, we collected sediment cores from the Yayao Waterway in Foshan City, China. The vertical distribution profiles of dissolved and labile Fe, Mn, Cd, Zn, Cu, Cr, Ni, Pb, As, and Co in the sediments were obtained using the thin-film diffusive gradient (DGT) and high-resolution peeper (HR-Peeper) techniques. In addition, the transport rates, contamination levels, and ecological concerns of the HMs were evaluated using the European Community Bureau of Reference (BCR) sequential extraction technique, the DGT-induced sediment fluxes (DIFS) model, and multiple contamination evaluation metrics. The results showed that most of the DGT-labile HMs were associated with Fe/Mn (hydrogen) oxides, and in particular, Zn, Ni, and Cr showed a significant negative correlation with Fe/Mn (p < 0.001). Additionally, Cd had the highest bioavailability (89.17%), and its net diffusive flux at the sediment–water interface (SWI) was positive, which indicated a high release risk from the sediment. However, the R-value of Cd based on the DGT-induced sediment fluxes (DIFS) operation was extremely low, suggesting that although Cd had the biggest supply pool of releases, its release rate was slow. The majority of sampling sites had significantly higher total HM contents in the surface sediments than the background values. The HM contamination in the sediments originated from human activities, primarily from industrial enterprises and with a large contribution from both agricultural and domestic sources. The most polluted HM with the highest ecological danger was Cd, followed by Cu, Zn, Ni, and As when the results of the four pollution evaluation indicators were combined. Consequently, the risk of contamination by HMs in inner-city river sediments should receive more attention.

Amino acids in the water-soluble and water-insoluble fractions of the aerosols at a forested site in Japan

In order to clarify the concentration levels and sources of the water-insoluble amino acids (WIAA) in aerosols that have been received little attention in previous studies and to discuss their potential impact on nitrogen deposition, the WIAA in the coarse-mode (d = 2.0–10 μm) and fine-mode (d < 2.0 μm) aerosols were measured at a forested site in Japan together with the water-soluble free and combined amino acids. The sum of the WIAA showed more than a 6-times higher concentration than that of the water-soluble amino acids in the coarse-mode range and a similar concentration to that in the fine-mode range, which suggests a significant contribution of the WIAA to the amino acids pool in aerosols. The WIAA were predominantly partitioned into the coarse-mode range. The concentration of the coarse-mode WIAA was the highest in the summer and a strong correlation was found between the coarse-mode WIAA and nss-K+ concentrations. These results suggest that plant debris and the associated materials are important sources for the coarse-mode WIAA and the increase in the suspension of these particulate materials caused the enhancement of the WIAA in the summer. Remarkably higher concentrations of the coarse-mode WIAA than the water-soluble amino acids would be caused by these particulate materials. In the fine-mode range, on the other hand, the concentration of the WIAA was the highest in the spring and strongly correlated with the fine-mode nss-K+ concentrations. The fine-mode WIAA would be mainly derived from the biomass burning particles. The coarse-mode WIAA were estimated to significantly contribute to the dry deposition flux of the total nitrogen. The present study implies a potential impact of the WIAA in the coarse aerosols on nitrogen deposition.

Dry deposition fluxes, source, and potential ecological impact of amino acids in the Danjiangkou Reservoir of China's South-to-North water transfer project

As a nitrogen source for biological growth, amino compounds can participate in global nitrogen cycle processes and directly impact ecosystems. Dry deposition samples were collected from September 2020 to August 2021 from the Danjiangkou Reservoir of the South-to-North Water Transfer Project. The dry deposition characteristics of amino acids in the reservoir area were analyzed, their sources were resolved, and the potential ecological impacts were evaluated. The results showed that the dry deposition flux of dissolved free amino acids was 0.48 kg N ha−1 yr−1 and that of dissolved combined amino acids was 1.09 kg N ha−1 yr−1 in Danjiangkou Reservoir. The dominant amino acid fractions were glutamic acid and aspartic acid. Agricultural activities, coal combustion, and primary biogenic particles influenced the amino acid deposition in the reservoir area. The potential source areas for amino acid deposition mainly influenced the northeast, southwest, northwest, and south of the reservoir. The amounts of amino acids entering the water bodies via dry deposition was 85.72 t N yr−1, contributing 0.83 g C m−2 yr−1 of new production to the reservoir water bodies. To summarize, this research depicted that the potential ecological impact of dry deposition of amino acids on artificial freshwater lakes should not be overlooked.

