Deposition Cycles Research Articles

Corrosion Resistance and In Vitro Biological Properties of TiO2 on MAO-Coated AZ31 Magnesium Alloy via ALD

The surface corrosion of magnesium alloys is effectively addressed currently by the creation of a micro-arc oxidation (MAO) ceramic layer. However, oxide film porousness restricts magnesium alloy use. Thus, this work used atomic layer deposition (ALD) to create a TiO2 coating on MAO-coated AZ31B magnesium alloy to plug micropores and increase corrosion resistance and biological characteristics. The samples were analyzed using SEM, EDS, XPS, and XRD to determine their surface appearance, chemical content, and microstructure. Micro-arc oxidation produced a 20 μm oxide coating. The TiO2 film reached 47.41 nm after 400 atomic layer deposition cycles. All corroded samples were tested for corrosion resistance using electrochemical and hydrogen evolution methods and examined for surface morphology. In vitro cell experiments examined biocompatibility. The results indicate that the TiO2 layer sealed the MAO coating’s micro-pores and micro-cracks, enhanced corrosion resistance, and preserved surface morphology following corrosion. The TiO2/MAO composite coating is more biocompatible than the substrate and MAO coating. This research proposes coating AZ31B magnesium alloy for bio-remediation to increase corrosion resistance and biocompatibility.

Reconstructing early sedimentation patterns of the lower Codó Formation (Early Cretaceous, NE Brazil): Evidence of marine influence and the onset of an alkaline hypersaline lake

The upper Aptian lower Codó Formation is an attractive stratigraphic unit within the Parnaíba and São Luís basins, northeastern Brazil, formed during the break-up of Western Gondwana. Located in a large sag basin, the formation records a dynamic depositional history of deltaic, lacustrine, and sabkha environments. This sedimentary evolution is reflected in a diverse lithological succession characterized by intermittent terrestrial input, episodic marine incursions, and restricted lacustrine phases culminating in sulfate evaporite precipitation. While the later stages of the formation have been extensively studied, the initial sedimentary processes and environmental conditions remain poorly understood. This research aims to reconstruct the depositional paleoenvironments during the initial stages of Codó sedimentation, elucidating the onset of the alkaline hypersaline lake environment and the earlier marine incursions in the study region. To achieve this, it was conducted a high-resolution facies analysis using core descriptions, trace fossil analysis, petrography, various types of X-ray fluorescence, scanning electron microscopy, X-ray diffractometry, and isotope analyses (δ1³C, δ1⁸O, and ⁸⁷Sr/⁸⁶Sr) on a ∼63-m-thick succession from borehole 2-TV-1-MA. Thirteen facies were recognized and grouped into brackish lake, prodelta, delta front, and alkaline hypersaline lake facies successions. The lower Codó Formation exhibits cyclic sedimentation, indicating fluctuating water dynamics associated with shifts between open and closed drainage systems controlled by paleoclimate. Tectonic subsidence drove the basin's evolution from a brackish lacustrine-deltaic environment with an incipient marine influence (balanced-fill basin stage) to a restricted system with the establishment of an alkaline hypersaline lake (underfilled basin stage).

Room Temperature Synthesis of Tellurium by Solution Atomic Layer Deposition.

This study demonstrates the deposition of tellurium (Te) on silicon/silicon nitride substrates using solution atomic layer deposition (sALD) at ambient temperature. The process employs tellurium tetrachloride (TeCl4) and bis(triethylsilyl)-telluride ((TES)2Te) as precursors, with toluene as the solvent. Growth parameters were optimized through systematic variation of the pulse and purge times. Morphological characterization via scanning and transmission electron microscopy revealed needle-like crystallites, while X-ray diffractometry confirmed the crystalline nature of the deposited Te. Increasing the number of deposition cycles resulted in larger Te crystallites and enhanced substrate surface coverage. A thin amorphous carbon shell surrounding the crystallites and carbon inclusions was observed, likely originating from the organic solvent. X-ray photoemission spectroscopy analysis indicated high-purity Te films with minimal surface oxidation. The small chlorine signal suggested a near-complete precursor reaction and the efficient purging of byproducts. This novel sALD approach presents a promising method for depositing Te on various surfaces under mild conditions.