Atmospheric deposition patterns in bulk open field precipitation and throughfall in Aleppo pine forest and black pine forest on the eastern Adriatic coast

The Mediterranean region, with its unique ecological characteristics, is particularly sensitive to global environmental changes, including climate change and impact of air pollution.Although Aleppo pine and black pine forests are the most abundant on the eastern Adriatic coast, atmospheric deposition in these forests is poorly studied. Changes in the chemical composition of precipitation as it passes through the tree canopy can lead to soil and groundwater eutrophication, and soil acidification, which affects plant vitality. In this study, the dynamics of ion deposition in Aleppo pine forest (Pinus halepensis Mill.) and black pine forest (Pinus nigra Arnold) on the eastern Adriatic coast are investigated, focusing on throughfall and bulk open field depositions.The aim of our research was to fill the gaps in understanding the influence of tree canopies on deposition fluxes in two different Mediterranean pine stands and to compare total inorganic nitrogen loads with critical loads. Over a period of two years, bulk open field precipitation and throughfall were sampled, measured and analysed using the ICP Forest methodology.The results indicate significant differences in ion deposition between bulk open field and throughfall, with throughfall showing higher values for almost all ions. The highest enrichment ratio was determined for K+. The comparison of the actual inorganic nitrogen load with the critical nitrogen load for Mediterranean pine forests revealed that the inorganic nitrogen load exceeded the critical load in the Aleppo pine forest. Ion deposition increased in the throughfall compared to bulk precipitation, which can be attributed to the seasonality of precipitation, including leaching and long dry periods. These findings enhance our understanding of ion deposition fluxes in vulnerable Mediterranean pine ecosystems and emphasize the need for long-term research on this topic in the actual changing environmental conditions.

Effect of turbulent mixing on the formation of intermediate nepheloid layer over the northern continental slope of the Andaman sea

An intermediate nepheloid layer (INL) serves as an important conduit for the cross-slope transport of particulate matter, including organic carbon, biological nutrients and other lithogenic minerals. Despite extensive reports on the substantial sediment influx from the Ayeyarwady River into the northern continental slope of the Andaman Sea (AS), the transport route and fate of these river-borne sediments remain poorly understood, due to lack of in situ observations of turbid INL over the slope. In this study, we present direct evidence of an INL over the northern continental slope of the AS during the winter of 2019/2020, accompanied by enhanced mid-water turbulent mixing. Mooring measurements reveal energetic internal tides with high-mode vertical structure in the study region; and beam-like structures of internal tides are observed, which could be responsible for the enhanced mid-water turbulent mixing coinciding with the INL. Moreover, available microstructure profiles reveal energetic turbulent mixing with bottom-intensified turbulent diffusivity over the study area. Numerical experiments suggest that inhomogeneous distribution of turbulent mixing over the continental slope could induce local convergence of the upwelling transport in the upslope direction, resulting in an intrusion from the boundary to the interior and consequently promoting the INL formation. The discovery of the INL and its mixing-driven generation mechanism provide new insights into sediment transport dynamics over the northern continental slope of the AS.

Surface-air exchanges of H2S and SO2 in an urban wetland in eastern China

Wetlands are widely recognized as hot spots for the emission or deposition of biogenic sulfur gases, including hydrogen sulfur (H2S) and sulfur dioxide (SO2), which significantly affect air quality and climate change. With the expansion of urban wetlands, it is critical to know the roles that urban wetlands played in atmospheric H2S and SO2 budget. In this study, the surface-air exchange fluxes of H2S and SO2 were measured by the Dynamic Flux Chamber (DFC) method in a typical urban wetland in eastern China from Sep 2022 to July 2023. It was found that the urban wetland did not have the expected high H2S emission, might be caused by the relatively high pH value and low sulfate concentration in the soil. Although H2S showed emission in the daytime of spring and summer, an overall H2S flux of −0.04 kg S ha−1 yr−1 was observed throughout the year. Meanwhile, the urban wetland presented a net sink of SO2, with a deposition flux of 0.14 kg S ha−1 yr−1. The negative peaks of SO2 flux corresponded to the suddenly elevated SO2 concentration in the ambient air especially in spring and winter. Through linear fitting of SO2 flux and concentration, the concept of SO2 “compensation point” was proposed. The compensation point is the concentration level at which the observed SO2 flux equals zero. The “compensation point” changed with the season and was related to temperature and humidity. The “compensation point” in summer and autumn were larger, being 2.37 ppb and 1.40 ppb, respectively, while they were 1.07 ppb and 0.86 ppb in spring and winter respectively. Our results suggest that the urban wetland expansion may have little risk of increasing air H2S but could act as a significant sink of SO2 with high SO2 concentration in the urban region.

Lithiation: A Pathway to Strengthen Sodiophilic Metal Interlayer of 3D Metallic Skeleton for High-Performance Sodium Metal Anodes.

Constructing a three-dimensional (3D) skeleton with a sodiophilic-modified layer (SML) has been proven to be an effective strategy to alleviate excessive volumetric deformation and continuous dendrite growth for sodium (Na) metal anodes. However, the weak binding force and violent reaction between the SML and the 3D skeleton lead to numerous cracks/defects and even pulverization of the SML during repeated Na plating/stripping. Herein, a lithiation pathway is presented to construct a sodiophilic Li-Sn alloy layer onto a 3D copper mesh to strengthen the SML for stable Na metal anodes. The lithiation 3D skeleton exhibits superior sodiophilicity, higher charge-transfer efficiency, and lower ion-diffusion barrier, contributing to the homogenization of ion-electronic flux and Na deposition. Simultaneously, the dense Li-Sn alloy is more stable than the monometal Sn-layer, which effectively prevents damage to the SML and enhances the stability of the SML. As a result, the asymmetrical cell exhibits great performance with a negligible nucleation overpotential and a high average Coulombic efficiency of 99.4%. Moreover, the full cell assembled with Na3V2(PO4)3 cathode delivers superior capacity retention of 91.3% after 1000 cycles at a current of 3C.

Wet depositional fluxes of fossil fuel-derived carbon in East Asia: Dynamics of Brown carbon

Over the past 50 years, fossil fuel consumption has increased dramatically, rising approximately eight-fold since 1950 and doubling since 1980. This surge has led to increased emissions of brown carbon (BrC) into the atmosphere, which are subsequently deposited onto oceans and land through dry or wet deposition processes. However, the source-specific fluxes of atmospheric organic carbon (OC) and BrC into the ocean are not adequately represented in the global carbon cycle. For the first time, we calculated BrC concentration using the optical intensity of organic matter and determined the global wet depositional flux of fossil fuel-derived BrC. Using the ratio of humic-like substances to OC fluxes, we estimated the global wet deposition of fossil fuel-derived BrC to be 2.0 ± 0.6 Tg C yr−1. Of this amount, the flux into oceans (0.7 ± 0.2 Tg C yr−1) represents 1.6% of the production rate of refractory dissolved organic carbon (RDOC) in the ocean (43 Tg yr−1). Notably, an increase in the proportion of fossil fuel-derived BrC in atmospheric OC may change the composition of OC in precipitation, resulting in a more refractory composition, which deviates from previously established paradigms. Our findings indicate that the flux of fossil fuel-derived RDOC from the atmosphere into the ocean, which is inadequately represented in current global DOC cycling models, may play a significant role in oceanic carbon cycles. These findings necessitate reconsidering our understanding of oceanic carbon cycling and highlight the need to improve existing models to better account for these newly identified processes and their potential impacts on global carbon dynamics.

Evidence for littoral convergence and sediment delivery to Mattole submarine canyon, Northern California