Motional Resistance as Highly Selective Descriptor to Probe Dynamic Formation of Surface Films on Zinc Anode

AbstractZinc anodes are expected as a promising alternative to lithium‐based anodes in energy storage systems due to their low cost, high theoretical capacity, and environmental friendliness. However, the development of efficient and stable zinc anode requires a fundamental understanding of the interfacial processes occurring during zinc deposition and dissolution cycling. In this study, we employed electrochemical quartz crystal microbalance (EQCM) analysis to investigate the potential‐dependent formation and decomposition of surface films on zinc metal anodes in sulfate‐based aqueous electrolytes. Changes in frequency and motional resistance served as complementary descriptors, with motional resistance being a highly selective indicator for probing dynamic surface film formation driven by side reactions at the zinc anode. While the frequency change provided the overall changes in the mass of both zinc metal and surface films, changes in the motional resistance selectively reflected the amount and nature of the visco‐elastic interface that comprise the surface films. The two descriptors provide quantitative and complementary means to discover the complex interfacial processes such as the formation of surface visco‐elastic films, guiding to the development of more stable and efficient zinc‐based electrochemical systems.

Synergetic effects of chlorinated paraffins and microplastics on microbial communities and nitrogen cycling in deep-sea cold seep sediments

Chlorinated paraffins (CPs) and microplastics (MPs) are commonly found in deep-sea cold seep sediments, where nitrogen cycling processes frequently occur. However, little is known about their combined effects on sedimentary microbial communities and nitrogen cycling in these environments. This study aimed to investigate the synergistic impacts of CPs and MPs on microbial communities and nitrogen cycling in deep-sea cold seep sediments through microcosm experiments. Our results demonstrated that the presence of CPs and MPs induced significant alterations in microbial community composition, promoting the growth of Halomonas. Furthermore, CPs and MPs were found to enhance nitrification, denitrification and anammox processes, which was evidenced by the higher abundance of genes associated with nitrification and denitrification, as well as increased activity of denitrification and anammox in the CPs and MPs-treatment groups compared to the control group. Additionally, the enhanced influence of CPs and MPs on denitrification was expected to promote nitrate-dependent and sulfate-dependent anaerobic oxidation of methane, thereby resulting in less methane released into the environment. These findings shed light on the potential consequences of simultaneous exposure to CPs and MPs on biogeochemical nitrogen cycling in deep-sea cold seep sediments.

The effect of seed layer cycles on the structural, optical, and morphological properties of ZnO nanorods.

In this study, ZnO seed layers with different cycles were formed on glass substrates by the sol-gel technique, and ZnO nanorods were grown on them by the hydrothermal method. Morphology and the structural characterization of the seed films and the ZnO nanorods are carried out by field emission scanning electron microscopy (FE-SEM) and x-ray diffraction techniques. In addition, to investigate the effect of seed layer deposition cycles on the optical properties of the ZnO nanorod arrays, UV/visible spectrophotometer and photoluminescence (PL) measurements were performed. The changes in structural and optical parameters such as dislocation density, strain, crystallite size, and optical band gap values on each seed layer deposition cycle were examined. The highest optical band gap and crystallite size were obtained for ZnO nanorods with 4 cycles seed layer as 3.22 eV and 63.6 nm, respectively. Also, in the PL spectrum, the largest ratio of UV-emission region to weak-visible emission region was obtained in ZnO nanorods having 4 cycles. In addition, the glucose detection properties of ZnO nanorods having 4 cycles were investigated using the PL measurements and it was found that UV-emission peak intensity of ZnO nanorods decreased as the glucose concentration increased from 8 to 40 mM. The results show that the number of deposition cycles of the seed layer has a strong influence on the orientation, crystal quality, and optical band gap of the growing ZnO nanorods, as well as significantly affecting their morphological properties. RESEARCH HIGHLIGHTS: High quality ZnO nanorods were grown on glass substrates by hydrothermal method. The effect of ZnO seed layer cycles on the structural, optical, and morphological characteristics of ZnO nanorods grown on were examined. It was found that the number of cycles of the seed layer is a critical parameter for growing quality and well-aligned ZnO nanorods.

New Insights on the Upper Triassic Silves Group in Algarve Basin, Portugal: Palynological, paleophytogeography and paleoclimatology advances

This paper presents the results of palynostratigraphic studies in the Silves Group in the Algarve Basin, Portugal. From bottom to top comprises the Silves Sandstones, the Silves Marl-Carbonate Evaporitic Complex, and the Volcano-Sedimentary Series. This study aims to detail the age of the Silves Group, bracketing the Triassic-Jurassic transition, using palynology. For this purpose, 250 samples were collected from 14 main sections. Previous results from a section above the Variscan unconformity, enabled to date the base of the Silves Sandstones and the onset of the Mesozoic sedimentary cycle in the Algarve Basin to lower Carnian. In this work, the top of the Silves Sandstones, containing Camerosporites secatus, Enzonalasporites vigens, Granuloperculatipollis rudis, Lagenella martinii, Patinasporites densus, Samaropollenites speciosus, and Vallasporites ignacii, is dated to the upper Carnian. The base of the Silves Marl-Carbonate Evaporitic Complex, consisting of Alisporites sp., Araucariacites australis, Classopollis meyerianus, Classopollis torosus, Paracirculina quadruplicis and Triadispora sp., indicates an upper Carnian age. The presence of Alisporites diaphanus, Araucariacites australis, Cerebropollenites macroverrucosus, Classopollis meyerianus, Classopollis torosus, Perinopollenites elatoides, Calamospora mesozoica, and Kraeuselisporites reissingeri allows to date the top of the Silves Marl-Carbonate Evaporitic Complex as upper Rhaetian-lower Hettangian. This study allows to date the Silves Group in the Algarve Basin from the lower Carnian to lower Hettangian (Triassic-Jurassic boundary) for the first time. The Carnian microflora provides new insights of the Onslow Microflora in the Western Tethys.

Aeolian sediments in western Mongolia: Distribution and (paleo)climatic implications

The largest dune fields in Mongolia are mainly restricted to the Basin of Great Lakes in western Mongolia. These dune fields extend from 800 m a.s.l. in the basins for 200 to 300 km into the mountains up to about 2100 m a.s.l. Analyses of these dune fields, using an integrative mapping approach, provide evidence for different wind regimes. The dune fields result from a long-term Quaternary sediment cycle. Rivers transported the sand into the basins from where the wind carried the sand eastwards along the dune fields with a concurrent loss of silt-sized particles. Different paleolake levels and sandy plains with mobilized sand at their western ends exist in the lake basins. The largest masses of dune sand are found in the central parts of the dune fields. Towards their eastern ends, lower and more vegetated dunes and sand sheets result from both the decrease in sediment supply and increased vegetation at higher elevations. Three climatic and paleoclimatic implications are derived from the mapping approach. A: Under the modern semi-arid to semi-humid climate, wind systems from north to the north-west prevail, whereas in the southern Mongolian Els also wind from the south-east occurs. B: The highest lake levels occurred during pluvial phases in the basins, caused by increased moisture supply, also due to water supply from glacier- and permafrost retreat. C: The fundamental west-east orientation of the dune fields is a result of westerly winds which were prevalent during arid periods.

Growth mechanism of HfO2 film on H-terminated Si (100) surface from atomic layer deposition process using tetrakis(ethylmethylamino)hafnium

The deposition of HfO2 on H-terminated Si (100) surfaces presents both interest and challenges due to the complexity of the surface reaction mechanisms. Previous experimental studies reported conflicting results regarding the formation of interfacial layers and the presence of incubation periods during the initial cycles of the HfO2 atomic layer deposition (ALD) process. In this study, we provide a detailed analysis of the surface reaction mechanism of HfO2 ALD on H-terminated Si (100) surfaces using tetrakis(ethylmethylamino)hafnium (TEMAH) and water. Our findings demonstrate that TEMAH chemisorbs onto the H-terminated Si (100) surface through the formation of two N-Si interfacial bonds. Additionally, the remaining ligands of the adsorbed Hf precursor are efficiently removed through hydroxylation during the water pulse, with low energy barriers of +25.9 to +30.0 kJ/mol. Furthermore, the N-Si interfacial bonds can be broken, allowing for the formation of Hf-O-Si interfacial bonds during either the water pulse or post-deposition processes. This work provides valuable insights into the surface reactions of HfO2 ALD and explains the varied interfacial bonding and incubation periods observed in prior studies.