At geologic timescales, a significant proportion of the sediment eroded from continents is transferred from rivers to littoral cells, then through submarine canyons to deep ocean basins. Accumulation and occasional discharge of sediment from canyon headwall regions is a likely driver for the sediment gravity flows believed to be responsible for much of this mass transport, but the responsible mechanisms and event timescales in canyon heads are imprecisely defined, largely due to the drowning of canyon heads since the last glaciation and the resulting dearth of modern depositional environments to observe. We investigated a littoral cell adjacent to Mattole submarine canyon in Northern California to better understand the influence of bathymetry and coast shape on sediment trajectories and hypothesize that canyon heads promote littoral sediment accumulation due to bathymetric sheltering of the adjacent coast from waves and convergence of littoral cells exposed to varying wave direction. The uppermost gullies of Mattole Canyon extend to the littoral cell, and a train of sediment waves within the uppermost thalweg of Mattole Canyon suggests that gravity-driven flows of shore-derived sediment may have recently occurred. Mattole Canyon and nearby Mendocino Canyon flow into the deep Mendocino Channel, which has the highest observed Late Holocene sediment accumulation rates in Northern California. We documented the beach slope, grain size, and sediment provenance along 15 km of coast adjacent to Mattole Canyon and conducted numerical wave modeling to infer the dominant direction and magnitude of sediment transport, relative wave sheltering by bathymetry, and estimated sediment mobility in the vicinity of the canyon head over a multi-year period. South of the canyon headwall, in the vicinity of the Mattole River outlet, coarser sediment rich in metasandstone clasts and steeper beach slopes coincide with decadal-scale beach accretion. North of the canyon head, sediments are generally finer, beaches are flatter, clast lithologies include more quartz and mudstone grains, and there is decadal-scale net erosion. Wave modeling suggests the Mattole headwall region is subject to sustained sheltering from waves due to canyon bathymetry, littoral sediment convergence above the canyon head for much of a typical year, and occasional bed entrainment of sediment in the canyon’s uppermost gullies by large waves. Larger winter waves from the northwest likely result in net southerly drift north of the canyon head, with a high likelihood of preferentially transporting fine-grained, more quartz-rich sediment towards the Mattole headwall. Smaller summer swells from the west and south likely results in net northerly transport of metasandstone clast-rich Mattole River-derived sediment towards the canyon head. The imbalance in seasonality in wave conditions, coast shape, and sediment delivery by the Mattole River and other coastal creeks is broadly consistent with the spatial patterns in grain size, mineralogy, slope, and beach width that we observe in the vicinity of the canyon, and the net delivery of sediment to the Mattole Canyon head. An approximate mass balance of sediment flux from coastal streams feeding Mattole River littoral cell suggests that sediment volumes likely accumulate in the canyon headwall region that could supply several density flow events in a typical decade. These findings highlight the importance of the connectivity of the canyon to the nearshore region for the processes and products in canyons and fans. We hypothesize that feedbacks between canyon bathymetry, sediment accumulation, and mass evacuating flows promotes the long-term persistence of canyon systems.

Sourcing and long-range transport of particulate organic matter in river bedload: Río Bermejo, Argentina

Abstract. Fluvial transport of organic carbon from the terrestrial biosphere to the oceans is an important term in the global carbon cycle. Traditionally, the long-term burial flux of fluvial particulate organic carbon (POC) is estimated using river suspended sediment flux; however, organic carbon can also travel in river bedload as coarse particulate organic matter (POMBed). Estimates of fluvial POC export to the ocean are highly uncertain because few studies document POMbed sources, flux, and evolution during long-range fluvial transport from uplands to ocean basins. This knowledge gap limits our ability to determine the global terrestrial organic carbon burial flux. In this study we investigate the flux, sources, and transformations of POMBed during fluvial transport over a ∼1300 km long reach of the Río Bermejo, Argentina, which has no tributary inputs. To constrain sourcing of POMBed, we analyzed the composition and stable hydrogen and carbon isotope ratios (δ2H, δ13C) of plant wax biomarkers from POMBed at six locations along the Río Bermejo and compared this to samples of suspended sediment, soil, leaf litter, and floating organic debris (POMfloat) from both the lowland and headwater river system. Across all samples, we found no discernible differences in n-alkane average chain length or nC29 δ13C, indicting a common origin for all sampled POMBed. Leaf litter and POMfloat nC29 δ2H values decrease with elevation, making it a useful proxy for POMBed source elevation. Biomarker δ2H values suggest that POMBed is a mix of distally derived headwater and locally recruited floodplain sources at all sampling locations. These results indicate that POMBed can be preserved during transport through lowland rivers for hundreds of kilometers. However, the POMBed flux decreases with increasing transport distance, suggesting mechanical comminution of these coarse organic particles and progressive transfer into the suspended load. Our provisional estimates suggest that the carbon flux from POMBed comprises less than 1 % of the suspended load POC flux in the Río Bermejo. While this represents a small portion of the river POC flux, this coarse, high-density material likely has a higher probability of deposition and burial in sedimentary basins, potentially allowing it to be more effective in long-term CO2 drawdown relative to fine suspended particles. Because the rate and ratio of POMBed transport versus comminution likely vary across tectonic and climatic settings, additional research is needed to determine the importance of POMBed in the global carbon cycle.

Spatial Variation of Asymmetry in Velocity and Sediment Flux along the Artificial Aam Tidal Channel

Tidal flats, crucial for biodiversity and ecosystem services, are facing significant alterations due to human activities such as reclamation. In South Korea, over 65% of tidal flats have been reclaimed since the 1970s, resulting in morphological changes and altered sediment transport dynamics. This study investigates sediment transport processes in the artificial Aam tidal channel, created as part of the megacity development project in Incheon, Korea. Using data from Acoustic Doppler Current Profiler and Vector instruments deployed in 2019 and 2021, we analyzed tidal asymmetry, current velocities, shear stress, and suspended sediment concentration. Our results reveal a pronounced tidal asymmetry influencing sediment transport, with ebb-dominant currents near the channel entrance and flood-dominant currents in the interior. We observed significant sediment deposition in the landward section of the channel, driven by tidal mixing asymmetry and rainfall events. These findings highlight the complex interactions between artificial structures and natural sediment dynamics, informing future coastal development and management strategies.

Substantial Overestimation of Terrestrial Water Storage Loss in Headwater Basins on Earth's Third Pole

AbstractThe Tibetan Plateau (TP) is suffering from a substantial decline in terrestrial water storage (TWS) in exorheic basins, threatening water resources that are critical for ∼2 billion people downstream. TWS changes are commonly estimated using gravity satellites through observations of the total terrestrial mass storage (TMS) change, with an implicit assumption of a negligible contribution from sediment transport. Through long‐term (2002–2017) sediment flux observations in seven headwater basins on the TP, we reveal that the gravity satellite‐derived TMS has decreased at a rate of 3.85 ± 0.23 Gt yr−1 in the seven basins, of which 0.35 ± 0.04 Gt yr−1 is contributed by sediment transport. Neglecting this contribution leads to an overestimation of the TWS loss by 10.1 ± 1.3%, equivalent to the annual water demand of an additional 0.62 million people in the surrounding nations. Regionally, the overestimation is surprisingly high in the Indus River and Yarkant River basins, reaching up to 50.8%–77.6%.

Multi-objective Identification Method for Influencing Factors of Soil Heavy Metal Content Change

Identifying the influencing factors of soil heavy metal content changes is the basis for reducing or preventing soil heavy metal pollution. Taking an agricultural experimental field in Changping District of Beijing as an example, the heavy metal content changes in As, Cr, Cu, Ni, Pb, and Zn from 2012 to 2022 were firstly analyzed. Secondly, the influencing factors of the heavy metal content changes were detected based on the geographical detector at the single-target and multi-target levels, respectively. Finally, comparative experiments with the correlation analysis method and existing studies were set up to evaluate the effectiveness of the identification method of influencing factors developed in this study. The results showed that human activity factors have exacerbated the changes in soil heavy metal content in the study area as follows： ① At the single-target level, the land use type was the main influencing factor on the changes in Cr, Cu, and Zn contents, and the annual deposition flux influenced the changes in As. The results of the interaction detection showed that there was an enhancement effect among the factors, and the interaction of the human activity factors dominated for the factor identification. ② The results of the multi-target level detection covered the results of the single-target level detection, which could identify more influencing factors. The land use type affected the changes in Cu, Zn, Cr, Ni, and As, and the changes in As and Zn were influenced by the annual deposition fluxes. ③ The multi-target identification method coupled with geographical detector and principal component analysis could effectively identify the influencing factors of soil heavy metal content changes, which was much more effective than the single soil heavy metal correlation method. The developed multi-target identification method for influencing factors of heavy metal content changes can provide technical support for the regional pollution monitoring and macro-management of soil heavy metals.