The increasing influence of oyster farming on sedimentary organic matter in a semi-closed subtropical bay

Oyster farming activities play a pivotal role in the biogeochemical cycles of coastal marine ecosystems, particularly in terms of sedimentary carbon cycling. To gain deep insights into the influence of expanding oyster culture on the sedimentary carbon cycle, surface sediments were collected from the Maowei Sea, which is the largest oyster farming bay in south China, based on six filed surveys between July 2010 and December 2022. The sediment samples were analyzed for total organic carbon (TOC), total nitrogen (TN), stable carbon and nitrogen isotopes (δ13C and δ15N) to evaluate the inter-annual variations in the source contribution to sedimentary organic matter (SOM). The results revealed that the average contents of sedimentary TOC and TN were 0.67 ± 0.41 % and 0.06 ± 0.03 %, respectively. Fluctuations in the C/N molar ratios ranged from 5.8 to 23.6, with an average of 12.6 ± 2.9, indicating a significant terrestrial input contribution to SOM in the study area. Furthermore, the integration of stable isotope analysis and Bayesian mixing model demonstrated a gradual increase in the mean proportion of shellfish biodeposition to SOM, from 12.0 ± 5.6 % in July 2010 to 21.1 ± 7.3 % in December 2022, consistent with the progressive expansion of oyster aquaculture along this coastal area, thereby emphasizing the substantial influence of oyster farming on SOM composition. With the anticipated expansion of oyster farming scale and production in the future, shellfish biodeposition is expected to assume a more important role in shaping SOM dynamics and sedimentary organic carbon cycling in coastal waters. Overall, this study provided an important perspective for better assessing the impact of expanding mariculture scale on coastal biogeochemical cycles, thereby making valuable contributions to future policy formulation concerning mariculture and ecological conservation.

Cyclostratigraphy of late Cambrian marine sedimentary records and reconstruction of Earth-Moon system parameters

The Cambrian period is an important era in geological history, marked by numerous major geological and biological events. To better understand these events, it is important to establish a high-precision chronostratigraphic framework. An astronomical time scale can be created by the identified Milankovitch cycles in well-preserved stratigraphic successions. Duibian B section in Jiangshan (Zhejiang Province, China) is the global stratotype section and point (GSSP) for the Jiangshanian Stage, and this section provides well-preserved records covering the upper Paibian to lower Jiangshanian stages. In this study, we use high-resolution magnetic susceptibility record to conduct cyclostratigraphic analysis of the Duibian B section. Our results indicate that the 2.44 m, 0.84–0.73 m, 0.20–0.19 m, and 0.12–0.09 m sedimentary cycles may represent long-eccentricity, short-eccentricity, obliquity, and precession cycles, respectively. Using the stable 405-kyr eccentricity cycles, we constructed an ∼5.96 Myr floating astronomical time scale to calibrate agnostoid trilobite zones. In addition, we reconstructed the precession rate k from geological records, and our result provides an insight into the Earth-Moon distance and length of day in the late Cambrian (Paibian–Jiangshanian, ∼494.2 Ma). It enriches our understanding of the Earth-Moon evolutionary history in deep time.

A multi-step discharge/charge model of Li[sbnd]O2 batteries coupled with electrolyte decomposition and carbon electrode corrosion reactions

Electrolyte decomposition and electrode corrosion stand as two primary side reactions in lithium‑oxygen (LiO2) batteries during their discharge/charge cycles. In this work, a comprehensive LiO2 battery model combining multi-step lithium peroxide (Li2O2) formation, electrolyte decomposition, and electrode corrosion is proposed. Based on this model, the deposition behaviors and cycling performance of the LiO2 battery under deep discharge/charge cycles are investigated. The stop of discharge is mainly ascribed to the loss of active surface area for the battery using tetraethylene glycol dimethyl ether (TEGDME) electrolyte, while both O2 transport limitation and active surface area loss lead to the discharge termination for battery using dimethyl sulfoxide (DMSO) electrolyte. The incomplete decomposition of Li2O2 and lithium carbonate (Li2CO3) clogs electrode pores, leading to a continuous decline in the discharge capacity of the LiO2 battery. For the TEGDME-based battery, the undecomposed Li2CO3 gradually dominates the deposition with cycles, wherein electrode corrosion becomes the primary source of the undecomposed Li2CO3 after 3 cycles. For the DMSO-based battery, undecomposed Li2O2 is always a dominant trigger for battery discharge capacity degradation, although electrode corrosion remains a key contributor to Li2CO3 generation. Despite the DMSO-based battery exhibiting lower rates of electrolyte decomposition and electrode corrosion, it demonstrates poorer cyclic performance than the TEGDME-based battery due to the generation of more toroidal Li2O2. Moreover, when the charging cut-off voltage is reduced to 4.2 V, discharge capacity diminishes more rapidly due to the increased accumulation of undecomposed Li2O2, despite suppressed Li2CO3 deposition. Finally, the results confirm that thick electrodes lead to deteriorating cycling performance, stemming from increased discharge/charge overpotential and extended discharge/charge times, thus intensifying the side reactions.