Multi-time Scale Variation of Atmospheric Ammonia Concentration and Dry Deposition in a Paddy Rice Region in Subtropical China

Meteorological factors and anthropogenic activities significantly affect atmospheric ammonia （NH3） concentration and its dry deposition. Former studies have examined the spatial and temporal variability in atmospheric NH3 concentrations at monthly scales. However, the characteristics of atmospheric concentrations at finer time scales such as hourly and daily scales and the influencing factors remain unclear. In this study, atmospheric NH3 concentration and related meteorological factors were continuously monitored online for one year in a double cropping rice region in subtropical China, and atmospheric NH3 concentration and its meteorological influencing factors as well as dry deposition were analyzed at different time scales （hourly, daily, and monthly）. The main results were as follows： The annual average daily concentration of NH3 in the rice area varied from 0.01 to 58.0 μg·m-3 （in N, same below）, and the annual average concentration was 5.3 μg·m-3. On the hourly scale, the 24-hour dynamics of atmospheric NH3 concentration showed a unimodal pattern, and the time of the NH3 peak appearance in different seasons was different； the time of the peak that appeared in winter lagged behind that in the other seasons. From the perspective of daily scale, NH3 concentration was mainly affected by fertilization in the paddy fields, peaking at 1-3 days after fertilization and then gradually decreasing. On the monthly scale, NH3 concentration peaked at 12.8 μg·m-3 in July and was the lowest in October at 1.6 μg·m-3. On the hourly scale, NH3 concentration varied seasonally due to the influences of meteorological factors, mainly as follows： NH3 concentration showed significant positive correlations with air temperature and solar radiation in all four seasons and with wind speed in spring and summer, whereas it showed significant negative correlations with relative humidity except in winter. On the daily scale, NH3 concentration showed a significant positive correlation with air temperature, rainfall, and solar radiation, whereas it showed a significant negative correlation with relative humidity. On the monthly scale, no significant correlation existed between each meteorological factor and NH3 concentration. The annual dry deposition flux （in N） calculated from the hourly average NH3 concentration was 8.5 kg·（hm2·a）-1, which was 11.6% higher than the annual flux calculated from the daily average and 12.4% higher than the annual flux calculated from the monthly average. In summary, there were significant daily and seasonal variations in atmospheric NH3 concentration in the paddy rice region in subtropical China, and conducting hourly-scale observations of NH3 concentration can help to reveal the multi-time scale variations in NH3 concentration and to quantify NH3 dry deposition more accurately.

Precipitation Control on Weathering Intensity and Depositional Flux of Meteoric 10Be Revealed From Soil Profiles Along a Climate Gradient (Chile)

AbstractAlong a climate gradient in the Chilean coastal mountains, we investigated denudation rates using the meteoric cosmogenic nuclide 10Be and its ratio to stable 9Be, and chemical depletion fractions (CDFs) in bulk soil samples. We find that the fraction of 9Be released from bedrock is a sensitive indicator of weathering, similar to CDF. Meteoric 10Be decreases exponentially with depth, reflecting the reactive nature of this tracer. We also measured denudation rates by the well‐understood in situ cosmogenic 10Be system on quartz. Assuming that both systems record the same denudation rate we calculated the depositional flux of meteoric 10Be for each study site. The flux agrees to that derived from atmospheric models in the mediterranean and humid areas. In contrast, in the arid and semi‐arid areas, the calculated flux agrees with a precipitation‐derived flux, indicating delivery of 10Be to be affected by small‐scale climatic variations not reflected by current atmospheric models.

Reconciling Rapid Glacial Erosion and Steady Basin Accumulation Rates in the Late Cenozoic Through the Effect of Glacial Sediment on Fluvial Erosion

AbstractThe onset of glaciation in the late Cenozoic caused rapid bedrock erosion above the snowline; however, whether the influx of eroded sediment is recorded in continental weathering and basin accumulation rates is an ongoing debate. We propose that the transport of glacially eroded bedrock through the fluvial system damps the signal of rapid headwater erosion and results in steady basin‐integrated sediment flux. Using a numerical model with integrated glacial and fluvial erosion, we find that headwater bedrock erosion rates increase rapidly at the onset of glaciation and continue to fluctuate with climatic oscillation. However, bedrock erosion rates decrease in the downstream fluvial system because larger grain sizes from glaciers result in an increase in sediment cover effect. When erosion and sediment flux rates are averaged, long‐term sediment flux is similar to nonglacial flux values, while localized bedrock erosion rates in the glaciated landscape are elevated 2–4 times compared to nonglacial values. Our simulated values are consistent with field measurements of headwater bedrock erosion, and the pattern of sediment flux and fluvial erosion matches paraglacial theory and terrace aggradation records. Thus, we emphasize that the bedload produced from glacial erosion provides a missing link to reconcile late Cenozoic erosion records.