The influence of bioturbator activity on sediment bacterial structure and function is moderated by environment

Bioturbation in coastal sediments plays a crucial role in biogeochemical cycling. However, a key knowledge gap is the extent to which bioturbation influences bacterial community diversity and ecosystem processes, such as nitrogen cycling. This study paired bacterial diversity, bioturbation activity and in situ flux measurements of oxygen and nitrogen from bioturbated sediments at six estuaries along the East coast of Australia. Bacterial community diversity, composition and predicted functional profiles were similar across burrow and surface sediments but were significantly influenced by bioturbator activity (measured as number of burrows) at sites with higher fine grain content. Sediment oxygen demand increased with bioturbator activity but changes in nitrogen cycling (as measured by fluxes and predicted bacterial functional gene analysis) were more spatially variable and were unrelated to bioturbator activity and bacterial community shifts. This study highlights how bioturbator activity influences bacterial community structure and functioning and what implications this has for biogeochemical cycles in estuarine sediments.

3D Microporosity Characterizations in the Heterogeneous Middle Jurassic Tuwaiq Mountain Formation: Insights into an Unconventional Sweet Spot.

Carbonate microporosity can vary significantly across depositional lithofacies and cycles, owing primarily to the high degree of heterogeneity in their pore sizes, pore throat radius, geometry, and connectivity. This is further compounded by the complex diagenetic alterations during various stages of burial. In addition, the presence of micropores, which are abundant in carbonate rocks, but not visible using conventional techniques, is challenging to characterize. To address this issue, our study focused on the Middle Jurassic Tuwaiq Mountain Formation (TMF) due to its importance as an analogue to subsurface conventional and unconventional reservoirs. Here, we utilized eight samples and performed pore network modeling to quantify microporosity distribution and connectivity from high-resolution microcomputed tomography images of different microfacies (MF) in the TMF from both mud- and grain-dominated facies. These results were then validated with petrographic, SEM images, and porosity-permeability measurements. Our study revealed that, in the high-energy, grain-supported microfacies of the shallow lagoon depositional cycle, micropores dominated by interparticle and microvug types were abundant and well-connected, with mean pore and throat sizes of 7 and 4 μm. Conversely, micropores within the low-energy mud-dominated microfacies of the deep lagoon depositional cycle dominated by intraparticle and intercrystalline types were isolated and rarely connected, even at the microscale (1-4 μm in diameter, with an average of 2 μm). This result suggests that pore connectivity at the microscale is not always related to matrix porosity, and the pore connectivity is present in submicron scale, which goes against common concepts in unconventional carbonate reservoirs. Furthermore, our observations indicate that primary depositional processes play a major role in controlling the distribution and connectivity of the Tuwaiq Mountain Formation's microporosity, while diagenetic processes only have minor controls. Our study emphasizes the importance of characterizing microporosity and its connectivity in heterogeneous carbonate rocks, which may reduce the uncertainty in exploring the properties of complex carbonate reservoirs worldwide.

Structural and stratigraphic history of the southern domain of the Indian Mountain Deformed Zone, southeastern New Brunswick, Canada: Tournaisian (Lower Carboniferous) tectonic ‘pop-up’ and collapse

The southern domain of the Indian Mountain Deformed Zone (IMDZ) in southeastern New Brunswick marks a major right-lateral strike-slip fault belt active during late Tournaisian (Lower Carboniferous) sedimentation. The rocks of the Sussex Group, representing a depositional cycle from subsidence to basin inversion, occupy this zone and lie unconformable on crystalline basement, the latter representing a partially exhumed portion of the adjacent (to the south) buried Westmorland uplift. Deformation is related to early reverse faults/thrusts, later strike-slip faults. and latest normal faults. The Gorge Fault zone in the southern domain of the IMDZ demonstrates many essential features of the entire zone. The offset of The Gorge Fault zone increases to the east. In the west it forms a blind thrust and asymmetric anticline whereas in the east it expands into a reverse fault/thrust complex. A progressive evolution from reverse faults/thrusts to strike-slip fault movement resulted in a tectonic pop-up, culminating in gravitational collapse along normal faults with listric profiles that flatten out within 100–200 metres of the present erosion surface. Megabreccias formed during deposition of the Sussex Group are contemporary with reverse fault/thrusts. The geometry of the various faults is best explained by progressive deformation within an overall right-lateral strike-slip regime under general shear, with early formed features rotating both congruently and incongruently to the main IMDZ boundaries. Further complexity is a consequence of many reverse faults/thrusts and normal faults occurring close to a free surface and the latter a response to gravitational instability of the pop-up structure controlled by topography. A revised stratigraphy for the Sussex Group in the Indian Mountain Deformed Zone and its interpretation is integral to constructing the structural history. Two units, Stilesville Formation and Briggs Cross Formation, are formally defined here.