Mercury stocks in discontinuous permafrost and their mobilization by river migration in the Yukon River Basin

Abstract Rapid warming in the Arctic threatens to destabilize mercury (Hg) deposits contained within soils in permafrost regions. Yet current estimates of the amount of Hg in permafrost vary by ~4 times. Moreover, how Hg will be released to the environment as permafrost thaws remains poorly known, despite threats to water quality, human health, and the environment. Here we present new measurements of total mercury (THg) contents in discontinuous permafrost in the Yukon River Basin in Alaska. We collected riverbank and floodplain sediments from exposed banks and bars near the villages of Huslia and Beaver. Median THg contents were 49+13/-21 ng THg g sediment−1 and 39 +16 /-18 ng THg g sediment−1 for Huslia and Beaver, respectively (uncertainties as 15th and 85th percentiles). Corresponding THg:organic carbon ratios were 5.4+2 /-2.4 Gg THg Pg C-1 and 4.2+2.4 /-2.9 Gg THg Pg C-1. To constrain floodplain THg stocks, we combined measured THg contents with floodplain stratigraphy. Trends of THg increasing with smaller sediment size and calculated stocks in the upper 1 m and 3 m are similar to those suggested for this region by prior pan-Arctic studies. We combined THg stocks and river migration rates derived from remote sensing to estimate particulate THg erosional and depositional fluxes as river channels migrate across the floodplain. Results show similar fluxes within uncertainty into the river from erosion at both sites (95 +12 /-47 kg THg yr-1 and 26 +154/-13 kg THg yr-1 at Huslia and Beaver, respectively), but very different fluxes out of the river via deposition in aggrading bars (60 +40/-29 kg THg yr-1 and 10+5.3/-1.7 kg THg yr-1). Thus, a significant amount of THg is liberated from permafrost during bank erosion, while a variable but generally lesser portion is subsequently redeposited by migrating rivers.

Aggregate Cloud Particle Effects in Exoplanet Atmospheres

Aerosol opacity has emerged as a critical factor controlling transmission and emission spectra. We provide a simple guideline for the effects of aerosol morphology on opacity and residence time in the atmosphere, as it pertains to transit observations, particularly those with flat spectra due to high altitude aerosols. This framework can be used for understanding complex cloud and haze particle properties before getting into detailed microphysical modeling. We consider high altitude aerosols to be composed of large fluffy particles that can have large residence times in the atmosphere and influence the deposition of stellar flux and/or the emergence of thermal emission in a different way than compact droplet particles, as generally modeled to date for extrasolar planetary atmospheres. We demonstrate the important influence of aggregate particle porosity and composition on the extent of the wavelength independent regime. We also consider how such fluffy particles reach such high altitudes and conclude that the most likely scenario is their local production at high altitudes via UV bombardment and subsequent blanketing of the atmosphere, rather than some mechanism of lofting or transport from the lower atmosphere.

Numerical simulation of wind–snow flow on a roof considering time-varying snow phase boundaries

Large-span roofs can be damaged by uneven snow loads caused by snow drifting. To predict wind-induced snow loads more accurately, this paper proposes a numerical simulation method. The method considers the interaction of wind and snow, the changing characteristics of snow phase boundaries over time, and corrects for snow deposition and erosion flux. The effectiveness of the method was confirmed by simulating wind–snow flow on a three-centered cylindrical shell and comparing the results with wind tunnel measurements. The simulation considered different snowfall conditions and time-varying snow phase boundaries on a large-span shell-shaped roof. The study investigated the influence of snowfall conditions and dynamic changes in snow phase boundaries on snow cover distribution by comparing simulation results.

Evidence of Secondary Bedform Controls on River Dune Migration

AbstractIn rivers worldwide, multiple scales of dunes coexist. It is unknown how the larger, primary dunes interact with secondary bedforms that are superimposed. We test the hypothesis that streamwise variability in the sediment flux inferred from the downstream migration of secondary bedforms explains migration of the host dune, based on bathymetric data from a lowland, sand‐bedded river. Results indicate that transport estimated from secondary bedform migration increases along the host dune stoss, eroding the stoss slope. When the superimposed bedforms disintegrate at the primary lee slopes, results indicate that all sediment transport associated to secondary bedform migration is arrested in the lee of the host dune, explaining migration of the host dune. When secondary dunes persist however, only part of the sediments transport linked to secondary dunes contributes to the migration of the host dune. This study gives novel insight into the fundamental mechanisms controlling the kinematics of compound dunes.