Genesis and reservoir preservation mechanism of 10 000‐m ultradeep dolomite in Chinese craton basin

AbstractThe 10 000‐m ultradeep dolomite reservoir holds significant potential as a successor field for future oil and gas exploration in China's marine craton basin. However, major challenges such as the genesis of dolomite, the formation time of high‐quality reservoirs, and the preservation mechanism of reservoirs have always limited exploration decision‐making. This research systematically elaborates on the genesis and reservoir‐forming mechanisms of Sinian–Cambrian dolomite, discussing the ancient marine environment where microorganisms and dolomite develop, which controls the formation of large‐scale Precambrian–Cambrian dolomite. The periodic changes in Mg isotopes and sedimentary cycles show that the thick‐layered dolomite is the result of different dolomitization processes superimposed on a spatiotemporal scale. Lattice defects and dolomite embryos can promote dolomitization. By simulating the dissolution of typical calcite and dolomite crystal faces in different solution systems and calculating their molecular weights, the essence of heterogeneous dissolution and pore formation on typical calcite and dolomite crystal faces was revealed, and the mechanism of dolomitization was also demonstrated. The properties of calcite and dolomite (104)/(110) grain boundaries and their dissolution mechanism in carbonate solution were revealed, showing the limiting factors of the dolomitization process and the preservation mechanism of deep buried dolomite reservoirs. The in situ laser U‐Pb isotope dating technique has demonstrated the timing of dolomitization and pore formation in ancient carbonate rocks. This research also proposed that dolomitization occurred during the quasi‐contemporaneous or shallow‐burial periods within 50 Ma after deposition and pores formed during the quasi‐contemporaneous to the early diagenetic periods. And it was clear that the quasi‐contemporaneous dolomitization was the key period for reservoir formation. The systematic characterization of the spatial distribution of the deepest dolomite reservoirs in multiple sets of the Sinian and the Cambrian in the Chinese craton basins provides an important basis for the distribution prediction of large‐scale dolomite reservoirs. It clarifies the targets for oil and gas exploration at depths over 10 000 m. The research on dolomite in this study will greatly promote China's ultradeep oil and gas exploration and lead the Chinese petroleum industry into a new era of 10 000‐m deep oil exploration.

Effects of ALD Deposition Cycles of Al2O3 on the Morphology and Performance of FTO-Based Dye-Sensitized Solar Cells

In dye-sensitized solar cells (DSSCs), materials classified as Transparent Conducting Oxides (TCOs) have the capacity to conduct electricity and transmit light at the same time. Their exceptional blend of optical transparency and electrical conductivity makes them popular choices for transparent electrodes in DSSCs. Fluorine Tin Oxide (FTO) was utilized in this experiment. The optical and electrical characteristics of TCOs may be negatively impacted by their frequent exposure to hostile environments and potential for deterioration. TCOs are coated with passivating layers to increase their performance, stability, and defense against environmental elements including oxygen, moisture, and chemical pollutants. Because of its superior dielectric qualities, strong chemical stability, and suitability with TCO materials, aluminum oxide (Al2O3) was utilized as a passivating layer for the FTO. In this research work, Al2O3 was deposited via atomic layer deposition (ALD) to form thin mesoporous layers as a passivator in the photoanode (working electrode). The work focuses on finding an appropriate thickness of Al2O3 for optimum performance of the dye-sensitized solar cells. The solar simulation and sheet resistance analysis clearly showed 200 cycles of Al2O3 to exhibit an efficiency of 4.31%, which was the most efficient performance. The surface morphology and topography of all samples were discussed and analyzed.

(Invited) Low Temperature Atomic Layer Deposition Processes for Large-Area Synthesis of 2D Transition Metal Dichalcogenides

2D materials have been the focus of intense research in the last decade due to their unique physical properties. This presentation will highlight our recent progress on the large-area synthesis of two-dimensional transition metal chalcogenides for nanoelectronics using advanced atomic layer deposition cycle schemes. First, how we can use advanced cycle schemes to deposit wafer-scale polycrystalline MoS2 thin films at very low temperatures down to 100 °C. We have identified the critical role of hydrogen during the plasma step in controlling the composition and properties of molybdenum sulfide films. By increasing the H2/H2S ratio or adding an extra hydrogen plasma step to our ALD process, we are able to deposit pure polycrystalline MoS2 films at temperatures as low as 100 °C. To the best of our knowledge, this represents the lowest temperature for crystalline MoS2 films prepared by any chemical gas-phase method.[1]The most dominant methods for preparing MoS2 via ALD is to alternately expose a substrate to a metalorganic precursor and a hydrogen sulfide (H2S) or a plasma containing H2S. H2S is a corrosive, toxic, and flammable gas that is heavier than air, which makes it hazardous and expensive to store, install, and transport. Alternative sulfur precursors in the solid or liquid phase would be beneficial in terms of cost and safety and would require the installation of no additional hardware for most ALD reactors. In the second half of this contribution, the widely researched ALD process using bis(tert-butylimido)bis(dimethylamino)molybdenum(IV) ((tBuN)2(NMe2)2Mo) and H2S plasma is compared to a novel ALD process using (tBuN)2(NMe2)2Mo, hydrogen plasma, and di-tert-butyl disulfide (TBDS), which is an inexpensive, liquid-phase sulfur precursor.[1] M. Mattinen et al., Chem. Mater. (2022), 34, 5104

Microbialitic third-order Rupelian cycles of the Kuwait Formation, and their global correlative surfaces

The microbialites identified in the Kuwait Formation (also known as the Kuwait Group) at the Jal Az-Zor escarpment were largely misclassified as calcrete beds. Through detailed geological field observations, five distinct microbial beds have been identified and are found to occur at the end of each depositional cycle. Over these cycles, three main facies have been identified; these are bioturbated cross-bedding, calcareous sandstones, and microbial facies. The combination of field and petrographic analyses indicates that these sequences are dominated by siliciclastic facies, with microbial facies primarily manifesting as thrombolites or laminites, with the former being more common. Mineralogical analysis of the microbial facies indicate that over 60% of this facies is composed of calcite, and energy dispersive spectroscopy measured a significant percentage of organic carbon that reached up to 39.3% wt. Scanning electron microscope imagery of the microbial facies identified filamentous bacteria and flagellates as the principal constituents of these microbial assemblages. The bioturbated cross-bedding facies is found to be deposited in an estuarine central bay, the calcareous sandstone facies is deposited in an estuary mouth bar system that transitions laterally into a shoreface setting, and the microbial facies is deposited in a peritidal setting. Strontium isotope (87Sr/86Sr) dating of the five microbial beds indicates that these beds were deposited at 33.99 Ma, 32.6 Ma, 31.5 Ma, 30 Ma, and 29 Ma, respectively, suggesting that the associated sequences are of a Rupelian 3rd order hierarchy. Our analysis correlates the Jal Az-Zor sequences with New Jersey's Oligocene oxygen isotope sequence boundaries and the La2004 obliquity nodes, suggesting a continued uplift rate during the Rupelian age at the studied area. This article challenges the assumption that the Oligocene success is absent in Kuwait and the surrounding region, opening the door for further assessment of these deposits.

Effect of deposition cycle and annealing on the structural, optical, electrical, and photoluminescence properties of SnS films obtained from rapid S-SILAR technique

AbstractIn this paper, we present an optimized procedure for depositing SnS thin films using the rapid S-SILAR technique. We also analyze the effects of deposition cycles and post-deposition annealing on various film properties. XRD analysis indicates the presence of orthorhombic and cubic phases in the films. Energy dispersive X-ray analysis confirms near-optimal stoichiometry. SEM images depict the growth of closely spaced spherical granules. High optical absorption is observed in the mid-visible to NIR region, with the absorption edge shifting towards the NIR region after annealing. The bandgap values range from 1.6 eV to 1.9 eV, which is ideal for photovoltaic applications. PL spectra show three clusters of peaks corresponding to red and green emissions. Hall measurements confirm that both the as-deposited and annealed SnS films exhibit p-type conductivity, with a hole concentration on the order of 1015 cm−3.